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By Pengfu Tan

In order to understand and control the formation of dioxins and furans in iron ore sinter plants and to possibly avoid expensive end-of-pipe removal stages, thermodynamic calculations on the stability of PCDD/Fs have been combined with sinter process modeling by means of kinetic simulations and computational fluid dynamics. Three thermodynamic databases of PCDD/Fs, derived using the Group Additivity approach and two computational molecular modeling methods, MNDO and PM3, respectively, combined with the SGTE database have been used to model the PCDDIF formation and the PCDD/F isomer distributions in iron ore sintering. The results show very similar conditions for the PCDD/F formation using the different databases. Concerning the isomer distributions of toxic PCDD/Fs, the calculated data derived from the MNDO method showed optimum agreement with measured values from industrial furnaces. The thermodynamic calculations also proved that the isomer distributions found in combustion processes are equilibrium values, while the concentration ratio of PCDDs and PCDFs in the wind boxes does not represent an equilibrium state. A CFD model of iron ore sintering was developed including the kinetics of 15 relevant chemical reactions with the aim of describing the temperature fields and the gas flow patterns in the sintering bed. On the basis of these information and experimental observations reported in the literature possible pathways for the PCDD/F formation in sinter plants have been identified: PCDD/Fs are formed in the critical temperature region of 250 to 450°C below the combustion zone, are then carried downwards with the gas and condensed close to the bottom of the sinter bed. Transported to the discharge end with the solid mixture, they are again released into the gas phase when the flame front approaches the bottom. PCDD/Fs are also formed in the last wind boxes when the hot off-gases cool down and reach the critical temperature range. Consequently, methods to reduce the dioxin formation reactions are proposed including inhibitor addition to the sinter feed and off-gas quenching.

Jan 1, 2003

By Pengfu Tan

In order to understand and control the formation of dioxins and furans in iron ore sinter plants and to possibly avoid expensive end-of-pipe removal stages, thermodynamic calculations on the stability of PCDD/Fs have been combined with sinter process modeling by means of kinetic simulations and computational fluid dynamics. Three thermodynamic databases of PCDD/Fs, derived using the Group Additivity approach and two computational molecular modeling methods, MNDO and PM3, respectively, combined with the SGTE database have been used to model the PCDDIF formation and the PCDD/F isomer distributions in iron ore sintering. The results show very similar conditions for the PCDD/F formation using the different databases. Concerning the isomer distributions of toxic PCDD/Fs, the calculated data derived from the MNDO method showed optimum agreement with measured values from industrial furnaces. The thermodynamic calculations also proved that the isomer distributions found in combustion processes are equilibrium values, while the concentration ratio of PCDDs and PCDFs in the wind boxes does not represent an equilibrium state. A CFD model of iron ore sintering was developed including the kinetics of 15 relevant chemical reactions with the aim of describing the temperature fields and the gas flow patterns in the sintering bed. On the basis of these information and experimental observations reported in the literature possible pathways for the PCDD/F formation in sinter plants have been identified: PCDD/Fs are formed in the critical temperature region of 250 to 450 °C below the combustion zone, are then carried downwards with the gas and condensed close to the bottom of the sinter bed. Transported to the discharge end with the solid mixture, they are again released into the gas phase when the flame front approaches the bottom. PCDD/Fs are also formed in the last wind boxes when the hot off-gases cool down and reach the critical temperature range. Consequently, methods to reduce the dioxin formation reactions are proposed including inhibitor addition to the sinter feed and off-gas quenching.

Jan 1, 2003

By B. K. Chakrabarti

Modeling and a screening design of experiment (DOE) was performed with the process variables to identify the greatest effect of variables on the response quality in the dead burning of magnesite refractory in a rotary kiln. Among various interdependent variable factors, the design variables chosen were raw magnesite (RM) feed rate, kiln rotation time i,e, seconds per rotation(SPM) and burning zone temperature (BZT). The response variables chosen were exit gas temperature and density of dead burnt magnesite(DBM). ANOVA and normal plots were used to evaluate the effects.This work had enabled to correlate the BZT, RPM, RM feed with the exit gas temp and density of magnesite produced. The result opens up an avenue to look into the optimum region of operations within the ranges of variables considered in order to conserve energy and to minimize the exhaust gas temperature and to maximize the density of the DBM produced

Jan 1, 2015

By Michael Goldin, Jonathan Ladner, Thomas Peacock, Nathaniel Johnson, Patrick Haley, Kris van Nijen, Andrew Rzeznik, Pierre Lermusiaux, Matthew Alford, Carlos Munoz-Royo

Surface processing vessels for deep-sea nodule mining operations will produce dewatering plumes that will be released at some depth into the ocean water column. We are studying all aspects of this part of the nodule mining process. First, we have developed analytical and numerical models to determine the effects of highly non-uniform, realistic stratifications on forced, compressible plumes with finite initial size. The classical plume model is developed to take into account the effects of compressibility and thermal conduction through the dewatering pipe. Our results show how small-scale features of a realistic stratification can have a large effect on a plume, and provide a basis for determining at what depth dewatering plumes can be released. These results form the basis for our PLUMEX field experiments, in which we will study the dynamics of dewatering plumes over the course of one week of field tests from the vessel R/V Sally Ride. The field experiments will use a Remotely Operated Vehicle (ROV) and a Phased-Array Doppler Sonar (PADS) system to study the characteristics of the dewatering plumes. The subsequent transport of the material in the dewatering plume will be monitored via shipboard surveys and, potentially, Autonomous Underwater Vehicle (AUV) operations, and these studies will be integrated with near real-time, data assimilating numerical model predictions. The ultimate goal of this project is to develop a field validated, recommend strategy for the release and monitoring of dewatering plumes, to help inform the development of ISA regulations and the planning of industrial operations.

Jan 1, 2017

By Thomas W. Smelser

A full-scale geotechnical model of a 15-foot (4.6 m) wide coal mine entry in correlation with computer finite-element analysis (FEA) is being employed at the Bureau of Mines Spokane Research Center for basic research on roof-bolt support systems. Physical and computer modeling of various coal mine roof-bolt reinforcement systems will increase our basic knowledge of how roof supports function. This information, in correlation with computer FEA and underground verification tests, will provide a basis for establishing safer, more cost- effective roof control plans and help establish guidelines for employing fully grouted and conventional bolting systems. The basic rationale for the research, research approach, methods and equipment employed, results to date, and future research plans are described in this paper.

Jan 1, 1982

By Michael L. Free, Shukla. Abhijeet

The short-circuiting tendency of a copper electrowinning cell (EW) based on the roughness of cathode deposits was investigated with varying parameters such as Cu concentration, guar concentration, current density, and temperature. A bench scale EW cell was set up to produce copper under conditions similar to industrial Cu EW. In addition, a statistical analysis and finite element analysis were performed to analyze the deposited thickness, surface roughness and maximum feature height. Interaction data for the cathode deposits suggest that current density and Cu concentration together affect the roughness of deposit more than the combined effect of guar and temperature. Model predictions of roughness were similar to experimental values. The predicted time to short-circuiting was similar to the measured time. This study provides an industrial relevant baseline against which new operating parameters can be compared.

Jan 1, 2014

By MOHAMED WAEL, ANASTASIA GOEVA, ABDULAZIZ TAWFEEQI, IHTISHAM TARIQ, S. M. ZAKIR HOSSAIN, NIAZ ALI KHAN, MUHAMMAD FAISAL IRFAN

Carbon capture and storage (CCS) is an attractive area of research in such fields as CO2 mineral carbonation, global warming and sustainable energy systems. In this study, carbonation efficiency for aqueous mineral carbonation (MC) was achieved through two steps,which include leaching of calciumfrom cement kiln dust (CKD) followed by the reaction of pure CO2 with the calcium hydroxide precipitates formed by the hydroxylation using NaOH. Response surface methodology (RSM) with a Box-Behnken design (BBD) was applied to optimize the calciumleaching yield,while the carbonation efficiency from CKD was assessed using RSMwith central composite design (CCD). Optimization of calcium leaching is highly important, as it is a rate-limiting reaction step in MC and also influences and enhances carbonation efficiency. Different parameters including acid concentration (HNO3), leaching temperature, leaching time, and dose of CKD sample were considered in order to optimize the maximum yield of Ca leaching from the CKD sample. In addition, different CO2 flow rates and temperatures were used as parameters for optimizing carbonation efficiency. Two quadratic regression models were developed for each process, i.e. calciumleaching and carbonation. For calcium leaching, a maximum of 98.55% calcium was extracted under the optimal set of acid concentration 4.13 M, 90 °C, 28 min leaching time, and 13.8 g of CKD sample. For carbonation, the maximum carbonation efficiency of 89.2% was achieved for a CO2 flow rate of 1163 cm3/min at 90 °C. Calcium leaching results indicate that the leaching yield was significantly affected by all the input parameters except leaching time. For carbonation, both factors affected the carbonation efficiency, with the effect temperature shown to be greater than that of the CO2 flow rate. Additionally, the predicted results agreed well with the experimental values for both calcium leaching and carbonation processes, with errors of less than 1% and 5%, respectively.

Jun 5, 2020

By MOHAMED WAEL, ANASTASIA GOEVA, ABDULAZIZ TAWFEEQI, IHTISHAM TARIQ, S. M. ZAKIR HOSSAIN, NIAZ ALI KHAN, MUHAMMAD FAISAL IRFAN

Carbon dioxide (CO2) mineral carbonation is a carbon capture and storage (CCS) technique that can sequester CO2 permanently in the form of durable carbonate minerals. Extendable permanent storage capacity — onshore and offshore storage reservoirs — and the exothermic nature of the mineralization process make this technique attractive [1]. In the present study, maximum carbonation efficiency for aqueous mineral carbonation was achieved through two steps: optimization of calcium leaching from cement kiln dust followed by the reaction of pure CO2 with the calcium hydroxide precipitates formed by hydroxylation using sodium hydroxide (NaOH). Optimization of calcium leaching is highly important, as it is a rate-limiting reaction step in mineral carbonation and also influences and enhances the carbonation efficiency. To maximize the calcium leaching as well as carbonation efficiency, response surface methodology — with either Box-Behnken design or central composite design — was applied. It is the most well-known statistical, fully randomized and bias-free method for determining optimized conditions using quadratic regression models.

By S. K. Sharma, R. Markandeya, G. Venkateswara

"In this study, a three level Box- Behnken factorial design combined with Response surface methodology (RSM) for modeling of process parameters of Multi Gravity Separator (MGS) for recovery Iron values from sub grade iron ore, Deposit No. 5, Bailadila complex has been developed. The three significant operational parameters of MGS, Drum rotational speed (RPM), Drum inclination (degrees) and quantity of wash water (LPM) were considered in the experimental work. Other parameters like feed percent solids, shake frequency and shake amplitude were maintained constant. The ‘as received’ sub grade iron ore sample is admixture of lump and fines and chemically assayed 40.80% Fe, 40.90% SiO2, 0.24% Al2O3 and 0.22% Loss on Ignition (LOI). The obtained results were evaluated with the Box-Behnken factorial design, RSM and also Quadratic programming(QP). Second order response functions were produced for Fe in terms of grade (%) and recovery (%) of the concentrate fraction. Taking advantage of QP, it was observed that maximum grade of 62.21% Fe achieved at an inclination of 4.3degrees, 2.7LPM of wash water and at a drum speed of 198 RPM. Similarly a maximum Fe recovery of 65.37% weight can be achieved at 4.3degrees inclination, 2.6LPM wash water and at a rotational speed of 212 RPM Predicted values of responses obtained using model equations were in good agreement with the experimental values. The influence of the process variables of the multi gravity separator concentrator on grade and recovery of concentrate fraction were presented and discussed."

Jan 1, 2014

By Peter A. Amelunxen, Richard LaDouceur, Courtney A. Young

"Many of the rare earth elements, the lanthanide series on the periodic table, are on the U.S. Department of Defense Strategic and Critical Materials list. In this regard, the U.S. Army Research Laboratory (ARL) has funded several projects at Montana Tech focusing on rare earth element recovery from natural resources. Current froth flotation operations utilize octyl hydroxamate for rare earth mineral extraction, however recovery is not ideal and flotation performance can be improved. Salicylhydroxamic acid (C7H7NO3) was identified as a novel collector due to similarities with n-octyl hydroxamate, notably the amine head group. Salicylhydroxamic acid is primarily used in the medical industry but due to the amine head group is ideally suited as a collector for rare earth mineral flotation.Parametric studies were performed for the flotation of rare earth minerals by modifying a wide range of variables. Mechanical variables of a 6L bench scale flotation cell, such as air inlet flow, rotor speed, and milling time for liberation were modified to elucidate energy input parameters for the desired minerals. Chemical parameters such as collector concentration and pH were varied to understand solution chemistry considerations of the salicylhydroxamic-rare earth mineral system. The study obtained a statistically significant experimental model for the flotation of rare earth minerals. A two stage compartmental model was also utilized for the determination of the first order flotation rate constants for each mineral. Optimized recovery of rare earth minerals was found to occur at near neutral pH ranges using salicylhydroxamic acid with maximum recoveries approaching ideal industrial standards although rare earth mineral grades were still not sufficient.INTRODUCTIONRare earth elements (REEs) are found in minerals that contain several REE which makes costeffective separation of the rare earths difficult. Significant scientific challenges have hindered mineral separation. The molecular similarity of rare earth elements results in minerals containing several REEs, such as bastnaesite [(Ce, La) CO3F]. This prevents efficient separation during concentration steps, for instance flotation, and has a direct impact on successive metallurgical processes. Consequently, concentration during flotation is of rare earth minerals (REM) as opposed to REE."

Jan 1, 2016

By Abraham Lindo

"Blasting plays a key role in hard rock underground mining. It is by nature a violent and destructiveextraction method designed to economically fragment the rock into a suitable size for it to be loaded and hauled as part of the specific mining process while controlling the amount of damage to the surrounding rock mass."

Jan 1, 2016

By C. Konya, A. Konya

"INTRODUCTION Over the past twenty years this Linear-Regression Modeling has become widely accepted for ensuring limits are not exceeded at a site, using the Scaled-Distance variable. In today’s industry, numerous equations are present for different scenarios, geologic environments, hole sizes, and numerous other factors with an emphasis on site-specific equations developed for all major projects; however, underground blasting applications have not been analyzed to a great degree of detail. Without previous knowledge this puts underground blasting operations into a guessing-game to ensure that vibration levels are not exceeded. This paper will review two recent projects that have been worked on by the authors and linear-regression models that were used with both burn cuts and stope blasts. BLAST VIBRATIONS MODELING The first major research project conducted in the United States on blasting vibration was Bulletin 442 (Thoenen & Windes, 1942) which looked at the relationship between blasting and blast vibrations in the fall of 1940. This study examined numerous blasts and began the investigation into topics such as damping, structural damage from vibrations, frequency dependency on vibration, resonance vibration, delayed blasting, and numerous other factors. Bulletin 442 had two major conclusions which are: 1. The vibration from a blast can be predicted with a relationship of size of the shot and distance to the structure (now known as scaled distance) 2. “The vibration of a structure at resonance does not in itself cause damage because of the restraining effect of damping inherent in the building” (Thoenen & Windes, 1942) Due to the increase of blasting near homes and busier areas the USBM commissioned an additional study to further develop a few of the topics covered in Bulletin 442; this study would go on to be published as RI 6561 (Duvall, Johnson, Meyer, & Devine, 1963) with the study looking into delayed blasting and the relationship between charge weight, distance, and peak particle velocity of the blast. This relationship would be termed as the ‘scaled-distance’ and take the form of:"

Jan 1, 2018

By C. Özgen Karacan

Methane emissions from a longwall ventilation system are an important indicator of how much methane a particular mine is producing and how much air should be provided to keep the methane levels under statutory limits. Knowing the amount of ventilation methane emission is also important for environmental considerations and for identifying opportunities to capture and utilize the methane for energy production. Prediction of methane emissions before mining is difficult since it depends on a number of geological, geographical, and operational factors. This study proposes a principle component analysis (PCA) and artificial neural network (ANN)-based approach to predict the ventilation methane emission rates of U.S. longwall mines. Ventilation emission data obtained from 63 longwall mines in 10 states for the years between 1985 and 2005 were combined with corresponding coalbed properties, geographical information, and longwall operation parameters. The compiled database resulted in 17 parameters that potentially impacted emissions. PCA was used to determine those variables that most influenced ventilation emissions and were considered for further predictive modeling using ANN. Different combinations of variables in the data set and network structures were used for network training and testing to achieve minimum mean square errors and high correlations between measurements and predictions. The resultant ANN model using nine main input variables was superior to multilinear and second-order non-linear models for predicting the new data. The ANN model predicted methane emissions with high accuracy. It is concluded that the model can be used as a predictive tool since it includes those factors that influence longwall ventilation emission rates.

Building block cave operations involves significant commitments to capital and time before arriving at completion or full scale production. The focus of the mine planners is habitually to minimize the upfront capital and achieve target development rates and construction dates. However, management of the construction of block cave projects requires understanding of the strategic/tactical decisions that the project planners can take to increase the value of the project and cope with schedule risks. As block cave projects involve development of vertical and lateral access to the underground footprint and ore body, more attention to uncertainties is required as most of those projects need to confront delays leading to a decrease in value. The standard process of development and construction scheduling is often not planned with provisions to realise uncertainties in the construction phase. Uncertainties and risks such as poor ground conditions and equipment breakdowns are the primary reasons for schedule slippage. As a result most of these projects experience delays. In order to mitigate risk to the project schedule, we centre our attention on increasing the value of the project by spending more money upfront and improving the schedule rather than focus on minimizing the upfront capital. Scenario-based simulations along with project appraisal methods hold great promise to address those challenges and enable mine planners to make better decision and enhancing project value. This paper will present a hybrid simulation based approach to model the process of development and construction based on discrete event (DES) and continuous based simulations (CBS). Such simulations will be conducted for scheduling multiple development headings (Apex, undercut, extraction, and haulage levels). Two scenarios are utilized to investigate the impact of risks on schedule and how flexibility in construction can be incorporated to minimize delays: (1) The bench mark scenario is created based on actual data from an existing case study. (2) The flexible scenario is an alternative way to use primary production infrastructure (Ore Handling System) including conveyer drifts, conveyer belt, and a gyratory crusher in the construction process and that requires the system to be in place before starting lateral development in the footprint. As a result, a truck-load system versus a conveying system will be studied to observe the gain in construction speed and to estimate the premium cost for mucking rock from headings and drawbells and transporting it to surface. Such strategic flexibility would be part of the original budget to make the tactical flexibility available during construction. Continuous cash flow models are used to evaluate and compare the scenarios. This study is an example of how new techniques in planning can be used to support decision-making processes in block cave design.

Aug 1, 2013

By Lei Wang, Xiancong Zhao, Hongxu Li, Lifeng Zhang

Recovery of Fe from red mud has been studied using statistically designed experiments. The effects of three factors, namely: reduction temperature, reduction time and proportion of additive on recovery of Fe have been investigated. Experiments have been carried out using orthogonal central composite design and factorial design methods. A model has been obtained through variance analysis at 92.5% confidence level.

Jan 1, 2015

By Milind Chikhale, Yogesh Reja, Keshav Tyagi

"Using computer models for process design is a well-established practice in the mineral industry. In recent years, there has been emphasis on modeling of processing plant as a whole. This paper covers development of a model for iron ore processing plant. Basic purpose of this model is to use simulation for efficient plant design and help in minimizing risk at the very initial stage of project. Feed to the plant is Hematite iron ore from a deposit located in Eastern India. Major processes in plant include multi-stage crushing, screening, grinding, classification, gravity and magnetic separation. Models for different process equipment were developed using METSIM and Bruno simulation software. Customized black box models and known mathematical models were used for predicting behaviour of processes. Data needed was identified based on the model type. The required data was arranged as per project requirement and processed for development and validation of model. Equipment models were developed and validated on the basis of process design basis, theoretical and empirical data from technical references, and bench scale and pilot scale testwork results. Validated process circuits were assembled to simulate and represent the entire plant process. The result shows expected variation in plant output as a result of variation in the feed. Study concludes by discussing potential applications of the model in plant design."

Jan 1, 2014

By Autumn Fjeld

The filling and solidification of an industrial scale composite casting has been simulated to investigate the re-melting of the outer shell material during casting. Production of a composite requires a two-step casting process which includes centrifugal casting of a hard outer shell material and subsequent conventional ingot casting of a tough core material into the shell-mold assembly. During casting of the core, a thin layer of the shell material re-melts and mixes with the core material producing a bonding layer of intermediate composition. The present numerical model employs the volume of fluid method and an enthalpy-porosity technique to couple the filling of the core material and re-melting of the shell material. The interface between the two materials is tracked and can be used as a guide to examine the extent of melting and, to some degree, mixing of the two fluids and species diffusion.

Jan 1, 2008

By Venkata S. Buddhiraju

Pelletization of iron ores involves balling on a rotating disc to produce wet pellets and induration of wet pellets on a moving grate to produce fired pellets. The quality of pellets produced and the productivity of the pelletization process depend strongly on the characteristics of the feed to the pelletization disc, especially the particle size distribution and the moisture content. The upstream processes involved in the preparation of pelletization feed include grinding, thickening and filtration of the iron ore slurry. The focus of the present work is the closed circuit wet grinding of iron ores. The circuit consists of a primary ball mill, a regrind mill and a hydrocyclone. A population balance model was developed to predict the grinding kinetics and an empirical model was fitted for the separation of fine particles from the coarse particles in the hydrocyclone. Batch grinding kinetics experiments were performed on a laboratory scale ball mill to obtain the ore breakage parameters which were subsequently used for the simulation of the industrial mills. The models were customized for the industrial operations and the effects of different process variables like feed flow rate, water flow rate, etc., on the size distribution of product from the grinding circuit were studied. Additionally, different circuit configurations were simulated to determine operating conditions that could result in the desirable product particle size distribution. The results of simulation were in close agreement with plant observations and the new circuits explored through simulation have helped in identifying potential opportunities for process optimization and control

Sep 1, 2012

By H. Chaouki

The aim of this work is to simulate the forming process of a green anode. For this purpose, a nonlinear compressible viscoelastic constitutive law is presented. The concept of natural reference configuration is considered. Within an isothermal thermodynamic framework, a Helmholtz free energy is proposed to take into account the nonlinear compressible deformation process occurring between natural reference configuration and current configuration. A dissipation potential is introduced in order to characterize the irreversible aspect of compaction process. Thus, the constitutive law is formulated through two equations: 1) an expression of Cauchy stress tensor and 2) a differential equation characterizing the evolution of the natural reference configuration. Material parameters are assumed to be a function of the bulk density. This allows capturing the micro-mechanical phenomena within the chosen macroscopic approach. An experimental study based on compaction tests is carried out in order to characterize the mechanical behaviour of the anode paste. A user's material VUMAT subroutine for finite element dynamic explicit analysis has been developed and implemented in the ABAQUS commercial software. To evaluate the model predictive capability, numerical simulations of the compaction forming process of anode paste were performed. Simulation results show that the constitutive law predicts the experimental trends and gives interesting physical responses. This constitutes a first step toward making a benchmark with experimental results on the forming process of anode paste.

Jan 1, 2011

By Tad S. Golosinsk

Use of computers for hoist evaluation and design dates back to the early 1960's. Mine hoist production calculations, repetitive in nature, were computerized first. More elaborate modeling of hoist operations followed soon. Typical for this, early period are the models described by Touwen (1973), and by Albert and McIvor (1984). Apart from the simple hoist production calculations, the models were very complex, typically written in Fortran, and often required advanced computing facilities and expertise to run the simulation. The early models were strictly deterministic, with no consideration given to the random nature of hoisting operations. The effects of randomness of the hoisting process on hoist performance were often accounted for by introduction of the deterministic factors, most notably of an "utilization factor" related to the hoist production. The value of the latter was based on observations of actual hoist performance, and could vary in a wide range. For example Harvey (1973) reports values of the "utilization factor" to be between 0.7 and 0.92.

Jan 1, 1989