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By Louis Stott

IT is well known that the oxide of beryllium was identified as a new "earth" in 17971 and the metal first isolated in 18272. The history of the many difficulties encountered by early investigators, the laboratory achievements of Lebeau3, Fichter4 and Oesterheld5, and the eventual development of methods for commercial production are well covered in the literature, particularly in the authoritative published work of Siemens and Halske6 reviewing their comprehensive investigation of the element. Accordingly it has seemed desirable to restrict this paper to the properties and uses of beryllium and its alloys.

Jan 1, 1936

By K. D. Mondale

The chemical and physical properties of samples from ten sedimentary zeolite deposits. (representing chabazite, clinoptilolite, erionite and mordenite types), have been determined as a prelude to the development of a wet beneficiation process. The mineralogical composition of each deposit and such properties as morphology, size, apparent density, surface area, pore volume, relative hardness and zeta potential in solution have been determined. Some of these properties, especially apparent density and relative hardness, were found to differ significantly from textbook values. Based on differences in properties between the zeolites and their associated gangue minerals, a wet beneficiation process has been developed which makes use of selective grinding, sizing, sorting and gravity concentration. Additionally, an alternative upgrading process using flotation has been developed for one of the deposits.

Jan 1, 1988

By Tibor Zoltai

Asbestos is a generic term for industrially useful fibers recovered from exploitable deposits of the asbestiform varieties of five silicate minerals: chrysotile, anthophyllite, actinolite-tremolite, cummingtonite-grunerite, and riebeckite. Asbestos and asbestiformm fibers of some other minerals are known to be carcinogenic. Minerals crystallized in the asbestiform habit are characterized by unique properties (morphology, strength and flexibility, physical and chemical durability, and defect-free surface structures). The key to the unusual properties, and health effects, of asbestifarm fibers appears to be in their unusual surface structure. In contrast, non-asbestiform crystals of the same minerals, including the five so-called asbestos minerals do not have these properties and are not carcinogenic (1, 2).

Jan 1, 1989

By V. A. Luganov

Methods of treatment of pyrite concentrates differ, depending on the content of pyrite and non-ferrous metals: oxidation roasting, sulphatization roasting, smelting, direct hydrometallurgical treatment and so on. Existing technologies do not provide for high recovery of metals, expenses associated with existing technologies are high, and environmental issues, associated with the existing technologies need serious attention. We have developed universal technology of the activating-dissociating autogenous roasting of pyrite concentrates using air based, or air, enriched with oxygen, blow. The basic process is taking place in accordance with the following reaction: (1-x)FeS2 + (1-2x)O2 = Fe1-xS + (1-2x)SO2 +Q The products of this reaction are pyrrhotinized cinder and roasting gases, rich in SO2 (up to 18 % in case of air blow) and poor in SO3, that contain up to 1 % of elemental sulphur. Cinder contains different forms of pyrrhotite. These forms of pyrrhotite differ by its content (from Fe0.843S to Fe0.945S), thermodynamic, magnetic (from 4.10-1 to 3.6 SI units), flotation properties (with pyrite dissociation the ?-potential of the product is moving towards more electrically positive charge, from 0.95 for pyrite to 0.2 for dissociation products) and other properties that depend on the conditions of roasting. The combination of pyrrhotizing roasting with different methods of cinder treatment allows to increase the level of sulphatization of non-ferrous metals during the roasting; reduce the amount of blow used during the processing; reduce dust losses to the gas phase; reduce the capacity of gas cleaning system and increase resistance to corrosion of the gas-treatment system, used for the production of sulfuric acid from pyrites. This combination of treatments also allows to use magnetic separation and flotation for separation of ferrous and non-ferrous metal compounds during cinder treatment; perform de-arsenation of arsenic containing concentrates and by-products. Pyrrhotinized cinder may be treated by oxidizing and non-oxidizing hydrometallurgical methods. Keywords: Pyrite, polymetallic ores, sulphidization roasting, pyrrhotite, magnetic separation, arsenic sulphide

Sep 1, 2012

By E. G. Williams

Underclays and shales are two natural resources associated with the coal measures. Underclays are widely used as the raw material for refractory, semi-refractory, and face bricks. Shales are useful for sewer pipe and lightweight aggregate. This study concentrates on the geologic controls over the properties of shales for use in the manufacture of lightweight aggregate, and the geologic controls over the properties of underclays for use in the manufacture of bloating ladle refractories. The industrial processes are similar in that both involve the trapping of a gas phase to cause bloating. They differ in that the bloating of lightweight aggregate occurs at lower temperatures (1000-1200°C) than ladle bricks (1350°-1470°C). Lightweight aggregate bloats during an initial rapid firing. Ladle bricks are manufactured by slow firing at 1100°C for up to 80 hours. Bloating occurs when these bricks are reheated to 1350°C . Bloating shales are those which expand twice or more times their original volume during fairly rapid firing. Commercial bloating is usually done by rotary kiln processing or sintering; in both cases the firing rate is much faster than the experimental rate (5/8°C/minute). Bloating results from the entrapment of gasses which are evolved during firing. The material must have adequate viscosity to trap gas bubbles throughout the temperature range of bloating. The finished product contains a high percentage of closed pores with a bulk density between 35-75 pounds per cubic foot. Expanded shale finds its most important use as a substitute for heavy concrete aggregate (crushed stone, sand and gravel) where low bulk density is desired property. The extent of bloating in lightweight aggregate is a function of the mineralogy and chemistry of the shale. Figure 1 shows a corner of the three phase diagram, kaolinite-quartz-(illite and chlorite). Several areas on the diagram are outlined which contain predominantly marine shales, fresh and brackish water shales, and underclays. Each sample was rapid fired and the resulting expansion was plotted on the phase diagram.

Jan 1, 1973

By E. W. Lithgow, E. G. Williams, R. R. Holbrook, B. R. Wilson

The mineralogy and geochemistry of Pennsylvanian shales and underclays were studied to determine their suitability for lightweight aggregate and refractory ladle brick. Eighty percent of the variation in bloating of shales and clays was explained by the variation of Si02, A1203, and fluxes (Fe203, MgO, CaO, Na20, and K20); 60% by variation in quartz, kaolinite, illite, and chlorite. The best bloating was exhibited by marine shales, whereas freshwater shales and underclays experienced little or no expansion. Regional paleogeographic maps o f Pottsville and Allegheny shales permit bloating to be geographically predicted. It was found that clays meeting the specifications for refractory ladle bricks were obtained from underclays having over 34.5% mica, over 40% kaolinite and less than 15% quartz. Underclays of this composition are confined to the lower Allegheney outcropping along the near-margins of the coal basin. The best clay is that underlying the Lower Kittanning coal. Porosity of the first fired brick was found to be inversely correlated with reheat expansion.

Jan 1, 1975

By Michael B. Cortie

Mesoporous gold sponge has the unique property of being both metallic and highly resistant to oxidation. It has potential application in catalysis, in bio-sensors, in optical coatings, in analytical chemistry and, as we show here, as the basis for a new kind of ultra-capacitor. Due to the cost of gold, the most probable niche for a gold-based ultra-capacitor would be in the high-power/high-energy regime, a region where gold would compete with devices based on RuO2. A high internal resistance limits the power that can be usefully drawn from existing carbon-based ultra-capacitors, and that this problem can potentially be overcome by gold-based devices. A simple proof-of-concept ultra-capacitor based on mesoporous gold is described and its behaviour during charge and discharge cycles examined. In this work a step change in the input or output voltage of the device was used as the controlling parameter. There was also a residual faradaic current resulting from traces of undissolved aluminium left over from the AuAl2 precursor used to make the sponge, and some charge storage due to polarization of the solution. Deconvolution of these three effects was not entirely accomplished, but an ostensible capacitance of about 7 to 14 mF/g Au was demonstrated. Further improvement from these early results seems likely.

Oct 1, 2003

By T Kang, V Sahajwalla, L Lu

During devolatilisation, physical behaviour of coals was investigated in horizontal electrically heated furnace with an inert gas atmosphere, and gasification rates of four coal chars and coke were measured thermogravimetrically in a carbon dioxide atmosphere at temperatures in the range 1100oC - 1500oC. The volume change of chars was also measured in horizontal electrically heated furnace at various temperatures. Both reactivity and the activation energy for the gasification of coal chars were found to be strongly influenced by pore structure and the carbonisation conditions employed during preparation. CO2 reactivity of chars increases with increasing reaction temperature, and particularly increases more rapidly over 1300¦C. CO2 reactivity of coke is lower than that of non-coking coal chars in the range of 1100¦C to 1500¦C. CO2 reactivity of chars with smaller pore area and bigger pore diameter is less than that of chars with bigger pore area and smaller pore diameter. During gasification, the volume of chars did not change significantly at the lower temperatures of 1100¦C and 1200¦C, but at the high temperatures, 1300¦C to 1500¦C, the volume of chars quickly decreased due to ash softening and melting. The CO2 reactivities of the chars are controlled by the mixed control of chemical reaction and pore diffusion in the temperature range 1100¦C to 1300¦C, and by bulk diffusion in the temperature range 1400¦C to 1500¦C.

Jan 1, 2000

By Christoph Schulte-Schrepping, Bou-Young Youn, Rolf Breitenbücher

"The main requirements of two-component grouts are a high workability and sufficient stability against sedimentation with a retention time of more than 72 hours, as well as a rapid strength development im-mediately after grouting. Component A usually consists of OPC, water, bentonite, and retarding agent. Component B, a liquid accelerator, is added to Component A during grouting at the end of the shield tail. Current investigations on different compositions of Component A showed a high workability lasting for at least 72 hours. The workability could be extended with increasing amount of the retarding agent to a certain degree. An increase of the bentonite content improved the stability of the mix, but had a negative impact on the flowability respectively the workability of Component A. High compressive strengths could be rather achieved by an adapted mixing ratio of Component A and B than by increasing the amount of the accelerator. Thereby, the interactions and compatibility of the selected constituents play an essential role. INTRODUCTION In mechanized tunneling with segment linings, the annular gap between segment ring and soil must be filled instantaneously with an adequate grouting mortar. The main functions of the annular gap grouting are to stabilize the tunnel lining and to minimize settlements of the ground surface at the same time. Thereby, two contradictory requirements are demanded on annular gap grouts: On the one hand a high workability and sufficient stability against sedimentation, on the other hand a rapid strength develop-ment immediately after grouting. Besides single-component grouts, which achieve the necessary stiffen-ing by dewatering into the surrounding soil, two-component grouts are used, especially in cohesive soils with a very low permeability. Basically, annular gap grouts are almost exclusively defined on empirical basis. Fundamental studies about the constituents and composition of the grout as well as the related achievable properties are still missing so far. Therefore, it is necessary to investigate the material-specific correlations regarding the relevant parameters of annular gap grouts – workability and flowability, stability of the mix as well as strength development – in comprehensive experiments. Based on the knowledge gained from the investigations, it should also be possible, to perform the grouting material according to a real design concept and thus, to ensure an adequate grouting in prac-tice considering the geological and hydro-geological conditions."

Jan 1, 2016

By Brison Robertson, W. P. Fishel

The carbide-forming tendencies of the various steel-alloying elements, or their affinities for carbon, is a subject that has received considerable attention, but little more than a probable arrangement of the elements as to their carbide-forming tendencies has been proposed. The physical properties of alloy steels depend upon the relative proportions of the elements present and their combinations. one important phase of this subject is the distribution of carbon between the various elements present. The distribution of car. bon between iron and other elements evidently sill depend upon: (I) the affinity of each for carbon; (2) the relative atomic masses of the elements present; and (3) the possible formation of compounds between the alloying and iron and between the elements themselves, In ternary steels the case is simplified, especially in systems in which the element and iron form no compounds, In such systems iron and the alloying element are competing for the carbon present. In this work the distribution of carbon between titanium and iron has been studied by measuring the relative amounts of iron carbide and titanium carbide present ill a series of annealed steels in which the ratio of titanium to carbon extended from 0.527 to 4.61. Ten Fe-Ti-C alloys, weighing about 250 grams each, were prepared by melting under a Vacuum, in an Induction furnace, Armco iron, carbon-free ferrotitanium (25 per cent Ti), and pure carbon. Vacuum melting prevented the formation of titanium oxides and nitrides, which would the the problem. The melts were made in graphite crucibles lined with sintered magnesium oxide. The ingots were the in the furnace under a vacuum and "'ere then completely annealed at 950°C. The determination of the amount of titanium carbide present was based upon the established insolubility of titanium carbide in boiling dilute (1:4) sulphuric acid, and the complete solubility Of free titanium and titanium-iron compounds in this acid. High-carbon ferrotitanium, which had been treated to remove free Ti and Fe. was found to be completely insoluble in the acid; and the carbon-free ferrotitanium used in making the alloys was found to be completely soluble. Others have reported the insolubility of titanium carbide in sulphuric and hydrochloric acids. Turnings from the ingots were digested with boiling sulphuric acid (1:4) until all action had ceased. The carbide residue was filtered off and analyzed for titanium, and in some cases for carbon. This represerifs the titanium that was united with carbon The filtrate from the carbide residue contains the portion Of the titanium that was in solid solution in the ferrite. Titanium

Jan 1, 1945

By Clarence E. Jackson, George G. Luther

The ever increasing array of information concerning the measurement of the effect of the welding process on the properties of a steel is an indication of the tremendous effort that is being expended in this field. The methods that have been considered may be divided into two groups: first, those that measure directly the effect of welding on the ductility of a steel, and, second, those that observe the change in some property, such as the hardness of the heat-affected zone, and assume a direct correlation between this change and the resultant ductility. The nick-bend test is a direct method designed for studying the effect of welding on the ductility of a steel. The test specimen (Fig. I) consists of a bar cut from a plate with a bead weld on the surface. The specimen is prepaxed with a saw-notch placed so as to restrict deformation to the heat-affected zone under the bead weld when tested as a static bend. Failure is caused by rupture of the low-ductility metal in the heat-affected zone. The angle at maximum load is used as an index of the effect of the welding process on the material. In the development of the nick-bend test considerable scatter was noted in some of the results, although the agreement of duplicate specimens welded at the same time and tested consecutively was excellent. Upon further investigation it was found that the change in ductility was dependent upon the interval of time between the welding operation and the testing of the specimen. For the six steels of Fig. 2, the angle at maximum load in lour cases was doubled and in one case was tripled. All steels that have been studied show an improvement in the angle of bend for longer intervals between welding and testing. This same behavior has been found in weldability tests using the Navy T-bend

Jan 1, 1945

By F. J. Meringer, C. W. MacGregor

Various investigations have been carried out to determine the effects of cold-rolling on the common physical properties as represented by the yield strength, tensile strength, percentage of elongation and ordinary reduction of area. Very little information is available in the literature with reference to the effects of cold-rolling on the true stress-strain properties. Since the ordinary physical properties base both the stresses and the strains on the original dimensions of the test piece, which are greatly changed during the test, they are essentially empirical values and do not represent physically either true stresses or true strains. Consequently, they do not give an accurate picture of the effects of different conditions, both mechanical and metallurgical, on the strength and ductility of the material. It is not, however, the purpose of this paper to review the various advantages accruing from the use of true stress and true strain values, since these have been shown elsewhere,1-l2 but to utilize them in representing the various effects considered. The true stress S and true strain (e = q') values mentioned above for the tension test are defined by1 S =1/A and where P, A, Ao are the axial load, the instantaneous area and the original area of cross section, respectively. From simultaneous readings of the axial load and the dimension or dimensions determining the instantaneous area of cross section, the true stress-strain curve is constructed by using the relations given in Eq. I. It is then the object of this paper to discuss the general effects of cold-rolling on the true stress and strain values for a low-carbon steel together with the effects of age-hardening and directionality on these properties. Preliminary Investigations The material considered throughout the paper is a low-carbon steel of the following chemical analysis: C, 0.19 per cent; S, 0.118; P, 0.092; Mn, 0.85; Si, 0.01. The stock was received in bars, 7 by 3/4 in., and was first annealed for one hour at 1650°F. followed by a furnace cool. Photomicrographs of this material showed considerable directionality even in the annealed condition. In view of the possible effects of the nonhomogeneity and directionality in this material, it was considered important to investigate their influence on the true stress-strain diagrams. In addition, the effect of strain-aging in this steel was also made the subject of a preliminary study. Effect of Aging on True Stress-strain Properties Since a certain time element would elapse between the cold-rolling operation and the final tension tests, it was determined to investigate the aging character-

Jan 1, 1945

By C. E. Sims, H. M. Banta, S. L. Hoyt

Over the past few years, metallic arc welding has been extended to steels of the hardenable type. As compared with other methods of fabrication, production has been facilitated, service performance frequently has been improved, and the overall results have been so favorable that engineers and production men have placed great emphasis on this application of welding. The metallurgist and welding engineer, however, have been confronted with new problems, since, for one reason, the harder steels are more apt to crack and special precautions must be taken if sound joints are to be procured. Some of the factors that are pertinent to this problem are metallurgical, and it is an object of this contribution to discuss steel manufacture and processing methods and to show how their control assists in reducing the hazard of cracking. By this time, the problem of cracking— specifically underbead cracking, or "hard cracks," or parent-metal cracks-—is well known, and a large amount of work has been published, both here and abroad, dealing with this subject.' The tests described are made under restraint to facilitate cracking and arc so designed that a semiquantitative, or at least a relative, value of the cracking tendency is obtained. As one would expect, it has been reported that the incidence of cracking increases with the carbon and alloy content of the steel. More specifically, the cracking tendency is said to increase with the hardenability of the steel, though it is now recognized that the situation is not so simple. The phenomenon itself, on the other hand, has been but loosely described, and it is in only broad generalizations that this cracking has been related to steel metallurgy. Thus, while it has been abundantly demonstrated that the hardenable aircraft steel, S.A.E. 4130, must tend to crack when are-welded, the problem still remains of why two lots of the same composition and the same hardenability can vary so greatly in cracking tendency, or what it is about the prior metallurgical history that so strongly affects the results. Further, while the efficacy of preheating and postheating in preventing cracking is recognized and utilized in production, the mechanism by which they function seems not to have been described. These points are thought to be significant in the production of steel for fabrication by metallic arc welding and, hence, of interest to mill and process metallurgists and welding engineers. Consequently, it is another object of this paper to discuss the mechanism of parent-metal cracking, including the influence of the condition of the steel and the control of cracking by manipulation of the time-temperature conditions during and after welding. A new method of rating the cracking tendency is also discussed, and the results of the test are related to steel composition and structure or prior history. The work to be described was the outgrowth of work in 1940-41 at Battelle Memorial Institutc on two projects, one

Jan 1, 1945

By John H. Holloman

In recent papers, O'Neill,' Vivian, and Zener and Hollomon3 have reviewed some of the information concerning the relations between stress and strain during plastic deformation. Since further information has been obtained since these reviews were published, this paper attempts to further coordinate and amplify the knowledge concerning the plastic deformation of metals in simple tension. Ordinarily the results of tensile tests of metals are presented as graphs in which the load divided by the original area is plotted as a function of the percentage of elongation measured over some specified gauge length. The interpretation of graphs of this sort is limited, since the stress required to deform the metal at any stage of the deformation is actually the load divided by the instantaneous rather than the original area. Furthermore, each increment of the deformation is performed on metal that has been previously deformed, and, as pointed out by Ludwik,4 the strain could be more effectively defined: where e is the strain and AO and A are, respectively, the original and instantaneous areas. The results of the tensile tests can be more effectively presented and interpreted if the stress* (load divided by actual area) is .lotted as a function of the strain as defined above. A schematic curve of this type is presented as Fig. I. In a previous paper,6 the concept of Ludwik7 concerning the flow and fracture of metals was successfully employed to explain some of the puzzling results of notched-bar impact tests of steel. It appears that the use of this concept ii; very fruitful and should be kept in mind in any study of the deformation charactcristics of metals. Ludwik considered that a flow stress-strain curve of a metal was essentially a locus of points that described the stress required for plastic flow of an infinite numbcr of specimens, each with a different strain history determined by the preceding part of the flow curve Each of these specimens can also be considered to have a fracture strength. Uniortunately (or fortunately depending upon the point of view), all the specimens, except the one deformed to the fracture strain, flow and do not fracture. Even though the metals do not fracture, the concept of a fracture-strength curve seems

Jan 1, 1945

By J. Gordon Parr, D. A. Whitaker, G. A. Yorko

High purity alloys of zinc with 25 per cent to 50 per cent aluminum, have been prepared. Mechanical properties of the as-cast and heat-treated alloys have been related to constitution, determined by x-ray diffraction and microscopic methods. Investigations include the effects of aging and of small nickel additions on the properties of the alloys.

Jan 1, 1960

By D A. Shushkov

Analcime-bearing rocks are one of the varieties of raw zeolite material, although the characteristics of analcime are not as good as other kinds of zeolites such as clinoptilolite or mordenite. However, some fields of application of analcime-bearing rock have been found, eg a method of water purification has been developed and patented. Analcime-bearing rocks are rather widespread in the Timan region of the Komi Republic of the Russian Federation. They are represented by Upper Permian siltstones and mudstones. The analcime-bearing rocks have the following mineral composition (per cent): clay minerals (50 - 70 per cent), quartz (ten to 30 per cent), analcime (one to 30 per cent), feldspars (two to ten per cent), carbonates (two to five per cent) and pyroclastic material. Analcime aggregates encrust cavities and infill microfissures in rock. Both microcrystalline (crystals <0.01 mm in size) and medium-crystalline (~0.5 mm) aggregates are observed. The mechanical, gravitational, magnetic, sorption and ion-exchange properties of analcime-bearing rocks have been studied. They are characterised by a high index of grindability and a low index of abradability and crush resistance, low values of the benzol-based pore volume and toluene-based specific surface area, and a medium porosity value. The magnesium based ion-exchange capacity (IEC) ranges from 28.7 to 196 mg+equiv/100 g. Analcime-bearing rocks of the Timan region are characterised by low beneficiation potential. Preliminary ultrasonic treatment of the analcime- bearing rocks is efficient for the destruction of intergrowths along their boundaries and production of free analcime aggregates. The proposed beneficiation procedure yields 95 per cent analcime concentrate. In the Komi Republic, analcime-bearing rocks are utilised in agriculture. They are also used for domestic needs (eg as biotoilets for domestic animals) and the solution of ecological problems (regeneration of soil polluted by oil). We have completed experiments on the purification of potable and industrial water using analcime-bearing rock subjected to thermal treatment. The experiments demonstrated that it was possible to decrease water colouration by 20 per cent, turbidity by 79 per cent, permanganate oxidation by 30 per cent and total iron content by 70 per cent.

Jan 1, 2008

By G. C. Gullo, H. Wabusseg, P. J. Uggowitzer, H. Kaufmann

"The basic concept of New Rheocasting (NRC) is described and the application of wrought alloys with this process is discussed. Practical experiments with the aluminium alloy AIMgSi I are explained. For this alloy the proper NRC - casting temperature was determined by using Thermo Cale - computer software and DT A and the essential processing conditions are shown. In the experiments the melt was taken from an aluminium holding furnace and cast into NRC steel cups. After controlled cooling the resulting slurries were cast into a 4-step die on an UBE HVSC 350 Squeeze Casting machine. The characteristic microstructural values such as grain size and shape factor were measured and compared with classical casting alloys. The influence of the wall thickness of the step part (6 mm, 10 mm and 14 mm) on the microstructure is described. Tensile properties in different heat treatment states are compared with characteristic prope1ties of the same alloys in forged condition. The ew Rheocasting - process CNRC)The NRC process is a recently developed new semi-solid processing method which allows the production of pore-free, pressure tight components.In the NRC process a fu lly liquid, but only slightly superheated melt is taken from a holding furnace and poured into specially designed steel crucibles, which are placed on a carousel next to the Vertical Squeeze Casting machine. In this ,NULL,slurry maker'· globul ar a-Al grains grow, following forced homogeneous nucleation at the cup wall [ 1, 2]. In the few minutes during which the melt is cooled to sem i-so lid processing temperature, a stable ske leton of a-Al phase forms. The resulting slug keeps a cylindrical shape during its slide into the sleeve of the Vertical Squeeze Casting machine, where it is cast into shape."

Jan 1, 2000

By Telfer Norman

THE use of cadmium as a base for bearing metals is one of the most interesting recent developments in this field. It has caused a strong demand for cadmium and a marked rise in its price. It appeared to the authors, therefore, that the situation might be relieved for users if accept-able substitutes could be developed. A preliminary investigation has revealed that to some extent mercury may be substituted for cadmium. Whether its use is justified cannot be stated at this time. Most of the authors' work has indicated that the addition of mercury to alloys of cadmium and nickel detracts from their desirable physical properties; but this work has not been extended to cover service tests, which might reveal that the addition of low percent-ages of mercury to the cadmium-base alloys would improve their per-formance. The results of tests made by the authors are therefore briefly summarized for this paper. Table 1 gives the proportions of the metals

Jan 1, 1937

By M. S. Badollet, N. W. Edgerton

"A study of the physical properties of long grades of asbestos fibers imported into the United States during the past eight years has disclosed information that will contribute materially to effective selection and use of fibers for electrical products. The study embraced fiber lengths, volume resistivity under three different conditions, total iron by chemical analysis, magnetic rating, conductivity of an aqueous ex-tract and its sodium chloride equivalent.The fibers examined included chrysotiles from Rhodesia, British Columbia, and Barberton area; marlime from Bechuanaland and Province of Quebec; amosite and crocidolites from Africa and Australia; and anthophyllites from Mozambique and from Georgia in the United States. Volume resistivity values provide a relative basis for estimating the electrical performance of end products; magnetic rating -an estimate of the quantity of iron compounds present in excess of those in the asbestos structure; conductivity of an aqueous extract; and an estimate of the ionizable impurities in fibers.Tests of these factors yield in-formation, not heretofore generally known, which may serve as a guide in the evaluation of asbestos fibers for electrical products."

Jan 1, 1960

In comparisons of a trial extruded brick containing 33 per cent coalwash and 67 per cent clay and a trial pressed brick containing 100 per cent coalwash with a standard extruded clay face brick, the mixed feed stock trial brick compared favourably with the standard brick. If a highly plastic clay is used to mix with the coalwash, satisfactory results are obtained in respect to dimension, strength, water absorption, efflorescence, resistance to salt attack, hardness, colour, weathering, mineralogy and porosity. Although a brick containing only coalwash can be successfully manufactured in a press, its mechanical and physical properties are inferior. This mixed feed stock brickmaking technology leads to the utilisation of a by-product with a potential saving of raw material costs. The extent of use is likely to depend on the proximity of the coal washery and the brickworks and the economicsof transportation costs.

Jan 1, 1992