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By A. Deepatana

Bioleaching of nickel laterite ores is based on the use of heterotrophic fungi organisms and their metabolites (organic acids) to dissolve nickel and cobalt from oxide minerals to form metal-organic complexes. Metal recovery from this process using an aminophosphonic acid based chelating resin (Purolite S950) was investigated as a function of metal concentrations, complexing agent including citric, dL-malic and lactic acids. Batch adsorptions were conducted using synthetic leachate solutions of nickel and cobalt with concentrations from 15 to 2000 mg/L prepared in 0.01 and 0.1 M organic acids. Adsorption equilibrium data were interpreted using the Langmuir, Freundlich and Dubinin-Kagner-Radushkevich (DKR) models. The results showed that equilibrium adsorption data for nickel-organic complexes followed the Freundlich model and those for cobalt agreed with the Langmuir model. It was observed that the maximum adsorption capacities of nickel and cobalt were 3.26 and 10.48 mg/g resins respectively. These were achieved in metal complexes prepared from 0.01 M lactic acid. Metal elution was conducted using 2 M nitric acid. High metal recoveries were achieved from low metal concentrations but were found to decrease with increasing metal concentration. The results suggest that effective recovery of nickel and cobalt from low concentration of metals, such as those generated from bioleaching operations, can be achieved suitably using chelating resins.

Jan 1, 2006

By A. Yoshida, H. Miura, S. Yamaguchi, Y. Oyama

A discussion is given on the ionic equilibria and precipitation reactions in seawater based on thermodynamic analysis, in order to understand the solubility of nutrient salts from dephosphorization slag for marine phytoplankton. Solubility of constituent ions in aqueous solution in equilibrium with solid phases are determined using thermodynamic data. It is proposed that CO2 potential defined as log Pco2 should be considered as an additional parameter to the Eh- pH diagram for the ionic equilibrium of slag components in seawater, since magnesium and calcium carbonate precipitation reactions determine the solubility of ligand ions in nutrient salts, such as phosphates, silicate, and sulfate.

Jan 1, 2004

By James Vaughan

Ionic liquids are solvents of interest for applications such as electro- plating, winning and refining of metals. Of particular interest is the possibility of processing reactive metals such as aluminium, magnesium and titanium that cannot be deposited from aqueous solutions. Aluminium has been electro deposited from AlCl3 : ionic liquid mixtures at low temperatures relative to conventional Hall-Héroult smelting. Imidazolium ionic liquids are have been used in the past due to their relatively high ionic conductivity and cation stability. The less studied and less expensive phosphonium ionic liquids systems may provide a viable alternative to imidazolium ionic liquids for certain applications. New information regarding the physical properties and electrochemical behaviour of phosphonium ionic liquid systems is presented.

Jan 1, 2006

By Fathi Habashi

THE CHOICE of a precipitant for a certain metal ion depends, beside the economic factor. on the following factors: 1) The precipitant should be specific as far as possible so that pure precipitates can be obtained

Jan 1, 1970

By M. C. Fuerstenau, D. W. Fuerstenau

Long-Chained aliphatic amine salts have been used for the separation of sylvite (KC1) from halite (NaC1) by flotation. It is puzzling how these two minerals, which are so similar chemically and crystallographically, can be separated by this method. Gaudin as postulated that the difference in floatability of halite and sylvite with salts of primary amines depends on ionic size: In the case of amine flotation, the cation would attach itself to the chloride. I have a speculation there, which I cannot prove, that the ammonium group, that is the –NH3 group in the amine, floats potassium chloride because the dimensions of this group as it has been measured in other compounds is almost identically the dimensions of the potassium ion, quite different from the sodium ion, and so it fits where potassium had been, in place of it and not attached to it.

Mar 1, 1956

By J. A. Rajala, R. W. Smith

The effect of increasing ionic strength, via monovalent and divalent ions, on alkyl sulfate flotation of hematite and quartz war investigated. The effects of collector chain length and pretreatment on this flotation were also studied. Sodium hexadecyl sulfate was shown to be a superior flotation collector to sodium dodecyl sulfate for recovery of hematite when there was no salt addition. Similar observation were made when sodium sulfate or sodium chloride was used to control ionic strength. Sodium dodecyl sulfate floated hematite better than its longer chutited counterpart under conditions of low pretreatment temperature and increasing calcium chloride concentration. The flotation recovery for all salt containing pulps was almost always improved after preboiling. Most of the results obtained when the pretreatment temperature was raised were attributed to increased solubility of the collector.

Jan 1, 1984

By John A. Rajala

The water chemistry of the froth flotation pulp is one of many parameters which can affect the flotation process. The fluid may contain certain inorganic salts which, along with increased ionic strength, can produce undesirable flotation depression or activation. A source of a salt could be the use of calcium chloride to prevent freezing in ore cars, chutes, and bins (Anon., 1980). Alternately, the salt or salts could be initially contained in the water as in the case of sea water and some brackish waters. These salts may become more concentrated because of the need for recycling of plant water due to environmental regulations and/or economic considerations (Davis, F.T., et. al., 1976). The presence of inorganic salts in flotation pulps and their effects upon the recoveries and surface chemistries of different oxide minerals have been the object of various studies. Some researchers (Fuerstenau, D. W. and Raghavan, 1976; Fuerstenau, D. W. and Modi, H. J. 1960; Kulkarni, R. D. and Somasundaran, P., 1977) have reported that addition of a salt can increase or decrease flotation recovery depending upon the particular system.

Jan 1, 1982

By M Suzuki

Although several models for the surface tension of molten oxide slag have been proposed, suitably accurate predictions of this property are not yet possible. The surface tension, or surface excess free energy, of molten oxides is largely determined by the ionic coordination induced by surface relaxation. However, the associated mechanism of surface structural relaxation for molten oxide mixtures such as slag is complex and not yet fully understood. To allow a better evaluation of surface relaxation characteristics, the present work analysed the ionic coordination associated with the surface-relaxed states of several oxide mixtures. This work especially focused on calcium aluminate slags because these materials exhibit complex relationships between composition and surface tension. The effects of incorporating low concentrations of SiO2 as a surface active component on the surface ionic coordination were also examined. X-ray absorption techniques were used to assess oxygen and cationic elements in glassy samples after surface relaxation treatments, and molecular dynamics simulations based on a polarisable ion model of molten slag with vacuum/melt interfaces were also performed. The X-ray absorption techniques provided data related to electron yields (which are primarily associated with surface features) and fluorescence yields (which evaluate the bulk material). Thus, the ionic coordination characteristics of both regions were investigated. The results of molecular dynamics calculations allowed statistical analysis of the distributions of Al- or Sicentred polymorphs as well as the bond angles between cations and oxygen anions in the vacuumexposed and bulk regions in the equilibrated melt. The results indicated that bridging oxygen ions were preferentially distributed in the relaxed surface region rather than non-bridging oxygens. These bridging oxygen ions represented vertex connections between AlO4 or SiO4 tetrahedra. In the case of the calcium aluminate slags, the addition of one Ca2+ ion as charge compensation for two Al3+ ions was found to be necessary to form two AlO4 tetrahedra. This specific feature of surface ionic coordination could be responsible for the complex trends observed in surface tension data. The incorporation of low concentrations of SiO2 reduced the proportion of tetrahedrally-coordinated Al ions such that higher coordination states become dominant in the bulk of the material, whereas AlO4 tetrahedra were preferentially distributed in the surface region. SiO4 tetrahedra were the preferred Si-centred polymorph and were likely connected to one another to form bridging oxygen ions at the surface. On the basis of these results, a model to predict slag surface tension was proposed, and the energy of the formation of the ionic clusters resulting from surface relaxation was taken into account.

Aug 21, 2024

By D Head

IonicRE acknowledges within our mining industry, there is a common belief that workplace health and safety, often referred to as safety, is just a matter of ‘common sense’ – something obvious and easy. However, at IonicRE, we hold a different perspective. We understand that safety is far from easy. We recognise the need to emphasise the importance of understanding and conveying the inherent difficulties of working safely. We are committed to implementing processes that support individuals in achieving our safety objective of eliminating fatalities and permanently disabling injuries. To build resilience and sustainability into safety performance, we draw parallels with the principles underpinning sustainable and exceptional production performance. Achieving sustainable safety performance demands effective leadership, meticulous planning, adept management, genuine care and unwavering commitment. We’ve leveraged various tools and techniques, such as DISC theory, Maslow’s hierarchy, process control, Kaizen, Six Sigma and Kirkpatrick’s 4 levels, among others, to facilitate this improvement. There methods play a pivotal role in developing a Safety Blueprint for enhanced safety performance. This paper provides an overview of IonicRE’s Safety Blueprint, a strategic framework for developing our safety capability. Our capability is underpinned by three key pillars. Firstly, a comprehensive risk management approach is imperative, encompassing the understanding of hazards, the identification of threats to our people and the associated risks. Secondly, it entails providing and enforcing accountability to sustain our safety capability. Lastly, it involves constructing an effective defence system against threats and harm. Implementing these pillars requires a meticulously devised change process. Anticipating resistance and potential setbacks, we underscore the importance of having the right people and a wellcommunicated vision for safety at IonicRE. A Safety Blueprint serves as a detailed plan outlining the path toward a future goal. At IonicRE, we contend that safety in the mining industry has generally lacked a coherent and effective Safety Blueprint – a comprehensive plan to navigate the journey toward a destination. Drawing parallels with NASA’s detailed plan for landing a man on the moon safely, we question why, as an industry, we cannot similarly eliminate fatalities. While progress has been made in the last century, we must not wait another 50 years to eradicate fatalities from our industry. Examining Safe Work Australia data from 2008 reveals that 47 per cent of mining fatalities result from vehicle activity and 40 per cent stem from individuals being struck by an object. As of December 7, 2023, seven lives have been lost in the mining industry in Australia this year, indicating a stubborn trend mirroring 2022, with limited improvement over the past 25 years. These incidents are not isolated or unexpected. We understand the hazards and controls, yet fatalities persist. IonicRE considers that the mining industry stands at a critical juncture – do we accept a plateau in mining safety performance, or do we rethink our approach? At IonicRE, we are thoroughly reassessing the hazards that threaten our people, systematically redefining effective risk control measures and establishing a robust framework to hold individuals accountable for the effective implementation of the control measure.

Apr 16, 2024

By K. Hausmann, P. A. Sashin, G. J. Prejean

Misfires caused by unreliable shock tube constructions can have significant cost implications and place field workers at serious risk during remediation. Ionomer materials, used as a subtube in shock tube constructions, provide superior hot tack strength, oil resistance, impact resistance at cold temperatures and excellent thermoformability properties. These are important features for resisting blast-throughs and ensuring blasting reliability in demanding environments, such as open pit mining in harsh environments. Superior hot tack strength, strain hardening, and excellent thermoformability properties of the ionomer materials ensure uniform powder distribution along the shock tube during construction and avoid undesired powder accumulation due to deformation or vibration during use. Oil or chemical resistance is another feature of Ionomers. This allows improved property retention in contact with oils and hence longer sleep times of the shock tube. Another feature of these highly engineered ionomers is superior impact strength at low temperatures. This plays an important role considering the resistance to fly rock impact in open pit mining operations in particular in cold climates.

Jan 1, 2011

Iowa Geological Survey, Des Momes, Ia. George F. Kay, State Geologist A list of publications will be sent upon request Most of the papers of the Survey have been published in the Annual Reports, issued since 1892. Separates of the many papers in the Reports may be had for postage, except where they are out of print, and except for vol 1 (1892), 2 (1894) and 14 (1903), where no separates are to be had. Thirty-five Annual Reports have been issued up to and including vol 35 (1929). A charge, plus postage, is made for vols, 4, 5, 7, 8, 9, 10, 28 and 33, others will be sent free upon request, plus postage on from 2 to 6 pounds Space prohibits giving more than a general picture of some of the contents; vols 4, 5, 7, 8, 9, 10, 11, 12, 13, 15, 16, 20, 27, 32, contain, among others, papers on the geology of Iowa, by counties Vol. 19 (1908), 6 lb , contains a number of papers dealing with the peats and coals of Iowa, and has bibliographies of those subjects Vol 22 (1912), 6 lb , contains an annotated bibliography of Iowa geology Vol-24 (1913), 6 lb , contains the analyses of 16 Iowa coals Vol 28 (1917, 1918), price $1 50, 4 lb , completely covers the subject of gypsum in Iowa, and has a bibliography of the sub¬ject. Each volume carries an administrative report and a review of mineral production for the period covered In addition, Technical Paper 2 (1930), Studies of Iowa coals, will be sent free upon request Also a geological map of Iowa, and maps of Iowa showing the distribution of the glacial drift sheets throughout the state, have been issued and are available

Jan 1, 1933

No early records of coal in Iowa have been found, although it is very probable that coal along the Mississippi, in the northeastern corner of the state, was seen very early. The United States Census of 1840 showed a production of 400 tons, mined of course in 1839, and the earliest mining, was in Jefferson and Fairfield Counties where the coal was hauled by wagons to shops in the Mississippi River towns years before any railroad was built in the state. In 1840 mines were opened in Van Buren County, near Farmington and Douds, and in Scott County, near Jamestown, all of the product being used locally.' In 1844 D. D. Owen reported seeing mines in the tongue of land between the Rock and Mississippi Rivers, in one of them the coal being 5 to 6 ft. thick, and several other seams south of this locality? In the, late forties a number of small mines were opened in various parts of the state, and in following years in practically every county having coal. The Mystic seam was first opened in 1857 in Appanoose County, since then consistently one of the large producing areas in the state. Consumption was local until the Milwaukee Railroad was built through the county in 1887.1

Jan 1, 1942

Dr Andrew Cosgarea, Jr, Associate Director of Opera¬tions of the U.S. Mint, and Chairman of the Awards Committee of the International Precious Metals Institute, announced the IPMI award recipients for 1985. The awards were presented at the Institute's Annual Banquet in New York City on 11th June, 1985. The Distinguished Achievement Award was presented posthumously to Dr E.M. Savitsky, of the A.A. Baikow Institute of Metallurgy of the U.S.S.R., for a life-time career devoted to investigations on the properties of the platinum-group metals. Dr Savitsky investigated over 300 phase diagrams, which became the basis for the selection of alloys and the prediction of properties. He published over 300 technical papers during his career. Dr Savitsky died during the summer of 1984 while being considered for the IPMI Award. The Engelhard Henry J. Albert Award was presented to Dr Stephen J. Lippard, Professor of Chemistry, MIT, in recognition of his research contributions in platinum chemistry and its application to nucleic acids. This prize

Jan 1, 1985

1910, hundreds of thousands of dollars of work and equipment in a 1500-foot shaft, crosscuts and pumping had found only copper-lean pyrite in two cross- cuts, and nothing in a third. Going aimlessly along the third crosscut one day, after looking at the barren face I happened to notice a dark spot in the white limestone, near the floor on one side. I picked, and found it was a little triangle of rich chalcopyrite. Next day I took Bill Gohring, then mine superintendent, in to see it. He said nothing else had succeeded so we might as well try that. The new drift broke into a full face of high grade copper ore in the first round, and continued in rich ore for 2200 feel broken only by a couple of short stretches of lean pyrite. The earlier crosscuts had happened to cut these lean areas. Q: Was there any single thing that called your attention to that little dark spot in the side of the Briggs crosscut, rather than to any other discolored spot? Joralemon: Nothing very definite. Maybe luck, maybe that indefinable subconscious thinking that

Jan 9, 1964

By AIME AIME

T HOUGH Ira B. Joraletnon has not had an eastern address since 1907, he is a New Yorker by birth, having been born at Antwerp, in the northern part of the state, on July 27, 1884. He got his scholastic training at Harvard, which gave him his A.B. degree in 1905 and an A.M. two years later. For the next fifteen years except for the war period, he was with the Calumet & Arizona Mining Co., with headquarters at Warren, Ariz., being assistant man- ager when he left that company in 1922. During the first World War he spent a year and a half in France, where he achieved the rank of major in the signal corps, air division.

Jan 1, 1941

By John R. Lotz

A team of American experts is tackling a whole nations's problems, under the banner of a seven-year plan evolved by the Iranians themselves.

Jan 7, 1950

By F Rashidinejad

Iran has had an active mining sector for some 7000 years. Exceptional in terms of its mineral diversity, Iran produces 62 minerals, and is ranked among the world’s 15 most mineral-rich countries. Many people around the world know Iran as one of the major petroleum exporters. Oil and natural gas dominate Iran’s economy, and oil exports provide the principal source of income, contributing more than 80 per cent of foreign exchange earnings. Transformation of Iran from an oil exporter to an independent country to oil has been on the table for many years, even before the Islamic Revolution of 1979. Development of the Iran’s mineral industry is one of the major replacements for petroleum exports. In the last decade, Iran invested billion dollars in the mining and mineral industry sectors and to increase the added value, tried to export processed minerals instead of the raw materials. In accordance with the ‘20-year Perspective 2025’ that targeted by the Supreme Leader, Iran will be a country with the first rank in economy, science and technology in its region. The objectives over this perspective include briefly increasing annual production to 55 Mt of crude steel, 800 000 tonne of copper cathode, 1.5 Mt of aluminium, 200 Mt mineral products, 300 000 tonne of zinc and 5 000 kg of gold. These goals are achievable in normal circumstances, but concurrency of the 20-year Perspective 2025 with commencement of the UN Security Council sanctions against Iran, frustrated objectives of the perspective, at least the ones related to the mining and mineral industry sectors. This paper tries to elaborate the development programs and following challenges for the mining activities of Iran by 2025.

Nov 22, 2011

By John R. Lotz

DEVELOPMENTS in Iran currently arousing interest in a considerable portion of the world, particularly on the part. of that country's immediate neighbor on the North and in our own country, an inseparably related to and largely dependent upon the government's attempts to strengthen its economy and improve the standard of living of its people. These efforts are encompassed by provisions of the Seven-Year Development Plan recently enacted and not, in the process of implementation. It is a fine example of what one financially sound but extremely backward and poorly equipped country has undertaken to do on its own account and with its own resources. This Seven-Year Plnil was formally authoriztld by an act of the Iranian Parliament in February 1948. Its stated objects are to carry out such plans for the development of the country and its economy as ail1 raise the standard of livinc: and standard of education of the people, and re- duce the cost of living. A seven-yrar program for carrying out the work within the limits of appropriations was assigned under the law. The total amount to be expended during the seven- year period was fixed at the equivalent of $670 millioil at current rates of exchange.

Jan 1, 1950

By Christoph Mueller

?Globalization and the impact on mine operations? is one of the themes of the 2003 annual CIM meeting. Global mining business in practice always means to act with local base material resources in order to reach the mining company?s global business goals. On the other hand these operations are characterized by cost pressure and cycling product prices. Driven by actual prices, local product markets and local production cost, one time one mine can be most efficient while under different circumstances another mine will be the most efficient producer for the same customer [PENSWICK, 2001]. Therefor in the future the most profitable mining companies will be those who have permanent ?real-time? control on their actual production cost level. Certain approaches are under way to provide reliable modeling tools for aiding mining companies in highly complex decision finding procedures. A high potential for enhancing efficiency is the integration of all single steps of the mining working chain into a production process structure to make advantage of an optimized flow of material and information through the ?moving ore factory? [WIGDÉN, 2001]. Crucial to all these activities is the ability of getting reliable, just-in-time information from the entire mining production chain. As modern mining machinery today is controlled electronically and even already operated autonomously, the theoretical preconditions for the data acquisition is already fulfilled. But up to now, there was no way of cost effectively exchanging the process information with databases, simulation tools and other enterprise level software. Any data exchange problem had to be solved by individual and expensive software development projects. To solve these problems, the International Rock Excavation Data Exchange Standard (IREDES) was launched in 2000 by major players in the industry. The task of this initiative is to define a ?common electronic language? for easy and standardized data exchange between mining machines and central computer systems. As in other industries, this standard is expected to have significant impact on the use of automated equipment. It shall provide easy ways of using multi vendor machine installations in data controlled mining processes. At the same time it reduces cost for individual development of interfaces for all parties involved. The standard?s technical architecture is flexible and open - also for future applications. It uses modern technology enabling easy data exchange with commercial databases as well as open on line networking.

May 1, 2003

By G. I. Voiloshnikov, V. E. Dementyev

Wide use of adsorption methods for metal recovery is one of the most important achievements of gold metallurgy of the last decades. Anion exchange resins or activated carbons may be used as adsorbents. This paper presents a brief overview of IRGIREDMET effotts on development, testing and implementation of techno­logical flowsheets using both adsorbent types and attempt to compare their technological properties. IRGIREDMET Institute was founded in 1871 as a laboratory for gold smelting and gold ore testing. In 1930 it obtained the status of the Research Institute. IRGIREDMET functioned as leading research center for gold mining industry in the former Soviet Union. At present it is the Open Joint Stock Company dealing with all s01t of research and design works for gold min­ing (ranging from geology to gold refinery). IRGIREDMET started development of ion exchange technol­ogy in 19641• The first stage of work (1964-1970) including development of principle flowsheet of RIP process was carried out jointly with the Moscow VNIIKHT Institute (All-Russian Scientific Research Institute of Chemical Technology)2• The flowsheet of RIP process is presented in Fig. I and includes the following basic operations: gold adsorption from pulp; washing of loaded resin; acid treatment; thiourea adsorp­tion; gold elution by acid thiourea solution; resin washing to remove thiourea; alkaline treatment of resin; resin washing and gold recovery from eluates by electrowinning. The technology developed and equipment used were tested for treatment of clayey ore of Kuranakh deposit at a pilot plant of the Lebedinsky gold complex ("Aldanzoloto" company, Yakutia, Russia). The pilot plant throughput was 200 t/day. At the same time IRGIREDMET conducted the tests on ion exchange technology for ore and concentration products of oper­ating gold plants and for ores of new deposits. Laboratory and pilot plant tests were done and developed initial data and process design criteria for designing of 15 plans of the former Soviet Union. In the course of this work a great number of newly synthe­sized anion exchangers including strong and weak base resins was studied, the peculiarities of anion exchange resins using two different raw material types ( ores and concentrates includ­ing clayey, carbonaceous, silver bearing, arsenic, antimony and base metals bearing products); some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption of gold and silver from silver gold ore, improved flowsheet for gold elution and resin regeneration, design of adsorption equipment including pulsation columns, design of electrowinning cells were developed; conditioning technology for pulp with complex ion composition prior to gold and silver adsorption was developed, etc.3·8• IRGIREDMET specialists took part in commissioning of practically all the plants in the former Soviet Union using RIP and RIL process including Lebedinsky, Kuranakh, Sovetsky, Karamken, Matrosov's plant and Mnogovershinny plants. Due to this works RIP process became standard technology for Russia and the CIS.

Jan 1, 1998