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By Terry L. Muldoon

This report describes development and demonstration of an upgraded stench fire warning system for underground wines. Current systems, which have been used since before 1920, release an ethyl mercaptan mixture into the mines' compressed and/or ventilation air during emergencies. Miners, when smelling ethyl mercaptan, evacuate the mine according to predetermined plans. These systems, while simple, have problems with safety and reliability. The upgraded system overcomes these problems. The system uses a different stench agent, is less toxic, less nauseating, and less corrosive than ethyl mercaptan. These combined with the feature of thiophane not reacting with iron oxides, makes the upgraded system safer and more reliable. The system also uses a combination of two simple principles: a standpipe with pressure balancing to provide a constant head, and a sized orifice to control the rate of release of the stench agent. This system enables the mine to release the agent for a longer period which provides better coverage and to ensure that miners will not be exposed to potentially toxic concentrations of the stench agent. The system is easy to operate, requiring only the turning of two 1/4-turn ball valves. The upgraded system has been successfully tested during two evacuation drills at an underground uranium mine. Using three injectors (one on the compressed air line and one on each of two intake air shafts), the system exhibited significant improvements in warning times over the mine's existing system. This report provides a detailed description of the system design and its demonstrated performance in two mine demonstrations.

Jan 1, 1981

By E. D. Palmes

Phase I of these studies demonstrated the feasibility of measuring the efficiency and capacity of sorbents in tube-type samplers for contaminant gases. This was accomplished by measuring concentration at various points along the length of the diffusion path during sampling. Concentrations were measured by removing small aliquots with gas-tight syringes and gas chromatography. With hexane as the gas and activated charcoal as the sorbent the procedure was quite successful and we proceeded with Phase II of the study; this involved application of the principle to gases of importance in diesel exhaust using a variety of sorbents. When we worked with high concentrations of the test gas we clearly demonstrated the differences in both efficiency and capacity of the sorbents for each of several gases. The chief drawbacks of the system were that we were unsuccessful in determining more toxic gases at realistic occupational exposure levels or determining formaldehyde at any level using the flame ionization detector. It was concluded that, although the method is feasible, more sensitive methods of measuring concentrations of gas in the tube must be developed to make the procedure applicable to regions of chief industrial hygiene interest.

Jan 1, 1983

By Ben Aleck

The objective of this program was to adapt Space Shuttle technology on high-performance spherical pressure vessels to cylindrical pressure vessels. Specifically, a cylindrical aluminum liner overwrapped with fiberglass filaments and prestressed by yielding the liner under a sizing pressure was to be replaced by a higher strength-to-weight ratio steel liner overwrapped with a higher strength-to-weight ratio filament. The steel was cryoworked stainless steel and the new fiber was Kevlar 49. In addition, the heavyweight ends of the aluminum liner were to be replaced by thin-walled domes which required multiple helix angle wraps for their support, in place of the single kite-string wrap from pole to pole of the aluminum overwrapped design. The use of cold swaging of tube-ends to form bosses, demonstrated on subscale development efforts, had not been achieved full-scale when the contract was initiated. Difficulties arose with the full-scale demonstration which were not solvable at the time with the designs and equipment available. hence, an unanticipated development was the finally selected method of making the 4-in.-diameter stainless steel liner with a single boss and no welds in an 0.020-in.-thick wall, from an 0.050-in.-thick, 13-in.-diameter disk. The demonstration vessel failed by leakage during the prestressing step because embedded oxides had formed flaws in the boss region. Such flaws have been avoided by proper temperature control during hot spinning. Hence, a new design was developed which weighs half as much as its recently developed predecessor. Funds ran out before adequate testable hardware was produced.

Jan 1, 1983

By John D. Foulkes

An investigation is made into whether commercially available equipment can be used to engineer effective emergency warning systems for underground coal mines. Discussions with members of the Bureau and the Mining Enforcement and Safety Administration established that the preferred system should operate over the existing Pager Phone twisted pair, and broadcast an audio alarm. Applicable equipments such as voice band tone signaling equipment, alarm sounding equipment, mine telephones and complete alarm systems from over thirty manufacturers are listed. Factors affecting the range over which an alarm could be detected in representative mine situations were studied. These included (a) the subjective masking effects of typical background noise found in mines, such as that due to continuous miners (b) the attenuation of sound in mines (using both a theoretical and experimental results) and (c) the attention-getting qualities of different sound for miners. Audio alarm systems meeting the requirements can be installed and representative systems are described.

Jan 1, 1977

By Z. Zborovszky

The feasibility of using the nucleation properties of combustion generated particulates for the identification of their sources was investigated, using the Cloud Condensation Nuclei (CCN) Spectrometer. The Investigated materials included coal, wood, belt materials, electrical insulation, brattice cloth, and diesel exhaust. The materials were heated In an oven using filtered air flow, and their time, temperature, and the critical supersaturation spectrum of condensation nuclei (also referred to as the CCN spectrum) produced by the combusting material were recorded. Some data was obtained on a typical metal-mine background containing blasting products. The data was processed and analyzed In an attempt to specify parameters and limits that would allow the identification of the combustion sources. It appears that under controlled test conditions It Is possible to Identify the source on the basis of data derived from the CCN spectrum. More general use of the Idea for fire detection under uncontrolled practical circumstances in an actual mining environment does have potential but would require further research.

Jan 1, 1978

By J. A. Kost

A survey of 80 coal producers was conducted to determine the extent and scope of respirable dust control research for underground coal mines and the current methods employed to control respirable dust. Results of the survey showed that proper face ventilation and an adequate water spray system are sufficient to comply with mandatory standards in room and pillar mining. Difficulties still exist with longwall equipment, auger miners and buring machines. In these cases, known dust control techniques are not sufficient to obtain compliance. Present state-of-the-art face ventilation and water systems were discussed in addition to the sampling program.

Jan 1, 1980

By E. D. Palmes

A new type of personal sampler for quantitative estimation of atmospheric concentrations of contaminant gases was first reported from this laboratory in 1972. The sampler requires no pumps or flow regulators and employs instead the motion of the gas molecules them-selves to furnish the power for sampling. Under this grant, work was completed on development of a kit for the field determination of both NO2 and NO. Detailed instructions for the preparation of the samplers and the use of the kit was supplied to the Technical Project Officer. Attempts were made to adapt the same type of sampler to the measurement of SO2 and CO. Both gas chromatographic and turbidimetric procedures for the final estimation of the S02 proved to be unsatisfactory. For CO no reagent was found which would react sufficiently rapidly with this gas to utilize the essential feature of the diffusion sampler, the maintenance of a diffusion gradient which is at least approximately numerically equal to the ambient concentration. A number of publications on use of the NO2 sampler, both at occupational and community air pollution levels, have resulted from this work.

Jan 1, 1979

By J. A. Kosek

Work has been carried out under Bureau of Mines Contract HO 395132 to develop improved sensor cells for use in direct-reading detectors and diffusion exposure meters. A pumped CO sensor cell was developed which has a shorter response time, improved temperature cycle characteristics, and improved linearity and stability at high CO concentrations. Diffusion CO sensor cells have shown good response level stability and linearity up to 1000 ppm. In addition, a new sensor cell catalyst has been developed for NO2 sensor cells which has a much shorter response time and improved response stability characteristics.

Jan 1, 1982

By Kevin Hennings

Screening efficiency models developed to date rely almost exclusively on empirical formulas based upon large amounts of acquired operating data. A screening model was developed using a combination of empirical coefficients and explicit mathematical expressions which quantify screening phenomena. A series of screening tests was run to supply data for purposes of correlation and empirical coefficient evaluation. The model has been implemented as a digital computer program. The validity of the modeling procedure has been established by laboratory testing. Results generated by the model have been used to compile an applications handbook, which can be used to predict screening performance in lieu of using the computer program.

Jan 1, 1982

By Allan M. Johnson

Case histories were used to document and evaluate deficiencies in underground mine closures which have resulted in post-operation problems such as subsidence shaft failures, acid or toxic water drainage and others. Three different underground mining districts in the United States were investigated; 1) an iron mining district in Michigan 2) coal mining districts in eastern Ohio and southern Illinois and 3) three metal mining districts in central Colorado. Previous work in the Michigan district on problems with subsidence and acid water drainage provided the background from which the concept for this project was developed Student investigators working towards their MS degrees in Mining Engineering did the work on the eastern coal and western metal districts. The combined studies show that problems from acid water drainage, subsidence and inadequately protected mine shafts are the most severe and widespread. Suggestions of a technical nature are presented as partial solutions to some of these problems. It was determined that pre-closure evaluations could result in the identification of some potential problems that may occur after the mine is closed. Early recognition of these problems would be an advantage for at this time more options are available to the mine operator to either prevent them or to plan for their occurrence. Mine closure and reclamation should be considered as a part of mining and be incorporated in the mining plan. This would result in reduced environmental impact and would be achieved at a lower overall cost to the mining companies and to society. The role of water in the occurrence of several types of subsidence during mine flooding was significant at some mines in the Michigan district. These mechanisms which involve, friction reduction, gravity loading, overburden transport and hydraulic forces in a flooded mine probably have a broader effect than is currently recognized. Control of these processes may offer some interesting options during mine closure. It is recognized that technical solutions alone cannot provide all of the answers to problems associated with underground mines. Education, modified attitudes on the part of regulators and operators, and a more realistic perception of the importance and value of mining by the general public are also needed.

Jan 1, 1983

By Donald James Butler

Problems resulting from underground mines in three inactive mining districts in Colorado were investigated. The purpose was to determine how these problems could be reduced or eliminated in new closings -- essentially by benefitting from lessons of the past. Mines in Leadville, Westcliffe and the Cripple Creek-Victor districts were evaluated. Two basic types of problems were found to exist in the districts: environmental degradation and hazardous conditions. Environmental problems result largely from acid and toxic drainage from the runes and from leaching of surface waste rock piles and mill tailings impoundment. The acid drainage contributes high levels of metals to streams and deposits sediment in the stream bottoms. Erosion of waste piles is a lesser problem. Hazardous conditions from open or improperly sealed mine shafts and adits, mine subsidence pits, and from deteriorating and unsafe surface structures are common to the three districts. These problems become worse with the ravages of time and vandalism. Engineering solutions which would correct or reduce many of these problems are presented. These recommendations should also be applied to new mine closures, however, more basic changes are needed to effectively implement improved mine closures. The changes must take place in the areas of legislation, mining practices and education. Legislated regulations should realistically reflect the needs of both the mine operators, protection of the environment and the best interest of the general public. Benefits should be provided for compliance with regulations instead of penalties being assessed for noncompliance. Hazardous conditions and environmental problems associated with mines can be alleviated through improved mine design and effective cloning procedures. Education should provide an appreciation by the general public of past and present problems facing mine operators. This will result in an improved mining climate which, in turn, will insure a continuing supply of minerals to meet increasing needs.

Jan 1, 1983

By Linneas W. Laage

Coal production from underground coal mines has been important to the development of the industrial economy of the United States. Environmental problems have developed from some abandoned operations. These problems include: mine and refuse pile drainage, subsidence, unsafe mine openings and to a lesser extent mine gases, slope stabilities, mine and refuse pile fires and abandoned equipment and structures. Field investigations in three eastern coal mining districts, two in Ohio and one in Illinois, were performed to document the mine closure procedures used and subsequent problems that developed. The purpose was to identify, evaluate, and rank the seriousness of these problems. Based upon this evaluation, the undesirable present day situations could have been avoided or at least minimized by varying certain mining practices or mine closure procedures. It was found that federal regulations address all of these problems during the pre mining, active mining and post mining phases except for abandoned equipment which is the least threatening problem category. Ideally current practice would prevent future problems. However, the extensive and complicated nature of the legislation, environment and mining practices will necessitate adjustments to the law. The investigator recommends the following: 1) Goal oriented legislation encouraging complete resource extraction, standardization and compilation of mining generated hydrological data, periodic review of the coal mining regulations, and improved communication and cooperation between coal interests, regulators and the public. 2) Permitting effluent limitations to accurately reflect natural conditions. 3) Solidly back filling shafts and individual assessment of sealing or capping requirements. 4) Installing shaft vent pipes into the fill material to intercept and vent methane.

Jan 1, 1982

The Menominee Range of northern Michigan was a major producer of direct shipping iron ore for nearly a century. When the last underground mine on the Range ceased operation in 1978, it marked the end of an era. For since the start of mining in the early 1880's the district has gone through a Lull cycle from the start-up of mining through close-down. During this period over 200 million long tons of iron ore were produced and shipped from nearly 100 mining operations. This development and production spanned the time from when the United States advanced from an essentially rural-agriculatural society through the industrial revolution and into the beginnings of the computer and space age. There are many lessons that can be learned from such a rich history. This report attempts to provide ouch a lesson. Through the use of case histories, deficiencies in past mining practices and mine closure procedures that have resulted in current mine related problems are documented. These problems -an be grouped into three areas; 1) subsidence 2) hydrological or drainage problems and 3) problems related to inadequate mine shaft sealing and capping practices.

Jan 1, 1983

By Russell J. Miller

A high-pressure intensifier system was designed, constructed and field tested as part of a program to determining the feasibility of applying high-pressure water jets on conventional mechanical rock excavation equipment to increase advance rates. Also developed were a high-volume swivel, capable of transferring the high-pressure water to a rotating cutterhead and manifold system for locating and protecting the jets on the cutterhead. Field tests were conducted in a granite quarry near Skykomish, WA, approximately 90 miles east of Seattle. The concept of improving excavation rates by using water jets to assist mechanical cutting was proven to be successful, with an average increase in excavation mete of 50 to 60%. For some tests, the excavation rate was more than doubled. Machine torque requirements were reduced approximately 25% when the water jets were used. It was suggested this was due to reduced cutterhead friction in the presence of the water jets. A comprehensive economic analysis was undertaken as part of a concurrent study to determine the degree of cost benefits attainable from increased advance rates. Very significant savings were seen to be possible. It was concluded that the basic concept of combining a water jet capability with a mechanical excavating machine is definitely possible.

Jan 1, 1976

By James L. Hendrix

A study was made of the United States Bureau of Mines' chlorine-oxygen leaching process for complex sulfide concentrates. The investigation sought to determine the kinetic order and IT mechanisms involved in the reactions betweens sphalerite, and galena with chlorine. The influence of copper on the extraction rates was also studied. It has been shown the rates of reaction of chlorine in aqueous solutions with sphalerite and galena are both zero order at 373K with the rate limiting step being the chemical reaction. Addition of cupric chloride increased the extractions of both lead and zinc.

Jan 1, 1980

By S. Vennos

As a result of Synopsis 73-16 Dynadyne responded with an unsolicited proposal offering the Bureau of Mines to develop an ultra-low volume coal mine dust personal sampler. In the ensuing technical discussions the choice of a desirable volumetric rate became a focal point. While, the initial proposal was based on a volumetric rate in the area of 50 cc/min the Government expressed interest in a variety of mass flow rates ranging from 50 cc/min to 2000 cc/min. The physical characteristics such as weight, volume and configuration of a personal sampler are to a large extent - dependent on the operating volumetric rate. It became readily apparent that the optimum size of such an instrument as a function of volumetric rate was not known and that a study of the choice of optima was essential prior to beginning the development, Hence, the Government authorized a two phase approach to this project. Phase I was to include a Technical Evaluation Study of optimum characteristics in the range between 0. 1 to 2. 0 lpm. Based on these findings and in consultation with MESA personnel, the Bureau of Mines was to authorize the second phase that is, the development. Phase II, was to include the drawing of a set of performance specifications stating among others the desired operating volumetric rate. In this report, every effort was made not only to present the actual work done over the course of this development, but to reflect also our engineering "thinking" providing answers as to the "why" we preferred certain solutions over others. We believe that this added dimension is not only useful for the Government official evaluating this report, but also that the Government is entitled to it providing the official with an educational content useful in avoiding future costly repetitions of similar situations.

Jan 1, 1975

By Steven R. Ruggieri

This report documents the work performed and the results obtained during the field demonstration of the Remote Sealing System at the USBM's Jenny Mine near Inez, KY in the Fall of 1978. Although various portions of the Remote Sealing System had been used on a number of prior occasions, the field demonstration at Jenny Mine marked the first use of the complete upgraded system including the use of the inert gas generating system for seal placement and the first application of the new froth foam system. The objective of the field demonstration at Jenny Mine was to demonstrate the complete system by emplacing and evaluating several complete underground seals under conditions representing those of a mine fire situation. Several critical sealing conditions were identified including: ? High entry airflow ? Standing water (1 to 2 ft) in the entry ? Flowing water (150 gal/min) ? Irregular roof ? Sealing a 4-way intersection. Four seals were successfully placed under the conditions mentioned above. The demonstration served to verify proposed techniques to handle these conditions as well as to dispel any doubts about the system's capabilities. As a result of the successful field demonstration, the Remote Sealing Equipment is now under the jurisdiction of MSHA's Mine Emergency Operation ready for a mine fire emergency.

Jan 1, 1980

By J. A. Kosek

Work has been carried out under Bureau of Mines Contract No. HO395132 to develop and fabricate gas sensors for mining applications. Promising new instruments have been designed, developed, tested and supplied to meet BuMines requirements. These instruments include prototype 1) remote-sensing, diffusion-type CO monitors for mine operation which can be operated in conjunction with a surface computer, 2) control modules for alternate in-mine readout of the remote diffusion type CO monitors, 3) personal CO diffusion-type dosimeters and 4) personal NO diffusion-type dosimeters. In addition, retrofit modifications were made to update and optimize operation of CO and NO2 direct-reading type detectors provided under a previous contract. Studies were conducted to evaluate and demonstrate the availability of stable, portable N02 calibration sources for NO2 instrumentation. The use of selected, commercially available cylinder sources for NO2 instrument calibration were recommended. Additional studies were also conducted to investigate the feasibility of instrumentation for rapidly monitoring CO, NO and NO2 in diesel exhaust.

Jan 1, 1981

By Ferron A. Olson

Natural bornite (Cu5FeS4) leached in ferric chloride or in sulfuric or hydrochloric acid solutions with oxygen showed several differences. In ferric chloride 80 of the copper was leached in two stages. The first (30 copper removal) requiring one minute was controlled by mixed kinetics (liquid ferric ion diffusion and chemical surface reaction). The second was controlled by formation of a surface sulfur layer and then diffusion through the sulfur. With oxygen in sulfuric acid reaction was slow and only the first stage was studied. Copper removal had an induction period. The bornite structure disappeared at 12% copper removal (also found with ferric chloride) and covellite formed on the surface with a species inside the particles having an x-ray structure similar to CuFeS2 but with composition Cu3FeS4 (also with ferric chloride). Copper removal was controlled by iron dissolution. Surface iron vacancies filled with Cu+ to give CuS while interior copper dissolution produced Cu3FeS4. Preliminary results with oxygen and hydrochloric acid showed 80% copper removal and sulfur as end products (similar to ferric chloride).

Jan 1, 1982

Five conclusions that emerged from ADL's Contractor Noise Measurements Assessment done for the Bureau of Mines and the 7 December 1971 Bureau of Mines Contractors' Round Table Meeting in Boulder, Colorado were: ? a limited amount of good data has been obtained for characterizing the noise environment for electromagnetic (EM) coal mine operational/emergency communications systems; ? significant noise date gaps still exist; ? suitable instrumentation and data analysis methods are available for filling these data gaps; ? the immediate and most important data gaps should be filled by means of a timely field measurement effort that is purposely limited in scope and duration; ? this field measurement effort should preferably be carried out by a team knowledgeable and experienced in coal mine EM noise measurements.

Jan 1, 1972