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By M. SIDDARAJU, Rameshwar Sah, T. Umadevi, K. S. SRIDHARA, B. D. Ganesh Shetty, M. RAJU

The production of high strength iron ore sinter for blast furnace iron making unit was developed by optimizing the granulometry of less than − 0.150 mm fines in sinter base mix which consists of iron ore fines (− 10 mm size with 0.150 mm: 41%), beneficiation plant jig concentrate, i.e., washed ore (− 3 + 0.150 mm size with − 0.150 mm 3 to 9%), beneficiation plant concentrate (− 0.150 mm size 97%), limestone, dolomite, coke breeze, lime, sinter return fines, direct reduced iron (DRI plant) fines, and micropellets produced from steel plant waste. The sintering process consists of preparation of base mix, mixing, and production of nodules using mixing and nodulizing drum by maintaining the optimum moisture, transferring of nodules to the sintering machine, and firing of sinter by applying optimum suction pressure. To optimize the < 0.150 mm fines in sinter base mix, the − 10-mm size iron ore fines was replaced with washed ore. The size analysis, granulation index (G index), and optimization of moisture w.r.t. sinter bed permeability were carried out by varying the washed ore addition from 0 to 55% in sinter base mix to vary the − 0.150 mm fine size. With decrease in washed ore addition from 55 to 0% in sinter base mix the finer fraction, i.e., − 0.150 mm in sinter base mix increased from 9.4 to 26.7%. Granulation (G) index increased from 1.46 to 3.10, sinter bed permeability increased from 33 to 53 Japanese Permeability Unit (JPU), and balling index increased from 1.4 to 3.0. With increase in − 0.150 mm fines in the sinter base mix from 9.4 to 26.7%, the sinter tumbler index (T.I) increased and sinter reduction degradation index (RDI) decreased. Increase in sinter strength and decrease in sinter RDI was due to increase in formation of Silico ferrite of calcium and aluminium (SFCA) phase and decrease in pore phase. The SFCA is the main bonding phase in iron ore sinter, and it provides strength to sinter. Sinter base mix with − 0.150 mm fines 18.9% (washed ore addition 25%) achieved desired sinter properties with moisture 8.0%, G index 2.44, balling index 2.3, and sinter bed permeability > 45JPU. Decreased the sinter properties with washed ore addition in sinter base mix beyond 25% due to decrease in − 0.150 mm fines in sinter base mix. Further, to improve the sinter properties with washed ore 30 to 45%, 3 to 10% beneficiation plant concentrate, i.e., − 0.150 mm fines was added to maintain the 18.9% of − 0.150 mm fines in sinter base mix. From the laboratory sintering studies, it was found that minimum 18.9% (range from 18.9 to 26.7%) − 0.150 mm fines should be maintained in the sinter base mix to achieve desired sinter properties.

Oct 16, 2021

By Sushil Bhandari

Presented here is the simplified process of fragmentation of homogeneous rocks by blasting based on experimental studies. Small scale single hole blasting experiments on jointed limestone are described. Results show that directions of joints overshadow the degree of fragmentation and also influence the remaining rock. The possible influence of joints on the process of fragmentation of non-homogeneous rock by blasting is also discussed.

Jan 1, 1983

By Vivek Priyadarshi, VIVEK KUMAR HIMANSHU, A. K. Vishwakarma, M. P. Roy, A. K. Mishra, RAVI SHANKAR

The nature and orientation of joints in rock strata affect the damage pattern under explosive loading. Most of the limestone deposits in India are found with severity of joints. Categorically, these joints may have variable orientations such as dipping out of the blast face, inside the face, horizontally or having strike parallel to the face. The damage pattern under the varying category of orientation will be different. Accordingly, a numerical model in Ansys-Explicit Dynamics was prepared to compare the damages of rock mass under different joint orientations. The physical nature of a joint reflects frictional and stiffness behaviour. Accordingly, the damages have been compared under bonded and frictional nature of joints. The output damage pattern from the model has been validated on the basis of blastability index proposed by Lilly. Different limestone mines in India show different nature of jointing in their rock strata. Accordingly, the blasting outputs from three different limestone mines, viz. Rawan limestone mine, Sagmania and Birhauli limestone mine and Injepalli limestone mine, have been compared along with their blast design parameters and the nature of joint. The comparative results show that the closely spaced horizontal joints support maximum in burden movement and rock fragmentation due to blast.

Nov 23, 2023

By W. G. Pariseau

A new approach to the direct inclusion of the effects of joints and geologic structure in rock mechanics analyses is applied to an elastic analysis of stability of a Lucky Friday undercut and 4111 longwall stope (WL) using the finite element method (FW). The approach is base+ on the concept of equivalent properties of a heterogeneous test volume, but does not depend on the assumption that a test volume is a representative volume element. Comparison with conventional FW results show greater variability in fields of stress, strain, displacement, safety factor and energy densities. Stability requires a knowledge of rock mass strengths as well as elastic moduli.

Jan 1, 1989

By Suleyman Tekeli, Serdar Salman, Bulent Aktas

"The effect of La2O3 content up to 15 wt% on phase stability, sintering and microstructure of cubic zirconia (8YSZ) was investigated. XRD results showed that the specimens containing up to 15 wt% La2O3 were composed of only cubic structure. Also, the specimens doped up to 5 wt% La2O3 revealed no La2O3 peaks, indicating that La2O3 was completely solubilized in the cubic structure. However, when> 5 wt% La2O3 was added, the peak of La2Zr2O7 compound emerged, showing that the overdoped La2O3 was not solubilized in the 8YSZ matrix. The lattice parameter of the 8YSZ slightly decreased with the increasing La2O3 content up to 1 wt% but further increase in the La203 amount resulted in an increased lattice parameter. The comparison of grain size of the 8YSZ specimens with various La2O3 content showed that grain size slightly increased with the increasing La2O3 content up to 1 wt% but further increase in the La2O3 amount resulted in a decreased grain size.IntroductionAt atmospheric pressures, three polymorphic forms of Zr02 are stable at different temperatures i.e. monoclinic, tetragonal and cubic. A high-pressure orthorhombic form of Zr02 has also been reported[l]. The successful production of pure Zr02 bodies is not possible all the time due to the large volume expansion associated with the martensitic tetragonal-monoclinic transformation. This fact restricts the applications of zirconia, in spite of its excellent mechanical and thermal properties. However, the stabilization of the high temperature polymorphs at room temperature as stable phases is made possible by addition of suitable dopants. Fully stabilized cubic Zr02 and partially stabilized tetragonal Zr02 show interesting properties and are widely used as ionic conductors, coatings and gas sensors in solid oxide fuel cells and structural applications[2]. Most frequently used dopants include Y203, CaO, MgO and Ce02, although other oxides, such as those of rare earth elements, can also act as stabilizers of the high temperature structures. The incorporation of aliovalent cations to the lattice, forming substitutional solid solutions, allows to control the concentration of anionic vacancies in the structure. This aspect is particularly important in designing ionic conductors[3], and is also determinant in the stabilization process[ 4]. The process of stabilization with larger ionic radii dopants is rationalized by the crystal chemistry model[ 5], that describes the dopant cations as typical stabilizer when they have larger ionic size, lower charged state and higher ionicity than Zr4+ The ionic radius of Zr4+ is 0.84 Å and that for La3+ is 1.016 Å [6]."

Jan 1, 2012

By Giuseppe Gaspari, Xiangrong Wang

The pandemic emergency is forcing transit agencies to define strategies allowing social distancing, which are more challenging in underground interchange stations in crowded downtown cores. Toronto Transit Commission’s (TTC’s) Bloor-Yonge Station Capacity Improvement Project in Toronto was approved to meet increasing demand and represents an opportunity to fight COVID-19. This paper discusses cost-effective solutions in expanding the cut-and-cover station box over the existing Toronto Subway Line 2 and connecting it through ventilation openings in the cast-iron tunnel liner. Potential uplift risks and structural damage due to minimal vertical clearance were analyzed via three-dimensional finite element analyses with advanced constitutive laws to simulate the multi-stage construction process. Based on the simulation results, a series of countermeasures, including excavation support systems, king posts, ground-consolidations, and liner reinforcements were integrated into comprehensive design options to ensure the serviceability and structural integrity of the subway tunnels.

Jun 13, 2021

By V. G. Mooradian, John T. Norton

THE diffusion of metal atoms into the crystal lattice of another metal and the assumption of regular positions to form a homogeneous alloy are some of the most fundamental phenomena of structural. metallurgy. The mechanism of this process has been the subject of a great deal of study from many viewpoints, but the picture is still far from complete. It is generally believed that if one metal is to diffuse into another, the first must have some solubility in the second1. This means that the solvent must be able to accommodate the stranger atoms, either on points of its own lattice or in the interstices between, without losing its own crystallographic identity. It is also a general observation that cold-working is a distinct aid in the diffusion process, causing it to take place with greater rapidity at the same temperature or with the same speed at a lower temperature. There is considerable doubt, however, as to the real significance of the deformation in its effect on the diffusion mechanism. Several factors associated with the cold-working. may be responsible for the increased diffusion rate. The plastic deformation causes a distortion of the solvent lattice, which may be an aid in the assimulation of atoms of another kind. There are many references2 in the literature that suggest that some distortion or "loosening" of the lattice is necessary for atomic migration and that diffusion cannot take place in the undis-

Jan 1, 1935

By V. G. Mooradian

THE diffusion of metal atoms into the crystal lattice of another metal and the assumption of regular positions to form a homogeneous alloy are some of the most fundamental phenomena of structural metallurgy. The mechanism of this process has been the subject of a great deal of study from many viewpoints, but the picture is still far from complete. It is generally believed that if one metal is to diffuse into another, the first must have some solubility in the second1. This means that the solvent must be able to accommodate the stranger atoms, either on points of its own lattice or in the interstices between, without losing its own crystal-lographic identity. It is also a general observation that cold-working is a distinct aid in the diffusion process, causing it to take place with greater rapidity at the same temperature or with the same speed at a lower temperature. There is considerable doubt, however, as to the real significance of the deformation in its effect on the diffusion mechanism. Several factors associated with the cold-working may be responsible for the increased diffusion rate. The plastic deformation causes a distor-tion of the solvent lattice, which may be an aid in the assimulation of atoms of another kind. There are many references2 in the literature that suggest that some distortion or "loosening" of the lattice is necessary for atomic migration and that diffusion cannot take place in the undis-

Jan 1, 1935

By J. Y. Kim, S. L. Chryssoulis

Lead ions that originate from galena during the processing of complex sulfide ores migrate onto the surfaces of sphalerite and iron sulfide minerals. This results in poor selectivity during differential flotation. Generally, in sulfide ore processing, the lead-activated minerals float in the Cu/Pb rougher circuit. The surface lead complicates the zinc flotation circuit by lowering the concentrate grade. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zu and Pb-Zu ores is discussed. Plant and laboratory-test data are interpreted by determining the surface compositions of individual grains of sphalerite and iron sulfide particles. For the first time, surface compositions were determined by using laser-ionization mass spectrometry (LIMS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS). Cationic and cationic species on the surface were analyzed to elucidate the phenomena. It was proven that these new techniques are very useful in understanding the basic mechanisms of a sulfide mineral-flotation system.

Jan 1, 1997

By James H. Barks

Exploration for ore deposits in southeastern Missouri in the 1950&apos;s resulted in the important discovery of lead, zinc, copper and silver in 1955. Further discoveries in the area led to the naming of the Viburnum trend. It has sometimes been referred to as the "New Lead belt" to distinguish it from older lead-producing areas to the east. As presently developed, the "trend" is 35 miles long, running north and south about 50 miles west of the Lead belt. Galena (lead) is the principal ore mined, with lesser quantities of sphalerite (zinc), chalcopyrite (copper) and silver recovered as economic by-products. The ore body is as much as 140 feet thick and 1,200 feet wide, and is found in the Bonneterre Dolomite (Upper Cambrian) at depths ranging from 700 to 1,200 feet. Since its discovery many companies have engaged in exploration and several major companies have developed new mines and constructed mills and a smelter in the area. The first mine in the Viburnum trend came on stream in 1960, but as more mines came on stream and others reached capacity, lead production increased to the point that the Southeast Missouri Lead district produced 432,576 tons of lead in 1970 to become the world&apos;s largest lead-producing region (Missouri Geological Survey and Water Resources, 1971). The Viburnum trend area with its rolling, heavily forested hills and numerous clear running streams is in the Clark National Forest of the Missouri Ozarks. Until the recent development of its mineral resources, the area was sparsely populated and nearly unmarked by the activities of man. Industrial development is almost certain to be accompanied by environmental changes. In a day of growing awareness of the need to preserve the quality of the

Jan 1, 1971

"The most common agglomeration technique in iron and steelmaking is sintering, which requires the use of iron ore/concentrate mixtures, limestone and dolomite as fluxes and coke as fuel in order to produce the required melt at high temperature to cause agglomeration of the particles. Sinter feed blends containing high proportions of magnetite concentrate are difficult to granulate and to produce granules of high permeability, and sufficiently robust quasi-particles for successful sintering operations. Since the granulation of iron ore sinter feed requires no use of a binder, the added fluxes play a vital role in holding the granule particles together until they sinter. The fluxes also help to improve the granule quality and control slag composition in the blast furnace. It is well-known that the particle size distribution of the fluxes affects the granulation effectiveness and green bed permeability which determine the productivity, physical and metallurgical properties of the granules and sinter. Hence it is necessary to understand the role of flux particle size on granule properties so as to improve the granulation of iron ore sinter feed blends containing high magnetite concentrate. In this study, laboratory granulation experiments have been carried out on iron ore sinter feed blends containing high proportions of magnetite concentrate at different addition levels of limestone and dolomite mean particle sizes, to understand the influence of limestone and dolomite particle sizes on granulation rate processes and granule properties.INTRODUCTION Increases in iron ore production to meet the global demand for iron and steel products has led to the depletion of high grade iron ores and thus the current utilisation of low grade iron ore fines and concentrates. However, sinter, pellets and the lump are the required feed types used in the blast furnace. The high basicity sinter is the main iron bearing feed accounting for 70-85% in the blast furnace due to its good metallurgical and mechanical properties that allow high productivity, efficient processes and low production cost (Adam et al., 2017)."

Jan 1, 2018

By B. Stewart, R. Li

Coal waste materials inhibit the direct establishment of vegetation due to adverse physical and chemical properties, particularly low water retention and high potential acidity. The Moss #1 coal refuse pile is located in Dickenson County, Virginia, and was idled in the late 1980s with little topsoil resources available for final closure. The refuse was acidic (Total S = 0.38%; pH = 3.6), black in color and high (70%) in coarse fragments. The refuse also had a low water-holding capacity (4.5% in < 2.0-mm fraction). A small plot experiment was established on the refuse pile to evaluate the effects of liming rates (50% and 100% of lime requirements) and topsoil thickness (15, 30 and 60 cm) on vegetative growth and leachate quality. Liming and topsoil amendment increased the surface soil pH from <4.0 to >6.0 over a two-year period, which resulted in greater vegetative cover and biomass than the control plots. All topsoil treatments resulted in greater vegetative cover and biomass than plots treated with lime only. This was due to improved surface soil physical and chemical properties. A topsoil treatment of 60 cm gave the thickest vegetative cover and biomass yield. Such a treatment, however, would be cost-prohibitive at this location. Applica¬tion of 27Mg ha`1 of lime to the refuse surface along with 15 cm of topsoil produced acceptable two-year vegetative cover and biomass, and this appeared to be the optimal treatment for this particular situation. Both liming and topsoil had no affect on leachate pH and the electrical conductivity of leachates collected below the plots. This suggests that surface revegetation will have little effect on the quality of water draining through the pile. Therefore, long-term water-treatment requirements may not be reduced by successfully revegetating the pile surface.

Jan 1, 2000

Coal waste materials inhibit direct vegetation establishment due to adverse physical and chemical properties, particularly low water retention and high potential acidity. The Moss # I coal refuse pile is located in Dickenson County, Virginia, and was idled in the late 1980&apos;s with little topsoil resource available for final closure. The refuse was acidic (Total-S = .. 38%; pH = 3.6), black, high (70%) in coarse fragments, and had a low water holding capacity (4.5% in < 2.0 mm fraction). A small plot experiment was established on the refuse pile to evaluate the influence of liming rates (50% and 100% of lime req.) and topsoil thickness (15, 30 and 60 cm) on vegetative growth and leachate quality. Liming and topsoil amendment increased the surface soil pH from < 4.0 to > 6.0 over a two-year period, which resulted in greater vegetative cover and biomass than the control plots. All topsoil treatments resulted in greater vegetative cover and biomass than plots treated with lime only due to improved surface soil physical and chemical properties. A topsoil treatment of 60 cm gave the thickest vegetative cover and biomass yield. Such a treatment, however, would be cost-prohibitive at this location. Application of 27 Mg ha-1 of lime to the refuse surface along with 15 cm of topsoil produced acceptable two-year vegetative cover and biomass, and appeared to be the optimal treatment for this particular situation. Both liming and topsoil had no affect on leachate pH and the electrical conductivity in leachates collected below the plots. This suggests that surface revegetation will have little effect on the quality of water draining through the pile, so long term water treatment requirements may not be reduced by successfully revegetating the pile surface.

Jan 1, 1999

By Dao Su, Ganghua Fu, Xuling Chen, Yufeng Guo, Min Gan, Tao Jiang, Xiaohui Fan

"The sinter quantity and quality of limonite in the magnetite and hematite sintering models were studied and compared. For the sintering of magnetite, the results showed that the increase of limonite improved the permeability of sinter mixture, increased the sinter quantity and quality. The sinter strength and productivity were decreased when the proportion of limonite exceeded 50%. The appropriate proportion of limonite was 40%-50%. For the sintering of hematite, the sinter quantity and quality were first maintained at the same level thereafter declined, more obviously when the proportion of limonite exceeded 40%. The amount of calcium ferrite increased whose shape changed from acicular to leaflike and block gradually with the proportion of limonite increased from 0% to 80%.IntroductionWith the fierce competition of domestic and overseas iron markets in the twenty-first century, cheap ores such as limonite are used to be sintering raw materials to cut the costs of sinter and pig iron for steel making, and boosts the competitiveness of steel companies [1, 2]. In addition, as the reserve volume of hematite of high grade is reducing year by year, the usage amount of limonite in sintering are expanding in major domestic and international sintering plant [3, 4]. Sintering can be divided into two types, majoring in concentrates and fine ores, according to the different types of raw materials. The sintering characteristics of limonite in the two types above have been studied and compared in this paper, which makes a significant sense for the research of limonite sintering properties and guidance of ore proportioning in sintering plants."

Jan 1, 2012

By S. Tandanand

The Bureau of Mines, U.S. Department of the Interior, assessed the geological effects on the ratio of maximum subsidence and extraction thickness, hown as the subsidence factor, to develop a simple method for predicting the maximum subsidence. The study is restricted to the Northern Appalachian Coal basin where data were collected from 13 coal mines. A model previously developed to relate the subsidence factor with the lithology and with the width and depth of working panels was used in the assessment. The result shows the possibility of determining maximum subsidence without resorting to a rigorous method.

Jan 1, 1982

By S. Tandanand, Powell. L. R.

The US Bureau of Mines assessed the geological effects on the ratio of maximum subsidence and extraction thickness, known as the subsidence factor, to develop a simple method for predicting the maximum subsidence. The study is restricted to the Northern Appalachian Coal Basin where data were collected from 13 coal mines. A model previously developed to relate the subsidence factor with the lithology and with the width and depth of working panels was used in the assessment. The result shows the possibility of determining maximum subsidence without resorting to a rigorous method.

Jan 1, 1985

By Peter Zhang, Daniel Su, Heather Dougherty, Jack Trackemas

"Longwall mining has a significant influence on gas wells located within longwall chain pillars. Subsurface subsidence and abutment pressure induced by longwall mining can cause excessive stresses and deformations in gas well casings. If the gas well casings are compromised or ruptured, natural gas could migrate into the mine workings, potentially causing a fire or explosion. By the current safety regulations, the gas wells in the chain pillars have to be either plugged or protected by adequate coal pillars. The current regulations for the gas well pillar design are based on the 1957 Pennsylvania gas well pillar study. The study provided guidelines for gas well pillars by considering their support area and overburden depth as well as the location of the gas wells within the pillars. As the guidelines were developed for room-and-pillar mining under shallow cover, they are no longer applicable to modern longwall mining, particularly under deep cover. Gas well casing failures have occurred even though the chain pillars for the gas wells met the requirements by the 1957 study.This study presents seven cases of conventional gas wells penetrating through longwall chain pillars in the Pittsburgh coal seam. The study indicates that overburden depth and pillar size are not the only determining factors for gas well stability. The other important factors also include subsurface ground movement, overburden geology, and weak floor, as well as the construction of gas wells. Numerical modeling was used to model abutment pressure, subsurface deformations, and the response of gas well casings. The study demonstrated that numerical models are able to predict with reasonable accuracy the subsurface deformations in the overburden above, within, and below the chain pillars, and the potential location and modes of gas well failures, therefore providing a more quantifiable approach to assess the stability of the gas wells in longwall chain pillars.INTRODUCTIONIn the eastern United States, abundant gas wells have been drilled through coal seams that are being actively mined by longwall mining. The existence of gas wells in the U.S. coal fields, whether active or abandoned, have caused many issues for longwall mining. First of all, any gas well in the mining area has to be located by all possible means. Secondly, the gas wells within longwall panels have to be plugged, as cutting through gas wells will allow natural gas to flow into the active longwall mines. On the other hand, the gas wells within longwall chain pillars or barrier pillars can be left in place if the wells are protected by properly designed pillars."

Jan 1, 2019

By B. R. Neufeld, M. G. Heximer, S. J. Roach, W. G. Van Luven, D. G. Reynolds

"Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. In the zinc plant, zinc concentrates are roasted to produce calcine, which is then processed in the leaching circuit for zinc recovery. Calcine is first dissolved at pH <2.0. This is followed by a precipitation stage using additional calcine that removes iron as a ferric hydroxide precipitate which is recycled to the lead operations. It is during this pH adjustment that impurities, notably arsenic, antimony and germanium, are co-precipitated with ferric hydroxide which is the primary removal phase for these elements. Recent processing conditions have resulted in lower iron inputs to the leaching circuit and this has resulted in insufficient co-precipitation of key impurities. This paper summarizes the influence of iron concentrations on impurity removal using laboratory and plant scale surveys, and emphasizes key specification limits for the primary iron removal circuit.INTRODUCTIONThe Sulphide Leach Plant (SLP) at Teck Metals Ltd., Trail Operations produces a zinc sulphate electrolyte from three different zinc bearing streams:1. Calcine, primarily containing zinc oxide, from the roasters2. Zinc electrolyte from the Oxide Leach Plant (OLP) is produced by leaching zinc oxide fume from the pyrometallurgical lead smelting operations3. Zinc slurry from the Zinc Pressure Leach (ZPL) autoclaveThe feed sources are blended and introduced to the iron removal process to precipitate iron in the form of a hydrolyzed iron precipitate which is recycled to the lead smelting operation. Along with iron, impurities, namely arsenic, antimony, germanium and silica, also co-precipitate; this process acts as the primary removal step for these elements. Following iron removal, the electrolyte is further processed in the zinc dust purification circuits. Cadmium and copper are removed in the cold stage circuit via zinc dust cementation, followed by cobalt cementation in the hot stage circuit."

Jan 1, 2016

By F. W. Hillnhutter

In plant tests with a 9.7 m hearth diameter high top pressure blast furnace the influence of disintegration of sinter during low-temperature reduction on blast furnace performance was evaluated. The blast furnace burden during the test period consisted of 74% self-fluxing sinter with a basicity of CaO/Si02 = 1.3, 15% pellets, 6% lump ore, and 5% recirculated slags. The sinter for the test was produced in a modern sinter plant. By changing the fuel rate and/or the MgO content at a constant basicity CaO/Si02 sinters with different low-temperature disintegration properties could be produced. The blast furnace was equipped with pressure monitoring devices at medium height of the furnace stack wall. This device provided in addition to the normal operating data readings of pressure losses in the upper and lower part of the furnace. The basic physico-chemical factors determining low-temperature disintegration are explained. The testing devices and the extent of quality control measures of sinter during the test period are outlined. Conclusions are drawn from the plant test in relation to sinter properties.

Jan 1, 1977

By Micheal McCarter, Biswadeep Saha, Meenakshisundaram Ramanathan, Chai Ren, Sivaraman Guruswamy

"Three-point bend test was used to study the effect of electrochemically charged hydrogen and magnetic field on the embrittlement behavior of AISI 4340 steel in this work. Acoustic emission signals were collected during the test and analyzed to gain an understanding of the crack growth process. Cathodic hydrogen charging in AISI 4340 steel resulted in drastic reduction of ductility and strength. Hydrogen embrittlement was characterized by a change in fracture surface from dimpled ductile surface to quasi cleavage type fracture. No significant effect was observed in the presence of magnetic field. The acoustic emission signals collected during the test provided an indication of the extent of energy released during the crack growth process.*Support of this work by NSF through the award DMR-0854166 is gratefully acknowledgedIntroductionGrowing interest in hydrogen as a clean fuel and use of steel and other iron based alloys for storage and transport of hydrogen has led to extensive study of the influence of hydrogen on the mechanical properties of these alloys. Hydrogen interaction with materials may result in degradation of mechanical properties. Embrittlement, either ductile or brittle, can be described as a condition which decreases the toughness of the material or increases the ease of crack growth. Hydrogen present even in few parts per million is sufficient to embrittle steels at room temperature [1]. In most cases, hydrogen exposure is through an electrochemical process in aqueous corroding environments. In such cases, they are prone to be exposed simultaneously to electrically induced magnetic fields, which are also believed to affect the hydrogen embrittlement susceptibility of these alloys. So it is also important to study the effect of magnetic field on the hydrogen embrittlement susceptibility. Hydrogen solubility by electrochemical process in aqueous solution is proportional to square root of current density for iron. [2,3]"

Jan 1, 2012