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By HJ Marais, J A. van Niekerk

An investigation was initiated by BILLITON Process Research and Gold Fields Limited for the efficient removal of thiocyanate and cyanide from leach solutions. This led to the development of the ASTERTM process, an acronym for Activated Sludge Tailings Effluent Remediation. The biological degradation of thiocyanate and cyanide in effluents provides an alternative treatment to the more traditional processes. This occurs with a large number of micro-organisms which include bacteria, actinomycetes and fungi. Cyanide and thiocyanate are degraded to ammonia and carbon dioxide. Most forms of cyanide-metal complexes are generally removed through a co.mbination of oxidation and sorption into the biofilm/biomass. Since the ASTER™ process has commercial applications, a patent has been lodged for the ASTER™ process. A culture containing thiocyanate degrading organisms has been deposited with the Australian Government Analytical Laboratories (AGAL). The identification of the bacteria is in progress. Tailings arising from a cyanidation process tend to contain cyanide and thiocyanate. The presence of these species prevents the recycling of this water upstream to a bioleach circuit due to its toxicity to the bacterial culture. Increasingly stringent legislation for the land disposal of cyanide containing solutions also necessitates the treatment of the solutions before disposal.

Jan 1, 2000

By Jeffrey R. Kelly, Paul M. Kubera, Richard A. Howk

Mixing of solid-liquid slurries is a unit operation that is widely encountered in the minerals processing industry. Applications may range from simple slurry storage in open tanks to complex chemical reaction systems under extreme conditions of temperature and pressure. The specific process requirements dictate both the degree of mixing required and the type of agitation employed to achieve the desired results.' Many continuous-flow process applications feature tanks operating in series to provide a discrete number of stages and a known residence time for the slurry. Because these tanks operate at a constant level in an overflow mode, the mixer must maintain uniform solids concentration and size distribution throughout the tank; failure to achieve uniformity results in accumulation of coarse solids in the tank, ultimately leading to a process or mechanical failure. Downward-pumping, axial-flow mixing impellers are widely employed to produce uniform solids suspension. The specific impeller type, number, size, and power draw is a function of each given situation. The use of high-efficiency, fluid-foil impellers (Figure I) has evolved as a recognized standard for these flow­controlled applications. Recent small-scale experimentation and full-scale experience has demonstrated that, when uniformity is required, capital and operating expense can be minimized by employing an additional upper impeller pumping in the upward direction.

Jan 1, 1995

By David Lunt, Evan Kirby, Peter Mason, Ian Ritchie

The treatment of refractory gold ores, in particular the "competing" technologies and their relative advantages and economics, has become a major segment of most mineral technology oriented conferences in recent years. A common theme is the increasing refractory nature of gold ores being treated. This is despite ores such as those at Kalgoorlie having required roasting for liberation since the last century. Papers on refractory gold treatment have examined the characteristics of refractory ores and the causes of reduced recovery (eg La Brooy 1994), the available technologies and their relative economics eg Litz 1990), and the selection of a suitable process route (eg Nicholson 1993, Weston 1994). The most comprehensive collation of data on such processes is provided in the different editions of Randol. A variety of classifications and definitions of "refractory ore" have been published. Due to the many factors which can impact on the recovery of gold it is perhaps not feasible to develop a universal characterisation that can be applied to all gold bearing rocks. La Brooy et al have provided the framework for characterisation shown in figure 1.

Jan 1, 1995

By Andre R. Laplante

Gravity gold recovery can be of significant economic importance for gold copper ores that cannot be directly cyanided. Gravity is typically followed by flotation to produce a smeltable copper concentrate. Flotation tails gold values are often too low to justify a cyanidation circuit. Given this typical scenario, a very effective gravity circuit can yield higher overall gold recoveries (i.e. gravity + flotation), and also improve the NSR of gold. Typical scoping work, whilst well suited to investigate the downstream circuit, be it flotation or cyanidation, often overestimates ore variability to gravity recovery and fails to yield the data needed to predict plant gravity recovery and design the optimum gravity circuit. This presentation examines why typical scoping work fails to address gravity recovery adequately and shows how a standard test to characterize gravity recoverable gold (GRG) can provide the missing data. Case studies are presented and used to illustrate the concepts of recovery effort and aggressive gravity recovery.

Jan 1, 2000

By Wendi H. Cooksey

This paper examines two comminution circuits on a hypo­thetical gold ore deposit with both small-scale (1,000 short tons per day) and large-scale (35,000 short tons per day) production rates. The most appropriate circuit is dependent on the highest economic performance with a combination of crushing and grinding equipment to achieve the desired product size. The selected circuit is dependent on costs associated with project cri­teria, equipment selection and ore characteristics. Factors influ­encing the selection of the comminution circuit require system­atic evaluation to optimize plant performance and maximize eco­nomic return. The small-scale circuit economics responded best to three-stage crushing followed by a single-stage ball mill. The large-scale plant favors a primary crusher followed by SAG milling and ball milling. The conclusions from this paper indi­cate that each project must be evaluated separately to determine the most economic means of reducing the size of the ore.

Jan 1, 1998

By S. R. LaBrooy, M. C. Costello, A. C. Bax

Nickel is present in a number of gold ores in Australia, Africa and the United States. The effects and behaviour of the nickel during the cyanidation and adsorption processes, and also during the elution and electrowinning processes have been examined by a number of researchers, usually as a part of a larger investigation. This paper examines the available data on the behaviour and effect of nickel during cyanidation and its associated unit processes. The presence of nickel is often not considered to be particu­larly important as it does not cause the same degree of problems across the circuit as those experienced in the presence of copper. It can however lead to increased cyanide consumption during leaching, and reduced adsorption of gold onto carbon. A proportion of nickel cyanide may be removed from carbon prior to elution by carrying out a hot (90° C) acid wash. The nickel which remains on the carbon will be partially eluted during the main elution step, and, dependent on its concentration in the pregnant solution, part of it may be deposited during electrowinning. There is always a risk that any nickel remaining on the carbon after the elution step will be reduced to metallic nickel during the regeneration step. This may ultimately result in an increasing base level of nickel on the carbon, as metallic nickel is insoluble in both cyanide and hydrochloric acid.

Jan 1, 1995

By Rebecca A. Miller, Terry M. Hertel

In-pit identification of neutral waste rock at the Zortman and Landusky minesites in Montana, by visual and chemical analy­ses, will assist in proper segregation and placement of rock so that soil and water resources can be protected. The use of too few or very general segregation criteria to identify neutral waste rock can result in ineffective waste rock segregation. Conversely, the use of overly restrictive criteria can result in the unnecessary loss of valuable reclamation material that would otherwise have to be mined elsewhere and hauled to the site. Recognition of nonre­active materials can be accomplished on a site specific basis with the use of visual observation and simple chemical analyses. The choice of chemical parameters used to analyze rock samples is constrained by the length of time needed to conduct the test. These analyses must require no more than 24 hours to complete so mining can proceed without delay. Limits set for the chosen parameters must be reasonable and defensible. To achieve these objectives over one thousand samples were collected at the Zortman and Landusky minesites and clas­sified by rock type, total sulfur content, paste pH, and net neu­tralizing potential (NNP). In addition, over 22 humidity cell kinetic tests were conducted to help corroborate static results for waste rock. Another 8 humidity cells were configured in series to test waste rock blending and waste rock/limestone capping alternatives as mitigation for acid rock drainage. Leachates were analyzed for pH, conductivity, alkalinity, acidity, sulfate, Al, Cd, Cu, Fe, Mn, Zn, Mg, and Cr in some cases. Petrographic analysis, as well as total sulfur content, paste pH, and static and kinetic test results identified three geochem­ically different waste rock groups: 1) Archean amphibolite gneiss and Paleozoic carbonates and shales, 2) Tertiary syenite porphyry, and 3) other less abundant Tertiary igneous and Archean metamorphic rocks.

Jan 1, 1996

By K. Barbetti, D. C. Wright, L. J. Warren, J. A. Rumball

This paper describes the advantages and disadvantages of cyanide sensors in gold processing operations, and their role in reducing process variability and lowering cyanide consump­tion. The importance of understanding the chemistry of the sensing principle, and the role of impurities, in order to choose the correct sensor setting, is demonstrated.

Jan 1, 1997

By S. Tavani, R. E. Browner, R. Dunne

Lead is used in CIP/CIL circuit to increase the leaching rate of gold from ores. At least four mechanisms have been proposed for the action of lead in gold leaching circuits: (I) precipitation of sulphides as highly insoluble lead sulphides preventing consumption of cyanide and oxygen; (2) su,face reaction on sulphide particles forming an insoluble lead sulphide layer peventing dissolution of those sulphides; ( 3) precipitation of lead sulphide, which undergoes further oxidation to soluble lead sulphate recycling the lead to solution,· ( 4) contact reduction of lead onto the gold szaface which then acts as a secondary oxidising agent. Rotating disc studies using a pure gold disc show that small amounts (5ppm) of sulphide ions are sufficient to significantly reduce the leaching rate of gold. Lead increased the leaching rate at small concentrations but at higher levels decreased the rate of leaching. The detrimental effects of lead were only found for a pure solution when leaching the gold disc. Ores mediate the amount of lead available by ads01ption/reaction, thus, reduced leaching rates from excess lead are not serious even when 500ppm of lead ions are added to the sluny. The detrimental effects of sulphide ions could be countered by lead addition during the leaching process. A penalty, in the form of reduced leaching rate, will occur the longer lead addition is delayed. A time lag was noted between the addition of lead and the increased leaching rate when a large concentration of sulphide ions was present.

Jan 1, 2000

By Rodney H. Sergent

After being forgotten or ignored for nearly 100 years, the ability of bromine chemistry to extract gold from ore has been rediscovered. While bromine chemistry is similar to chlorine, there are some important differences. Bromine in its elemental form is a dense, fuming, red liquid. Elemental chlorine is a gas and requires a substantial amount of equipment to handle, store and deliver to solution. Bromine has an advantage in its ability to rapidly and completely oxidize heavy metals to water soluble halide salts. The first patent for use of bromine chemistry for gold extraction was issued in 1881 (1). By 1895, work done in Colorado concluded well roasted ores required approximately 1-1/2 lbs/ton of elemental bromine for superior extraction of metals (2)). At that time, bromine was deemed to be cost effective vs. chlorine even though it was more expensive on a pound basis than chlorine. The advent of cyanide technology virtually eliminated both chlorine and bromine from consideration for leaching of ores. Cyanide was so inexpensive that it made deposits requiring unique technologies unattractive for mining. Only since the deregulation of gold price has bromine/chlorine technology been considered for those ores not amenable to cyanide. While chlorine has found its way into the pretreatment steps, bromine is just beginning to realize its niche in the marketplace.

Jan 1, 1998

By M. Misra, J. Nanor

The removal and stability of arsenic over a wide pH range (3.0-10.0) from synthetic solutions and industrial waste effluents (including mining waste tailing slurry) can be accomplished with addition of impure lanthanum chloride alone or in conjunction with ferric sulfate. The long term stability of these correspond­ing precipitated compounds is critical from the disposal stand­point. In this paper test results of this new process for arsenic removal and stabilization from the above mentioned systems are presented. Also, precipitated arsenic compounds (lanthanum arsenate, lanthanum-ferric arsenate, ferric-lanthanum arsenate and ferric arsenate) from synthetic solutions have been charac­terized. The characterization technique used was XRD. XRD patterns which shows that the lanthanum arsenate and lan­thanum-ferric arsenate formed in acidic and alkaline pH at room temperature are crystalline. On the contrary, ferric arsenate and ferric-lanthanum arsenate compounds formed under the same conditions as lanthanum arsenate were amorphous.

Jan 1, 1998

By Gary Jobson

The Mt Todd Gold mine is situated near Katherine in the Northern Territory of Australia. Commissioning of an 8 Mtpa processing facility incorporating a four stage crushing circuit, ball mills, flotation, concentrate regrinding, high rate thickening and CIL processing was commenced during late 1996. A 4.5 M tonne /annum crushing and heap leach facility was commissioned during late 1994, and was subsequently upgraded to a nominal 6 M tonne / annum circuit during 1995. Processing equipment used included primary gyratory, secondary cone and tertiary Barmac VSI crushers. Some of the features of that crushing circuit and heap leach facility were presented at the Randol Perth 95 conference by myself. The location is described as sub tropical with average climatic conditions including 1100 millimetres annual rainfall, predominantly during the December. to March wet season, and 3000 millimetres evaporation and maximum temperatures ranging from around 26 to 46 °C. The main gold occurrence at the Mt Todd site is the Batman deposit, with current published Reserves of some 60 Mt@ 1.20 g Au / tonne ( 0.0425 oz Au / ton ). The primary ore from the Batman deposit is an extremely competent greywacke and is very hard at an average Bond Ball Mill Work Index of26.5 kWhrs/ tonne. Other indicators include a Bond Impact Crush Work Index of 20 kWhrs I tonne, an Abrasion Index of 0.15 and Ultimate Compressive Strength values of 100 - 200 MPa. The main gold occurrence is very finely disseminated free gold (at an average grain size of around 5 micron) within a combination of quartz and mixed sulphide. This gold bearing component is confined to largely parallel veins ranging from 0.5 to 25mm wide within a greywacke matrix. Although the gold is essentially non­refractory, there is a strong recovery versus grindsize relationship due mainly to the liberation characteristics and the relatively low permeability of the host greywacke rock.

Jan 1, 1997

By James H. Nulty, Joseph S. Roti

Wetting agents used for heap leach gold applications would appear to have technical merit in aiding in recovering higher levels of precious metal. Many questions, however, remain as to whether they will function in practice, on what type of ore are they effective and if there are any negative affects associated with their use. A series of experiments are conducted at Bateman Labs, Sparks, Nevada, to determine under what conditions reagents of this type are useful. Carbon kinetics test work was also performed to determine if there are negative aspects associated with carbon loading with the use of these treatment chemicals. This paper outlines the results of these research evaluations, the general chemistry associated with action of wetting agents on leach ores and future work which is planned to further determine the viability of these products in the mining industry.

Jan 1, 1998

By C. F. Bonney

Spherical or oil agglomeration has been recognised for many years as a possible process for the recovery of mineraVmetal values. BP has investigated the potential of spherical agglomeration for a number of minerals as have other workers. Testwork has also been carried out by both BP and others on the selective agglomeration of fine coal. The spherical agglomeration of both minerals and coal depends on the use of an immiscible liquid e.g. a hydrocarbon which is added to a suspension of the solids in water. On agitation the oil is distributed over oleophilic/hydrophobic surfaces and particle impact allows inter-particle liquid bridges to form causing agglomeration. It is also possible to enhance the oleophilicity of the material to be recovered by the use of collectors similar to those used in froth flotation.

Jan 1, 1998

By Terry M. Hertel

The chemistry of waters processed by Acid Rock Drainage water treatment plants can affect the Total Suspended Solids quality of the plant effluents. The sulfate ions in the ARD water will combine with the calcium ions from the lime that is used to adjust pH to form calcium sulfate. When the sulfate content of the waters to be treated is greater than about 1400 parts per mil­lion, the resulting calcium sulfate concentration will be approx­imately 2100 parts per million. This concentration is above the saturation point for calcium sulfate, and the salt will drop out of solution until the concentration falls below the saturation point. This "salting" phenomenon affects the total suspended solids of the treatment plant effluents by virtue of the fact that the salts will report to the filtration apparatus used for the analy­sis. This scenario is exacerbated as an effluent sample ages. Zortman Mining's water treatment plant effluent was being affected by "salting" during the spring and summer of 1995, and it seemed as though the effluents were exceeding the TSS lim­its; for no obvious reason. A testing program was initiated to verify an observation that "salting' was taking place. Treatment plant samples were collected and allowed to age, with TSS analyses being performed every day that the samples aged. Synthetic solutions were also prepared to study the "salting" phenomenon.

Jan 1, 1996

By J. Libaude

The Changement mine in French Guyana has, since 1983, processed gold ore by classical gravity methods. A large part of the gold is in the form of very small, free or enclosed grains. Recovery by gravity methods is thus limited (25-30%) and the present plant produces about 40,000 t annually of auriferous waste assaying about 6 git. The company therefore decided to retreat the waste by heap cyanidation. After laboratory tests which showed the feasibility of the method, a pilot test was set up on site. An experimental 3000 t heap, composed of waste of 0-8 mm grain size, was laid out by bucket loader on an impermeable pad covered by PVC and geotextile cloth. The upper layer of the heap was reworked by mechanical shovel to break up the area that had been compacted by the passage of the loader so as to restore adequate permeability.

Jan 1, 1998

By Harrie van Dijk

Feeding laterite nickel slurry into high pressure acid­leach (HPAL) autoclaves in an aggressive environment with slurries heated up to 200°C requires a special pump design. For decades the GEHO piston diaphragm pumps have been used for autoclave feeding at gold ore pressure oxidation plants with slurries up to l 77°C. Lessons learned from these installations have been instrumental in designing second generation feed pumps for processing laterite nickel with operating temperatures of 200°C and a flow rate of 400 m3/h. The Australian nickel industry is using momentarily 8 GEHO positive displacement piston diaphragm pumps. For this application six GEHO ZPM 900 "dropleg" pumps have been supplied to the Murrin Murrin project and two to Bulong.

Jan 1, 2000

By Gary P. Marshall, Jeffery S. Thompson, Robert E. Jenkins

The effectiveness of the new DuPont Passivation Technology in eliminating acid generation from iron sulfides is presented. Passivation is achieved by treatment with a dilute basic perman­ganate solution. This treatment produces a thin impervious layer of iron/manganese oxide on the sulfide surface, providing a bar­rier to the environment so that the sulfide is not available for undesirable reactions such as the production of acid.

Jan 1, 1998

By P. Brooks, W. LaRochelle, J. M. Tranquilla

EMR's recently commissioned Pilot Plant in Fredericton, N.B. Canada, the latest and largest in the company's sequence of prototype and demonstration systems, is being used as a process development facility for mining clients worldwide. Fitted with two microwave reactors and 75 kW generators, this plant is designed as a two-stage continuous processor with a throughput in the 5-10 tpd range depending upon the material feedstream. This facility has been used principally to calcine pyrite and arsenopyrite gold concentrates although it can readily accommo­date carbonaceous materials as well as a wide range of other ore types. Engineering details of the plant and the results of the first nine months of operation are presented. The plant has proven very successful as an advanced process development facility as well as a basic production unit module.

Jan 1, 1998

By Andy Cole, Stanley Bunk, Steve Dunn, Thom McCord

In 1994, Goldstrike initiated a research program to investigate processing options for treating what was then the small amount of carbonaceous ore identified in the reserves. The focus of the research was on developing a process which incorporated the autoclave technology already utilized at Goldstrike. Over the next two years, Barrick pursued the development of an ammonium thiosulfate leaching (ATS) process. During the period in which the ATS research was being conducted the amount of carbonaceous ore in Goldstrike's reserves increased substantially and continued growth was projected. By 1996, significant advancement was made on the development of the ATS process. The work culminated in a series of integrated pilot plant runs incorporating autoclaving, ATS leaching, resin in leach, stripping and cementation. Several questions about the process chemistry remained unanswered, preventing commercial development. Barrick was committed to producing gold from the carbonaceous ore reserves by 2000. A due diligence review of carbonaceous ore processing options was initiated during the second half of 1996. Processes considered in addition to ATS were fine grinding/autoclaving, as practiced then by Santa Fe, and whole ore roasting as practiced by Independence Mining and Newmont. The objective by year-end was to recommend the most robust and economical process for Goldstrike's carbonaceous resources. In the fall of 1996, a detailed review of roasting as a processing alternative for Goldstrike was initiated. Throughout the ATS development period, whole ore roasting was used as the benchmark. All the ATS metallurgical and financial results were compared to roasting bench top test results. It was clear this data was too imprecise for use in due diligence study, a more definitive recovery value was needed to complete the carbonaceous ore review. The primary goal of the roasting review was to conduct pilot plant roast tests to gain a more thorough understanding of Goldstrike's carbonaceous ore's response to roasting and its effects on gold recovery. Using the test facility at Hazen Research, four pilot plant campaigns were conducted to determine optimum roast conditions and further define metallurgical design parameters. Conventional two-stage fluid bed technology based on Freeport­McMoRan's roasting patent was the specific process basis for testing. The ore's response to roasting exceeded expectations. In January 1997, a preliminary economic evaluation comparing ATS and roasting was presented, and the outcome was approval to proceed with a roasting prefeasibility study. In July 1997, approval for Goldstrike's Roaster facility was received and basic engineering started immediately thereafter. Detailed engineering _began in January 1998 and plant construction commenced in October 1998,t, Goldstrike's Roaster facility is designed to treat 12,000 tpd of a refractory gold ore, which contains both pyrite and organic carbon. Circuits in the facility include primary and secondary crushing, dry grinding, roasting, gas handling, neutralization, thickening and standard CIL. Gold desorbtion and recovery is carried out at Goldstrike's existing refinery. Plant start-up of the first dry grinding and roasting train is scheduled for March 2000, with the second train coming online in May 2000.

Jan 1, 1999