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By Rauf Hurman Eric

The high temperature liquid miscibility gap in the Ag-Ag2S pseudobinary portion of the Ag-S system has been redetermined by very carefully conducted equilibration-quenching experiments. Samples were contained in evacuated and sealed silica capsules. The stratified liquid phase compositions were obtained by chemical analysis. The miscibility gap extends from 14 to 32.3 atomic percent at the monotectic temperature of 906°C and closes at around 1320°C.Thermodynamic properties of the liquid solutions, including the limiting activity coefficient of sulfur in molten silver were expressed analytically by using the sub-regular solution model which proved to be in excellent agreement with the experimental findings.

Jan 1, 2006

By N. B. Gray, I. F. Taylor

"Gas injection to promote chemical reactions or mixing is a feature of many metallurgical processes. Often the aim of gas injection is to bring about a chemical reaction between the gas and liquid but most of the past physical and mathematical modelling work has ignored the influence of such reactions. In the work reported here, cold model studies have been conducted in which gas reacts with the liquid into which it was injected. The rate of liquid mixing has been measured as an indication of the mechanical energy transfer. It has been found that gas generated chemically within the liquid is significantly less effective at promoting mixing than the equivalent volume of inert gas. The relative ineffectiveness of chemically produced gas is thought to be due to smaller bubble sizes in comparison to the inert gas case. Small bubbles characteristic of chemically generated gas move with low slip velocities relative to the liquid and lead to different turbulence generation mechanisms.IntroductionIn processes such as steelmaking, copper conversion, bath smelting and ladle steel finishing gas is injected into liquid metal where it reacts chemically or simply serves as a source of agitation. An understanding of fluid flow phenomena in such situations is an essential pre-requisite to the calculation of process intensity and the optimisation of vessel productivity. Traditional physical cold modelling approaches to prediction of liquid flow in such situations are now often augmented by the techniques of computational fluid dynamics. Even with the availability of numerical modelling techniques cold physical models continue to have an important role for validation because it is generally difficult to obtain quantitative data from high temperature processes.Almost all previous cold modelling work has been based on the injection of an inert gas into water or some other non-reactive liquid. Such models do not include the significant increase in gas volume inherent in some processes. For example the oxidation of carbon in steelmaking leads to a twofold increase in molar gas flux through the reaction:"

Jan 1, 1996

By Shinya Hodoshima

A catalysis pair of tetralin dehydrogenation / naphthalene hydrogenation has been proposed in the present paper as a liquid organic hydride for operating stationary fuel cells. Catalytic naphthalene hydrogenation, having been commercialized since the 1940s, proceeds to generate decalin via tetralin as an intermediate. The storage capacities of tetralin (3.0 wt%, 28.2 kg-H2 / m3) are lower than decalin (7.3 wt%, 64.8 kg-H2 / m3) but both tetralin dehydrogenation and naphthalene hydrogenation are much faster than the decalin / naphthalene pair. Moreover, existing infrastructures such as gas stations, chemical tankers and tank lorries are available for storage, transportation and supply of hydrogen. With respect to the stationary fuel cells with large space for hydrogen storage, tetralin as a hydrogen carrier is superior to decalin in terms of fast hydrogen supply or power density. Rapid hydrogen supply from tetralin under mild conditions was only accomplished with the carbon-supported metal catalysts in the ?superheated liquid-film states? under reactive distillation conditions. In contrast to the ordinary suspended states, the catalyst layers superheated in the liquid-film state gave high catalytic performances at around 250OC. As a consequence, both serious coke formation over the catalyst surface and excessive consumption of exergy were prevented simultaneously.

Jan 1, 2006

By Frederick O?Neil

SCOPE OF THIS REPORT THE object of this paper is to describe the present status and possibilities of liquid oxygen as an explosive based upon the investigations, research and practical work of the Ingersoll-Rand Co., and of the Air Reduction Co., from early in 1922 to date. The following work was done. 1. A study of the history and physical theory of L. 0. X. as an explosive. (No attempt will be made in this paper to give the history or theory, as this has already been covered by the literature on the subject.) 2. An investigation of the use and the practice with L. 0. X. in the iron mines of Lorraine where L. 0. X. has its largest application in Europe. Although L. 0. X. is extensively employed in the; iron mines of Lorraine, many of the mines using it exclusively, and blasting with it a total of approximately three million tons of iron ore per year, the fact that the mining practice in Lorraine1 is to drill comparatively shallow holes and blast only a few holes at a time, renders the data obtained there of very little value in estimating the possibility of replacing dynamite with L. 0. X. in American mining methods. In fact, in the iron mines in Lorraine, L. 0. X. replaced black powder, or its equivalent. 3. Laboratory research work on properties of absorbent materials. 4. Work in the Bureau of Mines explosive laboratory at Pittsburgh, Pa., on the properties of L. 0. X. cartridges. 5. Practical work underground with L. 0. X. cartridges in the Witherbee-Sherman iron mines at Mineville, N. Y. 6. Practical work in the quarries of the Calcite Quarry Co., Myers-town, Pa. 7. Practical blasting in several quarries and open-pit mines.

Jan 2, 1926

By George Holderer

THE Enos Coal Mining Co. owns an area underlaid by coal, of approximately 5000 acres. This property is situated 9 miles from Oakland City, in the southern part of Indiana. The mine has been in operation 5 years, during which time some 350 acres have been stripped, and stripping is now proceeding at the rate of about 100 acres per year. TOPOGRAPHY These coal lands consist of gently-rolling agricultural fields which in times past were farmed for wheat. There is no timber and but very little brush to contend with. The overburden varies from 10 to 60 ft. in depth. A thin bed of slate overlies the coal, followed by limestone, which varies from 3 to 15 ft.; this, in turn, is followed by sandstone, slate, shale and clay. There is a very wide variation in the thickness of all of these beds. The coal has an average thickness of 5 ft., and is a good grade of high-volatile bituminous. MINING OPERATIONS Briefly, the sequence of operations is: drilling holes with churn drills; blasting with L. 0. X.; stripping overburden to, uncover coal and, finally taking up the coal, which is sent to a tipple for cleaning and sizing. In order to show what is being accomplished by the use of L. 0. X., results will be shown from May to November, 1926, inclusive, and compared to the same period in 1925. No work was done in No. 1 pit during May, 1925, hence all figures are unduly low for this month.

Jan 2, 1927

By George Holderer

THE Enos Coal Mining Co. owns an area underlaid by coal, of approximately 5000 acres. This property is situated 9 miles from Oakland City, in the southern part of Indiana. The mine has been in operation 5 years, during which time some 350 acres have been stripped, and stripping is now proceeding at the rate of about 100 acres per year. TOPOGRAPHY These coal lands consist of gently-rolling agricultural fields which in times past were farmed for wheat. There is no timber and but very little brush to contend with. The overburden varies from 10 to 60 ft. in depth. A thin bed of slate overlies the coal, followed by limestone, which varies from 3 to 15 ft.; this, in turn, is followed by sandstone, slate, shale and clay. There is a very wide variation in the thickness of all of these beds. The coal has an average thickness of 5 ft., and is a good grade of high-volatile bituminous. MINING OPERATIONS Briefly, the sequence of operations is: drilling holes with churn drills; blasting with L. 0. X.; stripping overburden to uncover coal and, finally taking up the coal, which is sent to a tipple for cleaning and sizing. In order to show what is being accomplished by the use of L. 0. X., results will be shown from May to November, 1926, inclusive, and compared to the same period in 1925. No work was done in No. 1 pit during May, 1925, hence all figures are unduly low for this month. Drilling There are in use 8 No. 44 Loomis clipper drills, caterpillar traction with gasoline engines; recently these were equipped with extra heavy stems, measuring 26 ft. overall and 4 ½ in. dia., to increase the speed of drilling. In addition, 4 No. 1 ½ G non-traction drills have been acquired, and are used to save the time of the larger drills when recleaning is necessary.

Jan 1, 1927

By A. J. Duncan, S. Viswanathan, Q. Han

"Measurements of liquid permeability in the mushy zones of Al-15.42% Cu and Al-8.68% Cu alloy samples have been performed isothermally just above the eutectic temperature, using eutectic liquid as the fluid. A modified method has been developed to determine the specific permeability, Ks, as a function of time during the test from the data collected on these alloys. Factors affecting permeability measurements are discussed. Permeabilties are observed to vary throughout the experiment. This is attributed to rnicrostructural coarsening and channeling that occurs in the sample during the experiment. The permeability is related to the rnicrostructure of the sample using the Kozeny-Carman equation. The correlation between the measured Ks, liquid fraction, gL and the specific solid surface area, Sv, improves markedly when compared to previous studies in which rnicrostructural coarsening was ignored.IntroductionThe permeability of interdendritic liquids flowing through dendritic structures ·is an important parameter needed to predict the level of porosity in castings. The permeability is a component of Darcy's Law, used to estimate the pressure drop due to the resistance to the flow of interdendritic fluid to feed shrinkage. Therefore, much research has focused on measuring the permeability of alloys in the mushy zone (1-10). The Kozeny-Carman equation for liquid permeability in the mushy zones of alloys may be written as"

Jan 1, 1999

By C. E. Capes

Reduction in the quality of resources and attendant increase in the quantities of fines to be processed present a major economic and environmental challenge for resource - based industries. It is becoming evident that agglomeration by immiscible liquid wetting will play a significant role in the treatment of these fines. Liquid phase agglomeration can be adapted to separate solids or liquids in highly divided form from liquid suspensions and emulsions. Diverse opportunities in coal fines recovery, novel fuels technologies and oily waste water treatment are cited here. The oil agglomeration of extreme fines from coal tailings, with consequent dramatic reduction in refuse for disposal, is now a commercial reality. It is suggested that this approach can serve as a prototype for the processing of extreme fines in an economical and environment ally sound manner.

Jan 1, 1989

By Peng Fan

Liquid phase tends to migrate from an aggregate of solid particles immersed in a liquid phase into another aggregate composed of the same solid particles and liquid but with smaller particle sizes and/or lower volume fraction of the liquid phase. This type of liquid migration in a two phase system can be attributed to the driving force for the system to decrease its total interfacial energy. With liquid migration pressure as a convenient measure for the total interfacial energy of a solid-liquid two-phase system, liquid migration can be attributed to the existence of liquid migration pressure gradient in the two-phase system. The kinetics of liquid migration is of great practical importance for many industrial processes, one of which is the liquid phase sintering of functionally graded WC-Co composite materials. During liquid phase sintering, WC-Co composite forms a typical solid-liquid two-phase system where solid particles of WC are immersed in liquid Co. For a sample composed of two layers of WC-Co with the same Co content but different WC particle size, Co gradient will be formed during liquid phase sintering; while for a sample composed of two layers of WC-Co with the same WC particle size but different Co content, the Co gradient will be eliminated during liquid phase sintering. The formation and elimination of Co gradient are controlled by the liquid migration pressure gradient. This paper describes a numerical simulation of the kinetic process of the formation and elimination of cobalt gradient.

Jan 1, 2006

By E. Keskinkilic

"Electrical steels are used in motors, power generators, and transformers for electrical applications owing to their superior magnetic properties. These properties are attributed to the presence of a significant amount of silicon in the steel composition. Silicon steels are mainly grouped into two categories: grain-oriented (GO) and non-grain-oriented (NGO). The Si content of silicon steels is generally between about 0.50% and 6.5%. Therefore, silicon steels are further classified as low-, medium-, and high- Si steels. In this paper, liquid steel processing practices for certain silicon steel grades are outlined by considering a steelmaking company that integrates a basic oxygen furnace (BOF), a ladle furnace (LF), and an RHtype degassing unit (RH). Possible problems are identified, suggestions are discussed, and conclusions are drawn on the basis of real plant data. IntroductionSilicon steels are widely used in motors, power generators, and transformers for electrical applications owing to their superior magnetic properties. They are mainly grouped into grain-oriented (GO) and non-grain-oriented (NGO) silicon steel grades. However, the differences in the properties and thermomechanical production of GO and NGO grades are outside the scope of this paper. In this study, liquid steel processing of certain silicon steels will be discussed. In the integrated iron and steelmaking process, converters are the primary steelmaking units that are used mainly for decarburization and removal of phosphorus, and for obtaining liquid steel with a specific chemical composition and suitable temperature for secondary steelmaking operations. Ladle furnaces are a type of ladle metallurgy station consisting of electrical and/or chemical heating facilities for adjusting the liquid steel temperature during alloying. Various types of vacuum units are used for decarburization and removal of nitrogen, hydrogen, and sulphur, depending on the metallurgical conditions of the vacuum units. In this study, an actual steel-production company is considered in which the primary steelmaking operation uses a basic oxygen furnace (BOF) converter with N2/Ar bottom blowing, and the secondary steelmaking operations involve (1) a ladle furnace (LF) heated by three graphite electrodes and equipped with Ar and N2 top/bottom mixing facilities, and (2) an RHtype (circulation) vacuum degassing unit equipped with a top-blowing attachment for oxygen blowing and an Ar-purging system from an up-leg snorkel."

Jan 1, 2018

By Stanley Griff, William Herrera, William O. Seals

"The Navy initiated liquid propellant research in the early 1940's. The first promising Navy liquid propellant, Otto Fuel II, was developd in the early 1950 as a potential torpedo fuel. Later, the Navy developed a HAN based liquid propellant designated NOS-365, a hydroxylammonium nitrate, isopropylammonium nitrate and water formulation. A large gas volume generated by this propellant produced a large wake behind the torpedo. As one can readily understand, this negated the useof the propellant for this application. Recognizing the large gas volume as a desirable propulsion system for guns, the Navy embarked upon a gun propellant proqam. Utilizing a bulk loaded gun sysytem, the program failed when the gun was destroyed by the propellant detonating."

Jan 1, 1990

By M. M. Papic, G. M. Kimber

"Hat Creek coal was treated by the liquid solvent extraction process in a continuous plant at the U.K. National Coal Board Coal Research Establishment.Extraction levels of over 80 per cent dry-mineral-matter-free (dmmf) coal were achieved.Total light oil yield was around 47 per cent of the dmmf coal. The light oil was shown to be a good feedstock for secondary refining into gasoline, jet fuel and diesel fuel.In spite of the high mineral matter content of the coal the solid residue was successfully removed from the coal extract by filtration.IntroductionBritish Columbia Hydro (BCH) and the National Coal Board of Great Britain (NCB) undertook a joint project to test the Hat Creek coal from British Columbia in the NCB's coal liquefaction process designed to produce transport fuels and feedstocks for the chemical industry by the liquid solvent extraction of coal(1), In this process most of the coal is dissolved in an aromatic solvent and the residual solids consisting of mineral matter and undissolved coal are removed by filtration. The resultant coal extract solution is fed to a hydrocracker for conversion to light liquid products and a fraction suitable for recycling as solvent. The light liquid products can be converted to gasoline and diesel fuel in a secondary refining stage.The dissolution of the coal is effected by heat-treating a slurry at a temperature in the region of 400°C which causes some bonds in the coal to rupture with the formation of radicals(2,3). These radicals are stabilized by hydrogen transfer from the hydroaromatic groups in the solvent, resulting in a reduction in the molecular weight of the coal. In the absence of donor groups the radicals combine to form an insoluble high molecular weight product(4). From studies of the kinetics of these reactions it has been shown that the formation and stabilization of the radicals is rapid at temperatures around 400°C(2,3). The dissolution of the depolymerizing coal is, however, relatively slow and the need to ensure complete dissolution in order to achieve a high extraction restricts the selection of digestion time(5). Further, it is important that digests do not contain depolymerizing coal as it may re-form under the applied stress in the filter cake inhibiting flow through the bed and resulting in low filtration rates(6).Thus, in practice relatively long digestion times are generally required in order to ensure complete dissolution of the depolymerizing coal, while it is also important to avoid depletion of the hydrogen donor groups in the solvent which would lower the rate of hydrogen donation to the coal and thus reduce the extraction yield and adversely affect the filtration(7). Clearly it is desirable to optimize the digestion time and temperature with regard to the extraction yield and filtration properties.The precise control of the distribution of products from the hydro-cracker is important for the composition of the recycle process solvent. The principal functions of the solvent are to provide a source of donatable hydrogen and a vehicle for the dissolution of the depolymerizing coal. Hydrogen transfer from the solvent, achieved by the conversion of hydroaromatic to aromatic groups, stabilizes the radicals formed by thermal cleavage of some of the bonds in the coal resulting in a progressive reduction in the size of the coal molecules(8,9) and dissolution in the solvent. The combination of radicals would result in the formation of insoluble material and a reduced extraction yield of the coal(4). Thus to achieve a high extraction yield the solvent should contain sufficient hydrogen donor groups to prevent extensive radical combination. The composition of the solvent should also be controlled to allow dissolution of the depolymerizing coal and to prevent precipitation of this material during the subsequent processing of the coal digest and extract solution. The formation of a precipitate not only reduces the extraction yield of the coal and adve"

Jan 1, 1985

By F. L. Jackson

The large scale transportation and storage of sulphur in the liquid state is a relatively new development, but is really only a logical extension of old mining and processing techniques, It is not known who the first person was to win a relatively pure sulphur from ore by melting, but this method was commercially used at least two hundred years ago in Sicily and is still in use today. The Frasch process of mining was invented over sixty years ago, and the development and improvement of-liquid sulphur pumping and handling techniques has paralleled the growth in the Frasch mining industry. During the last fifty years, improvements in the technology of using sulphur have included the premelting of sulphur prior to its being burned for acid production or conversion into CS2 and other compounds. Yet, until fairly recent times, sulphur produced as liquid has been solidified into large blocks at the producing point, broken down by blasting or with mechanical equipment, and shipped in bulk form as a solid.

Jan 1, 1962

By L. S. Fountain

A national survey, 1978-1980, found 180,973 waste impoundments used by industrial mining, municipal and other interests. Possibly 27,000 contain hazardous materials. The potential hazard of leaks polluting water supplies is a growing concern. An electrical technique was developed to efficiently and speedily detect and locate leaks in geomembrane-lined liquid impoundments without emptying the contents. A potential applied between the liquid and earth causes electric current to flow through leaks in the insulating geomembrane material to ground. The cur- rent density around the leak is used to detect and locate the leak. Field tests show single and multiple leaks 2.54 cm in diameter or less can be detected and located to within less than 30 cm.

Jan 1, 1986

Protect mine rescuers from heat-induced stress that drastically cuts their endurance and saps their strength. Approach To prevent exhaustion caused by thermal stress, a rescuer can wear a liquid-cooled hood and vest which absorbs heat, thereby reducing the heat-induced strain on the rescuer's heart and circulatory system. How It Works Liquid coolant is continuously circulated through a self-contained system in which the coolant is chilled by a heat sink on the wearer's belt. The coolant, which is a mixture of alcohol and water, is pumped from the heat sink to bladders inside the hood and vest where it absorbs body heat. After absorbing heat In the hood and vest areas, the coolant returns to the heat sink where it is rechilled by passing through a tube coiled around a steel can containing a block of ice. To adjust the temperature of coolant leaving the heat sink unit, a valve can be operated by the wearer, causing part of the flow to bypass the coil. A small pump and a rechargeable battery are also part of the assembly.

Jan 1, 1979

By N. B. Devi

The extraction of copper(II) from sulphate solution was investigated using LIX®984N in kerosene. The parameters that could affect the extraction, such as equilibrium pH, extractant concentration, salt concentration, various diluents, and temperature, were separately investigated. On the basis of slope analysis, the complex formed in the organic phase is proposed to be CuR2, where R is the anionic part of LIX®984N. The extraction equilibrium constant and Gibbs free energy ( G) of the extraction process were determined. The positive value of H obtained from temperature variation studies showed that the extraction process is endothermic. The extraction of copper was lowest when chloroform was used as the diluent. Separation and recovery of copper from a synthetic copper-nickel solution containing 6.35 g/L Cu(II) and 0.58 g/L Ni(II) was carried out using 20%(v/v) LIX® 984N. The separation factor ( = DCu/DNi) was found to be pH-dependent. A two-stage batch countercurrent extraction was carried out at an O:A ratio of 3:4 at equilibrium pH 1.05 for extraction of copper from copper-nickel solution, followed by copper stripping from the loaded organic phase with 15% H2SO4 at an O:A ratio of 3:1.

Jan 1, 2014

By Alexandre Chagnes

The extraction properties of two synthesized cationic exchangers, i.e. bis (1,3-dibutoxypropan-2-yl) phosphoric acid (BiDiBoPP) and bis(1,3-diisobutoxypropan- 2-yl) phosphoric acid (IPA), have been studied for the liquid-liquid extraction of Co(II), Ni(II) and Mn(II) contained in 1 M HCl. A comparison of the extraction properties of these extractants diluted in kerosene with Cyanex® 272 shows BiDiBoPP and IPA extract advantageously at lower pH than Cyanex® 272 and a better Co(II)-Mn(II) separation is achieved using BiDiBoPP or IPA than with Cyanex® 272.

By N. B. Devi

The extraction of Cu(II) from HCl media using Cyanex 923 in kerosene was investigated. The effect of shaking time, aqueous phase acid concentration, extractant concentration, chloride ion concentration, various metal ions (Mn2+, Mg2+, Fe2+, and Ni2+), and temperature on the extraction were studied. Using 0.1 M Cyanex 923 the extraction of Cu(II) was 6.7 per cent from 3 M HCl, which increased up to 78.5 per cent with 6.5 M HCl and then decreased due to acid extraction by the extractant. The maximum extraction (97.5 per cent) was obtained with 1 M Cyanex 923 from 5 M HCl solution. A mathematical model has been developed to describe solvent extraction equllibria over wide ranges of concentration of extractant, acid, and chloride ions. The composition of the extracted species has been predicted on the basis of slope analysis results and extraction equilibrium modelling. The negative values of enthalpy change and entropy change confirm the exothermic formation of the extracted complex.

Jan 1, 2012

By Jae-Chun Lee, Rajiv Ranjan Srivastava, Min-seuk Kim, Byung-Su Kim

Recycling of spent hydrotreating catalysts (HTC) can potentially contribute towards the sustainable extraction of metal values. Treating such materials by hydrometallurgical methods to separate metals from the leach liquor of either acid/alkali media is a major step. In the present study, separation of molybdenum from HCl leach liquor of spent NiMo type HTC has been investigated by applying solvent extraction using Cyanex-923. For this, the chloride solution containing 973 mg/L Mo, 254 mg/L Ni and 1634 mg/L Al was taken as the aqueous feed. The parameters including contact time, concentration of the extractant, acid and chloride, and phase ratio were varied to investigate their effect on the extraction efficiency. The McCabe-Thiele plot suggests that > 99% Mo-loading using a 2-stage extraction process. From the molybdenum depleted solution, nickel was selectively extracted by Cyanex-301 leaving Al in the raffinate.

Jan 1, 2014

By E. Vahidi

In this study, a hydrometallurgical treatment involving solvent extraction of zinc using D2EHPA (di-2-ethylhexyl phosphoric acid) has been investigated to recover zinc from an industrial zinc leach residue. The residue was leached with sulfuric acid producing leach liquor which was subjected to solvent extraction for enrichment of zinc and removal of impurities. Operating variables for the zinc extraction process, such as pH of the mixed solution (0.5~5.0), concentration of D2EHPA (5%~40%, w/w), temperature (25~60°?C), A/O volumetric phase ratio (1/2~4/1), concentration of tri-butyl phosphate (TBP) as modifier (3%~7%, w/w), concentration of NaR2RSOR4R in aqueous phase (0.05M, 0.1M, 0.2M) were also studied. Practically all zinc was extracted from the aqueous solution at pH 2.5 with 20% w/w D2EHPA in kerosene. At this operating condition, zinc could be extracted at one theoretical stage at A/O phase ratio of 1/1, as calculated by the McCabe-Thiele method.

Jan 1, 2014