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By M. Moats, J. Young

Short term laboratory cell electrorefining experiments were performed to examine the impact of electrolyte composition, current density and temperature on deposit structure, roughness, and adhesion to 2B mill finished 316L stainless steel. Copper electrodeposits were produced using synthetic electrolytes with thiourea and the continuous addition of glue. Deposit structures were evaluated using X-ray diffractometry. Surface roughness was measured using profilometry and analyzed using scaling analysis. Finally, an internally developed method was used to measure the force required to remove the electrodeposited copper from stainless steel to determine adhesion strength.

Mar 2, 2022

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By Robert Vidal

The performance of a laboratory-scale cell for the electrolysis of an aqueous chrome alum solution was studied. Electrode potentials, pH, and Eh were recorded. An optimum catholyte pH of about 2.5, consistent with information from the literature was observed. Values exceeding this range resulted in a precipitate formation and are detected by wavering cathode potentials. The role of anodically produced dichromate ions was investigated by chemical analysis. It was found that the steady state concentration of dichromate ions varies inversely with fluid flow from catholyte to anolyte. This concentration was also reduced with the use of precious metal coated titanium anodes.

Jan 1, 1994

By J. A. Beukes, M. Marais

TICOR South Africa is a new titanium feed stock producer. In the Ticor South Africa plant the ilmenite feed to the smelter plant is roasted to enhance its magnetic properties. This allows for the magnetic separation of chromite from the ilmenite. The magnetization reaction relies on partial oxidation with both under- and over-oxidation causing insufficient magnetization. To subject the roaster plant feed material to the required physical conditions a circulating fluid bed (CFB) roaster is used. This paper describes the development of a laboratory model that will aid in the control of the CFB roaster.

Jan 1, 2003

By D. J. Sapsford

This paper details results from laboratory simulation of an innovative underground bioleaching process. The underground reactors are periodic flushed with recycled leachate to remove uranium that accumulates within the reactor water. This leaching cycle has been recreated within the laboratory. This study examines the influence of varying cycle protocol on uranium leaching. Protocol variants examined include variation of flushing frequency, flush volume, leachate recycle, nutrient solution (NPK) addition to reactors and Fe(III) sulphate addition to reactors. The presented data highlight the dramatic improvements in uranium recovery that might be achievable by varying the operating protocol for the actual underground reactors.

Aug 1, 2010

By J. A. Finch

Samples of feed and product from a closed grinding circuit treating a heterogeneous lead-zinc ore were taken. The feed was subjected to laboratory batch grinding in a rod and ball mill with the objective of simulating the closed-circuit size distribution. It was concluded that the batch rod mill can closely simulate this product if only the over-all size is considered, but mineral-by-mineral large differences occur. If, as is suspected, the mineral sizes are the important factor in flotation, the differences could lead to problems in interpreting flotation results. An example of mineral recovery as a function of size is described to illustrate the potential problems.

Jan 1, 1979

By Kalanadh V. S. Sastry, D. W. Fuerstenau

A locked-cycle balling procedure has been designed to simulate continuous, closed- circuit balling drum operation in the laboratory. By this method, it is possible to simulate the surging in green-ball production rate and circulating load that is experienced in industrial balling circuits. Through an investigation of the effect of feed rate on the stability of the locked-cycle, balling process, it was found that higher feed rates lead to increasing instability in the process. An analysis of the experimental ,results is presented and the utility of the locked-cycle experimental technique for evaluating the stability of an industrial balling drum operation is discussed.

Jan 1, 1976

"Successive seismic waves may cause progressive weakening of a fault zone, which has been recognized as the mechanism of earthquake aftershocks. However, it is unclear that how a fault zone slips under each wave cycle and how slip displacement accumulates under continuous wave cycles. This laboratory study provides direct evidences on the slip process of a simulated granular fault zone dynamically induced by an incident wave without the effects of late-arriving and reflected waves. The experimental observations show forward and backward slip paths of the fault zone and partially recovered slip displacement after a wave incidence. The unrecovered slip displacement after each wave cycle can be accumulated until it reaches a critical slip distance for seismic faulting, which may reinterpret delayed triggering in earthquake dynamics. The limited interseismic period restricts fault self-healing in strength. The experimental results also indicate that the dynamically induced frictional slip on the fault zone is associated with a complex frictional system, including seismic wave radiation, frictional slip initiation and normal stress vibration. Different from the dynamically induced frictional slip on the fault zone, the statically induced frictional slip causes a permanent increase of slip displacement along the shear loading direction. INTRODUCTIONAn earthquake mainshock may induce aftershocks by suddenly changing external stresses applied to another fault zone in the near field (Kilb et al., 2000) and by slightly perturbing a fault zone from a critical steady state to stick-slip faulting in the far field (Gomberg and Davis, 1996). The dynamically induced frictional slip on a fault zone has been recognized as the mechanism of earthquake aftershocks (Marsan and Lengliné, 2008; van der Elst and Brodsky, 2010). Although earthquake aftershocks have been extensively studied by many seismological methods, a simplified laboratory fault zone can provide possible interpretation on real faulting and detailed analysis on a friction process (Dieterich, 1979; Nielsen at al., 2010). According to a few laboratory experiments related to the dynamically induced frictional slip on a simulated fault zone (e.g., Uenishi et al., 1999; Johnson et al., 2012), the slip process induced by successive seismic waves exhibits continuous motions. However, it is unclear that fault slip response under each wave cycle and slip displacement accumulation under continuous wave cycles."

Jan 1, 2015

By M. C. Bétournay

Strainbursts are common in overstressed brittle rock around deep mine openings. Such failures are characterized by a biaxial state of stress in the plane of the opening boundary. A zone of compressive stresses imposes initial failures near or at the surface of the opening that results in spalling of thin slabs of rock roughly parallel to the free face. While the failure of rock under biaxial loading conditions is increasingly common in deep underground mines, only a few representative laboratory studies have been reported in the literature, without emphasis on rockbursting aspects, and none in the last decade. This paper presents the results of a testing program on a granite rock type. Biaxial testing, conducted on 100 mm cubic samples, was carried out to examine the influence of lateral confinement and loading rate on the rock’s ultimate strength. The paper reports the test results in terms of normalized biaxial failure envelope s1/sc-s2/sc. A discussion of the failure mechanisms observed is presented. Les coups de toits de déformations sont choses communes dans le rock cassant surcontraint en place autour des ouvertures minières profondes. De telles ruptures sont caractérisées par un état de contraintes biaxiales dans le plan de la périphérie de l’ouverture. Une zone de contraintes compressives impose des ruptures initiales à ou près de la surface de l’ouverture, qui produit des relâchements de minces plaques de roc plus ou moins parallel à la surface. Bien que les ruptures de roc sous des conditions biaxiales sont de plus en plus communes dans les mines à grandes profondeurs, il n’y a eu que quelques études représentatives en laboratoire de publiées, sans emphase sur des aspects de coups de terrains, et aucunes publiées depuis la dernière décennie. L’article présente les résultats d’une campagne d’essais appliquée à un type de granit. La campagne d’essais biaxiaux, sur des échantillons cubiques de 100 mm, avait pour objectif d’examiner l’influence du confinement latéral et le taux de chargement sur la résistance ultime du roc. Cet article fait part des résultats en terme de l’enveloppe de rupture biaxiale normalisée s1/sc-s2/sc. Une discussion sur les mécanismes de ruptures observés est présentée. Dehnungsbrüche findet man häufig in übergespannten spröden Felsen um die Öffnung von tiefen Minen. Solche Brüche sind von einer zweiachsigen Spannung in der Ebene der Grenze der Öffnung charakterisiert. Eine Zone von Druckspannungen verursacht initiale Brüche, entweder an der Öberflache der Öffnung oder in der Nähe. Davon scheiden sich dünne Felsplatten mehr oder weniger parallele mit der freien Wand. Obwohl Felsbrüche unter zweiachsiger Beanspruchung immer mehr häufig in tiefen Minen beobachtet sind, hat man über nur einige repräsentative Laborversuche in der Literatur berichtet. Diese Studien diskutieren das Thema ohne Betonung auf Felsbrüchen, und keine sind in den letzten zehn Jahren erschienen. Die vorliegene Arbeit gibt die Ergebnisse eines Testprogramms auf einem Typ von Granitfels. Durch zweiachsige Prüfungen von kubischen Proben mit Seitenlangen von 100 mm sollte man den Einfluss von seitlicher Ermittlung und der Beanspruchungsrate auf die Bruchfestigkeit des Felsen studieren. Man findet auch die Prüfergebnisse in bezug auf das normalisierte, zweiachsige Bruchkriterium s1/sc-s2/sc. Die beobachteten Bruchmechanismen sind auch diskutiert.

Jan 1, 2003

By Wright J. K

A description is presented of the results of reduction experiments using a laboratory reduction apparatus in which simulation of the gas and temperature profiles which occur in direct reduction shaft furnaces is achieved using microcomputer control. The apparatus allows continously changing reduction conditions to be impressed on lump or pellet samples to simulate the environment that is experienced by iron ore burdens during their transit down the shaft of a direct reduction furnace. Three pellet samples and three lump ore samples were reduced in the apparatus. Comparative reduction curves and strengths after reduction for the materials were obtained over a range of reduction temp- eratures using Midrex-type gas compositions. The resulting reduction and strength curves show considerable variation in behaviour and reflect the physical and chemical variations in the individual ore and pellet types. A comparison is made of the reduction rates and modes of reduction of the samples reduced under "conventional" test conditions using a single unchanging gas composition and the simulated shaft furnace reduction conditions. It was observed that the course of reduction is very different in the two procedures and the major influence of temperature on the strength of the reduced product is noted.

Jan 1, 1987

By K. M. Banks

Multiple-pass hot-strip-rolling schedules of carbon steels and niobium-microalloyed ferrite-pearlite steels were simulated on a Gleeble 1500 thermomechanical test apparatus. The effects of finishing temperature, coiling temperature, and chemical composition on the as-deformed ferrite grain size and hardness of the steels were determined. Low finishing temperatures and low coiling temperatures both contributed to ferrite grain refinement. Good agreement was found for the microstructure and hardness of the steels between the as-ruled condition and the results obtained from rolling simulations. The progress of recrystalization and precipitation was followed from examinations of the flow-stress curves during the hot-rolling simulations. The flow-stress behaviour during the finishing passes was consistent with the resulting changes in final ferrite grain size. It was found that the no-recrystalization temperature, TNR, is raised by increased additions of niobium.

Jan 1, 1993

By E. Bane Kroeger

For many years, researchers around the world have been investigating coal pillar stability. Many have focused on trying to optimize the size of the pillars by examining stable and failed pillars in underground coal mines. For mines that are already in operation or companies that are opening a new mine adjacent to an existing mine where the pillar dimensions and stability can easily be determined, this is the preferred technique. However, when a new mine is planned for an area where there has been relatively little mining, then samples of the coal need to be drilled and tested for strength. Because of the fractured nature of coal, this lab testing is often problematic and may often yield poor results because of the limited size and number of samples that can be obtained from the core. To remedy this problem, research was conducted in the labs at SIUC to determine if improvements could be made when optimizing the size of pillars for underground coal mining in Illinois. Through a greater understanding of the relationship between dimensions and strengths of coal samples tested in the lab, it was hoped the in situ strength of coal pillars could be determined with greater accuracy. This could allow the extraction ratio to be increased and more of the coal resources in Illinois recovered without impacting the safety of the mine workers. Many different agencies around the world have published recommended minimum numbers of samples for strength determination based on the size of the coal samples. For two inch cubes, uniaxial testing of at least seven samples is recommended and this minimum number decreases to four when testing four inch cubes. However, the laboratory testing of coal from two seams thus far has suggested this number should be almost doubled to accurately determine the coal strength. Testing also showed there is a pronounced decrease in the variation in the strength of the samples tested as the dimensions of the sample were increased. From the testing results thus far, it is recommended that a sample size versus strength curve be constructed for every coal seam for Illinois. Creating such a curve will better determine both the minimum number of samples and minimum sample dimensions for that seam or region of a particular scam. A second set of tests were conducted in the laboratory to determine the increase in strength with reduction in height for samples with the same width and length. In Illinois, typical pillar dimensions are 40 to 80 feet (12.2 to 24.4 m) wide and long, with coal thickness varying from about 4 to 9 feet (1.22 to 2.74 m). This provides width/height ratios ranging from 4.5 to 17.5. Coal samples having width/height ratios ranging from 0.5 to 13 have been tested thus far. As with most pillar design formulae, the strength of the Murphysboro coal versus width/height ratio was linear and closely matched shape factors published by other researchers. The laboratory testing thus far has identified three factors that affect the strength of laboratory samples, the number of discontinuities, the angles of critical discontinuities, and the shape of the samples. The factor that probably had the most pronounced effect on the strength of the coal samples was the angle of critical discontinuities. This testing has confirmed that there is still a gap that needs to be bridged between the strength obtained from laboratory testing and the in situ coal strength predicted.

Jan 1, 2004

By Quast K. B

Samples of limestone and micaceous hematite have been ground in a laboratory batch mill using equal weights of either rods or balls. Values of the Schuhmann distribution modulus, a, have been shown to depend on grind time and do not remain constant as often reported. The linear reduction in a with grind time was attributed to a change in grinding mechanisms with time. The product sizing from ball milling limestone showed a bimodal distribution, but rod milling produced a unimodal size distribution. The product sizing from milling micaceous hematite was difficult to interpret due to the major influence of the shape factor on the transition from screen sizing to cyclosizing.

Jan 1, 1995

By Quast K. B

Laboratory batch rod and ball milling tests were conducted on samples of Heavy Medium Separator (HMS) sinks from Renison Tin Limited. The product size distributions for this heterogeneous material were very different to similarly sized homogenous material previously reported by the authors. The effects of pulp density on product size distributions were only evident at pulp densities greater than 80 per cent solids. At high solids density, the major weight distribution product peak fell and broadened indicating less efficient breakage, particularly for rod milling. Tin distribution in the ground products was also affected by pUlp density, and there was always less cumulative per cent tin than cumulative per cent weight, ie there was no tendency for cassiterite to slime down to 10/lm.

Jan 1, 1995

By K B. Quast, A Schuurmans

Laboratory batch rod and ball milling tests were conducted on samples of Heavy Medium Separator (HMS) sinks from Renison Limited. The effects of mill rotation speed, rod volume and ball size on the resulting product size distribution were investigated. Between 48 and 69 per cent of critical speed, the product sizing distribution curves remained very similar, with a finer grind resulting from increasing the speed of rotation at constant grind time. Increasing the rod loading from ten to 53 per cent by volume caused the product size to become finer and more closely sized with a transition occurring at approximately 29 per cent. This was interpreted as a change of dominant grinding mechanism from abrasion to impact. No preferential grinding of the cassiterite was observed. The effect of increasing ball size at constant charge weight was to preferentially grind the coarser particles and generate more intermediate sized particles, whereas the product from a mixed ball charge gave a distribution similar to that obtained when a charge containing only smaller balls was used.

Jan 1, 1998

By K B. Quast

Changes in feed size distribution can have significant effects in rod mill grinding. The product sizing resulting from wet batch milling of a tin ore showed little influence on fines production after truncating the feed at either the coarse or fine end. The addition of fine material caused a less amount of fines to be produced and a possible increase in grinding at coarse sizes, although this is complicated by the changing feed size distribution. The changes in feed size distribution caused no tendency for preferential grinding of the cassiterite.

Jan 1, 1998

It is possible to closely simulate the product sizing distribution from an industrial rod mill by the correct choice of parameters in laboratory batch milling. For laboratory batch rod milling, changes in per cent critical speed and per cent rod volume cause the product sizing distributions to move in parallel at a constant slope. For ball milling, larger sized media in batch milling grind more coarse material giving a closer simulation to the industrial rod mill product. Changing the feed size distribution by removal of coarse particles or addition of fine particles changes the product sizing distribution, but would not normally be practiced in laboratory testing. These data should be applicable to many instances where laboratory simulation of an industrial product size distribution is required.

Jan 1, 1998

By P G. Hicks

The influence of feed size and pulp density on the specific rate ofbreakage of quartz was investigated. Plots of log fraction of feedremaining within the feed size interval against grinding time allowed the application of the first order grinding model to be examined. Substantial non-linearities were observed for all feed sizes due to environmental and material factors. For feed sizes above 1.3 mm, the specific rate of quartz breakage was higher with rod milling than ball milling, but below this size the reverse was true. Material that remained in the feed size interval after the initial grinding broke more slowly in subsequent grinding than the original feed material. Grinding media and time as well as feed size influenced the effects of pulp density on grinding. More dilute pulps (eg 50 per cent solids density by weight) were favoured for higher rates of breakage in rod milling but for ball milling, the optimum pulp density appeared to be 60 to 70 per cent solids by weight.

Jan 1, 1998

The usefulness of laboratory studies - petrology and mineragraphy in the search for, and investigation of, mineral deposits should not be exaggerated, but it should not be overlooked, because such studies will always contribute to an understanding of the geology of the deposits, and can on occasions provide invaluable information not otherwise available. A few examples furnished by the investigations of the Mineragraphic Section of the Commonwealth Scientific and Industrial Research Organisation will show this.Petrology.In the early stages of the investigation of the King Island scheelite deposit, during the war, when the nature of, the deposit was not understood, a series of samples embodying the exposed rock types was submitted to the Mineragrap;hic Section for petrologicalexamination by the Mineral Resources Survey. It was at once apparent to the petrologist that the King Island scheelite ore was a contact metamorphic deposit, in which a series of argillaceous shales, calcareous shales, impure limestones and limestones had beenintensely metamorphosed. The shales had been converted to finegrained biotite and actinolite hornfels, according to their lime content, and the impure limestones to fine-grained diopside hornfels, garnetdiopside hornfels and garnet hornfels (calc-flint), the garnet being the lime variety grossularite. The limestones, however, after being first converted to marbles, had suffered intense pyrometasomatism, involving substitution of immense quantities ,of silica and' iron for lime and carbonate, and had been converted largely to a coarsegrained garnet rock, in which the garnet was the lime-iron variety, andradite. The silica and iron were derived from the mineralising solutions of the adja,cent ,granite. intrusion, responsible for the contact metamorphism, and were accompanied by tungsten and some molybdenum. The tungsten in the presence of so much mobile lime, was precipitated as schecelite, much of it finegrained and enclosed in or intergrown, with the andradite garnet or the quartz interstitial to the garnet.It was apparent that the King Island scheelite deposit, was a perfect example of selective pyrometallomatic replacement in a bedded contact metamorphic deposit. The bedded nature of the original rocks was preserved, and the scheelite was practically limited to the original limestone beds, 'Which had been so much more susceptible to replacement after recrystallization, than the other sediments. The further geological study of the deposit then resolved itself into the task of mapping the folding and faulting of the deposit, with bore cores to provide the stratigraphic sequence, and establish the number of scheelite-bearing beds.A second example is provided by a petrological investigation of the mineral composition and genesis of the talc deposits of the Gumeracha district of South Austral.ia, which was undertaken at the request of the South Australian ,Mines Department, in conjunctionwith mapping of these deposits. The field geologist mapping the deposits was experiencing some difficulty in interpreting the structure...

Jan 1, 1950

By H. R. Hardy Jr., E. J. Kimble Jr., H. W. Shen

"The primary objective of this research project is to study the character of the bit-coal interaction during coal cutting and its influence on the size and shape distributions of the generated dust. Secondary objectives include the investigation of the acoustic emission technique as an indirect method for coal dust characterization and remote bit wear monitoring. The results of the project will be useful in developing efficient coal cutting techniques which significantly reduce the harmful coal dust components, and in providing methods for remote monitoring of bit condition and associated coal dust character. This paper will outline recent experiments carried out on coal under uniaxial compression, linear single-bit cutting, and cutting using a laboratory-scale, single-bit shearer. During the experiments acoustic emission and a variety of other mechanical parameters were monitored. · A commercially available artificial intelligence computer package, namely: JCEPAK (Intelligent Classifier Engineering Package), has been utilized to provide a powerful and objective means for AE waveform analysis. This program is able to evaluate a number of features of each AE event and to make objective comparisons between AE signals associated with different loading or cutting parameters. Finally, the paper will discuss the results obtained from a variety of coal breakage tests.INTRODUCTIONStudies to date clearly indicate that the reduction of the severity, and eventual elimination, of Coal Workers' Pneumoconiosis (CWP) depends on gaining fundamental understanding in a number of major areas. These include dust generation and entrainment, transportation, suppression, medical effects of dust and possible treatment. At present a project is underway by the authors to investigate the character of the bit-coal interaction during coal cutting and its influence on the size and shape distributions of the generated dust. An important aspect of this on-going project is the development of acoustic emission (AE) criteria which will make it possible to carry out remote monitoring of coal cutting operations. Suitable on-line analysis of monitored AE data would allow engineers to evaluate factors such as shearer bit condition and cutting efficiency, and to quantify the particle size and shape distribution of the generated dust. The on-going AE studies are fundamental in form and were undertaken to evaluate the general feasibility of AE monitoring techniques using simplified coal cutting procedures. This paper will outline recent experiments on coal under uniaxial compression, linear single-bit cutting, and cutting using a laboratory-scale, single-bit shearer. Additional information on these studies are presented elsewhere [4]."

Dec 1, 1996