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By M. A. Chandler, G. T. Adel, J. N. Richardson, E. C. Gutierrez

A rapid, bench-top analyzer has been developed to determine P2O5 content and CaO/P2O5 ratio in phosphate ores. The analyzer utilizes a portable computer equipped with a frame grabber to measure the reflective intensity (gray level) of phosphate samples placed in front of a television camera. P2O5 content is related to the average gray level of the sample, while CaO/P2O5 ratio is determined from the amount of bright material present. The sensor is currently being used to analyze flotation concentrate samples at Texasgulf's phosphate operation near Aurora, North Carolina. Sensor development along with results from laboratory and in-plant testing are discussed.

Jan 1, 1993

By R. S. Hearon

The image of the open-pit miner in the eyes or the Environmentalist has never been very outstanding. The phosphate industry, whose history in Florida reaches back to the late 1800's, can-not be credited until recently with a large number or accomplishments in terms of protection or the environment to change this image. This lack of action was not deliberate or in opposition with the desires of the public. In the formative years, there was little or no public and the companies found it necessary to build towns to house their employees and their families, towns which remained in existence until the late 50's and early 60's or formed the core of present large communities. Neither these pioneers nor most subsequent resource developers considered themselves un-thinking spoilers, nor were they so regarded by their contemporaries. Instead, they acted in a manner consistent with their environmental circumstances and intellectual heritage. Early Americans did make mistakes in using the land but the mistakes became apparent only in the opinion of later generations. Over the past five to ten years, there has been a new self-awareness in the industry with regard to environmental responsibilities brought about, in part by a continuing onslaught of new regulations with jurisdiction over our activities. Part of the new regulations are aimed at industries as a whole while many, particularly state regulations, pertain specifically to the phosphate mining industry. Why all the new regulations? The reasons are encased in a complex web of activity but stem primarily from a new public awareness of its environment. More and more of our youth have become interested in the environmental science areas such as biology and ecology. The tremendous growth rate in both the population and industry has made personal issues out of subjects such as atmospheric inversions and water shortages which previously were abstract concepts. The State has grown from a population of 1,500,000 in 1930 to approximately 9,000,000 people today. This personal impact and general lack of knowledge on the part of the public concerning economics has resulted in big business no longer being held in awe, often in contempt and generally in suspicion where environmental concerns are encountered.

Jan 1, 1978

By AIME AIME

LEADING off the Thursday morning session on Non-metallics was C. E. Heinrichs' paper, "Phosphate Flotation, Its Place in the Technology and Economics of the Phosphate Industry." Mr. Heinrichs also presented a closely related paper, "Milling Methods and Costs at the No. 2 Concentrator of the Phosphate Recovery Corporation," by H. S. Martin. The first of the papers points out the great significance of flotation to the phosphate industry, inasmuch as flotation practically doubles the potential recovery, thereby decreasing production costs and increasing reserves materially. The second paper describes three such plants, two of which are in Florida, the third being at Wales, Tenn. Operating characteristics and costs are reviewed. Answering inquiries from the floor, Mr. Heinrichs said that the adoption of a new parallel-shell dryer, from 60 to 80 ft. long, instead of the old single-shell countercurrent dryer, had increased the unit drying capacity over 300 per cent and had reduced the drying cost to less than 25c. per long ton of dried product. The initial moisture is from 15 to 18 per cent and the final about 2 per cent.

Jan 1, 1933

By Ingvar Ymén, Alexandra Lundmark

"The depressive effect of dichromate on galena was evaluated with chemical experiments and small-scale depression experiments at a pH of around 12. The depressive effect was measured with Dynamic Vapor Sorption (DVS), which measures the water uptake of a sample as a function of the % relative humidity. The depression is due to PbCrO4PbO, which in the presence of Ca2+ and SO4 2- forms a more or less amorphous solid solution (Pb,Ca)(CrO4,SO4)PbO, which clogs to the surfaces of the ore. Free Pb2+- ions are needed for depression to occur and at high pH Pb2+ - hydroxide complexes, supply enough Pb2+ - ions to precipitate (Pb,Ca)(CrO4,SO4)PbO. In air CO2, precipitates CaCO3 which slowly lowers pH, precipitating more (Pb,Ca)(CrO4,SO4)PbO and CaCO3 on galena. Similar experiments where performed with five alternative depressors whereof phosphate, which forms an amorphous precipitate of approximate composition Pb3Ca13(PO4)10SO4, gave the best results. Phosphate was tested in laboratory scale flotation experiments giving encouraging results.INTRODUCTIONWithin Boliden Mines, concentrating of copper and lead from complex sulfide ores is performed by bulk flotation, meaning that copper and lead are concentrated in the same product. Downstream, copper and lead are separated by flotation of chalcopyrite, and depression of galena. Boliden has for many decades used sodium dichromate to depress galena (reference 1). Dichromate is both toxic and carcinogenic and Boliden has for many years investigated several alternatives. So far, however, the best results have been obtained with dichromate. Since Boliden has tried to substitute dichromate for a long time without finding a process as effective, Boliden decided to clarify the function of dichromate in the depression of galena and on the basis of the outcome find alternative depressors with similar function. This study was given to RISE Bioscience and Materials / Surface, Process and Formulation as a consultancy assignment. This paper presents the outcome of the combined efforts of Boliden and RISE."

Jan 1, 2018

By Jinrong (Patrick) Mang

Three of the most challenging problems in phosphate beneficiation are discussed: flotation efficiency, resource conservation and environmental impact. Some new flotation machines offer the opportunity of reducing power and reagent consumption significantly, while increasing specific capacity many fold. Efficiency might also be improved dramatically by replacing the "double float" process with a single-collector scheme. Model based software control is a powerful tool for improving overall plant efficiency. Recovery of phosphate values from the phosphatic clays could extend phosphorus reserve life significantly. phosphate recovery from the slimes might be achieved by sizing-flotation, selective flocculation and bioleaching. Reducing the volume of phosphatic clays produced is another key stop to minimizing phoephate logs. Such a reduction may be realized by floating at finer cut size. Although an ideal' dolomite separation process is yet to be developed, a cationic flotation process may prove to 'be economically feasible. Loss of phosphate in the desliming stage is the major problem with most of the flotation schemes for removing dolomite.

Jan 1, 1995

By Jinrong (Patrick) Zhang

Improvement of conventional flotation efficiency, separation of carbonates from apatite, recovery of phosphate values from phosphatic clay and other ways of utilizing the clay, disposal of clay slurries and subsequent reclamation of the settling areas, and conservation of resources and energy remain major challenges in the beneficiation area for the phosphate industry. These problems have been actively investigated by the industry, government agencies, and research organizations for decades with modest success. However, some recent research activities have generated promising results and possible new technologies. The dominant position of the Crago process in phosphate beneficiation is being challenged by some of the single stage processing schemes. Heavy media separation enables one producer to process a portion of high carbonate ores. Separation of dolomite from apatite by reverse flotation of carbonates with phosphate depressants showed potential for industrial application. Consolidation of phosphatic clays in mine cuts using a modified "sandwich" process is being tested. Beneficiation in the acidulation plant or grinding at the mines may be considered in the future.

Jan 1, 1993

By Z. D. Hora

Sedimentary phosphate-bearing rocks are found over a considerable area of so utheastern British Columbia that extends from Fernie east to the Alberta-British Columbia boundary and from the International Boundary northward to the headwatei: s of the Elk River. Phosphatic beds occur at the following four stratigraphic levels: 1. lower part of the Banff-Exshaw sequence of Mississippian age; 2. lshbel Formation of Permian age; 3. base of the Fernie Group of Jurassic age; 4. belemnite bed within the Rock Creek Member of the lower part of the Fernie Group. To date, considerable tonnages of phosphate rock have been proven in the area. However, no commercial production has been initiated because of a relatively low P2O5 grade. Data on assays and thicknesses of the phosphatic beds are in part recalculated from the paper by Telfer (I 933) and in part from assessment reports filed at the British Columbia Ministry of Energy, Mines and Petroleum Resources.

Jan 1, 1984

By Virgil Kirkham

NORTH AMERICA has for many years led the world in phosphate production, but with development of African deposits and their marketing conditions with respect to European countries, this leadership will shortly pass to Africa. Algeria, Egypt, Tunis, and Morocco have large phosphate reserves and a correspondingly large production because of easy mining and a ready European market, which was developed during the war. An increase in home consumption is destined to develop for the eastern American fields, and the countries of the Pacific will provide a market for the western producers. New processes indicate a decrease in fertilizer costs, which will encourage a more widespread domestic use and assure better marketing conditions. The African deposits, although benefited by a water haul, have the disadvantage of being isolated from a source of acid so that the crude rock is shipped from Africa to its destination, whereas in the United States the chief product shipped is acidulated rock or various types of superphosphatic fertilizers. The principal types of phosphate deposits used in the manufacture of fertilizers are guanos, apatite, phosphatic marl, phosphatic limestone, phosphatic shale, and phosphate rock which is also known as phosphorite. Some of these deposits are found on each of the continents; Table 1 gives their occurrence, age, location, character, extent, etc. Most of , the information found in this table represents a compilation of information published elsewhere in a different form and widely scattered.

Jan 1, 1925

Two small coral islands in the Pacific Ocean, situated close under the equator, and formerly classed among the Line Islands, have, during the last three or four years risen into prominence owing to the valuable deposits of phosphate of lime discovered on them.The deposits of Ocean and Pleasant Islands are under the control of the Pacific Islands Company (1902) Limited, of London and, Sydney, and the high grade of the phosphate, together with the exceptionally favourable facilities for mining this mineral, of which there are several millions of tons on these islands, give this company advantages which enable them to command the Australian and New Zealand markets, and also to make large contracts with Japan and other countries. Both islands, as far as surface indications are concerned, are entirely constructed of coral, with phosphate on the top from the highest points to the present sea level, there being no sign of volcanic rocks, with the exception of a few pieces of drift pumice on the coast.Banaba (Paanopa according to. the Admiralty charts), also known as Ocean Island, was discovered in 1804. It is situated in lat. 0° 52" S. and long. 169P 3[)" E.

Jan 1, 1904

By E. B. Graves

I have been asked to talk to you this morning about phosphate marketing and distribution. In discussing this I will attempt to answer such questions as: What is phosphate? Where do we get it? What form is it and how do we sell it? How do we distribute it? How is it applied? And last, but not least, What about the future? To start with, phosphate is one of the three primary plant nutrients. It is the element essential for root structure of plants. Plants, like humans, need a balanced diet. Thus, the amount of phosphate required by individual plants is, in part, related to how much of the other nutrients are used. Virtually all soils contain a certain amount of available phosphates. Back at the turn of the century the most common source of additional plant nutrient, including phosphates, was from cattle manure. The use of chemical fertilizers is something that has grown significantly during the last half century, and in particular, the last 20 years.

Jan 1, 1977

By Lyle A. Hale

The subject area known as upper Dry Valley is located 15 miles due east of Soda Springs in Sections 14 and 23, Township 9 South, Range 44 East, Caribou County, Idaho. The railroad extending from Soda Springs to its terminus at El Paso's Maybe Canyon mine is 8z miles to the north in lower Dry Valley. Initial data derived from trench work in 1962 revealed a variety of econom¬ically significant alterations of the phosphatic beds related to the rather unique geomorphic development in the northern part of phosphate lease 1-012989. It was apparent that such conditions, while valid for near-surface beds in a strike direction, would be misleading if projected to the proposed depth limits of strip mining. Consequently, a subsurface mapping program was initiated in 1963 to determine: (1) the depth and horizontal extent of weathering and related phe¬nomena, (2) the depth, thickness, and quality of ore beds and intervening strata, and (3) structural geology as a guide for mining procedures. Successful use of a scintillometer in 1956 to detect the subcrop position of phosphate beds in the Smokey Canyon area of southeastern Idaho led to the conclusion that gamma radiation surveys of drill holes could be a useful aid in subsurface mapping. The objectives of this paper are: (1) briefly to describe geologic features characteristic of the phosphate lease area and (2) to demonstrate the practical application and theory behind gamma radiation logging as an effective tool in the economic evaluation of a phosphate lease.

Jan 1, 1969

By K. D. Jacob

ALL types of commercial phosphate rock produced throughout the world contain fluorine in quantities ranging from approximately 0.4 to 1.3 per cent in the Curacao and Christmas Island phosphates to 3.1 to 4.2 per cent in the phosphates of the United States and North Africa1. For a given type of rock, the fluorine content is usually roughly propor-tional to the phosphorus content. SIGNIFICANCE OF FLUORINE IN PHOSPHATE ROCK On the basis of chemical and X-ray diffraction studies, Hendricks and co-workers2 concluded that fluorapatite, Ca10F2(P04)6, is the essential phosphatic constituent of the commercial types of domestic phosphate rock. On the other hand, Bredig and co-workers3 have recently advanced the opinion, also based on X-ray diffraction studies, that the mineral phosphates usually contain carbon dioxide in the apatite lattice, and that the phosphate rocks of. the United States are really fluorcarbonate apatites. However, the domestic types of phosphate rock do not seem to differ greatly from coarsely crystalline fluorapatite in their behavior toward chemical reagents in general, and for the purpose of this paper it will suffice to consider fluorapatite as being the essential phosphatic constituent of these types of rock.

Jan 1, 1936

By Paul R. Smith

Preparation for flotation begins with dragline mining, pumping, washing, screening, and desliming. Slimes, nominally -150 mesh material, constitute large quantities of phosphate and water which are a disposal problem. Older techniques involve sizing at about 35 mesh for separate coarse and fine treatment. The plus 14 mesh fraction does not require concentration. Coarse treatment includes agglomerate spiralling, belt flotation, thickening, scrubbing with sulfuric acid, de-oiling for reagent removal, and cationic flotation of fine quartz. A recent trend is to screen at coarser than 35 mesh size and eliminate coarse particle treatment, sacrificing some grade of this product. Techniques for flotation concentration of the fine size fraction are discussed.

Jan 1, 1976

By G. Rinelli, Paul R. Jr. Smith

Preparation for flotation begins with dragline mining, pumping, washing, screening, and desliming. Slimes, nominally -150 mesh material, constitute large quantities of phosphate and water which are a disposal problem. Older techniques involve sizing at about 35 mesh for separate coarse and fine treatment. The plus 14 mesh fraction does not require concentration. Coarse treatment includes agglomerate spiralling, belt flotation, thickening, scrubbing with sulfuric acid, de-oiling for reagent removal, and cationic flotation of fine quartz. A recent trend is to screen at coarser than 35 mesh size and eliminate coarse particle treatment, sacrificing some grade of this product. Techniques for flotation concentration of the fine size fraction are discussed.

Jan 1, 1976

By S. M. Javad Koleini

Processing of phosphate ore sample was investigated for increasing phosphate content and reduction of its gangue minerals such as carbonates and silicates. Experimental designs were per-formed using Taguchi method. Different flotation methods were investigated for Moundon phosphate ore sample and three methods were used as follow: direct cellophane flotation, reverse calcite flotation and reverse quartz flotation. Because of the sensitivity of cellophane flotation to slime content, prior desliming was carried out before the experiments. Direct flotation experiments carried out and a concentrate contained 23.80% P2O5, 6.88% SiO2 and 72.33% recovery were produced. The achieved P2O5 content in the produced concentrate from reverse flotation of calcite was 26.44% and the recovery was 82.56%. The concentrate products obtained at optimum conditions by direct flotation of phosphate and indirect flotation of calcite were subjected to indirect flotation of calcite and direct flotation of appetite and final concentrates with P2O5 grade of the order of 24.19% and 26.96% were obtained, respectively. It was concluded that one stage direct flotation is unavoidable to achieve a product with low SiO2 content.

Jan 1, 2014

By S. K. Kawatra, T. C. Eisle

In froth flotation of phosphate, it is important that the flotation be as selective as possible in order to maximize grade and recovery without adding additional stages of flotation. Flotation columns provide a means for improving the selectivity compared to conventional flotation machines and are of considerable interest for phosphate processing. The selectivity of a flotation column is largely limited by the degree of back mixing of tailings into the froth zone, and its recovery is limited by the degree of short-circuiting of feed to the tailings. The horizontally baffled flotation column was therefore developed to minimize back mixing and short-circuiting without introducing problems with plugging or reduced capacity. The introduction of horizontal baffles to a column reduces both entrainment of feed water into the froth and short-circuiting of feed to the tailings, which improves the column selectivity. The results of horizontally baffled column flotation of phosphate are presented for fatty acid flotation of phosphate, with comparison to conventional flotation using the same reagents.

Jan 1, 1999

By G. M. Wilemon, J. G. Davis, R. G. Swanton, B. J. Scheiner

The US Bureau of Mines has conducted investigations on extracting phosphate values from wastes generated during the mining and beneficiation of phosphate matrix. These wastes may contain up to one third of the phosphate originally present in untreated ore. Samples of wastes were air-dried and leached using 93% sulfuric acid in the presence of methanol. Evidence for the formation of a calcium sulfate hemihydrate coating that hinders complete dissolution of phosphate is presented. Solid-liquid separations were enhanced when flocculation was effected using poly(ethylene oxide) (PEO) in conjunction with hydroxypropyl cellulose (HPC) or hydroxyethyl cellulose (HEC). A conceptual flowsheet for a proposed process using an acid-alcohol leaching technique is presented.

Jan 1, 1991

By G. M. Wilemon

The U.S. Bureau of Mines has conducted investigations on extracting phosphate values from wastes generated during the mining and beneficiation of phosphate matrix. These wastes may contain up to one third of the phosphate originally present in untreated ore. Samples of wastes were air-dried and leached using 93 pct sulfuric acid in the presence of methanol. Evidence for the formation of a calcium sulfate hemihydrate coating that hinders complete dissolution of phosphate is presented. Solid-liquid separations were enhanced when flocculation was effected using poly(ethylene oxide) (PEO) in conjunction with hydroxypropyl cellulose (HPC) or hydroxyethyl cellulose (HEC. A conceptual flowsheet for a proposed process using an acid-alcohol leaching technique is presented.

Jan 1, 1990

By E. Cortese

PHOSPHATE occurs in many places in Egypt,. in two main zones: one in Upper Egypt, along the Nile Valley, principally on the right side, and one near the Red Sea coast. In the Nile zone, the principal layers of phosphate rock are to be found: in the mountains east of Mahamid (right side of the valley); in the hills near Sibaiya, also called Sebaieh (both sides); in the hills of Agula, Hagaza and Gurn (right side); and further on, along the cancel road leading from Kena to Kosseir, a few miles east of Legheita's Oasis. Following, that track, after, having crossed the watershed, underlain by rocks like granite, serpentine, porphyry and diabase, one comes again to the Cretaceous formation containing considerable quantities of phosphate, at Gebel Duwi, Gebel Nakheil and Gebel Kosseir El Kadim, not far from the coast. More to the north, in the hills near Safaga Bay (Um El Uettat El Wasif) is another rich bed of the same formation. There are reports of phosphate existing near Suez and in the Sinai peninsula, and possibly some other zones can be traced or discovered in the future. The mines are well developed on the right bank of the Nile at Sharawna (near Sebaieh Station) and along the Red Sea coast, at' Safaga and near Kosseir. Prospecting work has been done at Gebel Duwi, Gebel Gurn, Agula, Hagaza, and near Mahamid. The phosphatic formation in Egypt is quite variable, not only from place to place, but even within small areas. The phosphate is all of Cretaceous age, as is proved by the fossils found in it. It is considered to belong to the Campanian or, more appropriately, to the Maestrichtian series. The principal fossils are: Alectryonia Villei Coq. sp.; Roudereia Auressensis Coq. sp.- R. Drui Mun. Chalm.; Trigonoarca multidentata, Newton.; Cardita libyca, Zittel; Libycoceras Ismäely, Zittel; Nautilus sp.; Ancystrodon libycum Dam.; Corax pristodontus Ag.; Lamma biauriculata Zittel sp. Above the Maestrichtian beds, we have the Danian series, unconformably covered by Lower Eocene beds. Under the phosphate is a grayish marly clay, and beneath this, bluish-gray scaly shales resting on the Nubian sandstone (Santonian).

Jan 2, 1918

By A. Nicotra, E. H. Roux, J. H. du Plooy, D. H. de Jagger, P. De Waal, G. J. van der Linde

This paper reviews the geology, history, current beneficiation practices, uses, marketing, and future outlook of phosphate in South Africa. The vastness of the reserves, and the industry's efficiency and competitiveness in world terms, are highlighted.

Jan 1, 1989