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By Zhigang Liang

Investigation into the mixing of 150t ladle furnace by two-nozzle jetting was performed by a water model simulation of 1:4. The effects of nozzle arrangements including separation angle, radial position and asymmetry as well as tracer adding position on the mixing time were studied. The most favorable mixing is achieved when the two nozzles are symmetrically arranged at half radii in the ladle, with 45o separation angle. The empirical relationship between the mixing time and stirring power intensity has been established for two-nozzle jetting based on the present experimental results. In addition, the swelling above bath surface is also investigated with two-nozzle jetting.

Jan 1, 2009

Effective strata control, utilising fully encapsulated roof bolts, is dependent on the installed quality of the reinforcement elements. One mechanism by which fully encapsulated roof bolts may become less than fully effective is by gloving (glove fingering) and un-mixing of the resin. Following some small roof failures containing gloved bolts, investigations have been undertaken in some New Zealand coal mines to determine the extent of, and mechanisms involved in, the gloving of fully encapsulated roof bolts for a range of roof types and installation methods. Gloving, in this context, refers to the resin cartridge partially or completely enveloping a length of the bolt, typically with unmixed resin filler and catalyst/hardener remaining within the cartridge. Results have shown that gloving and un-mixing is a systematic and widespread phenomena, occurring across a range of resin and/or bolt manufacturers, and across a variety of roof types. Gloving was found in bolts installed using: hand held pneumatic and continuous miner mounted hydraulic methods, under run of mine (ROM) conditions by mine workers, and under controlled "best practice" conditions. The roofs bolts investigated are all 1800mm (6ft) long, and have shown that, on average, 485mm (-19") of the bolt length is gloved and/or unmixed. This equates to a 27 percent reduction in effective bolt length. The effected length of bolt is sufficient to impact on the load transfer/reinforcement capabilities of the bolt system, and hence impacts on the design assumptions and subsequent stability assessments. Furthermore, there is a direct relationship between the mechanism for the gloving of bolts and an increased occurrence of resin loss and reduction in encapsulations length in soft (less than 10 MPa) and/or highly fractured rock. Investigations have concentrated on developing an understanding of the mechanisms involved. This has been undertaken using both field installations and recovered bolts, as well as test bench trials. The mechanisms involved have been confirmed as being: the development of a pressure front as the bolt encounters the resin and is spun up the hole, which, in turn, leads to over-pressurisation and radial expansion of the resin cartridge, resulting in an increase in diameter of the plastic resin cartridge, which allows the bolt to be spun up into the cartridge without making sufficient contact to shred the cartridge or the hardener tube, resulting in an unmixed portion of resin.

Jan 1, 2003

By D Elmo, M Scoble, Y Liu, B Klein, J Scholar, S Nadolski

A cave-to-mill study being conducted at the New Afton block caving operation demonstrated the potential for sensor-based ore sorting equipment to reject waste and improve the grade of feed to the mill. The lack of selectivity and potential for dilution entry associated with the block cave mining method results in many caving operations having to mine and process material that is below cut-off grade at certain stages of production. Online monitoring and bulk sorting systems have the potential to alleviate this problem and improve the productivity of caving operations while reducing energy and water requirements for each tonne of concentrate produced.As part of the cave-to-mill study, the suitability of a range of sensors, such as X-ray fluorescence and induction-type sensors, to sort mine production at the New Afton mine was investigated. Results showed that the discrimination of ore and waste can potentially be carried out by implementing surficial sensors into the material handling system. The study also showed that a combination of sensor outputs could be used to identify a certain ore type so that pre-emptive changes can be made in the mill to improve beneficiation performance. Overall, the outcomes of the study on implementing sensor systems at block cave mines are considered to be of significant relevance to a number of existing and future caving operations.CITATION:Nadolski, S, Klein, B, Elmo, D, Scoble, M, Liu, Y and Scholar, J, 2016. Investigation into the implementation of sensor-based ore sorting systems at a block caving operation, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 393–400 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

When a mine decides to construct surface structures close to, or on undermined ground, it is required in terms of the regulations of the Mine Health and Safety Act to obtain permission from the Department of Minerals and Energy (DME). Apart from the legal requirements, the stability of the structures is crucial as damage to the structures due to surface movements could result in loss in life, equipment and/or production. This paper deals with the rock engineering aspects of a study that was conducted on one of the chrome mines in the Bushveld Complex (BC) involving the construction of plant structures on shallow undermined ground. The paper addresses the legal requirements and guidelines regarding ground stability of surface structures placed on undermined ground and the assessment of the undermined area with regard to the following: ?sources of potentially damaging surface movements ?safe mining spans ?stability of the pillars ?effect of the loading of plant structures on underground stability. Due to the irregular layout and geometry of the pillars in conjunction with a changing surface topography, numerical analysis and not the conventional tributary area theory was used to determine the imposed loads on the pillars. In order to subject the plant structures to minimum movement, the plant should be located in areas where the pillars would remain stable, the elastic deformation of the hanging wall is minimized and hanging wall failure extending to surface is unlikely to occur. The study indicates that although the depth of undermining is shallow (between 27 m and 60 m), potential damaging surface movements are not anticipated due to the stability of the pillars, competent nature of the overlying strata and negligible effect of the plant structure loading on the underground stability.

Jan 1, 2004

By R. B. Krog

The use of belt air as an intake source at longwall operations has greatly changed over the past decades. The practical considerations for the use of belt air are controlled by a variety of factors including airflow quantity and velocity, coal methane content, methane desorption rates, coal mining rate, belt length, stopping leakage, and the number of gateroad entries. At longwall operations, the advantages and disadvantages of belt air are different for gateroad development and longwall panel extraction. During gateroad development, the use of belt air to ventilate the working section will reduce the leakage from the intake to the belt compared to the belt air being ventilated outby the working sections because of lower pressure differentials. A greater quantity of airflow will reach the last open crosscut with belt on intake than outby, given the same amount of pressure and airflow available at the mouth of the section. This paper will investigate the current ventilation practices regarding the use of belt air during gateroad development and longwall panel extraction. Operating considerations regarding air quantities and pressures to deliver the required airflow will be investigated using ventilation network modeling.

Jan 1, 2009

By Pamela Paradis-Sokoloski, Deni Thibodeau, J. Denis, Samantha J. Espley, P. O’Donnell

"During the previous decade, the role of spray-on liners within the mining industry was limited to providing a corrosion resistant coating to screen and bolts; however, increasingly, liners are being used as ground support products. Expanding use and testing of liners have demonstrated their ground support function, yet the definitive support mechanism is still under debate. The most promising theory is the retain/hold/reinforcement concept (Kaiser et al.,1992). This conceptual theory has been the basis for the recent underground trials at INCO where, specifically, shotcrete and MIROC Mineguard were tested in two trials to further define limitations and applications of each liner.In a cursory overview, shotcrete is becoming accepted as a support product, while Mineguard is only slowly gaining acceptance.This discrepancy is the result of the corresponding life-spans within the industry, whereby shotcrete has had wide-spread use for decades, yet Mineguard has only recently been introduced. Currently at INCO, shotcrete is primarily used: to provide support in poor ground conditions, to add stability when developing through backfill, and to provide damage control in seismically active mines. It is also used to protect production headings and secondary-blasting chambers from fly-rock damage during blasting. Despite an obvious support function of the liner, shotcrete has always been used in addition to bolts and screen. Comparatively, Mineguard is still in the testing stage, where the greatest potential is increased productivity for applications in multi-tasking development headings. In this scenario, Mineguard provides instant support to replace screen, and bolts temporarily. When the heading has advanced, the drill and support crews work in tandem, drilling off the next round and installing bolts for long-term radial support, respectively. Other potential applications of Mineguard are within production headings to replace screen in the back, and screen and bolts in walls. The potential for both liners to replace conventional support is clearly war-ranted, such that defining the support role was the primary goal of the two underground trials."

Jan 1, 1996

By Yunsheng Yao, P. Golledge, A. D. S. Gillies

In order to investigate the explosibility of sulphide mineral dusts, sulphide ore samples were collected from five underground metalliferous mines in Australia. The mineralogical and chemical composition of the dust samples was analysed by X-Ray Powder Diffraction and Atomic Absorption techniques. Simulated post detonation fumes were produced and used in dust explosibility tests to examine the influence of the fumes on sulphide dust ex- plosions. These tests were conducted in a 20 Litre Siwek Explosion Chamber with measurement and control system that is regarded as a standard testing system worldwide for dust explosion studies. The dust mineralogical composition and dust explosibility tests indicated that the content of sulphur can not accurately predict the explosibity of the sulphide dust. The percentage content of pyrite in the sulphide dust can be a relatively reliable diagnostic criterion in evaluating the risk of sulphide dust explosions in the mining of a massive sulphide orebody. The hybrid explosion tests demonstrated that the post detonation fumes from ANFO not only decrease the lower explosion limit of the sulphide dusts, but also increase the severity of the dust explosions. The explosion pressure reaches its peak value when the fumes content in the explosion chamber is about 20 per cent by volume

Jan 1, 1997

By Chi-Mun Song, Seok-Hyun Choi, Seok-In Hong, Han-Kee Jang

Accurate measurement and evaluation of hand-transmitted vibration from a power tool is an important issue for tool manufacturers, because they are obliged to develop low-hazard power tools for workers. The International Standard ISO 5349(1) dictates a systematic procedure for the measurement and evaluation of hand-transmitted vibration. However, the uncertainty in this measurement is too large for manufacturers to apply such data to the design and modification of power tools. There can be several sources of this uncertainty in such measurements; e.g., operator-dependent, power tool-dependent, and operational conditions (see Table 1). For a manufacturer to characterize the exposure of a power tool’s use to a given level of vibration, the relationship between these uncertainty factors and the measured vibration must be elucidated. In this study, we investigated the effect of several factors on the uncertainty in measurements. [ ] Methods In this study, some of the factors in Table 1 were selected for examination, and their effect on the measured variation was quantitatively investigated. Three tools from the same manufacturer were sampled at random in our experiments, and each of five of the same type of insert (disks or tips) was installed into each tool. Although each of the tools and inserts were of the same design and were made by the same production process, they differed from one to another, which can be a source of the variation in the measured vibration. Three human subjects participated in our experiments, which were carried out as stated in ISO 5349. The subjects were asked to maintain their posture, and the applied force was kept as constant as possible. The applied force was monitored using an indirect method, where vibration energy was displayed in real time during the experiment using a three-axis accelerometer attached to the work piece at a specified point. The appropriate range of the applied force was predetermined to cover the range of real work operations. The engineering tolerance between the inner diameter of a grit disk and the outer diameter of the tool shaft leads to an eccentricity of the mass at the center of the disk. The degree of eccentricity varies with installation, and this is another source of uncertainty. In our study, the effect of this eccentricity was investigated by carrying out repeated assembly and disassembly of an insert.

Jan 6, 2006

By Peter N. Calder, Garston Blackwell

"The history and analysis of a structurally complex open-pit rock slope displacement are described. The failure involved part of the only haulage access to a major ore zone. The ongoing movement was monitored using an electronic distance measuring device and a continuous electronic system specifically designed for the problem. A major fault, infilled with a thick clay gouge, and intersected by other structural features, resulted in the transfer of weight to a rock mass acting as a buttress in the lower regions. Movements were affected by blasting vibrations and ground-water conditions. Remedial measures included limiting blasting levels and lowering the water table, following which mining was successfully resumed in the area.IntroductionBrenda Mines is situated in a mountainous region of the southern interior of British Columbia; the location is indicated on Figure 1 . The elevation is approximately 5000 ft , giving a climate typical of more northern areas. Temperatures vary from -30°C to + 30°C. A snowfall level of 400-800 cm is experienced from November to April. During the spring, a heavy runoff period occurs, increasing the pumping rate in the pit from a nominal 50* gal/min to 2000 gal/min.The orebody occurs in a fractured Jurassic rock mass referred to as the Brenda Stock; it is approximately 3000 ft in diameter and 1000 ft deep. The Brenda Stock was intruded into the Upper Triassic Nicola Group tuffs, breccias and argillites. Mineralization occurred in several stages in a relatively homogeneous quartz diorite host rock. Shearing, faulting and jointing occured later in many stages, producing mineralized clay gouge zones up to several feet in thickness'> , These gouge zones have a major effect on the stability of the pit walls.The structural geology of the pit walls is otherwise relatively simple. Figure 2 is a conventional pole diagram indicating the orientation of the rock structural systems which are present. The major system has an average dip of approximately 70 degrees to the south and strikes approximately east /west , it is not undercu t by the pit slope. Figure 3 is a photograph of part of the North wall on which this system is indicated.The basic pit design consists of a working bench height of 50 ft, with a final wall height of 100 ft between berm s and a 100-ft-wide berm every second lift. Combined with a local face slope of 50-70 degrees, the resulting wall slope, not including haulage roads, is 45 degrees. Figures 4 and 5 are generalized plans and sectional views of the pit."

Jan 1, 1980

By C. O. Aksoy, G. G. U. Aksoy, A. Fisne, I. Alagoz, E. Kaya

Coal produced in underground mines is transported to the surface by means of conveyor belts throughout long roadways. The combustion of belts puts a large number of employees at great risk. Underground collieries differ from other underground mines -due to the combustible nature of the product. The most prevalent cause of belt fires in underground coal mine is spontaneous combustion due to oxidation of the coal, which also enables the conveyor belt to burn over time. In 2014, a belt fire in an underground coal mine in Manisa-Soma, Turkey caused 301 fatalities. A study has been conducted on this accident for approximately 3 years, consisting of combustion tests in a purpose-built research gallery, comparison of the test results with mine records of the accident, and CFD modelling of the mine environment. The intensity of the fire was sufficient to redirect the air flow underground, causin large amounts of toxic gases to fill almost the entire mine in approximately 15 minutes. It is recommended that CFD analysis be used in planning emergency action strategies in underground mines.

Dec 13, 2023

By N. S. Tanious

This paper summarizes results from an investigation into possibly the largest coal pillar failure in the USA. The newly opened coal mine worked an 3.35 m (11 ft) seam under overburden depth that ranged from 91 to 671m (300 to 2200 ft) . The mine main entries, and the enclosed pillars, experienced a massive slow squeeze. The squeeze could not be controlled and the mains were lost. A new set of mains were driven. Entry convergence (closure) measurements were carried out behind the advancing face to monitor stability. Pillar stresses were also measured under four different depths of overburden: 229.433, 472.579 m (750,1420,1550, and 1900 ft). The strength of pillars in the new mains was calculated from the loads that triggered the failure in the old mains, using three pillar strength formulas. The stress measurements showed that the new pillars supported more load than their predicted strength, indicating that current strength formulas are inadequate under deep conditions.

Jan 1, 1992

By N. S. Tanious

This paper summarizes the results of an investigation into possibly the largest coal pillar failure in the USA. The newly opened drift mine is located in Southeastern Kentucky and worked an 11 feet thick coal seam, all other mines in the District worked seams 4-5 feet thick. The initial mine development consisted of 14 main entries (Fig. 1) which were driven in two sets of 7, under increasing depth of overburden. As the left seven entries came under deeper overburden the pillar ribs began sloughing which caused many of the concrete-block ventilation stoppings to crack. The mine management stopped the advance in the left seven and continued with the right seven entries. During the spring of the following year development resumed in the left seven, rib sloughage occurred again and this time severely cracked many stoppings and many were totally disintegrated from the excessive deformation. Within few weeks the sloughage was so heavy that many of these entries behind the active face were filled with piles of sloughed coal slabs. When the face reached a depth approximately 1150 feet, the sloughage became a slow, massive squeeze. The entry convergence (closure) reduced their height from 11 to 7-8 feet and the squeeze spread back to shallower depth covering an area roughly 300 pillars.

Jan 1, 1989

By M. J. Friedel, D. E. Scott, T. J. Williams

Rock masses in deep level mines are subject to high stresses, which can result in unexpected failure of rock into mined-out openings. Historically, various independent methods have been used to discern the causes of rock bursts and to evaluate stress conditions in rock masses susceptible to violent failure. Personnel from two research centers of the former U.S. Bureau of Mines, Spokane and Twin Cities, investigated a rock burst that occurred in May of 1994 in a rock mass between the 4400 and the 4600 levels of the Sunshine Mine, Kellogg, ID. The team evaluated the current state of stress in the pillar and the most likely cause of the rock burst by studying the seismic history of the pillar, examining the geology, analyzing the available in situ stress data, calculating possible fault-plane solutions for the burst, and performing a seismic velocity tomographic survey. The results of the study showed that post-rock-burst seismicity was concentrated about 15 to 30 m west of and about 15 m above the rock-burst location. The pillar is composed of a very hard sericitic-to- vitreous quartzite of a type rarely found in the mine, but that is often found in other district mines having a history of seismic activity. In situ stress analysis of the pillar and the surrounding rock mass showed a probable stress rotation from northwest-southeast to east-west. Of four fault plane solutions, the most probable was either a left-lateral, strike-slip movement with a compressive principal stress oriented nearly north-south, or a right-lateral, strike-slip movement oriented east-west. Finally, tomographic images showed low-velocity areas (interpreted as areas of low stress) associated with the crosscuts and haulageways, and high-velocity areas (interpreted as areas of high stress) associated with the rock-burst location. High velocities were also found in a planar area oriented in an elongate northeast-southwest direction.

By David Garry, Michael J. Brnich, Lynn L. Rethi, Henry P. Cole, William J. Wiehagen, Roberta A. Calhoun

This document contains most of the materials needed to use the exercise. The main part of the document is the instructor's copy. It tells how to use the exercise, presents the objectives, the master answer sheet, the scoring key, and discussion notes to be used following the exercise. The next section summarizes results from field tests of the exercise, and reports the miners' evaluation of the activity. The last part of this document is three appendices. Appendix A is the exercise problem booklet. This booklet can be duplicated locally. The booklets are reusable. One is needed for every person in the classroom. Appendix B is the answer sheet and the trainee's questionnaire. Copies of this answer sheet must have the latent image (invisible) ink answers that appear in Appendix C printed on them.1 Answer sheets are consumable. One is needed for each person or each small group of persons who work the exercise. Exercise Summary Read this section first. It determines if the exercise is appropriate for your classes. If you choose to use the exercise, examine the table of contents and review the remainder of this document. Type: Latent image Audience: Supervisors, Safety Personnel and Accident Investigators Length: Eight questions (30 minutes for administration plus 30 for discussion) Skills: Developing a strategy or plan to prevent slips and falls Following correct procedures in conducting an accident investigation Preventing unsafe work practices Recognizing and instituting hazard controls in the section Identifying and implementing safe work procedures Location: Underground coal mine section Problem: You have been the general mine foreman at White Rock Mine for 4 years and have worked at this mine for 12 years. The mine superintendent calls you into his office. He gives you an accident report of an employee in 4-G section who was injured while carrying rock dust bags from the rock dust car to a battery powered scoop. It is several days after the accident and the mine superintendent assigns you and the safety supervisor to thoroughly investigate the accident to determine all the contributing factors. Your job is to make specific recommendations to prevent future slipping/tripping accidents.

Jan 10, 1999

By Gary Buchan

"Mine-wide ground control stability is essential to any mining operation to prevent catastrophic failure of underground structures. The ability to recognize or indicate the potential for ground control hazards in underground mine operations is highly desirable to reduce or eliminate ground-control-related injuries and fatalities. The acoustic emissions (AE) form of non-destructive testing has been used for decades to determine material or machine deterioration or potential failure. This paper presents the findings of research in AE with the results of laboratory bolt pull tests and comparisons to field experimentation, including AE sensors and bolt load data in an underground stone mine. The goal of the project is to compare laboratory results of AE sensors on roof bolt pull tests with field experimentation to determine the capability of predicting bolt failure or roof deterioration.INTRODUCTIONMine-wide ground control stability is essential to any mining operation to prevent catastrophic failure of underground structures. The ability to recognize or indicate the potential for ground control hazards in underground mining operations is highly desirable to reduce or eliminate ground-control-related injuries and fatalities. Typical ground control monitoring devices involve drilling into roof or rib, grouting or gluing of sensors, and dedicated cabling for data collection. One of the original goals of this research was to develop a methodology for a simple wireless device that could provide an indication or warning of potential roof bolt or roof failure. Various types of nondestructive testing (NDT) have been used for decades to determine material or machine deterioration or the potential failure of either. One type of NDT is acoustic emission (AE) monitoring, which has been studied for use in mining to predict rock bursts and mine failures since the 1940s (Obert, 1941; Obert and Duvall, 1942). The primary goal of the work was to compare laboratory results of AE sensors on roof bolt pull tests with field experimentation to determine the capability of evaluating bolt loading or roof deterioration in an underground stone mine. Bolt pull tests were conducted in the laboratory to establish a repeatable trend of AE activity versus bolt load. The second part of the project was to then install bolt load cells in an underground stone mine and monitor AE activity in the vicinity of mining."

Jan 1, 2018

By Sunny Schoone, Maximilian Getz, Felix Leaman, ELISABETH CLAUSEN

Hydraulic transport is commonly used in mining for moving particles or ore concentrates in pipes over long distances with a water stream. Control and monitoring of this process require sensor technology that can obtain relevant characteristics of the two-phase flow. This work investigates the acoustic emission (AE) technology for monitoring a hydraulic system with different sand concentrations, showing the strong relationship between friction behavior in the pipe and the measured AE signals.

Apr 1, 2023

By Sunny Schoone, Maximilian Getz, Felix Leaman, ELISABETH CLAUSEN

Jan 5, 2023

By S. Ozbilen, B. Erdogan, M. Erdogan

To study by thermal analyses the response of precipitation hardenable alloys of Al-Cu-Mg and Al-Li-Cu-Mg system to natural and artificial ageing, a series of ternary and quaternary Al-alloys with nominal compositions of Al-l.13wt%Cu-0:65wt%Mg (alloy-I), Al-1.15wt%Cu-0.57wt%Mg-0.07wt%Li (alloy-2), Al-l.19wt%Cu-0.56wt%Mg-0.75wt%Li (alloy-3), Al-2.0lwt%Cu-0.89wt%Mg (alloy-4), Al-2.14wt%Cu"0.56wt%Mg-0.07wt%Li (alloy-5) were used in the present investigation. Samples in the form of rolled sheets are subjected to water quenching at 25EC after solution treatment at 530EC for 20 min. Alloys were aged naturally at room temperature (25EC) up to 2 months and artificially at 190EC up to 2 days. By using differential scanning calorimetry (DSC) in the temperature range of25-300EC, differential thermal analysis (DTA) in the temperature range of25-600EC together with Vicker's hardness measurements, the response to natural and artificial ageing of the alloys used in the present study were investigated. It was observed that in these alloys, GPB(Cu, Mg) zones [Guinier-Preston zones with Cu and Mg] do form during water quenching at 20EC following solutionizing heat treatment. Natural ageing of the same alloys causes formation of more GPB(Cu, Mg) zones, which results in hardening in the alloys. Artificial ageing at 190EC up to l day results in GPB zone dissolution causing preliminary decrease in hardness values while two days of artificial ageing in the alloys cause S' (Al2CuMg) precipitation confirmed by DSC/DTA analyses resulting in an increase in hardness values. Li addition up to 0.75wt% helps T1 (Al2CuLi) and T 2 (Al6CuLi3) phase formation together with S' precipitation as DSC/DTA analyses show after the same heat treatment.

Jan 1, 1998

By Serdar Aktaş, Burcu Nilgün Çetiner

According to critical statistical studies, antimony is one of the rarest elements in the world, and global resources could be exhausted by 2050. In light of these observations, its extraction will be costly due to poor-quality ore, deep mining, remote locations, and high energy consumption. In the present study, an alkaline leaching process was carried out on stibnite concentrate to evaluate the effect of reaction parameters on the percentage of antimony extraction. The leaching efficiencies of different sulfur and hydroxide sources were studied and compared to one another to create a better understanding of the reaction process. Kinetic models were investigated to identify the reaction pathway and calculate the activation energy. The activation energy of the stibnite dissolution was assessed as 19.13 kJ/mol using a two-dimensional diffusion-reaction model. The value of activation energy indicates the quantity of energy necessary for a reaction to proceed. As expected, potassium hydroxide leaching was significantly more successful than was sodium hydroxide; however, in terms of economics, the use of sodium hydroxide was found to be more cost-efficient. Interestingly, this finding indicated that caustic leaching is still the most effective method for stibnite extraction.

Jul 23, 2020

By BURCU NILGUN CETINER, Serdar Aktas

Antimony has been used extensively in industry and in everyday life since the 19th century, and antimony sulfides have been known since around 4,000 B.C. Antimony’s most significant applications are as a flame retardant in the manufacture of electronics and textiles, as a catalyst for plastic fabrication, and as paint pigment and fining agent in glassware, opacifier in ceramics and an alloying element in ammunition and battery manufacturing plants. It is also used in vehicle brakes and tires. Brake pads contain stibnite (Sb), the sulfide compound of antimony. In particular, stibnite is used in automobiles as a lubricant, vibration reducer and friction stability improver. Anthropogenic activities are the primary source of antimony in the atmosphere [1,2]. Annual global consumption of antimony has increased to more than 1.4 × 105 t, and China is the most significant producer [2].