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By William F. Brandom

INTRODUCTION Cross, et al. (1974), produced a retrospective study of standard setting for underground miners. This report had two distinct components; i) criteria of importance for the protection of the miners, and ii) economic considerations for standard setting. The methods for setting radiation safety standards reviewed were: dose calculations and consensus methods; epidemiology; pathology; bioassay; animal experiments; sputum cytology; chromosome aberrations; and, the Mantel-Bryan Model. By looking back, the authors intended to enable officials to look ahead in making future decisions based on reasonable conclusions. Now it may be time to consider underground miners' protection from another perspective: are there miners who may be especially susceptible to toxic environments?; and if so, are there any biomedical assays that might be indicative of exceptional sensitivities to toxic substances? The human population is genetically very heterogeneous. The data of Saccomanno, et al. (1973), reveal great variability in individual response to radon daughter exposure and only a small portion of the miner population subject to toxic inhalants develop squamous cell metaplasia (Saccomanno, et al., 1970). The majority of the miner population is either not susceptible or is resistant to the toxic agents. This information suggests the existence of a small subpopulation with increased sensitivity or reduced resistance and underscores the need for indicators from biomedical assays that might prove of value for the detection of such individuals. The heightened awareness of the contribution of pollutants in the environment for the potential induction of mutations and carcinogenesis lead to a profusion of short-term bioassays to circumvent the high cost and time-consuming large toxicity animal studies. Over 100 bioassays across taxa from microbes to man are at various stages of use or development (Hollstein, et al., 1979). Less than a dozen tests currently offer early promise for application to[ in vivo] effect studies of man. Many are still in early development, lack the sensitivity needed for a retrospective or prospective study at current permissible exposures, are impractical to conduct in the field, or are not cost effective. The purpose of this paper is to review some of the bioassays that may now, or in the near term, prove applicable for the detection of individual underground miners with increased susceptibility to toxic agents. Throughout this statement, it is assumed that any single test may give false negatives or false positives and, therefore, a tier of tests should be investigated. The possible tests are in various stages of development; some tests better proven than others with a firmer data base and, therefore, with greater probability of usefulness. Some of the less proven assays are not ruled out if they have practical or theoretical promise as indicators. Table I summarizes the assays critiqued for their potential to monitor the effects of [in vivo] exposure to genotoxic substances. POTENTIAL INDICATORS OF HIGHLY SENSITIVE MINERS Assays of Body Fluids It is desirable to have data on the agent(s) to which subjects are exposed when humans are monitored by biomedical effects. Obviously, to varying intensity, the underground mining environments are monitored for radon daughters and it is recognized that the miners are also exposed to other pollutants, most notably, uranium ore dust and diesel fumes. Further testing for the metabolites of the pollutants can be done on body fluid, urine. [High Performance Liquid Chromatography (HPLC)]: This is a very sensitive method for the detection of mutagenic metabolites in urine. The urine is treated with the enzyme sulfatase and beta-glucuronidase to permit identification of substances that are made nonmutagenic by conjugation as glucuronides. The sample is then passed through an XAD-2 resin column and the absorbed organic molecules eluted with acetone. The sample is then split and evaporated to 1 ml and used for direct chemical analysis using HPLC. One drawback to the test is the inability to measure cumulative exposure, but multiple samples can be obtained and comparison to baseline (control) and exposure samples can reveal qualitative differences as a consequence of exposure to mutagens. [The Ames/Salmonella Microbiological Assay]: The Ames/Salmonella microbiological mutagen test is the most extensively used short-term bioassay, with over 2,600 chemicals having undergone testing by this method (Hollstein, et al., 1979). The method, thoroughly worked out and tested for 10 years, consists of taking the second split urine sample from the HPLC preparation, evaporating to dryness and dissolving in dimethylsulfoxide (DMSO). The sample is then applied directly to

Jan 1, 1981

By Charles A. Kliche

The Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) established a national program for responding to releases of hazardous substances into the environment. The funding mechanism for this program is the Hazardous Substance Response Trust Fund (commonly referred to as Superfund), which provides funding for the implementation of removal and remedial response actions.

Jan 1, 1997

By Clement K. Chase, George M. Potter

Copper dump and heap leaching operations are conducted worldwide for production of substantial amounts of copper Such dumps and heaps contain appreciable amounts of other potentially valuable elements such as gold, Iron, magnesium, manganese, molybdenum, silver, titanium, and uranium. Except for uranium, recovery of these elements has not been attempted to any significant extent However, such recovery merits attention based upon availability of existing chemical techniques. This paper presents some thoughts on possible techniques together with opportunities for commercial applications.

Jan 1, 1983

By Willey GJ

A brief test program was undertaken to assess the viability of air-sparged hydrocyclone beneficiation at the Cadjebut concentrator. Three different process streams were processed (lead rougher feed, lead scavenger tail and `mine water' solids) in a small scale ASH unit (one litre volume, feed rate 1000 to 1800 kg solids/hour). Analysis of the concentrates indicated that ASH based flotation was successful, selective and capable of achieving improvements to the overall metallurgical performance of the concentrator. The flow regime inside the device accentuates the selective flotation of the finest particle size ranges generally not recovered to any significant extent in conventional mechanical flotation devices. The testwork proved that the ASH is a viable alternative option for increasing the flotation capacity of the lead beneficiation stage of the Concentrator.

Jan 1, 1993

By J. Engelbrecht

Understanding the deportment of minerals in size fractions has already led to improvements in the flow sheets for platinum minerals beneficiation. There are, however, more potential changes in the flow sheets that may improve the recovery of platinum group metals or reduce the costs of beneficiation before refining. Based on known technology of pre-concentration, milling, gravity concentration, flotation, and magnetic separation a number of potential alterations or additions can be considered and motivated based on the mineral deportment in size fractions.

Jan 1, 2012

By James Bennett, Jinichiro Nakano, Anna Nakano

Previous empirical research demonstrated that by mixing gasification and metallurgical slags at a specific composition in a CO2 enriched environment, enough exothermic heat would be generated to transform CO2 to CO. The process capacity may be limited by the availability of the slags, however, it could be used to supplement existing energy or chemical production to reduce overall carbon emission. In this study, computational simulations were performed to explore optimal process conditions based on effects of individual slag constituents and thermal input for maximal gas conversion rate, heat production, and volume increase. In simulated conversions of CO2 to CO and H2O to H 2, comparisons were made by varying CaO, FeO, versus V2O3 slag constituents. The result indicated the optimal slag composition may be obtained by appropriate source selection and mixing of gasification and metallurgical slags in order to maximize carbon reduction and/or H2 production.

Mar 1, 2017

By J. M. Barker

Formation of commodity agreements depends mainly on the economic instability and associated mitigation measures inherent in the economic conflict between more developed and less developed nations. Five types of possible agreements exist: futures market, buffer stock, restrictive agreement, multilateral contract, and compensatory finance. Lack of market separation between sulfur consumers and producers coupled with large world production and highly concentrated export production in theory suggest a restrictive agreement as most likely. In practice, stockpiling of sulfur, an informal buffer stock, as done in Canada and perhaps the Middle East, has been the main sulfur price-supporting mechanism in the past two decades. No commodity agreements involving sulfur now exist except for multilateral contracts. Sulfur agreements apparently have existed rarely, if at all, in the past. Law (1975) refers to sulfur as one of a group of commodities where "there have been additional control efforts of various types." Clearly, sulfur was a candidate, at least conceptually in the past, for some form of commodity agreement. The following discussion centers on the world sulfur market from 1976 to 1985 in this context.

Jan 1, 1987

By Kiseong Hyeong

Geochemical characteristics, shapes and surface textures of manganese nodules from two blocks located in the southern (9°N~11°N) (KR5) and northern parts (16°N~17°N) (KR2) of the Clarion-Clipperton fracture zone between 130°W and 133°W were investigated in terms of sediment distribution and metal contents for better understanding of controlling factors of seabed manganese nodule genesis. Two blocks, ~700 km away, are dominated by the nodules with different origins, each of which has distinctive chemical compositions and shapes. KR2 block is dominated by irregular and poly-type nodules of hydrogenetic origin with low Mn/Fe, Cu, and Ni contents and high Fe and Co contents, while KR5 block is dominated by discoidal and ellipsoidal nodules of diagenetic origin with high Mn/Fe, Cu, and Ni contents and low Fe and Co contents. In addition, nodules from two blocks show different surface textures: smooth and transitional in KR2 and dimorphic and rough in KR5. Sediment distribution is also distinctly different in two blocks. The study area consists of three sediment types: Unit 1 ? dark brown mud with an intermediate metal content, Unit 2 - yellowish brown mud with poor metal content, and Unit 3 ? black metalliferous mud. KR2 is characterized by the thick occurrences (<250 cm) of Unit 1 at the surface while Unit 1 distributes thin (<12 cm) in KR5. Higher primary production rate in the southern block proximal to equator and resulting high supply rate of metals to the sediment might be the cause for the dominance of diagenetic nodules in the southern block, but potential controls of different sediment distribution on the nodule genesis can not be excluded. If it is the case, Unit 1 with an intermediate metal content likely has been acting as a sink for metals by precipitating micro-nodules within the sediment column. Within the KR5, the hydrogenetic nodules occur preferentially on the seabed where Unit 3 distributes at shallower depth (<50 cm). Unit 3 has 2 or 3 times higher metal contents than other types of sediments. It might play the same role as Unit 1 in the northern block that prevents the supply of metals to the sediment surface. It also supports the potential effect of sediment distribution on nodule genesis. Keywords: Nodules genesis, Sediment distribution, Supply rate of metals

Jan 1, 2008

By Katherine L. Heineken, Timothy J. Tope, Kim David Murphy

One method for small arms disposal is the use of a deactivation furnace or explosive waste incinerator. There are numerous hurdles a facility typically encounters to get the furnace or incinerator fully operational and permitted. For example, one Department of Defense installation was in the permitting process 7 years, which included numerous facility upgrades and modifications. This paper will discuss the technical approach for proactively addressing permitting issues and requirements and will identify potential pitfalls to avoid as well as ways to reduce costs. For example, when determining the waste profile, the facility should forecast its treatment needs (taking into account the net explosive weight limits of the furnace/incinerator) and then classify the wastes into "chemical families" based on the type and composition of the wastes. One waste from each family should then be selected for potential inclusion in the trial burn. Modeling the waste disposal can help to narrow down the number of wastes requiring characterization during a trial burn, as well as the number of analyses.

Jan 1, 1997

By K. W. Lee, C. Pound, J. Carmody, L. Petersen, C. Nelson, J. G. Cai

The feasibility of developing the Underground Science City below the Kent Ridge Park has been investigated. The primary aim of the study has been to explore the possibility of creating underground space to house a new community of research laboratories and offices. The investigation represents the first such study undertaken in Singapore for a non-military underground facility. The paper describes the geology of the Underground Science City site and illustrates the layout and plan of the Underground Science City. The geology and rock mass below the Kent Ridge Park is generally favorable for the development of an underground cavern complex. Underground Science City can be potentially developed housed in a cavern complex. Several potential development schemes are studied; with various combination of deep/shallow mined caverns of different span sizes and access options. The preferred scheme is shallow, mined room-and-pillar caverns with large spans and shaft accesses at both existing surface Science Park 1 and Science Park 2. The scheme can be potentially expanded laterally to create more underground space for new Underground Science Cities at Kent Ridge area.

Jan 1, 2001

By M. L. Sorokin

The thermodynamic of nickel production from laterite ore and from sulfide concentrate can be analyzed using PO2 - PS2 diagram of the Ni-Fe-S-0-SiO2 system. The procedure of the diagram computation is suggested and the diagrams for various temperature and Fe/Ni ratio are calculated. Three-suffix Margules equations are used for the calculation of the thermodynamic properties of three solutions: liquid matte, liquid slag and solid Fe-Ni alloy. The diagrams are used for the considerations about direct one-stage metallic nickel production.

Jan 1, 1994

By Tapp BA

Australia, considered an energy and mineral resource rich country, is poised on the verge of a major mineral industry &apos;boom&apos;. It has been repeatedly emphasised that this growth in the mineral industry will form the basis of future economic development. Currently the mining and mineral processing industries use some 32% of the annual primary energy consumption in Australia. This share, although large even now, will increase with the realisation of the 1980&apos;s production expansions to 40% by 1985. Two metal industries dominate the energy scenario; iron and steel and aluminium. Major expansions in the local industry will be dominated by the aluminium industry. This highly energy intensive industry has planned major increases in metal production throughout the eighties. The implications of exporting cheap energy to pay for expensive oil imports, the ramifications on Australia&apos;s infrastructural ability to supply these major energy needs and the other options that might be

Jan 1, 1981

By J. Manchisi

Laboratory investigations were conducted to establish the feasibility of bioleaching a mixed copper oxide/sulphide rougher concentrate from Nchanga Mine on the Zambian Copperbelt. The objective was to determine the kinetics and extent of copper extraction for this material. Batch experiments were conducted under different solution conditions in stirred tank bioreactors. The progress of (bio)leaching was monitored through measurements of soluble ferrous and ferric iron, copper, pH, and redox potentials, while bacterial activity was monitored online through 02 and C02 gas utilization rates. About 20 per cent copper was solubilized within 2 hours in all cases of non-oxidative (abiotic), oxidative (abiotic), and bioleaching experiments. This was attributed to the dissolution of mainly copper oxides. Subsequently, bioleaching experiments resulted in an overall copper extraction of 93 per cent, with up to 8 g.L-1 copper after six leaching days, compared to 58 per cent copper extraction in the abiotic oxidative acid leaching experiments. However, there was little effect of time (i.e. poor dissolution kinetics) on copper recovery for abiotic non-oxidative acid leaching of the material. Hence, the rate of sulphide leaching increased due to the activity of bacteria. Thus, the material is potentially bioleachable under mesophilic conditions. However, more exhaustive test work needs to be conducted to establish the effect of bioleaching variables and heat requirement.

Jan 1, 2012

By Donald D. Carr

Four counties in Indiana--LaPorte, Vigo, Vanderburgh, and Switzerland--have potential for deep underground limestone mining because they are in or are near high population areas and have no surface-minable limestone de- posits. The principal markets are Gary-South Bend, Terre Haute, Evansville, and Cincinnati. Minable seams suitable for aggregate are 120 to 150 meters (400 to 500 feet) below the surface in LaPorte and Vigo Counties, about 90 meters (300 feet) below the surface in Switzerland County, and about 600 meters (2,000 feet) below the surface in Vanderburgh County. Some deposits are also suitable for high-purity uses or for cement raw materials, which enhances their potential for exploitation.

Jan 1, 1980

By C. H. Ault, D. D. Carr

Four counties in Indiana- LaPorte, Vigo, Vanderburgh, and Switzerland-have potential for deep underground limestone mining because they are in or near high population areas and have no surface-mineable limestone deposits. The principal markets are Gary-South Bend, Terre Haute, Evansville, and Cincinnati. Mineable seams suitable for aggregate are 120-150 m (400-500 ft) below the surface in LaPorte and Vigo Counties, about 90 m (300 ft) below the surface in Switzerland County, and about 600 m (2,000 ft) below the surface in Vanderburgh County. Some deposits are also suitable for high-purity uses or for cement raw materials, which enhances their potential for exploitation.

Jan 1, 1983

By J. Crummy, I. K. Anderson, A. J. Hall, R. S. Haszeldine

Bedrock gold mineralisation has been located in association with an extensive float train 25 km west of known alluvial gold. It is in the form of open, matrix-supported breccias comprising pyritic quartz/sericite clasts in a vuggy, cherty chalcedonic and crystalline quartz matrix. Fluid inclusions in pyritic clasts indicate trapping temperatures for gold mineralising hydrothermal fluid of 170-240 degrees C. This mineralisation could represent the upper part of a feeder zone to an exhalative hydrothermal system. It is possible that other high-level feeder zones could be preserved elsewhere in the area. Deep weathering of such a system could provide a source for the alluvial gold localities near Helmsdale. It is suggested that east and central Sutherland presents good prospects for exhalative epithermal gold mineralisation and the associated feeder zones

Jun 19, 1905

By Joseph W. Leonard

Evidence is presented to show that certain coals can be super-cleaned, using present coal preparation processes, to reduce sulfur below levels that are commonly believed to be possible. The evidence points to the need to develop continuous sorting methods by which coal coming from a mine can be segregated so that different raw coal types can be processed separately to produce a super-clean coal in addition to coals cleaned to more common levels of sulfur. Evidence is presented and techniques discussed that may be applicable for making the method feasible.

Jan 1, 1976

By Derek J. Fray

"In order to extend the application of fused salts in\the electrowinning and electrorefining of metals, it is necessary to maximise the current density, minimise the voltage drop and greatly increase the area of electrode surface so as to compete with the space-time yield of pyrometallurgical reactions. The various designs of electrowinning cell are reviewed and it is shown that by the application of a modest centrifugal field it is possible to reduce the anode to cathode interelectrode spacing to 4 mm whilst still maintaining a current efficiency of 85-90%.The thermodynamic potential for electrorefining is far less than for electrowinning yet fused salt electrorefining is only applied in limited cases. The reasons for this are discussed and the important design parameters evaluated. It is concluded that by using packed bed electrodes, separated by a diaphragm, the possibility of electrorefining with very low energy consumption can be achieved. Carbothermically-produced metals are always cheaper than those produced by electrolysis but suffer from the disadvantage of low purity. It is proposed that fused salt electrorefining may offer an energy efficient way of upgrading the metal. IntroductionThe majority of metals can be deposited from fused salts (1,2) but as commercial production is restricted to the more reactive elements, it is worthwhile considering the advantages and disadvantages of fused salt electrolysis as' compared to smelting and aqueous electrolysis. The advantages over aqueous extraction are as follows:1) the much higher conductivities and diffusivities result in much lower IR losses and higher current densities can be achieved at modest voltages;2) the elevated temperatures of operation result in larger exchange currents which give rapid kinetics and lower activation polarisation for the electrode reactions;3) the absence of water as a solvent means that it is not necessary to consider the evolution of hydrogen as a competing cathodic reaction. Furthermore, alkali halide salts, often used as solvents in fused salt electrolytes, have high deposition potentials;4) molten salts generally are mutually soluble and, therefore, concentration polarisation effects are minimised."

Jan 1, 1988

By MacLean L

In 1975 the Commonwealth Government established import parity pricing for all liquid hydrocarbons discovered after the 16th September, 1975. These discoveries were termed "new oil" to differentiate them from existing discoveries and production. Overnight the price of the product being sought trebled, resulting in greatly enhanced economics by increasing the potential returns on existing prospects and by making smaller plays economically viable. After 18 years of drilling, the offshore Gippsland Basin has attained a moderate level of exploration for a basin of its size. Fifty seven prospects have been drilled within the basin but only a few of these were drilled along the southern and northern margins, while the deep water areas along the eastern margin have remained virtually undrilled following the Hapuku-1 oil discovery. The major hydrocarbon accumulations within the basin are trapped beneath the Latrobe Unconformity surface and exploration has largely concentrated on this single play in areas immediately adjacent to the major producing fields.

Jan 1, 1982

By O. A. Ogunseitan

The contamination of aquatic ecosystems by mercury wastes is one of the most serious forms of environmental pollution associated with the metal mining and electrochemical industries. The transformation of inorganic mercury to alkylated species is a reversible bacterially-mediated process. The production of methylated mercury is of ?major public health and eco-toxicological concern because these forms of mercury are highly toxic ?and they bioaccumulate in aquatic organisms. We determined the response of the genetic determinants of mei:cury transrormation by Pseudomonas species (that predominate in contaminated soils and sediments), to the concentration and species? or available mercurfiations. By combining selective isolation and gene. ?probe techniques, the intrinsic genetic potential for mercury detoxification in a contaminated environment ?can be estimated. We determined that genetic units required for mericury volatilization (merA ?for mercuric reductase) are naturally amplified in response to mercury. Mercury-resistant bacteria that tolerate up to 100 ug Hg(Il)/ml of medium contain about 10 times more DNA fragments encoding merA than in unadapted bacteria. The exposure of bacteria to methylated.Hg (10 ug/ml lake water) produced increases (up to 10 times) in .genetic units, and higher levels of genetic expression (up to 50 times) per ml of lake water for the mercury reductase system, than on-induced lake water. The findings suggest that in environments where methylated Hg may accumulate as a result of bacterial activity, the reverse reaction which leads to the removal of mercury through volatilization from the system, may be achieved by inducing genetic ?amplification and expression of the mercuric reductase gene system.

Jan 1, 1991