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By K. A. Foo

Minproc Resources Inc. is developing a tailings retreatment project in Bolivia at the Colquiri zinc-tin-silver mine, in the Bolivian Andes. Mining at Colquiri has been continuous since 1940 and COMIBOL, the Bolivian state mining company, has owned and operated the underground mine since 1964. There are 10 million tonnes of tailings at Colquiri containing 0.51% Sn, 4.21% Zn and 50 g/t Ag. Minproc plans to mine and concentrate the tailings at 1.15 million tonnes per year to produce feed for pyrometallurgical upgrading. The tailings are moderately complex, with cassiterite grain size ranging from 200 to 5 pm. The marmatite (ZnFeS) in the tailings is relatively easily recovered, with zinc recovery of 80% to a 40%-45% Zn concentrate. The major problem with the zinc metallurgy is that the marmatite is complexed with iron, which results in iron contents of 14%-17% Fe in concentrate. This makes the product very difficult to sell because of the low Zn:Fe ratio. Most zinc smelters require a Zn:Fe ratio of 6:1 or 7:1, whereas this concentrate has a 3:1 ratio. Concentrate sale terms are therefore unfavorable, and the high cost of transportation from Bolivia to the smelters is an additional burden.

Jan 1, 1992

By Iley J. D

The production of zinc from low grade concentrates, particularly those high in iron, has a poor economic return due to a combination of higher concentrate transport costs, increased processing costs and an increased cost for disposal of iron residues. The production of iron-bearing residues from the electrolytic zinc process is also seen as undesirable for both cost and environmental reasons. This paper details the pilot plant testwork conducted at the Pasminco Research Centre in conjunction with Minproc for the production of zinc oxide fume from a high-iron zinc sulphide concentrate from Colquiri in Bolivia. The concentrate is derived from a tailings retreatment operation and has a high iron content (40 - 45 per cent Zn, 14 - 17 per cent Fe) due to the presence of marmatite. Pilot plant trials were conducted using the slag bath reactor at Pasminco Research Centre at rates up to 500 kg/h of pelletised zinc concentrate, using a natural gas/oxygen-enriched air lance. The fume produced averaged 76 per cent Zn at recoveries up to 96 per cent and was recovered in a baghouse after gas cooling. The iron was oxidised into a fayalitic slag that passed the TCLP test (toxicity characteristic leaching procedure) and the sulphur was oxidised to produce a high SO2 gas which would be suitable for sulphuric acid production. The process produces a zinc oxide fume that can replace calcine as a feed for electrolytic zinc plants. The iron reports to a stable slag for disposal, thus eliminating the need for its disposal as jarosite from the leach plant. Only a simple leaching operation on the fume is required as there is no zinc ferrite present.

Jan 1, 1993

Those who have had an occasion to apply geostatistics to the estimation of ore reserves are familiar with the conventional approaches of estimating average grade of quality values for arrays of regular grid squares or blocks. Further, the technology to perform geostatistical analysis and prediction for irregular two-dimensional areas has been available in a practical, readily useable form for some time. However, the generalization of this technology into three dimensions has been hampered by lack of a suitable geometrical characterization for realistic, three dimensional shapes and volumes. The extension of these estimation techniques into three dimensions has now been made possible by a successful integration of the volume modelling capabilities of 3D Component Modelling with proven 3D Geostatistical Techniques. The result is a powerful new technique for mineral ore reserves estimation in a practical, useable form. The technique allows direct geostatistical estimation of grade and quality values for precisely defined, irregular, realistic, geological, and mining shapes or volumes. This paper describes the two technologies, their integration and their application in practice to the estimation of mineral ore reserves. The paper closes with a discussion of the benefits provided by the new approach, in terms of accuracy, efficiency and practicality.

Jan 1, 1991

By Y V. Haarlem, P Coghill, N G. Cutmore, M Millen, I Carter

Due to the low concentration of gold, ore sorting for gold has always required measuring indirect properties, such as density or colour, to allow separation on a rock by rock basis. This only works on an ad hoc, by deposit basis and is likely to be least reliable where it is most required in low grade ores. One candidate technique, Gamma Activation Analysis (GAA) has been demonstrated to directly measure gold extremely accurately in powder samples of around 500gm and is used in the Chrysos PhotonAssay assay system. This method uses a linear accelerator (linac) to generate the X-ray radiation that activates the ore at low levels to emit a characteristic gold gamma ray that is then measured by a radiation detector. CSIRO is adapting this measurement technique to application on a belt at up to 800tph to measure pods of ore. The principal differences between measuring samples and an on-line measurement of pods are the requirement to measure coarse ore (<50mm), to measure a larger volume of ore as uniformly as possible, and to have an open-ended geometry with adequate shielding of the linac radiation source. These issues have all been addressed with measurements of coarse ore reported down to around 1ppm in sub-optimal test conditions. They have been demonstrated for <75mm particles with detectors capable of measuring a large volume geometry continuously. These are projected to allow measurements down to 0.3ppm in more optimum conditions for a 10 second measurement time period where the U/Th content of the ore is less than ~10ppm. Extensive Monte Carlo modelling has demonstrated that adequate shielding can be provided in relatively simple geometries with only 1 right angle transfer in the material handling. Steady progress is being made to reach the technical position required to trial an ore sorting system.

Nov 10, 2020

By John D. VandeKraats

Yielding rock bolt support systems have been developed to accommodate ground movement in shifting ground such as in coal operations; in creeping ground such as salt, trona, and potash; and in swelling ground associated with some clays. These systems, designed to remain intact despite ground movement, should enhance mine safety and help contain costs in areas where rebolting of rigid non-yielding systems is typically required. Four such systems were tested in straight tensile pulls in the laboratory. They include the Slip Nut System from Dywidag Systems International USA, Inc., Ischebeck&apos;s bolt mounted Titan Load Indicator, Rocky Mountain Bolt Company&apos;s Yielding Cable Bolt, and a rock bolt installed variation of the yielding steel post developed by RE/SPEC Inc. The first two systems are currently marketed products and the latter two are prototype systems. Each system responds to load and displacement by yielding in a unique manner. All are designed to yield at predetermined loads. A description of each system and its yield function is provided. Each system was tested over its prescribed yield range in a test machine. At least five tests were performed on each system. Each system yielded and continued to provide support according to its design. Each shows promise for ground control use in shifting or creeping rock. This work helps to illustrate the comparative differences in performance between these specialized systems and the applications where they may be most useful.

Jan 1, 1996

By Kurt Svens

"As zinc consumption is gradually increasing all the time in the world, many zinc plants are looking for possible expansions. As the sulphuric acid market as well as the fertilizer market in many areas is saturated, the costs for the roasting-acid plant section of the zinc plant will create problems when making feasibility calculations for possible expansions. For solving the customers' situation, two proven zinc concentrate direct leaching technologies are available. A third one, which is possible, does not have any industrially proven applications in the zinc area.IntroductionTime to time, the zinc plants in the world scrutinize their operations with respect to their cost efficiency, the total zinc recovery and the near-by or far-away consumer markets, especially the for zinc and sulphuric acid. Their preliminary profitability calculations can show that a possible total expansion is not economical, when they are looking to expand the whole roasting/acid plant - leaching - solution purification - electrowinning - casting route, as the possible market price for the sulphuric acid is low or the sulphuric acid market is too far away. Based on these facts, their economical study often indicates that implementing a zinc concentrate direct leaching option could be more favourable. Regarding this situation, several aspects concerning three alternative direct leaching methods will be discussed, of which pressure leaching and the atmospheric leaching processes have several industrial applications in the zinc industry, as the ultrafine grinding - conventional leaching process at present has none. As iron is also dissolved during zinc concentrate direct leaching, iron removal processes generally used in the zinc industry are additionally discussed below."

Jan 1, 2012

By Sharma T

Laboratory investigations have been carried out on direct leaching of lead-zinc complex sulphide ore and zinc concentrate using ferric chloride. From the investigation it was observed that the use of 0.15 M and 2 M FeC13 gave an optimum dissolution of metal ions from ore and concentrate respectively. The kinetic studies conducted showed that the leaching reaction followed a shrinking core model for galena and sphalerite. The presence of impurities such as pyrite had increased the dissolution rate and reduced the consumption of ferric chloride. Further, the studies were conducted to recover dissolved zinc from the chloride solution by selectively precipitating it as zinc ammonium chloride.

Jan 1, 1992

By R. W. Adams

A new process has been developed for leaching zinc sulphide concentrates at atmospheric pressure using air or oxygen plus nitrogen dioxide in dissolved or gaseous form as? an oxygen carrier. The process is flexible and can cope with variations in the degrees of retention and regeneration of dissolved nitrogen dioxide in the leaching phase. By controlled addition of concentrate a leach solution with low residual nitrate concentration can be produced. Following separation by filtration of unleached solids and elementa1 sulphur and conventional oxidation/precipitation of dissolved iron, the leach liquor can be treated with metallic zinc to remove the remaining nitrate and other meta111c impurities such as copper, cadmium and cobalt to provide a solution suitable for electrolytic recovery of zinc. Pilot scale testing of the process .has given zinc recoveries in the high nlnet1es, production of a hi.gh grade jarosite-free Pb/Ag residue (50% Pb.) and a saleable high grade of elemental sulphur. .A wide range of concentrates can be treated containing substantial levels of lead and copper as well as zinc. Indicative cost estimates suggest that the new process is competitive with alternative procedures such as pressure leaching.

Jan 1, 1990

By A. Vien

Over the past several years, Svedala has developed a continuous charge monitor (CCM) for tumbling mills. It consists of a strain gauge embedded into a rubber lifter and associated electronics. This paper describes the results of a research program to evaluate the technical and economical merits of such a device on a SAG mill. The evaluation includes validation through discrete element modelling and comparison to measured static volumetric load. Inclusion of the measurement into a control strategy and its potential for condition monitoring is discussed.

Jan 1, 2001

By Philip Barnhard, Lyman G. Bahr

By recording the arrival time of a pipe wall at evenly spaced intervals in a plane perpendicular to the pipe axis, application of the equations of motion permits calculation of the pressure of the explosive acting to accelerate the pipe wall. Data observed from various non-ideal explosives are presented, together with values of pressure to be expected from thermodynamic calculations.

Jan 1, 1981

By R. P. King

A new device, called the dual impact load cell, has been developed and built at the Comminution Center to measure fracture energy and damage accumulation in brittle particles that are subject to impact. The results show that damage accumulation during impact is not a significant factor in determining the fracture energy or the particle strength. However, predamage induced by thermal pretreatment of the particles has a significant effect on both fracture energy and particle strength.

Jan 1, 1995

By Lei Pan, Roe-Hoan Yoon

"Direct force measurement for bubble-particle interaction has been difficult due to bubble deformation, which makes it difficult to know the separation distances between the two macroscopic surfaces. In the present work, we have developed a method of monitoring the deformation accurately, while directly measuring the interaction forces. In effect, we can ‘see’ bubbles interacting with mineral surfaces under different hydrodynamic and chemical conditions and determine both the hydrodynamic and surface forces involved. In the present work, a high-speed camera has been used to record the optical interference fringes of a thin liquid film (TLF) of water formed on a mineral surface. The recorded fringes are then used to reconstruct the spatiotemporal profiles, from which one can determine the hydrodynamic pressure using the Reynolds lubrications theory. From the forces directly measured in the present work and the hydrodynamic pressures obtained from the fringes, we have determined the disjoining pressure. The results show that air bubbles interacting with hydrophilic surfaces form stable TLFs with zero contact angles. The TLF formed on a hydrophobic surface thins fast, form a ‘pimpled’ film, and ruptures to form a finite contact angle. The new information obtained in the present work may be useful to better understand the role of hydrodynamic and surface forces affecting bubble-particle interactions."

Jan 1, 2014

By S. Assemi

Interaction forces between a hydrophilic silica particle and an air bubble were measured by atomic force microscopy using simplified model systems with deionized water and dilute KCl solutions. Contributions from the hydrodynamic force were minimized by using a low piezo speed. Particle-bubble separation distance and the bubble spring constant were calculated from linear regression of the piezo extension versus cantilever deflection. The bubble surface potential was then estimated from fitting the AFM-measured forces to the Hogg-Healy-Fuerstenau (HHF) model, using the surface element integration (SEI) method. Surface potentials obtained for the bubble at a low applied force were comparable with the literature data, suggesting that the simplified model used here can give a reasonable estimation of the bubble surface potential under moderate applied forces. Interaction forces between a silica particle and an air bubble were also measured at different locations on the air bubble surface. The force curves obtained at the edges of the bubble fitted very well to the theoretical force curves regardless of the applied force, while curves obtained at the center and halfway to the center, were more difficult to fit, in particular at higher applied forces (> 13 nN), suggesting that force curves obtained at the edges of the air bubble might be less prone to deformation effects.

Jan 1, 2008

By J. A. Finch, Zhenghe Xu

The competitive adsorption of xanthates on sulphide minerals in a binary mineral system (pentlandite and pyrrhotite) was studied using the pseudo-in-situ technique of attenuated total-reflectance FTIR spectroscopy. The minerals were placed in the same collector solutions, either separated by a glass wall or in direct contact with each other before magnetic separation and separate analysis. The effect of mineral interaction on xanthate adsorption was clearly demonstrated spectroscopically for the first time. At low concentrations of xanthate, its adsorption on pentlandite was activated by physical contact with pyrrhotite; the effect may be attributed to the enhancement of electron transfer through electrical contact between the two minerals. The results emphasise the need for caution in extrapolating results obtained from single-mineral studies to flotation practice

Jun 18, 1905

By S. E. Khalafalla

A method for preparing ferrochromium alloys containing less than 2 pct carbon has been devised in a single vacuum furnace reactor. This method can conserve chromium and should reduce the capital and energy requirements relative to chromite electrothermal reduction. Reduced products containing less than 2 and as low as 0.01 wt pct carbon were obtained by reacting pellets of chromite and carbonaceous reductant mixtures at pressures of 0.1 to 1 ton and temperatures of 1,230° to 1,320° C. The extent of reduction increased with increased temperature and decreased pressure; however, operating conditions were limited due to the onset of significant chromium vaporization at higher temperatures and lower pressures. Foundry coke, anthracite, and carbon black were found to be superior to graphite as reductants. The reduction of chromite to metallics was found to proceed via the carbide intermediates Fe3C or Cr3C2. Lime accelerates the. rate of solid state reduction of chromite and can shorten the furnacin1r time at 1,3000 C under vacuum from 13 hours to less than three hours. Additional lime and silica are added to the hot reduced chromite after releasing the vacuum and raising the furnace. temperature to 1, 700° C. Soaking the charge for about 20 minutes gave a button of low carbon ferrochromium alloy beneath a well-defined slag layer.

Jan 1, 1985

By Tong Qin, Jinxia Zhang, Fusheng Niu, Limei Bai

"The interaction between a deformable bubble and a rigid particle in viscous liquids under microgravity conditions is studied by direct numerical simulation via an Arbitrary-Lagrangian-Eulerian (ALE) method. Due to the microgravity, the bubble will stay as a sphere in the fluid without external forces and its deformation is caused by the moving particle. In this study we assume the flow field is axisymmetric and the motion of the gas inside the bubble is neglected. The particle equations and the Navier-Stokes equations for the fluid are solved in a unified finite element framework. The particle obtains an impact velocity by an external force and the impact velocity is varied over a wide range. A ‘critical time scale’ T0 was identified for the interaction process. For successful contacts between particle and bubble, the time scale of their relative motion must be less than T0.INTRODUCTIONThe particle-bubble interaction is an important process in many applied industrial domains such as water treatment, froth flotation and liquid steel purification. It is a complex three phase process in that it embraces many research areas: fluid hydrodynamics, interfacial forces, particle and bubble behaviour and solution chemistry.Derjaguin and Dukhin(1961) clarified the particle-bubble interaction by introducing three-zone model for small and medium size particles. When the particle is far away from the bubble surface, the hydrodynamic forces are dominant. The particle is driven toward the bubble surface by the particle inertial and gravity. This region is regarded as Zone 1 and the interaction in this zone is a collision subprocess. As the particle gets close to the bubble, it exits a zone where the liquid flow around the bubble surface creates a tangential stream from the upper surface of the bubble toward the rear of the bubble. This is Zone 2 which is called the diffusiophoretic zone. In Zone 3, the particle is very closed to the bubble, surface forces like van der Waals, electrostatic and structural forces are considered. Contrast to Zone 1, Zone3 can be regarded as an attachment subprocess."

Jan 1, 2016

By Andre Thess, Oleg Zikanov

"Direct numerical simulation methods are applied to study the influence of a constant magnetic field on turbulent flows of liquid metals. The flow is assumed to be homogeneous and the problem is reduced to the classical case of the turbulent flow in a 3D box with periodic boundary conditions. The main subject of the study is the anisotropy developing in a liquid metal flow affected by constant magnetic field.To investigate the long-time evolution of initially isotropic flow the large-scale forcing is applied to maintain the flow energy at a statistically steady level. It is found that the flow evolution depend strongly on the magnetic interaction parameter (Stuart number). In the case of small Stuart number, the flow remains three-dimensional, turbulent, an approximately isotropic. At large Stuart number (strong magnetic field) the turbulence is suppressed rapidly and the flow becomes two-dimensional and laminar. Very interesting is the intermittent flow evolution at moderate Stuart number. Long periods of almost two-dimensional, laminar behavior are interrupted by strong turbulent three-dimensional bursts.The influence of a constant magnetic field on scalar transport properties of liquid metal turbulence is investigated using the simplified formulation of homogeneous flow driven by an imposed mean temperature gradient. Such a flow consists primarily of two turbulent antiparallel jets providing an effective mechanism for heat transfer. It is shown that the magnetic field parallel to the mean temperature gradient stabilizes the jets and, thus, enhances heat transfer considerably."

Jan 1, 1999

By Lin Li, Xiang Li, Yifang Zheng, Jilai Xue, Jun Zhu

"Al drops and gas bubbles in the anode-cathode space of aluminum electrolysis cell are of great importance for cell operation improvement in metal loss, current efficiency and energy consumption. A direct observation on the Al drop, gas bubble and ultrasound was carried out through a see-through cell. The Al drop immersed into the cryolitic melt was found moving up and down irregularly in the anode-cathode space without electrolysis, which was then completely dissolved into the melt. During electrolysis, the Al drop came to the anode area and reacted with the gas bubbles generated on the anode. Under ultrasound, the gas bubbles were removed from the anode surface while the Al drop was kept on the side of anode. The observed phenomena were useful for technology improvement in reducing the anode-cathode distance or lowering the energy consumption in aluminum electrolysis.IntroductionDuring aluminum electrolysis, aluminum metal drop and anodic gas bubble are in close contact each other within the anode-cathode space, and the interaction between them can produce significant impact on metal loss, current efficiency and energy consumption. The motions of the Al drop and the gas bubble are also related to the dissolution of aluminum metal into cryolitic melt and the cell voltage drop due to the bubble layer covering the anode surface.A number of studies have been carried out using different types of see-through cells, where the dissolving process of metal Al into cryolitic melts (metal fog) in the anode-cathode space was directly observed and photographed [1, 2]. With the similar method, some direct observations on the anodic bubble behaviors with and without ultrasound were performed during aluminum electrolysis [3-6]. However, to our best knowledge, there is no published work on direct observation on the behavior of Al drops and anodic gas bubbles staying together within the same anode-cathode space, as well as the motion and interaction of them in cryolite-alumina melts."

Jan 1, 2011

By S Natsui, Y Goto, S Kawanishi, J Takahashi, H Nogami

The demand for copper increases yearly, and further improvements in copper smelting efficiency using flash furnaces are required. This study was conducted to understand and promote the interfacial reaction associated with the collision of silica flux and iron oxide particles, ie the formation reaction of fayalite slag, in the reaction shaft of the flash furnace. High-temperature microscopy was used to observe the reaction behaviour of a 2 mm granular SiO2 reagent in contact with micrometreorder- sized FeO reagents in situ. When the amount of FeO was lower than the stoichiometric amount with SiO2, the molten slag formed at the interface between FeO and SiO2 diffused into the SiO2 particle before dissolving the remaining FeO particles. It did not contribute to the subsequent reaction, and despite having the lowest amount of FeO among the samples in this study, many unreacted FeO particles remained on the surface of the samples after testing. On the other hand, under conditions with high FeO content and close to the eutectic composition of the FeO-SiO2 system, a liquid phase formed from low temperatures, gradually increasing in volume and eventually completely dissolving the 2 mm SiO2 grain. These results indicate that the early-stage slag is essential in increasing the interfacial area between FeO and SiO2 and facilitating the supply of FeO to SiO2. In other words, the FeO/SiO2 determines the amount of liquid phase and significantly influences the subsequent interfacial reaction rate between FeO and SiO2. Therefore, the local FeO/SiO2 of the particles falling down the reaction shaft should also be optimised to ensure early slag formation. Meanwhile, the time required for 2 mm SiO2 to complete the reaction for the temperature history employed in this study was significantly longer than the particle residence time in the reaction shaft. Further detailed investigation of the effects of silica flux particle size, composition, and reaction temperature on the reaction time will help find the conditions under which the reaction of silica flux can be completed in the reaction shaft. These kinetic approaches could contribute to future innovations in the copper smelting process using flash furnaces.

Jun 19, 2024

By Edward B. Hughes, Frank G. Norris

OXIDATION is characteristic of all processes for making steel from pig iron. This thought has been aptly expressed by H. W. Graham13 in the most recent Howe Memorial Lecture, "The process of steel-making consists of using iron oxide to reduce the carbon content of the pig iron to the desired level." Direct oxidation refers to the reaction that results from introducing oxygen either alone or mixed with other gases directly into the steel bath. In working a heat, oxygen in some form is added to the steel to remove the undesirable constituents as oxides. There are two general methods of supplying this oxygen to the open hearth bath. The method in which the oxygen is added as a, compound such as C02-or iron ore is designated an indirect method because the steel bath must first decompose the compound to attain oxygen in a usable form. The other method in which oxygen is added to the bath in the elemental or gaseous form, more or less diluted by other gases such as nitrogen, is a direct, method because no decomposition is necessary before the oxygen reacts with iron to form FeO which is dissolved in the bath in a usable form. Bubble formation (at least of a macroscopic size) presents no problem in case of direct oxidation because the reacting agent (oxygen) is in the form of bubbles when entering the metal. Regardless of whether oxygen is introduced into the bath directly or indirectly, several reactions proceed concurrently. In the presence of the bath of molten iron, FeO is formed either by oxidation of iron by oxygen or reduction of oxides by iron. This FeO dissolved in the molten iron is the source of oxygen for the oxidation of manganese, carbon, silicon, and phosphorus if these are present. The oxidation of carbon from steel is the controlling steelmaking reaction. The introduction of oxygen into the bath, its reaction in the elimination of impurities, and its control by the use of de-oxidizing additions have been subjects of importance since steel was first made by the bessemer process. Direct oxidation is, in a sense, an application of the bessemer principle to the open hearth process. Graham13 states: "The use of oxygen or air jets introduced into the metal bath is essentially an effort to approach in the open hearth the turbulence, rapid interface reaction, and high production rate per hour that exists in the bessemer process." The general subject, "Oxygen in Steelmaking," was given new life by the studies of Herty and associates starting about1925. The current interest in elemental oxygen is intimately related to the large scale production of oxygen developed during the war period. Some of the first applications were made during the early summer of 1946 at the Steel Co. of Canada using oxygen with the fuel. Such a use is of considerable interest and importance in contributing to faster heats but is not the subject of the present discussion which deals entirely with the introduction of elemental oxygen directly into the open hearth bath. A recent article12 reviewing the current

Jan 1, 1948