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By Waladan M, Elliot B, Rankin W. J

A survey was undertaken on the Kalgoorlie Nickel Smelter in which samples of slag and matte were taken along the length of the integrated flash smelting furnace and analysed to determine the variation of nickel and iron concentration. At the same time the oxygen potential of the slag and matte was measured using disposable tip solid-state oxygen probes. The results show that the oxygen potential of the slag is higher than that of the matte and that both decrease from the reaction shaft end to the slag tap hole end of the furnace. The slag and matte are not at equilibrium except towards the tap hole end. Reduction of nickel and magnetite from the slag occurs before the slag enters the slag-cleaning appendage by reaction with iron in the matte. Thermodynamic modelling and laboratory experiments showed that the equilibrium nickel and magnetite contents of the slag in the absence of a carbonaceous reducing agent are about 0.4 per cent and 7.5 per cent, respectively. A carbonaceous reductant is required to obtain a lower nickel content in the slag.

Jan 1, 1991

According to our experimental results, the following oxygen probe recommended, that is, the magnesia stabilized zirconia was employed as a solid electrolyte and Fe.FexO solid elect- rode was used as a reference electrode. Using such an oxygen probe, we tried to measure the oxygen potentials in molten metals, mattes and gases in the following fields of non-ferrous metal industry, molten copper in the side launder before casting, molten crude lead in the forehearth of ISP blast furnace, molten copper mattes in the forehearth of blast furnace and in the settler of flash smelting furnace, gas in the settler of copper flash smelting furnace and flue gas in the electric furnace for ferro-silicon. In the past ten years or so, many experi- mental results in the field of fundamental studies have confirmed that the equilibrium oxygen potential could be measured conveniently and accurately by an electrochemical method using a zirconia solid electrolyte. Recently, such an electrochemical technique has been also applied to a device for physicochemical invest- igation or process control in the non-ferrous metal industry. Such a device consists of an oxygen con- centration cell with stabilized zirconia, and it is commonly called an "oxygen probe" or "oxygen sensor".

Jan 1, 1980

By Zhigan Deng

Ni–Mo ore is a black shale containing amorphous colloidal sulfides which have highly active. The oxygen pressure leaching behavior of nickel from black shale in aqueous media is presented. The effects of agitation speed, temperature, oxygen partial pressure and particle size on the rate of nickel leaching were determined. The results indicate that at low temperature hydrothermal and excess oxygen presence, the amorphous sulfides are easily oxidized to sulfuric acid and sulfate, and leaching nickel. The mathematical analyses of the experimental data for various experimental conditions indicated that the dissolution process was controlled by the chemical reaction during the early stage of dissolution, and was then controlled by liquid-film diffusion. In the initial stage of leaching, the reaction depends on oxygen partial pressure.

By Canterford J. H, Sparrow G. J, Dyson N. F

Pressure leaching of a bulk flotation concentrate prepared from a complex Cu-Pb-Zn sulphide ore was carried out at 150 and 190¦C under 1050 kPa oxygen overpressure in 1 L and 4 L titanium autoclaves to extract zinc, and to obtain residues for smelting tests and leach liquors for purification and recovery of the zinc by electrowinning. Dissolution of 95% of the zinc was achieved at both temperatures. Copper and iron dissolution and the degree of oxidation of the sulphide sulphur to elemental sulphur or sulphate depended on the temperature of the leach. At 190¦C, a jarosite (a basic iron sulphate) was the major iron-containing material in a residue that contained 17% total sulphur. Its formation was associated with dissolution of 18% of the iron. At 150¦C, oxidation of the sulphide sulphur and dissolution of the iron were significantly less. Only 7% of the iron was dissolved and a residue containing 25% total sulphur, present as a lead jarosite, lead sulphate, and elemental sulphur, was obtained. The formation of small pellets of unreacted sulphides coated with elemental sulphur caused problems during the leaching at 150¦C, and also during scale-up from the 1 L to the 4 L autoclave at 190¦C. At 150¦C the concentrate required two stages of leaching to achieve dissolution of over 90% of the zinc. These problems are discussed.

Jan 1, 1989

By H. Y. Sohn, H. K. Lin

The leaching of primary porphyry chalcopyrite ore under simulated solution-mining conditions was studied using a packed-bed reactor. A mathematical model incorporating the intrinsic leaching kinetics of chalcopyrite and pyrite grains, the pore diffusion of dissolved oxygen within the ore fragments, liquid-solid mass transfer, and the effect of fluid flow and axial dispersion was formulated and tested for the overall leaching process. The dependence of oxygen solubility on ionic strength of the solution was also incorporated into the model. Satisfactory agreement between model pre- dictions and experimental data was obtained. The model can also predict the rate of the leaching process under different temperatures, oxygen pressures, solution flow rates, and different size distributions of ores.

Jan 1, 1991

By Ono K, Oishi T

Electrochemical determination of the oxy- gen partial pressure in the Fe-0-SiO 2 ternary systems saturated with solid silica was done by measuring the activity of oxygen in a silver bath in equilibrium with the molten slags using zirconia solid electrolyte galvanic cells. From the data obtained, the activity ~Faii.st composition relations were calculated

Jan 1, 1980

By D. A. J. Swinkels

The problem of determining oxygen levels in liquid steel to aid in deoxidation control has received general attention for a number of years. Work in this direction started at the B.H.P. Central Research Laboratories early in 1967 with an evaluation of sampling techniques followed by vacuum fusion analysis to determine the oxygen content of the samples (1). It was found that these techniques had a number of drawbacks if they were to be used for deoxidation control. The method of analysis was rather too slow to allow effective control and measured total oxygen level rather than dissolved oxygen. Furthermore, the results were found to be very variable due to slag entrainment in the samples. Attention therefore turned to the galvanic cell method using a solid oxygen ion conductive electrolyte such as cubic stabilised zirconia. The ionic conductivity properties of electrolytes such as (ZrO2) 85 (CaO).15 had been studied by a number of investigators and had already been applied to the measurement of oxygen activity in gases, in lower melting metals such as copper, lead, tin, silver, alkali metals and indeed the first studies in steel had been made (2,3). Since then the results of a number of studies in the development of an expendable oxygen probe for steel have been reported (4-9).

Jan 1, 1972

By L. A. Taylor, R. O. Colson, D. S. McKay

The production of oxygen on the Moon utilizing indigenous materials will be essential for successful lunar colonization. Several processes have been put forth to accomplish Lunar Liquid Oxygen (LLOX) generation. The schemes that have received the most study to date involve: 1) Reduction of ilmenite (FeTi03) by H2, CO, CH4, CO-Cl2 and Cl2, plasma. 2) Molten silicate electrolysis, both unadulterated and fluoride fluxed. 3) Several others, including H, reduction of glass, carbo-chlorination, HF acid leaching, fluorine extraction, magma oxidation, and vapor pyrolysis. The H2 reduction of ilmenite and molten silicate electrolysis processes have received the most study to date. They are both feasible schemes and have various pros and cons, including their feedstock requirements. However, all processes should be addressed at the onset of LLOX research. This paper reviews several of the most studied and feasible processes for winning oxygen front lunar materials. There is an obvious need for more experimentation and study.

Jan 1, 1994

By L. A. Taylor

The production of oxygen on the Moon utilizing indigenous materials is paramount to a successful lunar colonization. And several processes have been put forth to accomplish this. The LLOX generation schemes which have received the most study to date are those involving?: 1) the reduction of ilmenite (FeTi03) by H2, C, CO, CH4, CO-CI2, & Cl2 plasma, 2) magma electrolysis, both unadulterated and fluoride-fluxed, and 3) several others, including carbo-chlorination, HF acid leaching, fluorine extraction, magma oxidation, and vapor pyrolysis. The H2 reductions of ilmenite and magma electrolysis processes have received the most study to date. They are both feasible schemes with various pros and cons, including their feedstock requirements. However, all processes should be addressed at least at the onset of our considerations. There is an obvious need for considerably more experimentation and study. Some of these requisite studies are in progress, and this paper reviews several of the most studied and feasible processes for winning oxygen from lunar materials.

Jan 1, 1991

By K. J. Murphy, A. R. Smith, A. P. Odorski

"The need for large quantities of oxygen for use in metallurgical processes was a major driving force in the commercialization of tonnage air separation plants. Oxygen, nitrogen and argon impact the quality, energy efficiency and environmental aspects of metals production. Cryogenic air separation processes have been used to supply most industrial requirements, however, newer technologies are available or under development to meet the needs of today's and tomorrow's metallurgical processes. This paper reviews the technical features and state of development of adsorption, chemical, cryogenic and membrane technologies. The technologies are compared in terms of plant size, oxygen purity and pressure, nitrogen and argon co-production, product use pattern and back-up requirements. Computer control systems are described that optimize operation over varying load patterns and ambient conditions; substantially lowering energy consumption. IntroductionOxygen production totalled 390 billion cubic feet in 1987. Although current production is lower than the peak of 455 billion cubic feet reached in 1979, oxygen remains the fifth leading chemical product manufactured in the u.s. (1) Metals manufacturing and fabrication accounts for sixty percent of the oxygen consumed in the u.s. Oxygen use in the steel industry consists of air enrichment for conversion of iron ore, purification of the iron in basic oxygen or other furnaces, and for cutting and welding the finished steel product. Nonferrous ores are smelted in oxygen enriched atmospheres to reduce energy consumption and increase capture of sulfur compounds to meet environmental requirements. In the future oxygen usage is expected to become even more important in metals production as energy costs increase, environmental standards become more stringent, and as new coal based processes become commercialized. Oxygen usage per ton of metal in the new direct reduction processes can be up to ten times higher than traditional steel making."

Jan 1, 1988

By Peter G. Mason

Pressure oxidation is now a well estab­lished process for the treatment of refracto­ry gold ores and concentrates. The process utilizes pure oxygen to oxidize mineral sulphides in an aqueous slurry at elevated temperature and pressure. Gold released from the sulphides becomes amenable to subsequent cyanidation. A major component of the operating cost of this process the supply of oxygen. The quantity required is dependent on the sul­phide grade, the extent of oxidation and the percentage utilization of the oxygen. As the sulphide grade is fixed and complete oxida­tion is generally required to maximize gold liberation, the only opportunity for saving in oxygen consumption is to improve its utilization. Under circumstances where the feed material contains substantial carbonate, oxygen utilization can be improved by strip­ping carbon dioxide from the autoclave vent and recycling the associated oxygen. Fluor Daniel Wright included an oxygen recycle circuit in the Getchell pressure oxidation plant, which is operated by First­Miss Gold in Nevada. FirstMiss Gold has applied for patent rights to the process as implemented at Getchell.

Jan 1, 1990

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By C. A. Pickles, J. M. Toguri

The refining of two molten Ag-Cu alloys, containing 7.5 and 11.2 mass% Cu, with a borosilicate slag was investigated using both air and pure O2 to determine the effects of the following variables: flow rate of oxidising gas; injection time; mass of sodium borosilicate flux; and injection of the oxidising gas into either the slag or the metal. The results demonstrate that more than 90% of the Cu can be removed with Ag losses of less than 5% and that refined metal with a Cu content of less than 0.5 mass% can be produced. Ag losses to the slag increased with the amount of Cu removed, and a mechanism is proposed to account for this

Dec 1, 1995

By Komosa T, Muir D. M

Adequate levels of dissolved oxygen are essential for efficient gold dissolu- tion. The actual levels in plantpuips can be seriously reduced by the presence of oxygen consuming reactive minerals, and reduced oxygen solubility in saline water. The rate of gold dissolution is then limited by oxygen availability rather than cyanide. Ion selective electrode dissolved oxygen meters can give an effective indication of the relative oxygen saturation, but they are not able to give meaningful values of dissolved oxygen in saline water, without custom calibration curves. When the dissolved oxygen concentration is rate limiting, the addition of oxygen or peroxide can improve gold leaching kinetics as well as reduce cyanide consumption.

Jan 1, 1991

By Michael Brittan

For several years, Independence Mining Co. (IMC) has routinely used oxygen fluid-bed roasting to pre-oxidize refractory gold ores ahead of conventional carbon-in-leach (CIL) processing. Oxygen serves jointly as the fluidizing medium and the combustion gas. This technology has proven to be reliable, environmentally sound and cost-effective. IMC is a subsidiary of the Minorco group. The company operates the Jerritt Canyon (a joint venture with FMC Gold) and Big Springs gold mines in the Independence mountain range north of Elko, NV. Ore bodies in the range contain characteristic refractory ore. It requires pre-oxidation ahead of conventional CIL processing. This article describes the technology developed specifically to treat these difficult ores.

Jan 1, 1995

By R. E. Johnson

The No. 3 reverberatory furnace at Phelps Dodge. Corporation's Morenci, Arizona copper smelter first received oxygen from a new oxygen plant during October 1982 and began operation with oxygen-fuel and oxygen sprinkle smelting burners which burn concentrate with oxygen. The furnace was completely converted to roof-mounted oxygen-fuel firing in October 1982. All conventional air-fuel bridge wall burners were extinguished at that time. The novel arch-mounted oxygen sprinkle smelting system began continuous operation April 1983. Since startup, unit fuel requirements decreased and furnace throughput significantly increased. Furnace off gas SO2 strength increased from an average of 1.5% SO2 to an average of 20% using only oxy-fuel burners. Oxygen sprinkle burner operation also has given excellent results, with the furnace off gas strength increasing to 35%-60% S02. There has been a reduction in overall arch temperatures, an increase in matte and slag temperatures, and a lowering of furnace bottom buildup with oxygen smelting. Furnace off gas is blended with converter off gas and treated in a sulfuric acid plant.

Jan 1, 1983

By McAllister J

Oxygen was in restricted use at Port Kembla until tonnage oxygen became available for steelmaking in the open hearth furnaces. In adopting the new process various modifications to furnace design and operation were necessary and some of these, including increase in roof height and variation in firing and draft control, are discussed.The design of oxygen lances is also discussed and various steelmakingtechniques considered.Steel production increased with oxygen roof lancing-one- furnace producing 8,507 tons in one week-but new problems, such as rate of refractory wear, and disposal of fumes, were created.Design of future open hearth oxygen furnaces is predicted.INTRODUCTIONIn the post-war era, the availability of "tonnage" oxygen caused a major revolution in steelmaking techniques. Various pneumatic processes showed that steel can be madeat a very fast rate and that oxygen steelmaking can be applied to open hearth furnaces. Methods used are surface impingement with roof lances, bath injection with door lances, flame enrichment with fuel firing, mixed gas and oxygen firing, and enrichment of normal combustion air by oxygen injection into the flue systems.Owing to its previous restricted availability and high cost, oxygen was used in rather small quantities in the open hearth furnaces at Australian Iron and Steel Pty. Ltd.(A.I. & S.), Port Kembla, until about the middle of 1960.At that time tonnage oxygen became available and roof lancing commenced on No. 33 furnace at No. 2' open hearth shop.

Jan 1, 1962

By Robert D. Pehlke

"The evolution of oxygen steelmaking is reviewed and new operating processes are described. The developments which could impact this technology are summarized. Staged and continuous steelmaking are considered in the light of new technologies. The future opportunities for oxygen steelmaking processes are overviewed. IntroductionThe use of oxygen in steelmaking was originally brought on the scene by the development of pneumatic steelmaking. Sir Henry Bessemer in England originally conceptualized the use of gaseous oxygen in steelmaking, and then he and William Kelly in Eddyville, Kentucky independently developed the original pneumatic process which involved blowing air through a bath of molten pig iron to oxidize the carbon and silicon and produce steel. This process and many following processes, including those which would use pure oxygen gas, have been proposed.Beginning with the first commercial oxygen steelmaking vessels at Linz, Austria in 1952, the world steelmaking industry has adopted this style of processing. In general, the process has involved the use of steel scrap in amounts from 20 to 35% of the metallic charge with molten pig iron produced in blast furnaces making up the remainder. The impurities in the charge are oxidized through the use of oxygen gas injected into the steelmaking vessel.However, currently being adopted into commerical practice and on the horizon are a number of advances in this process which include the use of iron ores as a source of iron and oxygen, the use of an all scrap charge, incorporation of pre-reduced iron, the use of auxillary fuels to change the balance of cold and liquid iron-base charge materials and numerous refining techniques."

Jan 1, 1988

By Ismar Antônio Sardinha

Usually outer straight steel tubes are used to blow supersonic oxygen into LD converters (BOF) to make liquid steel, although conical tubes are used too. Inner tube for oxygen blow and intermediary tube for water IN and water OUT are normally straight steel tubes. Present paper shows the influence of outer tube shape and metal used to in lance cooling and, consequently, a skull retention on lance surface. There are two parameters more important related to lance cooling: velocity of water out and the total lance cooling by addition of thermal conductivity of outer tube metal to it. For this comparison outer tubes are made of carbon steel or copper, and can be straight or conical. As related to velocity of water OUT, outer straight tubes have bigger efficiency than conical tubes. As related to total lance cooling, outer tube metal made of copper has much bigger efficiency than steel because of its thermal conductivity 7 to 12 times more depending on work temperature. The lance cooling has much bigger efficiency for the patented SKULLS3® technology with no skulls on the lance and no skulls into the mouth of LD converters (BOF).

Aug 17, 2017