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By Gail I. Bakker, Mark E. Smith, George Sintay, Allan Young

The Snow Caps mine was an open pit and conventional cyanide heap leach gold project located 10 Km east of Independence, California in the Owens Valley. The project is unique in that it is one of the first projects to go full-cycle, from design through closure, under California's Chapter 15 mine waste regulations adopted in 1984. The property was acquired by Sunshine Mining Company in 1985. During 1986, final design and permitting were completed and the facility was commissioned in 1987. Mining continued to mid - 1990, when the minable ore body was depleted, and heap leaching continued into early 1991. Rinsing of the spent ore was completed in 1991, and final closure will be complete in 1992. The spent ore will be left on the leach pad for its final disposition. The focus of this paper is the permitting and closure aspects of the project as required by California's Chapter 15, Article 7 regulations.

Jan 1, 1992

By F. W. DeVries, J. Brent Hiskey

The search for noncyanide lixiviants for treating gold and silver ores and concentrates is not a new endeavor. However, in recent years, the overall activity to seek a less environmentally controversial reagent than cyanide has occasioned considerable developmental work. While the elegant economy and simplicity of cyanide, because of its selectivity and the ease of recovering gold and silver from the cyanide complexes, is well recognized, two failings have justified the search for alternates: increasing concerns and costs to assure avoidance of environmental damage from cyaniferous liquids and solids, and the need to simplify recovery of gold and silver from refractory ores. Generally, process development work to date on the alternate reagents has lacl<::ed environmental focus ( Hiskey and Devries, 1992). This paper covers briefly the chemistry of various alternates to cyanide and reviews their environmental implications. In each case, environmental overtones are reviewed following the chemistry. For ease of follow-up, the authors have listed sources of information in detail. Alternates examined include:

Jan 1, 1992

By W. P. Staunton, K. Jones

INTRODUCTION The increased activity in the Aus­tralian gold industry over the last decade has resulted in a concomitant increase in the use of sodium cyanide, with a projected consumption of 80,000 tonnes in 1991. Growing environmental awareness by government, industry and the public has generated increased interest in the fate of cyanide near gold mine tailings dams and has highlighted the lack of basic knowledge in the area, particularly for Australian conditions. In 1989 the Chemistry Centre (W.A,) commenced a' project, under the auspices of the Australian Mineral Industries Research Association entitled "Fate of cyanide in the Enviroment Near Mine Tailings" to investigate some of the issues arising from the management of tailings containing cyanide, The project, which has been supported by thirteen companies has three broad aims:

Jan 1, 1991

By David E. Peterson, F. Merz

The Waihi Gold Mining Company Limited, Martha Hill Project was the first major hard rock mining operation following the resurgence of the mining industry in New Zealand. Because of its location adjoining a town and at the southern part of the sensitive Coromandel Peninsula, the operation received a high level of public scrutiny. Very srrict limits for effluent criteria had to be met and led to the necessity for advanced wastewater rreatment technology. The process technology selected was the copper catalysed oxidation of cyanide using hydrogen peroxide, with subsequent removal of heavy metals by precipitation and filrration. This paper discusses the adoption of environment limits together with the detailed description of the plant and design criteria. Data of the one year's operational history is also presented.

Jan 1, 1991

By Frank Kitzinger, Jacques Nantel

Under special circumstances, electrical energy can successfully replace chemical ex­plosives for blasting rock. High pressure plasma can be generated in the confines of a drillhole, by a powerful electrical dis­charge. The energy level can be adjusted to replicate the effect of a high explosive. The main difference is the almost total ab­sence of gas generation with electric blast­ing. Once the rock fractures, the small amount of matter used for generating the plasma rapidly cools off and regains its former volume. High speed film studies clearly show, that the initial speed of blasted rock fragments is the greatest, no further gas propelled acceleration takes place .. Figure 1, shows a typical electric blast of an oversize boulder of quarzite in an open pit mine.

Jan 1, 1992

By Jean-Guy Deschamps, Allen H. Gipson

Profitability of heap leaching projects could be greatly improved if heap heights were significantly increased. Currently, heaps have been designed to a maximum height of approximately 450 feet. Higher heaps reduce ore processing costs by handling greater quantities of ore per unit area of pad. In areas with high rainfall, higher heaps also offer the benefit of a reduced catchment area resulting in less meteoric water to manage. The concern with high heaps is the functionality of geosynthetics and piping under extreme loads. Knight Piesold in Denver has developed the capability to test geosynthetics and collection piping under loads equivalent to those imposed by

Jan 1, 1996

By Thomas J. Ferree

The efficiency of Carbon-in-Pulp and Carbon­in-Leach circuits is determined by the degree to which the carbon can extract the gold from the slurry and transport it to the stripping circuit. The 'pick-up' efficiency of the carbon particles is affected by several factors which include the following: * The concentration of the carbon in the slurry. * The surface area of the carbon particles. * The reactivity characteristics of the carbon particles. * The retention time of the carbon in the slurry.

Jan 1, 1992

By Donald R. East

The impacts of the economic storage or disposal of mill tailing wastes are becoming more important to the mining industry as environmental regulations become more demanding. Mill tailings have long been considered the stepchild of the extraction process and have not, until recent years, been treated as a separate entity of the mining and milling process with distinct and complex physical and chemical characteristics. As a waste product, the economic value of mill tailing is usually very small whilst economic and the environmental liabilities can significant. be Disposal of tailing is commonly identified as the single most important source of environmental impact for many mining projects.

Jan 1, 1990

By James McMaster

The Kamyr Countercurrent Tower Leaching Process is intended to combine, in a single tower, thickening, leaching, separation and clarification of pregnant solution, and washing of leaching chemicals from the tailing pulp. For a gold or silver metallurgical plant, the flowsheet would consist of crushing and grinding, cyclones for size control and partial thickening, the Kamyr tower, and a gold or silver recovery system of either carbon in solution, zinc precipitation, or direct electrowinning. Ancillary systems for the Kamyr metallurgical plant would include cyanide preparation, fiber preparation and recovery, and flocculant preparation.

Jan 1, 1990

By Joseph A. Dos Santos

Developed in 1983, high angle conveyors - HAC®s are proven versatile systems for elevating materials continuously from a lower to an upper level. Such systems may also be used to lower materials continuously. HAC®s have found commer­cial application in widely varying materials (including coal, refuse, coarse ores [-250 mm], hot clinker, municipal sludge, wood chips, gypsum, slag, excavated earth, various grains and RDF), at widely varying throughput rates from 0.27 to 4250 t/h. The conveying profiles have varied widely and elevating heights range from 3.66 m to 175 m. HAC®s have found application in coal, copper and iron mining, and preparation, in municipal waste treatment, rapid transit projects, pulp and paper mills, cement plants and in gold mining. While noting a wide variety of applications in general, the present writing focuses on Newmont Gold's HAC®, near Carlin, Nevada, which elevates very coarse gold ore to the screening plant. Additionally, upcoming HAC® applications in gold mining are discussed and a proposed multi-flight vertical HAC® system from a deep underground mine is described.

Jan 1, 1996

By James R. Arnold

With all of the publicity, criticism, and notoriety that the mining industry has received over migratory birds, it is diffi­cult to remember that six years ago no one even suspected that this issue would'emerge. After all, cyanide had been used in Nevada mining for 20 years without significant effects on wildlife. Although the mining industry has been buried in unjustified criti.cism for not having a clearer crystal ball, most of those critics forget that no one else predicted this problem either. In fact, the Nevada Department of Wildlife reviewed and had no objections to the Paradise Peak Plan of Operations before they began production. As we now know, Paradise Peak had one of the first and most severe avian mortality prob­lems in the State. It should also be noted that Paradise Peak has done more to research and solve the migratory bird problem than all of the rest of the Nevada mines put together. It is not possible to review all of the research and field work that has gone into investigation of the avian mortality problem over the past five years in this short paper, but a synopsis can be presented. In most instances we can say that we have solved the problem, We have learned what works and what does not. Let's start with what does not work. Unfortunately, the list is long and elaborate, but can easily be summed up in one word: hazing.

Jan 1, 1990

By Ralph P. Hackl

Biooxidation processes for treating arsenical and other types of refractory gold ores are touted by many as being simple, inexpensive and environmentally friendly. One of the advantages claimed by proponents of biooxidation is that arsenic is disposed of as insoluble ferric arsenate which is suitable for long term disposal in tailings ponds. However, there is considerable controversy as to the stability of ferric arsenate with respect to re-dissolution of arsenic. In particular, there is concern that the amorphous ferric arsenate produced at low temperature is not stable, especially at the alkaline pH's required for cyanidation. There is a general lack of published information on the stability of arsenical bioleach tailings. Past work on ferric arsenate stability has usually involved purely chemical systems and the use of synthetically prepared precipitates. Upon completing the Salmita bioleach pilot plant campaign (Hackl and Wright, 1989) the author had the opportunity to test the stability of the arsenical bioleach/cyanide tailings which were produced. This paper summarizes the results of that work.

Jan 1, 1990

By Alex Ruzycki

Gold Fields-Mesquite is a 7.5 million ton per year heap leach operation located in the Maj ave Desert of Southeastern California. Extraction of gold is carried out on multiple lifts, with over 33.3 million tons of ore leached since the inception of operations in 1985. The delineation of the gold left in heap residue is a formidable task. Gold removed from active leach areas can be routinely monitored through sampling of emerging solutions but exact recoveries from specific heaps remains nebulous due to factors such as cross flow between sections buffering effects from multiple lifts, and releaching. In order to better quantify ultimate heap recoveries and increase releach efficiency, Mesquite initiated a residue drilling program. The project progressed through an evaluation of sampling protocol, drilling of residue by reverse circulation, entry of assays into a software package capable of producing grade-based contour maps, and a production scale releach test that evaluated the system's ability to predict residue grade.

Jan 1, 1992

By Terry Mattioli, Buck Bradshaw, Terry Fagg, Larry G. Nisle

Deposition of calcium carbonate scale on activated carbon in the Pinson Mining mill carbon column circuit was causing erratic gold recovery rate, long acid wash time, high carbon attrition and long strip times. Continuous addition of a blended antiscalant into the mill thickener overflow at 8 ppm reduced the average carbon acid wash weight loss from approximately 10% to < 2%. Cleaner carbon improved the gold loading rate in the mill column. The loading on Column I was increased to 175-225 oz/ton carbon from 125-150 oz/ton for a two-day carbon advance cycle. The higher loading capability has given Pinson more flexibility and better control of gold flow through their carbon adsorption, stripping and electrowin­ning processes. Preventing calcium carbonate build-up on activated carbon with this antiscalant reduced acid wash batch time. This enabled Pinson to acid wash and regenerate every batch of stripped carbon for all the adsorption circuits. Shorter strip times have also resulted from the lowering of the calcium carbonate scale level in the loaded carbon. Carbon consumption has been reduced and is now averaging 0.046 lb/ton ore for the first six months of 1990 compared to 0.072 and 0.083 lb/ton respectively in 1989 and 1988.

Jan 1, 1990

By L. D. Jayaweera, R. G. Robins

The pocessing of gold bearing sulphide minerals wr ich contain arsenopyrite and other complex arsenic sulphide minerals results in arsenic containing emissions and effluents which must be given careful consideration in relation to clean air and clean water standards. The sources of arsenic and the various process options for treating arsenical gold ores and concentrates are briefly reviewed. The problem relating to the removal of arsenic from gaseous emissions from roasting processes is considered. Residues from aqueous processing contain a variety of arsenical materials which have not been characterised, and the long-term stability of these is suspect. 'rhe use of lime to stabilise aqueous residues as either calcium arsenate or calcium arsenite has been shown to be inadequate for long term disposal since both compounds are converted into calcium carbonate due to the influence of carbon dioxide in the atmosphere. Ferric ion solutions have been used to precipitate ferric arsenate or to form ferric hydroxide which binds the arsenic for short term disposal, The long term stability of these ferric materials is poor, but could lead to the acceptance of a slow release option rather than complete containment of residues.

Jan 1, 1991

By C. A. Fleming, K. W. Sarbutt, P. K. MacPhail

The SART process has been developed for Teck to treat bar­ren solution from the cyanidation/CIP process that has been developed for the Lobo-Marte project in Chile. The objective of the process is to recover cyanide in a form that is suitable for recycling to the leaching part of the process. The Marte and Lobo ore bodies require a dosage rate of about 2 kg/t NaCN, of which only 0.5 kg/t is truly consumed (as thiocyanate, cyanate and ferrocyanide species). The remaining -1.5 kg/t is present as cop­per cyanide (-1 kg/t) and free cyanide (-0.5 kg/t), and is poten­tially recoverable and recyclable. SART is an acronym that describes the unit operations in this cyanide recovery process; namely, .. Sulphidization .. Acidification .. Recycling of precipitate " Thickening of precipitate The basic chemistry has been applied previously, and has also been the subject of two patents (American Cyanamid Company, 1965, Potter et al., 1986). The process involves the conversion of all free and WAD cyanide in solution to hydrocyanic acid by acidification of the tailings solution to pH :s,4, and the conversion of all copper in solution to cuprous sulphide (synthetic chal­cocite) by the addition of a sulphide salt:

Jan 1, 1998

By Mark Godfrey, Wickus Slabbert, Debra Miller, Dave Dew

Sao Bento Mlnerai;;ao Mine (SBM), located 100 kms northwest of Belo Horlzante, Brazil, was commissioned In 1987t1l to produce 185 kg per month of gold from 240 tpd of refractory sulphide flotation concentrate. The concentrate Is processed by a Sherrill Gordon design pressure oxidation circuit followed by conventional CIL gold recovery process (Flgur .. J). The original plant design foresaw expansion to 480 tpd, and In this regard the acidic effluent neutralisation, CIL and carbon circuits were designed for future expansion to treat the higher tonnage. The pressure oxidation section was sized for 240 tpd with the Intention to double the Installed plant equipment to provide 480 tpd capacity when required. This decision was based In part on the novelty of pressure oxidation to treat refractory sulphide concentrates in 1984 when the process design was finalised. General Mining, Metals & Minerals (Pty) Ltd (GENMIN), has been actively Involved for the past 30 years in the development of bacterial process for the oxidation of refractory gold concentrates; the results of this development program have provided the registered process BIOx®. The successful Implementation of BIOx® technology for treatment of refractory gold concentrates at GENMIN's Fairview Mine In October 1986t2l, as well as the substantial experience accumulated in laboratory and pilot testing of some 40 other sulphide concentrates, Justified reconsideration of the oxidation process best suited to provide the Incremental sulphide oxidation capacity planned for SBM.

Jan 1, 1992

By Brian D. Smith, Batric Pesic

Typical sulfide gold bearing ores are refractory to standard cyanidation practice. This type of ore always needs some form of oxidative pretreatment to destroy the original host mineral matrix to make the cyanidation possible. The oxidative pretreatment can be achieved by roasting, autoclave leaching, bioleaching, or some other chemical method. Today, the most common practice of ore oxidation is either roasting or pressure leaching. The other methods are still considered developmental.

Jan 1, 1992

By W. Hopkin

INTRODUCTION Necessary science and technology are not well established for the design of responsible treatment and disposal of arsenical residues from refractory gold ores. Specifically, there is uncertainty about the precise composition and behaviour of oxidised arsenic species in these wastes, and an analysis of possible chemical behaviour suggests that potentially difficult control and disposal problems remain to be so 1 ved. In tackling these the undoubted toxicity of arsenic in excess and its bad press should not blind one to the realities of actual behaviour in the environment, and that some adverse behaviour inevitably has to be to 1 erated as a cost in return for the recovery of an operation's gold for society. The problem is to minimise any such cost. Each refractory ore will be different. Many will contain so little arsenic that it will cause only trivial problems in disposal, but there remain others with significant arsenic content, say in the order of 1% or more, to cause concern. As already implied, concern can be over emphasised but equally underestimated. The balance which must be struck in the design of responsible disposal in the widest sense requires objective and practical assessment of a complex range of chemical, biochemical, engineering and economic design factors, all of which should involve the process design team in constructive dialogue with the 1 oca l regulatory authorities. In British terms, the general objective should be the Best Practicable Environmental Option. Arsenic is ubiquitous in waters, rocks and soils and all living things. Its compounds undergo natural geochemical and bi ochemi cal cycles including powerful adsorption and precipitation processes which return to nature all leakage from the inevitable disturbance of mining and extraction operations. Within limits, all life is tolerant to its presence, and adaptation and detoxication processes occur to deal with local excesses.

Jan 1, 1991

By Richard E. Deery, Reginald E. Reid

A large portion of the public lands in the United States is managed by the U.S. Department of the Interior, Bureau of Land Management (BLM). Public lands administered by the BLM comprise about 39 per cent (270 million acres) of the entire Federal surface estate or about 1/8 of the surface of the United States. Most of this land, located in the 11 Western States, including Alaska, is available for mineral exploration and development. The BLM is a multiple-use land management agency responsible for the balanced management of the public lands and their resources. The BLM's task is to ensure the balanced and sustainable development of the public lands and resources. This task translates into the management of people and their use of the public resources. As a result, the BLM manages a diverse group of programs including recreation, range lands, timber lands, fish and wildlife habitat, watershed, wilderness, scientific, cultural, and historic properties, and most importantly for this paper, energy and mineral resources. The BLM has developed several new policies with respect to mining, including policies on inspection and enforcement, financial guarantees for reclamation, and the use of cyanide. The goal of these policies is to demonstrate to the American public that mineral exploration and development can be an integral part of sustainable development on public lands in an environmentally sound manner.

Jan 1, 1991