Search Documents

By G. Plascencia, A. Warczok, M. Zamalloa, T. Utigard, N. Behnood

The objective of this investigation was to investigate interactions between high-grade copper mattes and Rexal 60DB direct bonded basic bricks. The infiltration and attack of Rexal 60DB bricks by copper matte and continuous converter matte was investigated in laboratory tests at temperatures up to 1300 °C. The brick dissolution and infiltration tests did not show any significant difference between the 70% Cu and the 81% Cu mattes. More metallic copper was visible in the pores in the case of 81% Cu matte. An important mechanism for direct-bonded magnesia-chrome brick destruction is that oxysulphides start to infiltrate the brick, followed by slow oxidation of the matte producing metallic copper and cuprous oxide, which then react with MgO and Cr2O3, primarily attacking the direct bonds of the brick.

Jan 1, 2004

By Michot LJ, Kongolo M, De Donato PH

Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS), Hallimond tube flotation tests and microelectrophoresis measurements have been used to investigate the reactions involved in the adsorption-ion of K-amyl xanthate on finely ground pyrite. Pure pyrite was finely wet ground, at different pH values, in specially built laboratory stainless steel or iron rod mills. Amyl dixanthogen was the only product identified on the surface of pyrite when stainless steel rods were used. When iron rods were utilised, ferric xanthate and physically adsorbed xanthate ions were observed in the superficial phase. The use of iron media was found to depress slightly the floatability of the mineral.

Jan 1, 1993

By P. Semberg, B. Bjorkman, C. Andersson

"In this study, the interaction between magnetite and the additive olivine was studied after oxidation as well as after isothermal reduction at temperatures in the 500º-1,300º C range. In the olivine sample, the forsteritic olivine particles react partly during the oxidation pretreatment to form magnesioferrite and vitreous silica along the particle corona. This breakdown of the olivine particles during oxidation liberates magnesium from the particles, which do not react until temperatures of above 1,150° C in reducing atmosphere. When the hematite in the sample is reduced, and when the temperature is high enough to allow solid-state diffusion at ~800º C, the magnesium of the magnesioferrite redistributes, so that the magnesium concentration approaches the same level throughout the iron oxide structure. For magnetite, this did not occur until 800° C. At 1,000° C, this magnesium reacts further with the silica in the glassy slag phase, which crystallizes into fayalitic olivine. At this temperature, the magnesium has diffused over distances of more than 600 µm from large olivine particles after 2 hrs reduction. From this point, the primary slag phase in the pellet, until melting, is solid fayalite. Upon reduction to metal, the metallization front concentrates the MgO in the remaining wustite, which can lead to MgO levels of up to 10 mole% locally. The melting point of the fayalite is raised from 1,145º C to a melting range of 1,238-1,264º C due to the MgO increase, as estimated based on phase diagrams, which were adapted to the pellets tested. Much of the olivine that remained unaltered in the oxidation process will be encapsulated by iron before the particles begin to dissolve in reducing conditions and, therefore, plays no role in the reduction before final melting of the particles occurs.IntroductionEnvironmental concerns have placed increasing pressure on the CO2-intensive iron and steel industries to further optimize operation toward higher productivity and more efficient use of reducing agents. At the same time, high demand for iron ore has caused new iron ores with lower grades and more complex chemistries to be taken into production. In Scandinavia, the main iron-bearing material is magnetite-based pellets with olivine, which allow operation with very low slag volumes and, hence, lower fuel rate ( Slagnes and Sundqvist Ökvist, 2008; Hallin et al., 1994). Both the MgO and SiO2 of the olivine, as well as the elements of the gangue of the ore, i.e., Si, Mg, Ca, Al and alkali, interact with the iron oxides to give the finished pellet product its final properties in the blast furnace. Tailoring the additive mix to be used for a certain iron ore for optimal product properties, therefore, requires detailed knowledge of the mechanisms by which these elements dissolve and react in the pellet."

Jan 1, 2015

By M. Zolghadri

MIBC and sodium metasilicate are used as a frother and a dispersant in coal flotation respectively. In order to study interaction between them, flotation experiments were performed on fine coal (<150 microns). It was found that if the frother (MIBC) dosage is in excess of a certain limit, it has an activation effect on the gangue minerals associated with coal. In addition, it was found that however sodium metasilicate can disperse clay slimes eliminating slime coating, but in the case of excess dosage, could intensify activation effect of MIBC, which is undesirable in coal flotation. Keywords: coal flotation, sodium silicate, frother, dispersion, activation

Sep 1, 2012

By Aly M. Mohammad

The 12th and 14th Street Viaducts, which carry Route 139, are located west of the Holland Tunnel in Jersey City, New Jersey. The two viaducts, provide access to and from the Holland Tunnel (which connects New York City and New Jersey) and carry upwards of 50,0000 vehicles per day from Jersey City and New York City to points west. The New Jersey Department of Transportation (NJDOT) selected AECOM to perform design services including rehabilitation and seismic retrofit for the 12th Street and 14th Street Viaducts while maintaining traffic at all times. Building a new parallel bridge just north of the 14th Street Viaduct was essential in avoiding extremely costly traffic delays. Installation of the new foundation, in close proximity to the existing viaduct, required drilling through some of the existing timber piles supporting the bridge. As a result, the existing bridge was required to be reanalyzed for this new foundation configuration. This proposed structure consisted of 8 piers each supported on a single six (6) foot diameter drilled shaft. Currently this portion of the bridge structure has been constructed. The shafts were constructed with rock sockets that were five feet six inches (5?- 6??) in diameter and were extended 11.2 feet (3.4 meters) into rock. A 2300 ton Osterberg Load Test was performed on one production shaft to confirm the capacity of the shaft. The rock socket for the test shaft was in sandstone. This paper will present a description of the design methodology and construction methods adopted for the foundations. In addition, the paper will illustrate the Osterberg Load Test including: equipment used, number and locations of strain gages, and interpretation of results. Additionally, regarding the close proximity of the new foundation, the paper will present the type of equipment used to drill through the existing timber pile foundation while minimizing the impact on the integrity of the existing foundation. We will also present the method of analysis for analyzing the redistribution of load on the remaining piles. The results presented in this paper will assist the design engineer by providing a comparison between the geotechnical design assumptions and the actual measurements obtained by field measurements for this rock formation.

Jan 1, 2009

By H. Polat

Relatively large amounts of such hydrocarbons as fuel oils are often needed in flotation of low rank coals. The amount of oil can be decreased considerably by using surfactants as promotors. The reagents which are good candidates as surfactants to promote hydrophobicity can also act as emulsifying and wetting agents. Since the physical and chemical variables influence various sub-processes in different ways, their influence on the performance parameters is complex. The results of laboratory tests are presented to show that the dual role of reagents can be judiciously exploited to increase both the recovery and grade of clean coal. The mode and order of reagent addition is critical in enhancing their efficacy as flotation promotors. The results demonstrate the benefits of proper conditioning of the pulp prior to flotation.

Jan 1, 1997

By H. Polat, S. Chander

Relatively large amounts of hydrocarbons such as fuel oils are often needed in the flotation of low rank coals. The amount of oil can be decreased considerably by using surfactants as promoters. The reagents that are good candidates as surfactants to promote hydrophobicity can also act as emulsifying and wetting agents. Because the physical and chemical variables influence various subprocesses in different ways, their influence on the performance parameters is complex. The results of laboratory tests are presented to show that the dual role of reagents can be judiciously exploited to increase both the recovery and grade of the clean coal. The mode and order of reagent addition is critical in enhancing their efficacy as flotation promoters. The results demonstrate the benefits of proper conditioning of the pulp prior to flotation.

Jan 1, 1999

The objective of extensive underground experimentation on three longwall coal faces was to improve the stability of mechanised longwall faces through investigation of the relations between support resistance and convergence and resultant deformation of roof and face strata. In particular the influence of high setting and yield pressures on several strata and support parameters was studied in great depth. Increased setting pressures resulting in an increase in setting load densities from 0.15 MN/m2 to O.45 MN/m2 were shown to reduce convergence, face spalling roof flaking, lateral movement of roof and floor, extrusion of the face wall and progressive failure of the coal wall ahead of the face. This was shown to result mainly from the change in roof strata deformation from a wedge shaped compression zone with tension at the face edge to an even beam shaped compression zone over the face area. Debris thickness above the support canopy and below the base was observed to be the one of the most variable parameters which influenced the support characteristics particularly the rate of load acceptance by supports and the roof to floor convergence. A setting load density of 0.4 MN/m2 to 0.5 MN/m2 was found to be optimum under soft to moderately strong sandstone roofs. The authors demonstrated that use of guaranteed set valves with powered supports contribute to good strata control, reduce face down-time and increase face productivity.

Jan 1, 1984

By M. W. Grabinsky, J. H. Curran

"Characterizing the spatial distribution of rock stresses is a challenge, especially in the geologically complex environments typically found at most metalliferous mines. Therefore, instead of focusing, specifically, on the task of making stress measurements, the engineer should instead attempt to develop a better understanding of the interaction between stress, mining geometry and rock mass behaviour. This paper demonstrates such an approach using a Canadian Shield hardrock mine case study, in which geomechanical models are used to relate stress, mining geometry, and rock mass properties to observed excavation response, and numerical modelling is used to better quantify this interaction.IntroductionUnderstanding how the mine geometry, field stresses and rock mass interact to produce the observed rock mass response to mining can be a significant challenge. Consider our present ability to quantify the basic geomechanical design input data. Mine geometry is normally quantified in more detail than is required for analysis purposes. Our understanding of rock mass strength and stiffness is far from complete, but established procedures do exist to obtain estimates of these parameters based on index and laboratory testing data and field mapping. Our ability to quantify field stresses is probably the most limited, in part because stress measurements are difficult and expensive to carry out, and in part because the stresses vary to an unknown degree from point to point within the rock mass. The engineer must, therefore, consider whether or not stress measurements are justified and, when they are, where the average stress state needs to be quantified and how many of which type of measurements will be required to determine the average stresses.Such was the case at Ansil mine, a massive sulphide deposit in hard rock located at a depth of more than one kilometre in the northern Québec portion of the Canadian Shield. The Ansil orebody was relatively rich, but small, with the potential for significant stress-related problems. As a result, geomechanical design had to be done carefully from the start – there would be little opportunity to modify the mining strategy once production had begun, and the economic consequences of stope dilution and rock mass instability would be severe. An extensive stress measurement campaign was carried out, but the determined stress magnitudes were unexpectedly low. The designers were, therefore, faced with a dilemma:"

Jan 1, 1997

By Peter Townsend, Sergei Diachenko, Allan Moss

The Palabora Mining Company has successfully extended the life of its operation by developing a 30,000tpd block cave underground mine below the now closed open pit. The process of transitioning from surface to underground mining has been technically, operationally and managerially challenging. This has been due to a number of factors; in particular, the development of a block cave in a very competent rock mass. The competence of the rock mass is clearly demonstrated in the open pit that preceded the block cave, one of the steepest deep open pit excavations in the world. With cave breakthrough, however, the pit was ?instantaneously? deepened by 400m causing a major failure of the northwest wall involving close to 100Mt of waste material.

Jan 1, 2006

By A. Moss

The Palabora Mining Company has successfully extended the life of its operation by developing a 30 000 tpd block cave underground mine below the now closed open pit. The process of transitioning from surface to underground mining has been technically, operationally and managerially challenging. This has been due to a number of factors, in particular, the development of a block cave in a very competent rock mass. The competence of the rock mass is clearly demonstrated in the open pit that preceded the block cave, one of the steepest deep open pit excavations in the world. With cave breakthrough, however, the pit was ?instantaneously? deepened by 400 m causing a major failure of the north-west wall involving close to 100 Mt of waste material.

Jan 1, 2006

By C. S. Spirakis, A. V. Heyl

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The modified basinal brines, containing partly oxidised sulphur species, scavenged metals from basement rocks and sediments and transported them through the host rock, which contained local concentrations of organic matter. Reacting in various ways with the mineralising solution as temperatures at the sites of mineralisation changed, organic matter caused the precipitation and dissolution of a variety of minerals in the ore zones; it was organic matter that caused all of these reactions to occur at the same sites. Thus all components of the mineralising fluid - salt, water, heat, sulphur and metals - were obtained within the ore district. The siting of the mineral districts was related to the locations of faults through U- and Th-enriched granites beneath sediments containing basinal brines, and the locations of ore deposits within the districts were controlled by local concentrations of organic matter

Apr 1, 1995

By F. Karakas

Water based paint formulations consist of some industrial minerals with quantities varying from 20 to 50 %. Quality of paint is directly related to these minerals used as pigment or filler in the production. Titanium dioxide is the most important and expensive pigment in paint formulations. Other minerals such as calcite and calcined kaolin are used as filler and mainly as a substitute for TiO2. Consequently, particle-particle interactions including adsorption, coating and size distribution of pigment mixture directly affects the paint quality. In the present paper, a new type of pigment mixture for possible use in architectural water based paints was developed through grinding. The effect of different types of grinding methods on physical properties of TiO2 and calcite mixture and the quality of paint produced by these mixtures have been revealed. Three different types of mills; conventional ball mill, vibratory ball mill and high-speed attritor were used for grinding of TiO2 and calcite. Viscosity, zeta potential and particle size distributions were used to characterize the pigment mixtures obtained upon grinding. The quality of paint was evaluated by standards based on both wet and dry paints such as viscosity, density, opacity and gloss. The paint produced with the pigment mixtures prepared in vibratory ball mill and high speed attritor showed improvement in physical properties particularly in the distribution and dispersion of mineral particles. Keywords: grinding, pigment, paint, TiO2, calcite

Sep 1, 2012

By John C. Brower

The purpose of this paper is to examine the Gays in which- the policies of the U.S. government, mining companies and third world countries affect each other with regard to the availability of minerals. The interaction involves U.S. policy towards the mining industry, the policies of the companies themselves, and the policies of third world countries towards the U.S. and multinational companies. It is assumed in this discussion that U.S. policy will continue to be to seek certain minerals from abroad rather than attempt to develop domestic sources for all its requirements. This would seem to make sense both from the standpoint of cost, and for preserving what domestic resources there are so as to maintain some degree of market leverage. In today&apos;s jargon, this means greater dependency on the "third world", which, for this discussion, includes virtually all the nations in Africa, South America and Asia. Concern for availability raises the important distinction between dependency and vulnerability, and as the Director of the Bureau of Mines has pointed out, the two are not the same. Dependency is not neccessarily a bad thing; it is vulnerability that counts (Norman, 1980)

Jan 1, 1982

By D. Denton, C. Peppin, D. Tesarik, D. Bayer, J. B. Seymour

Hecla Mining Company and NIOSH cooperated in a study to document the safety of rock support supplied by reinforced cemented paste backfill at the Lucky Friday Mine. Data are presented on backfill modulus values from laboratory tests and compared with modulus values from in-mine wall closure on the backfill. It is theorized that a compressive zone is created in the backfill between the upper and lower bearing plates on the reinforcing bolts, and that the backfill remains stable as long as the compressive zones from adjacent bolts overlap.

Jan 1, 2001

By R. K. Dunham, A. N. Styler

The results of two studies into the effects of undermining offshore room and pillar workings by longwall faces are presented. The first study indicated no potential instability from undermining one level of room and pillar workings. On the basis of this it was decided to undermine two levels of room and pillar workings, again monitoring pillar stability. The results showed no signs of increased instability.

Jan 1, 1982

By S. Veeramasuneni

The interaction of soluble salt particles in their saturated brines is of interest from both a fundamental and practical perspective. The state of dispersion/aggregation of alkali halide particles as determined by optical microscopy can now be described based on non-equilibrium electrokinetic measurements for alkali halides. These results indicate that the sign of the surface charge has a significant effect on the extent of particle dispersion/aggregation. Atomic force microscopy (AFM) is now being used to directly measure the interaction forces responsible for the stability of these alkali halide aggregates observed in optical microscopy studies. These experimental results can be explained based on the interfacial polar interaction theory. In this regard the nature of such particle interaction forces at high ionic strengths are examined to improve our understanding of these systems.

Jan 1, 1997

By V. K. Paruchuri, J. D. Miller, J. Nalaskowski

An understanding of forces responsible for the stability of dispersions of colloidal particles when interacting with each other in aqueous solutions is of great interest academically and industrially. When water-soluble polymers are adsorbed onto colloidal particles, various effects on the stability of their suspensions can be expected ranging from steric stabilization to bridging flocculation. The possibility of detailed characterization of such systems using direct measurements of interaction forces between particles can help in further improvement of existing technologies of solid-liquid separation. An atomic force microscope (AFM) colloidal probe was used to measure the interaction forces between a silica sphere and a silica substrate in the presence of water-soluble polymers. Poly(ethlene oxide) (PEO) with three different molecular weights (7,000, 43,000, and 63,000), each with a very narrow molecular weight distribution, were used in this study. The interaction forces measured with the AFM over an extended time scale are discussed in terms of the adsorption kinetics measured through in-situ FTIR/IRS measurements.

Jan 1, 2003

By Falbo A, Quarestima S, Cozza C, Barbaro M

A new synthetic reagent of the mercaptobenzoxazole class, 5- methyl-2-mercaptobenzoxazole, has been studied. This reagent exhibits powerful selective collecting action towards copper sulphides present in several complex ores, as demonstrated both by laboratory and pilot plant tests. Industrial production is expected to start in the near future. The way this reagent reacts with pure chalcocite has been studied utilising in situ FTIR techniques, adsorption tests, electrokinetic potential measurements and Hallimond cell flotation tests. The FTIR studies have indicated the nature of the surface phase. Adsorption isotherms obtained by the rest method have revealed the quantitative evolution of surface products, permitting the determination of surface coverage at various reagent concentrations. The electrokinetic potential has been utilised to verify the stability of individual species in diverse concentration ranges. Correlation of the results obtained has provided indications on the chemical interaction of this reagent with the surface and on the surface Arrangement.

Jan 1, 1993

By Yujing Jiang, Xuezhen Wu, Bo Li, Tomomi Iura, Gang Wang

"Yielding bolt has been widely used for rock reinforcement in mining and civil engineering in high stress conditions. However, the interaction mechanism of yielding bolt and matrix mass is still not clear at present, and no analytical model is available to predict its reinforcement effect quantitatively. In this paper, the mainstream yielding rock bolts were reviewed firstly. After that, a coupling model is proposed to account for the interaction between yielding bolt and matrix mass. Based on the plane strain axial symmetry assumption and the incremental theory of plasticity, equilibrium equations and compatibility equations of matrix mass, and also the response of yielding rock bolt are deduced theoretically. The proposed method was programmed in Visual Basic development environment, and a semi-analytical solution for the coupling model is achieved. The reinforcement mechanism of yielding bolt in conventional tunnelling is clearly demonstrated through an illustrative case study. The reinforcement effect of yielding bolt is estimated quantitatively, and the distribution of axial force along the bolt is presented. In addition, the validity of proposed method is verified by numerical simulations. INTRODUCTIONHigh stress in surrounding rock mass can cause serious stability problems such as massive squeezing in soft rock and rock burst in hard rock. It is observed that many conventional rock bolts failed when experiencing large displacement, which implies that they are too stiff to sustain large deformation and dynamic conditions (Stillborg, 1994; Hoek et al., 1995). Yielding bolt, which can also be called energy-absorbing bolt, has been widely used for rock reinforcement in mining and civil engineering for these conditions (Neugebauer, E., 2008). This paper focuses on the static reinforcement effects of the yielding bolts with analytical method and numerical simulations."

Jan 1, 2015