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Jan 1, 1941

Jan 1, 1938

By Shadia J. Ikhmayies

"Cadmium sulfide (CdS) in the form of thin films is an interesting material because it has a large variety of applications ranging from photovoltaic to luminescent devices. N-type CdS is usually used as a window layer in the heterojunction CdS/CdTe thin film solar cells. A review of the photoluminescence (PL) spectra ofn-type CdS thin films prepared by different techniques was performed. The effects of different dopants and impurities and the effects of temperature and deposition parameters on the PL spectra were discussed. Annealing in different atmospheres causes the changes in material structure and phase change from cubic to hexagonal phase which can be detected through the variations in the PL spectra. CdCh heat treatment improves the cystallinity of the films and enhances the exciton peaks and the green band in the PL spectra.IntroductionThin CdS films deserve attention because their expected gap emission lies very close to the highest sensitivity of the human eye. Thus, one might assume that thin CdS films are an appealing host for photonic devices [ l]. They have been used in a lot of applications including electronic and optoelectronic devices [2]. Thin films ofn-type CdS are widely used as a window layer in heterojunction solar cells such as CdS/CdTe solar cells. Doped and undoped CdS thin films can be obtained by different techniques such as; spray pyrolysis (SP) [3], chemical bath deposition (CBD) [2, 4], pulsed laser deposition [5, 6, 7], laser ablation [l], thermal evaporation [8].Several experimental techniques have been used in order to study semiconductor defects. In particular, photoluminescence (PL) has been shown as a powerful and sensitive tool in examining the crystal quality of polycrystalline thin films. PL can be used in the detection of defects which are radiative active. These defects can also act as traps in the transport of carriers [9]. The photoluminescence (PL) of thin film CdS is strongly influenced by the unbalanced stoichiometry, which is typical for CdS and is in general evoked by a Cd surplus. With increasing Cd content, the emission spectra move far below the gap to the red spectral range. Besides stoichiometry problems, independent of the material deposited, the PL properties of thin films depend on surface features and the influence of the interface between the film material and the substrate [10]."

Jan 1, 2013

By Shadia J. Ikhmayies

"Cadmium telluride (CdTe) is a very interesting material that has many applications. Thin films of p-type CdTe can be used as the absorber layer in the heterojunction CdS/CdTe thin film solar cells in which n-type cadmium sulfide (CdS) works as the window layer. A review of the photoluminescence (PL) spectra ofp-type CdTe thin films prepared by different techniques was performed. The presence of defects and impurities such as oxygen and chlorine influence the PL spectrum. Copper and other dopants change the PL spectra and enhance the defects band. Chemical-heat treatment especially with CdCh is known to improve the quality of CdTe thin films because it decreases the Cd vacancies and quenches deep traps, so it enhances the PL signal. A discussion of chemical-heat treatment especially with CdCh, the effect of the ambient atmosphere, and that of the measuring temperature is performed.IntroductionCadmium telluride (CdTe) is a II-VI compound semiconductor that has a cubic zincblende (sphalerite) structure with a lattice constant of 0 A4~11]. Other than all of II -VI semiconductors, CdTe can be made both n- and p-type. But due to self compensation it is not easy to get p-type CdTe films [2]. Polycrystalline CdTe thin films are interesting because they have a lot of applications. Most of the problems associated with the use of these films are attributed to inhomogeneity, self-compensation, and the difficulty of forming a stable and lowresistivity ohmic contact [3]. CdTe technology has been established for a large number of applications, including solar cells, optical and nuclear detectors, and thermal- and radiationimaging devices [3]. At present, the highest demonstrated conversion efficiency for a CdTe based heterojunction (ID), with CdS as a window layer, is 16.5% [4, 5]. CdTe thin films can be prepared by different experimental techniques, such as thermal evaporation [l], electrochemical deposition (ED) [3], close-spaced sublimation (CSS) [3, 4, 6], physical vapor deposition (PVD) [3], chemical molecular beam deposition (CMBD) [7], and close space vapor transport (CSVT) [8].The objective of this paper is to make a review of the photoluminescence (PL) spectra ofp-type CdTe thin films prepared by different techniques and discuss the factors that influence the PL spectra. The composition of the film is very interesting in determining its PL spectrum. Different kinds of defects, impurities and dopants have their finger prints in the PL spectrum. Deposition techniques and deposition parameters such as the deposition temperature and ambient atmosphere also have their influence. Heat and chemical treatments which are known to improve crystallization and reduce the defects change the PL spectrum."

Jan 1, 2013

By Riyad N. Ahmad-Bitar, Shadia J. Ikhmayies

"CdS/CdTe solar cells were built by depositing a 200 nm layer of Sn02:F on glass substrates by the spray pyrolysis (SP) technique, a 500 nm CdS:In layer by the same technique and a 1-1.5 µm CdTe layer by vacuum evaporation. The cells were CdCh heat-treated in nitrogen atmosphere for 30 minutes at 350 -.C. The photoluminescence (PL) spectra were measured at the CdS/CdTe interface for two cells with different values of the CdTe layer's thickness at temperature T = 60 K. A deconvolution peak fit was performed from which it is found that the peaks are characteristic of the solid solution CdSxTei-x· The parabolic relation that relates the bandgap energy with the composition was used to estimate x, where xis [S]/([Te]+[S]) and [Te], [S] are the concentrations of Te and S atoms respectively. The results show that the interface is smooth and the change of the bandgap occurs gradually.IntroductionCdS/CdTe heterojunctions represent a combination of materials promising various applications, and for solar energy conversion in the first place [1]. In photovoltaic cells the CdS material acts as a wide bandgap window. Direct bandgap CdTe with high optical absorption coefficient is used as an absorber [1]. Solar cells with efficiencies of 10 to 16% have been obtained with CdTe grown by close space sublimation, electrodeposition, vacuum evaporation and rf sputtering methods [2]. In this work the CdTe layer was prepared by vacuum evaporation because it results with films of minimum impurities, while the Sn02:F and CdS:In layers were deposited by the spray pyrolysis technique because it is a low cost method which enables intentional doping and large area thin films."

Jan 1, 2011

By B. Pregerson, M. Gaft, J. Rabinowitz

The main phosphate minerals, apatite and francolite, are characterized by intensive selective photoluminescence, connected with impurities of Eu2+, Ce3+, V4+, Mn2+ and (UO22+ ). The non-uniform distribution of phosphate minerals in lumps makes photoluminescence sorting possible. As result, an intermediate product is recovered which is enriched by P205 and has relatively small amounts of chert, dolomite, calcite, fluorite, etc. In the case of Zin Phosphate Plant coarse rejects, for example, it is possible to separate a product enriched by francolite, practically free of chert and with a lowered calcite content. This material is suitable for flotation, with a potential 6-7 % increase yield of concentrate.

Jan 1, 1993

By C. A. Young

The remediation of cyanide (CN-) and nitrate (NO)-) anions in mine and agricultural waters by various photolytic methods has been reviewed and investigated. Photolytic methods such as direct photolysis, homogenous photolysis, and heterogeneous photocatalysis are briefly described and compared. Results and discussions show that each method has certain advantages and disadvantages. For each method, Eh-pH diagrams prove useful for determining reaction mechanisms. Preliminary results obtained for cyanide oxidation and nitrate reduction show that homogeneous photolysis can be superior due to faster kinetics than the other methods. The photolytic methods were individually, not simultaneously, tested and compared. Differences in concentrations of products were obtained and attributed to differences in photoconversion efficiencies and other inherent characteristics of .the photolytic methods. Various reaction mechanisms are proposed in accordance with the literature as well as measurements obtained from solution analysis using ion selective electrodes and ion chromatography .

Jan 1, 1995

By R. J. T. Charles

Introduction An apparatus that will measure the surface area of a few of the simple minerals with a high degree of accuracy has been described by J. W. Bell (1). His apparatus consisted essentially of a photometric device that would measure the turbidity of fine particle suspensions. Turbidity, in this case, was considered as a function of surface area. Bell's method of surface area determination seemed to offer possibilities of extension and improvement to the point where it might approach a general method of particle size measurement. Theoretical and Practical Considerations of the Photometric Method In order to illustrate how turbidity may be considered as a function of average particle size, and to indicate the type of results expected from a photometric method of particle size measurement involving turbidity, the following theory may be hypothecated. If a number of particles, considered as spheres of uniform diameter, are placed at random in the path of a beam of light, the following expression, which will give the change in light intensity as a function of the diameter of the particles, the specific gravity of the material, and the weight involved, can be formulated from the Beer-Lambert Law:

Jan 1, 1951

By David G. Kidd

The principles of Ore Sorting in general and photometric sorting in particular are discussed with detailed reference to the Model 16 machine. The operating principles and design of the Model 16 are discussed and a case study presented to demonstrate the use of sorters to process an industrial mineral. In addition, an economic study is presented, to highlight the benefits of ore sorting, by evaluating the increased revenue that can be achieved using an ore sorter to process a particular ore body.

Jan 1, 1983

By R. J. Gordon, N. J. Keys, N. F. Peverett

Photometric sorting of ore on a South African gold mine by N. J. KEYS. B.E. Met. (Queensland) (Visitor). R. J. GORDON. (Visitor). And N. F. PEVERETT. B.Sc. (Eng.) (Wits) (Fellow) This paper concerns the development and application of a high-throughput, multi-stream photometric sorting machine developed for the South African gold mines. It is now believed that this sorter and its progeny may be found suitable for a large proportion of all possible sorting applications. A laser-light source and sensitive photomultiplier are employed in a scanning system to detect light reflected from the surfaces of rocks passing through the sorting zone. Electronic circuitry then analyses the photomultiplier signal, which represents the varying intensity of the reflected light, and produces control signals to actuate the appropriate valves of an array of air-blast rejection devices to remove from the feed certain particles selected by the analysing process. Typical throughput per machine ranges from 50 t/h for a minus 60mm plus 30mm feed to 200 t/h for minus 150mm plus 70mm material.

Jan 9, 1974

By N. J. Keys

This paper concerns the development and application of a high throughput multi-stream photometric sorting machine developed for the South African gold mines. It is now believed that this sorter and its progeny may be found suitable for a large proportion of all possible sorting applications. A laser light source and sensitive photomultiplier are employed in a scanning system to detect light reflected from the surfaces of rocks passing through the sorting zone. Electronic circuitry then analyzes the photomultiplier signal, which represents the varying intensity of the reflected light, and produces control signals to actuate the appropriate valves of an array of air blast rejection devices to remove from the feed certain particles selected by the analyzing process. Typical throughput per machine ranges from 50 tons/hour for a-2 ½? + 1 ¼? feed to 200 tons/hour for -6" +2 ¾ " material.

Jan 1, 1974

By Daniel B. Conn, John L. Floyd

PhotoSeis™ is a blast analysis method that combines the advanced technologies of high speed motion picture photography and digital seismology. When fracturing rock with the use of explosive energy, the human eye cannot detect the details of the process due to its short duration. An extended time base is required to accurately quantify the response of the rock mass to the detonation process. This time base is provided by the use of high speed motion picture cameras. The control of ground vibrations and airblast is an important consideration when developing efficient blast designs. High vibration and airblast levels can be an indication of improper design, inaccurate detonators, or adverse geology. Since many factors can elevate airblast and ground vibration, a greater understanding of the site specific response to the blast design is needed that is beyond the scope of simple seismographic recordings. By synchronizing the photographic record provided by the high speed motion picture cameras with the airblast and vibration information from digital seismological monitoring, the Photoseis™ technique can be of great assistance in controlling airblast and vibration and optimizing the use of explosive energy for rock fragmentation.

Jan 1, 1990

Coal cleat and faulting influence failure, gas release, and choice of preferred mining directions, locations, and sequences. Unfortunately soil and younger rock cover restrict direct mapping of these structures ahead of mining operations. Aerial photographs of cover contain indirect indications of concealed structures in arrays of linear photostructures. These arrays are commonly too complex for interpretation by simple visual inspection.Analytical techniques applicable to complex arrays are illustrated for a covered part of the Galilee Coal Basin, Queensland. These techniques are: optical determination of sets in arrays of photostructures; correlation of these sets with sub-surface structures; filtering of m-rays for particular sets; detection of anomalies associated with concealed structures in the density distributions of particular sets; fitting filtered arrays to trajectories; correlation of trajectories with the regional directional variations of concealed structures; contouring of ratios of sets to discriminate anomalies associated with concealed fractures and variations in the total and bed thicknesses of cover; kinematic and dynamic inference on the basis of fracture-trace angular and spatial relationships.

Jan 1, 1979

By Nord L. Gale

The discovery of important new ore deposits of lead, zinc, copper and silver in 1955 in Southeastern Missouri has resulted in the development of a thriving mineral industry known as the "New Lead Belt" or "Viburnum Trend", to distinguish it from the older lead producing areas to the East. This region has recently become the world's largest lead producing district with production in 1970 reaching 432,576 tons or 74.4% of the entire United States lead mine production. The area is heavily forested with rolling hills dotted with numerous clear running streams in the Clark National Forest of the Missouri Ozarks. The location is within 70 miles of St. Louis, Missouri and has a natural abundance of water resources which provide an important recreational area for fishing, hunting, camping and other outdoor activities. Until this recent development, the area was sparsely populated and industrialization was almost unknown. The infusion of $150 million in mining capital has brought about a dramatic change in the economic structure of the area and will almost surely be accompanied by changes in its environmental picture. In an effort to maintain this bountiful national resource and to evaluate the changes occurring in surface water quality and aquatic life forms present, an inter- disciplinary research program at the University of Missouri has been undertaken with the support of the National Science Foundation. Research has been carried out to determine background values, establish natural baselines, and to evaluate the extent and causes of changes in streams effected by mine water discharges and wastewater from ore milling operations. The unique topography of the "New Lead Belt" area allows the channelization of milling and smelter wastes to separate stream systems (Figure No. 1) thus allowing measurements of the pollutional effects on an individual basis.

Jan 1, 1973

By E J. Coyle, L A. Millington

Tailings storage facilities are geotechnically complicated structures that develop heterogeneous strength profiles and varied porewater conditions. The monitoring of porewater pressures is one of the only direct measurements that can be performed to monitor the performance of a facility throughout its life and is of particular importance in upstream facilities. Foundation underdrainage, continuous and staged tailings deposition, climate inputs (rain, snow, humidity, evaporation, etc), and stratified tailings permeabilities can complicate this critical measurement that introduces uncertainty to stability analyses. These difficult conditions manifest in vibrating wire piezometer measurements as very low or negative pressure readings, both of which are within the instrument’s range of accuracy. However, the data can be difficult to interpret, and a range of interpretations are adopted from optimistic low phreatic surfaces to conservative fully saturated tailings. Where tailings are potentially liquefiable, these very low readings introduce further uncertainty regarding the pore space saturation ratio and liquefaction potential above the estimated phreatic surface. This area of uncertainty is the vadose zone, and its affect on tailings behaviour is not well understood. The two facilities analysed in this paper are upstream, raised embankments with tailings classified as clayey, sandy silt that have been found to be potentially liquefiable. The vibrating wire piezometers (VWP) at both sites show very low or negative readings when they are initially installed near the surface and then go through cycles of re-saturation and de-saturation. Eventually the readings settle as the VWPs are buried deeper within the tailings. The instrumented sections within the tailings column do not show consistent readings that would be indicative of a hydrostatic phreatic surface at either site. Rather, they are highly variable and can be interpreted as either representing a high phreatic surface within the tailings or as a ‘perched’ phreatic zone within the tailings layers. How the VWP data is interpreted has a significant impact on how the facilities are raised and operated. The design outcome for Site 1, which adopts a lower phreatic surface, results in an embankment that meets factor of safety (FoS) requirements under residual strength conditions without any buttressing. Conversely, a conservative (high) phreatic surface has been adopted for Site 2 and has resulted in the facility requiring a significant buttress to meet FoS under residual strength conditions.

Jul 1, 2021

By Dietmar Eifler, Benjamin Jost, Marcus Klein

This paper focuses on the ductile cast iron EN-GJS-600 which is often used for components of combustion engines. Under service conditions, those components are mechanically loaded at different temperatures. Therefore, this investigation targets at the fatigue behavior of EN-GJS-600 at ambient and elevated temperatures. Light and scanning electron microscopic investigations were done to characterize the sphericity of the graphite as well as the ferrite, pearlite and graphite fraction. At elevated temperatures, the consideration of dynamic strain ageing effects is of major importance. In total strain increase, temperature increase and constant total strain amplitude tests, the plastic strain amplitude, the stress amplitude, the change in temperature and the change in electrical resistance were measured. The measured values depend on plastic deformation processes in the bulk of the specimens and at the interfaces between matrix and graphite. The fatigue behavior of EN-GJS-600 is dominated by cyclic hardening processes. The physically based fatigue life calculation “PHYBALSIT” (SIT = strain increase test) was developed for total strain controlled fatigue tests. Only one temperature increase test is necessary to determine the temperature interval of pronounced dynamic strain ageing effects

Jan 1, 2015

By E. M. Wise, T. E. Kihlgren, N. B. Pilling

SYSTEMATIC data are presented on the relation of composition of nickel silvers to color, tarnish resistance, hardness and liquidus temperatures, for alloys containing up to 30 per cent nickel and 50 per cent zinc, further modified at certain nickel and zinc contents by 0 to 8 per cent of tin and 0 to 10 per cent of lead. Attention has also been directed, using a still more limited range of alloys, toward a study of tensile properties and such casting properties and characteristics as fluidity, shrinkage and pressure tightness. In some of these, rather broad ranges of composition are dealt with; in others, it has been expedient to focus attention on the Federal Specification 20 per cent nickel silver casting alloy, WWP-541.

Jan 1, 1935

By T. E. Kihlgren

SYSTEMATIC data are presented on the relation of composition of nickel silvers to color, tarnish resistance, hardness and liquidus temperatures, for alloys containing up to 30 per cent nickel and 50 per cent zinc, further modified at certain nickel and zinc contents by 0 to 8 per cent of tin and 0 to 10 per cent of lead. Attention has also been directed, using a still more limited range of alloys, toward a study of tensile properties and such casting properties and characteristics as fluidity, shrinkage and pressure tightness. In some of these, rather broad ranges of composition are dealt with; in others, it has been expedient to focus attention on the Federal Specification 20 per cent nickel silver casting alloy, WWP-541. INTRODUCTION The demand for an alloy essentially white in color, which could be cast and worked by simple methods and which possessed strength and corrosion-resisting properties superior to the usual brasses, led to the discovery and early use of cupronickel alloys containing zinc, and some-times tin, lead and other metals. This type of alloy was generally known as German silver until the war, when the term "Nickel Silver" became generally accepted. The element principally responsible for the white color of the alloy and for its strength and corrosion resistance is nickel, which may constitute from 8 to 30 per cent of the alloy. The functions of the other elements will be described later. The manifold uses of nickel silver are largely due to its color, corrosion resistance, ease of casting, fabrication, joining and rather moderate cost. In many instances the alloy is finished by grinding and polishing while in others it may be finished with a silver or nickel plus chromium plate. Electroplates

Jan 1, 1935

By Martin H. Stanczyk

Under the Solid Waste Disposal Act, the Bureau of Mines initiated several accelerated in-house research programs to develop new and improved methods of proper and economic solid waste disposal. The program being conducted at the Bureau' College Park Metallurgy Research Center is concerned with eliminating the current waste of valuable materials in municipal refuse by developing low-cost methods for reclaiming and recycling the metal and mineral values contained in incinerator residues. Each year the United States must collect and dispose of in some manner or other, about 150 to 200 million tons of municipal solid wastes. The monetary output for this service ranks third among public services, exceeded only by the costs for schools and roads based on population growth projections and materials use patterns, the quantity of refuse generated by the early 1980's may approach 300 million tons annually. Currant estimates indicate that only 10 to 20 percent of the total municipal refuse generated is disposed of by incineration. If all refuse were properly incinerated the residues would contain more than 11 million tons of iron and nearly a million tons of mixed nonferrous metals including aluminum, copper, lend, zinc, and tin.

Jan 1, 1969

By D. R. Spink, G. L. Rempel, C. O. Gomez Bueno

"A morphological and chemical study of the Great Canadian Oil Sands Ltd. (GCOS) fly ash has been carried out. Extensive scanning electron microscopy, as well as light microscopy, showed that the GCOS fly ash consists of two fractions, one composed of unburnt or partially burnt irregular-shaped carbon particles and an ash fraction composed of transparent and opaque, often coloured, glassy spherical particles-some of them cenospheres (hollow spheres) and the others plerospheres (hollow spheres packed with smaller spheres). Microcrystals (0.1 to 0.3 um long) growing on the inner and outer surfaces of some of the spheres were also noted and found to contain more Fe, Ti, Ni and V than the spheres.The carbon-free GCOS fly ash particle size follows a lognormal distribution, with a geometric median particle size (by count) of3.8um and a geometric standard deviation of 1.84. IntroductionCanada's current energy situation strongly suggests that oil from the Alberta tar sands deposits will probably be recovered more extensively in the future. Today's commercially proven technology to recover oil from the Athabasca tar sands, as practised by Great Canadian Oil Sands Ltd. (GCOS), involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil; the production of significant amounts of petroleum coke and sulphur during the bitumen upgrading process. The bulk of the petroleum coke is burnt in boilers to fulfill the energy requirements of the entire operation. The boiler ash, which contains appreciable amounts of metals, such as vanadium, nickel, titanium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke-fired steam generation plants. Thus, as well as representing a petroleum resource, the tar sands represent a resource for vanadium and possibly other metals providing that metal recovery processes can be developed."

Jan 1, 1980