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By Larry J. Hulbert, Louis J. Cabri, John L. Campbell, Gilles Laflamme, Chris G. Ryan, Soey H. Sie, Rolando Lastra

"Abstract- The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fme-grained minerais which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700Jo of the major Ni carriers and 78% of the major Cu qmier will be liberated at a grind of 80% -'}f,.7 J.Uil (-500 mesh) for typical low-grade gabbro (West zone, sample No. 1). For typical ""clinopyroxenite"" (West zone, sample No. 2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3) the liberation would be 71""lo and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total24.5% for typicallow-grade gabbro (West zone, sample No. 1), 15% for typical ""clinopyroxenite"" (West zone, sample No. 2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fme grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as sorne would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No. 2 and No. 3 is closely associated with magnetite.Palladium occurs in diverse ways. It occurs in the form of several Pd minerais (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tel­ lurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chal­ copyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerais and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate. However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No. 2 and No. 3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No. 3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No. 3, in order to improve Pt and Pd recoveries.Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefmed Re-Ir-Os-Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By Lastram Rolando, Larry J. Hulbert, Louis J. Cabri, J. H. Gille Laflamme, John L. Campbell, Soey H. Sib, Chris G. Ryan

"The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fine-grained minerals which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700/0 of the major Ni carriers and 78% of the major Cu qurier will be liberated at a grind of 80% -U,.7 ,an (-500 mesh) for typical low-grade gabbro (West zone, sample No.1). For typical ""clinopyroxenite"" (West zone, sample No.2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3) the liberation would be 71% and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total 24.5% for typical low-grade gabbro (West zone, sample No. I), 15% for typical ""clinopyroxenite"" (West zone, sample No.2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fine grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as some would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No.2 and No.3 is closely associated with magnetite. Palladium occurs in diverse ways. It occurs in the form of several Pd minerals (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tellurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chalcopyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerals and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate.However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No.2 and No.3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No.3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No.3, in order to improve Pt and Pd recoveries. Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefined Re-Ir-Qs..Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By X. P. Zheng, H. K. Lin

During slow-cooling crystallization of iron-making blast furnace slags, most rare earth elements recrystallize in an artificial "mineral" identified as calcium cerite. Scandium (Sc) and europium (Eu), however, concentrate in a sheetlike "mineral." In this investigation, the mineralogy of this sheetlike "mineral" was studied. It was identified as being in the mica group and was called a rare earth-bearing barium fluorophlogopite. One of the objectives of this study was the recovery of this "mineral." The study indicated that it can be effectively recovered from the slag by flotation using dodecylammonium acetate or a combination of dodecyl-ammonium acetate and sodium oleate as collectors.

Jan 1, 1998

By H. K. Lin

During slow-cooling crystallization of iron-making blast furnace slags, most rare-earth elements in the feed recrystallize as cerite-calcium while scandium and europium concentrate in a sheet-like "mineral". The mineralogy of this "mineral" is studied with one of the objectives being the extraction of the "mineral" from the slag for recovery of Sc and Eu. This "mineral" has been identified as one of the mica group minerals and can be named as rare-earth-bearing barium fluorophlogopite. The mineralogical characteristics of this "mineral" are investigated and discussed. This "mineral" can be effectively recovered from the slag by flotation with dodecylammonium acetate or a combination of dodecylammonium acetate and sodium oleate as a collector.

Jan 1, 1996

By D. M. Hausen

"Refractoriness in Carlin-type gold ores results mostly from fine locking of gold in pyrite, locking in various gangue phases, notably quartz, and a ""preg robbing"" condition attributed to organic carbon. All three conditions may occur in any given deposit, including Newmont &apos;s Carlin and Gold Quarry deposits in Nevada, where types of ref ractoriness occur locally in minor amounts.Measurements of specific gravity, water absorption and screen size distributions of gold in alteration rock types from Gold Quarry show transitional changes from siliceous cherts through decreasingly silicified and increasingly argillized siltstones.Low permeability of siliceous ores contributes to ""size dependent"" refractoriness in cyanidation test work. Colligative physical and chemical measurements demonstrate that silicified cherty ores are difficult to grind, poorly permeable, and less amenable to cyanidation. Refractoriness in pad or column leaching of coarsely crushed siliceous siltstones and cherts is shown to correlate with interrelated measurable mineralogic and physical parameters.IntroductionMetallurgical treatment of variably amenable and refractory types of gold ore may be guided by both analytical and mineralogic data on the interlocking of gold (microscopic an d sub- microscopic) in assorted gangue/sulphide phases. Most oxidized ores from the Carlin gold mine, north of Carlin, Nevada, are amenable to direct cyanidation. The permeability of most oxidized ores from Carlin coupled with the fine size of the gold < 1.5 um) yields rapid extractions and high recovery without fine grinding.Small portions of the Carlin ore body, and also the nearby Maggie Creek and Gold Quarry orebodies, are less amenable to cyanidation, and are classified as refractory. Refractory conditions may be attributed mostly to the association or interlocking of gold with pyrite and /or microcrystalline quartz or chert, and also by the adsorption of leached gold by deleterious forms of carbon, termed ""preg-robbing"" carbon. Each of these conditions are described and defined, with emphasis on a form of silica-locking, which has been referred to as "" size dependent"" refractoriness."

Jan 1, 1985

By Joe Zhou

"Mineralogical characterization and metallurgical extraction of silver is challenging due to its complex mineralogy and chemistry. Over 200 Ag-bearing minerals have been identified and a silver-rich ore body would typically contain 5 to 10 different silver minerals. Silver can occur not only as discrete microscopic (visible) silver minerals but also as submicroscopic (invisible) silver in other minerals. During processing, silver may form passivation compounds such as silver hydroxide, silver sulphide, jarosite-like silver sulphate, silver halide or silver cyanide precipitate, all of which may negatively impact on silver extraction. Knowing the deportment of silver in the ore and its metallurgical products is important in flowsheet design and plant optimization. This paper begins with the classification of silver ores and minerals and a review of processing techniques, and focuses on the major mineralogical factors to explain why and how these factors affect silver extraction. Case studies are provided to demonstrate the application of silver process mineralogy in flowsheet design and plant optimization.INTRODUCTIONSilver was known to and utilized by mankind since ancient time. Actually, it was one of the earliest metals discovered and utilized by mankind after gold and copper.Silver is the whitest metallic element. It is rare, strong, corrosion resistant, and unaffected by moisture, vegetable acids, or alkalis. Silver is also resonant, moldable, malleable, and possesses the highest thermal and electric conductivity of any substance. The chemical symbol for silver is Ag, from the Latin argentum, which means white and shining. Although silver does not react with many chemicals, it does react with sulfur, which is always present in air at trace amounts. The reaction causes silver to tarnish, and consequently it must be polished periodically to retain its luster.Silver possesses many special physical characteristics and qualities that make it useful to a variety of industries. The photography industry is the biggest user of silver compounds. Silver forms the most light-sensitive halide salts, which are essential to developing highquality photographic prints. Silver also has the highest electrical conductivity per unit volume of any metal, including copper, so it is used extensively in electronics."

Jan 1, 2010

By Manqiu Xu, Andrew Lee, Frederick D. Ford, Cara Wercholaz

"Platinum-group minerals (PGM) typically occur in such low concentrations that quantitative mineralogical evaluation is difficult or impossible. The FEI MLA system used by Vale Base Metals Technology Development has been successfully employed to produce large PGM data sets that are statistically robust. The MLA Sparse Phase Liberation mapping routine produces false colored images that accurately document mineral textures, including intergrowths between various platinum group minerals and between PGMs and other tellurides and sulfides. MLA PGM search results can be used in conjunction with mineral chemistry to calculate platinumgroup element distribution to minerals and the MLA PGM images can be used to produce model grade-recovery curves.INTRODUCTIONThe platinum-group minerals (PGM) found in Sudbury area deposits have been extensively catalogued and reviewed by many authors including, but not limited to: Farrow and Lightfoot (2002), Cabri and Laflamme (1984; 1976) and Cabri (1981). The PGM list currently used has 12 minerals summarized in Table 1. As noted by Farrow and Lightfoot (2002), platinum-group minerals in Sudbury are dominated by tellurides, bismuth-tellurides and arsenides, with an absence of platinum-group element (PGE) sulphides or ferro-platinum alloys such as tetraferroplatinum - PtFe."

Jan 1, 2011

By E A. Agorhom, M Beyuo, C Owusu, I Quaicoe

Understanding the mineralogy and liberation of gold particles in an ore is key to the development and optimisation of gold processing operations, being cyanidation or gravity separation. This can be achieved through basic historic geological information, gold deportment studies, chemical speciation and metallurgical test works. The present study assessed the nature of the occurrence of gold particles (mineralogical composition, liberation, associations and surface chemistry) and its effect on the process route (cyanidation and gravity separation) of a typical paleo placer gold ore deposit within the Tarkwaian Rock system. The investigative approach used involved chemical assay, quantitative X-ray diffraction (QXRD) and quantitative evaluation of minerals using scanning electron microscopy (QEMSCAN). The ore samples (A, B, C, D, E, F) used were obtained from six active pits of a gold mine working on this orebody. The results of the mineralogical analysis revealed that the ore is highly oxidised and comprised quartz (>80 per cent) and Muscovite mica (>6 per cent) as the major mineral phases in all the samples. Trace amounts of hematite, kaolinite and todorokite were also identified in all the samples. The chemical analysis showed presence of gold (Au) in all the samples with samples B (3.62 g/t) and C (3.96 g/t) containing the highest concentrations. Trace amounts of copper (Cu), iron (Fe), sulfur (S), aluminium (Al), arsenic (As) were also detected in all the ores. The QEMSCAN mineralogical liberation and gold association results revealed that the gold grains were relatively coarser in all samples (P80 > 80 µm Au in size) except F (P80 < 32 µm Au in size). Gold grains were highly liberated especially in sample B with the majority of the locked gold grains forming complex associations. All the samples responded well to cyanidation and gravity separation except samples C and F, respectively.

Aug 24, 2022

By D. M. Hausen

This study identifies and describes various crystalline phases of the V205-Na20 system, and relates their properties to metallurgical aspects of vanadium production. Phase equilibria and stability ranges of sodium vanadate phases of varying molar ratios of Na20/V205 were investigated in a variety of plant products, ranging from fused "black cakes" (V20 melts) to "salt roast" calcines. Crystalline compounds, Including vanadium pentoxide, V205; sodium vanadyl vanadate, 6 phase, Na2O.V2O5.5V2O5; sodium vanadyl vanadate, y phase, 5Na20.V204.12V205; sodium metavanadate, Na20 .V 05; sodium pyrovanadate , 2Na20 .V205; and sodium orthovanadate, 4Na20.~2~5, have been characterized with the aid of X-ray diffraction patterns, infrared spectra, and optical properties in addition to chemical analyses, as a guide to mineralogical "troubleshooting" of plant problems and processes in vanadium pyro- and hydrometallurgy.

Jan 1, 1984

By S. Mathieu, R. Mennillod-Blondin, P. Cousin, N. Valle, H. Bouzahzah, P. Marion

The gold deposit of the Lapa mine has a complex mineralogical gold state with coarse and fine native gold, aurostibite and submicroscopic gold within arsenopyrite. A specific mineralogical characterization of the refractory fraction was conducted combining various techniques such as optical microscopy, electron microscopy, electron microprobe and secondary ion mass spectrometry. In parallel, the mineral processing behaviour and the recovery of the refractory gold were studied by pressure oxidation and cyanide leaching. This paper presents the mineralogical methodology developed to characterize the refractory gold distribution within arsenopyrite. These results are presented and interpreted in order to plot gold recovery versus sulphide oxidation. The comparison of the metallurgical behaviour yields predicted from the mineralogical data and the one calculated from leaching tests shows a good agreement and allows mineralogical explanations of the gold metallurgical behaviour.

Jan 1, 2011

The last twenty years of development in Process Mineralogy are reviewed. Since the milestone review by Henley in 1983, which projected the concept and suggested closer working relations between mineral processing and mineral science, the second generation (1983-2003) has made significant progress. Examples are to be found in improved sampling and high-confidence flotation testing, and in automated quantitative mineral measurement. The recent addition of end-member studies has provided a clearer view of the overall ore mixture milled from its constituent geological components. In all, better predictive abilities have resulted from these improvements to Process Mineralogy. These improvements have led to more significant business impacts in mineral resource characterization, and in optimization of existing concentrator operations.

Jan 1, 2004

By R. Kramer

The Process Mineralogy review arrived too late to appear in the May issue. The Process Mineralogy Committee scheduled programs with both SME and The Metallurgical Society. At the 1991 SME Annual Meeting in Denver, CO the committee sponsored five sessions containing 31 papers. Four process mineralogy sessions were sponsored at the 1992 annual TMS meeting in San Diego, CA. Process mineralogy is used to understand and evaluate mineral behaviors during mineral beneficiation, phase reactions during metallurgy, recoveries and reactions of precious metals during processing and mineral and phase behaviors with respect to environmental problems. The most recent refinement in mineralogical studies with respect to mineral beneficiation has been the wider use of image analysis and combined materials balancing techniques of image analysis data. Image analyzers that can perform analysis with respect to mineral beneficiation are expensive. They are used only for solving major processing problems. Nevertheless, the methodology of analysis continues to be refined. Much better data are collected, and methods of evaluating the data continue to improve. One interesting development involves modifying the ultrasound unit used in medical studies to perform a three-dimensional analysis of ore particles.

Jan 1, 1992

By D. Chetty

Process mineralogy forms an integral part of geometallurgy, with ore body characterisation being but one piece of the puzzle in optimising value derived from ore. This value is not only financial, but importantly speaks to sustainability from environmental and social standpoints. The reactive approach of traditional process mineralogy is increasingly being replaced by predictive methods in the geometallurgical sphere, for which mineralogical information must be timeously acquired on judiciously selected sample sets to understand ore variability and its impact on orebody processing. Such processes are not only metallurgical, but must incorporate mining and waste management protocols. Dwindling resources like water and energy also demand innovative approaches for lowering consumption and/or promoting recycling along the value chain. Addressing such challenges relies on appropriate characterisation of ore behaviour under different process regimes. Coupled with this, emerging characterisation tools are increasingly applied to understand the mineralogy of unconventionallypresented and difficult-to-process ores to meet societal and technology demands. Such tools are often accompanied by the generation of large, computationally intensive datasets, for which data management and storage are key requirements, particularly when deciphering temporal trends in ore and process variability. This paper will elaborate on these themes with examples that highlight the importance of process mineralogy throughout the minerals value chain. Keywords: Process mineralogy, ore characterisation, geometallurgy

Jan 1, 2020

By Richard D. Hagni

Process mineralogy has not been given adequate attention in years past, because geologists have not been sufficiently interested in applying mineralogical techniques to industrial processes, and most process engineers are not adequately trained to use them. Although some individuals and institutions have made efforts to improve the situation, it is only in the last few years that the significance of applying the methods of mineralogy to a wide variety of industrial processes has been fully appreciated. Presently, the formation and organization of several groups devoted to applied mineralogy have created a more amenable climate for the development of process mineralogy. As a result, the presentation, discussion, and publication of the results and case histories of process mineralogy have become fairly common. Short courses affording hands-on experience with applied techniques are now available to the many geologists and process engineers engaged in industrial mineralogical processes. The future role of the process mineralogist is viewed as an expanded one, which will increase in value.

Jan 1, 1982

By T. K. McMahon

Formally, a mathematical model could be defined as: A set of equations whose solution will approximate the response of a physical process or system to a set of stimuli which appear as parameters in the equations. The purpose of a mathematical model is to permit the rationalization of experience to proceed by simulation rather than by physical experimentation. In the application of digital computer control to an industrial process, the mathematical model of the process (subsequently called the process model) is needed to calculate the present process performance from the measured variables and to predict the response of the process to a control change. Functionally, the cardinal element in process model development is a concise set of control objectives. These, besides implicitly defining the boundaries of the system to be modeled, will determine the accuracy demanded of the model its nature: dynamic or steady-state, and so forth, The objectives should explicitly define what process efficiencies, production rates, qualities are to lie within the scope of the computer control project, thereby providing a basis for simplifying assumptions in the development of the model. This requirement, a limited set of control objectives, is so often disregarded in formulating industrial control problems that its repetition can scarcely be avoided.

Jan 1, 1965

By Pengfu Tan

Electric arc furnace (EAF) dust from the steel industries is listed by the United Sates EPA as a hazardous waste under the regulations of the Resource Conservation and Recovery Act due to the presence of lead, cadmium and chromium. The disposal of the approximately 650,000 tons of EAF dust per year in the U.S. and Canada is an expensive and unresolved problem for the majority of steel companies. The Waelz process has been considered as the best process for treating EAF dust. A process model, combined thermodynamic modeling with heat transfer calculations, has been developed to simulate the chemical reactions, mass and heat transfer and heat balance in the kiln. The injection of air into the slag and the temperature profile along the kiln has been modeled. The effect of (CaO+MgO)/SiO2 on the solidus temperature of slag has been modeled also and discussed. Some optimizing results have been presented in this paper.

Jan 1, 2005

By M. A. S. Siraa

A program of work was undertaken at the Kennecott Smelter and Refinery to model the complex. This effort contributed a total of eight models of the plant: flash smelting furnace, flash converting furnace, slag concentrator, anode furnace, offgas scrubbing system, acid plant, hydrometallurgical dust treatment plant, and the precious metals plant. Some of these models have been used in a variety of investigations ranging from offgas capacities for a steam generation analysis to an examination of impurities. The culmination of this enterprise has resulted in an on-line control scheme for the flash smelting and flash converting furnaces. These two process control schemes incorporate their respective steady-state heat and mass balances that are executed in response to feed changes while a feedback loop calculates when product grade and temperatures deviate from setpoints. This system has been put into place to improve furnace control and on- line time.

Jan 1, 1999

By F Tang, Ö K. Büyükuslu, M Baben, S Petersen

GTT-Technologies’ ChemApp for Python was developed to provide a powerful, easy to use interface to ChemApp for a programming language highly popular with scientists and engineers. It is used, for instance, by GTT to develop program modules such as the CALPHAD Optimiser for the FactSage™ software, by customers to move from interactive FactSage calculations to perform versatile scripting with Python, and by GTT and its partners in research projects in the area of materials informatics. Computational thermochemistry is fundamental for advancing sustainable metallurgy and creating new alloy compositions for engineering applications. Materials informatics involves handling vast amounts of data and complex workflows. GTT’s approach uses ChemApp for Python and the FactSage thermodynamic databases to design recyclable alloys from the start, incorporating a higher percentage of scraps while aiming to simplify the workflows to simulate material design steps. Challenges arise due to recycling scraps, introducing more elements for consideration. CALPHAD-based databases accurately cover materials from primary metallurgy, but additional data for minority and critical elements is crucial for precise computational modelling. GTT combines machine learning-based ab-initio databases with traditional CALPHAD databases to cover the complete chemical space with appropriate accuracy. The design of a hardfacing alloy through a high-throughput materials informatics approach is used as a demonstrator of the current possibilities.

Jun 19, 2024

By Nathaniel Arbiter

The question of automation of concentrator operations with computer control is under increasing consideration. Some of the problems involved will be discussed from the viewpoint of the availability of the requisite, detailed knowledge of the unit operations. The justification for full-scale automation of a mill must ultimately be economic--an increase in profitability over and above the cost of instrumentation and development, Potential savings would be in three probable directions: decrease in operating labor costs by substitution of machine control; improved metallurgy through continuous effective control; and decreased operating costs by achieving higher unit capacities and process efficiencies.

Jan 1, 1962

By Charles L. Allie

In June, 1980, Reserve Mining Company completed a 370 million dollar construction project which included process modifications required to reduce the silica content from nine to five percent by weight and increase the iron con- tent of Reserve&apos;s pellets from 62.5 to 65.8 percent by weight (dry basis); process modifications and additions required to implement "best available technology" water quality controls; and installation of "best available technology" air emission controls. The new process began operation on June 24, 1980 and is being optimized to meet design objectives. Dry cobbing, fine screening and flotation additions to the concentrating process have reduced the silica content of Reserve&apos;s pellet from nine percent to five percent by weight. The process reclaims and reuses all process waters, stores all tailings in a zero discharge tailings basin and meets all air emission standards.

Jan 1, 1980