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By H. J. Sohn

Systematic studies were carried out on the adsorption of the silver thiourea complex on activated carbon. The experimental isotherm data fit the Freundlich isotherm equation. The adsorption rates increased with increasing temperature and decreased slightly with the increase of free thiourea concentration. The concentration of sulfuric acid had little effect on the adsorption rate. Adsorption kinetics correlated well with the Elovich equation, indicating adsorption is the rate-determining step.

Jan 1, 1987

By A. S. Ibrado, D. W. Fuerstenau

The adsorption of the cyano complexes of Ag(I). Cu(l), Hg(II), Cd(II), and Zn(II) on activated carbon was investigated as a function of pH and correlated with the speciation diagram for each metal. The results show marked changes in uptake with pH, closely resembling the predominance profiles of their neutral and singly charged cyano complexes. Multicharged negative complexes are repelledby the negatively charged carbon surface. The sensitivity of activated carbon to the charge of the adsorbing species indicates that silver adsorbs as an anion, not chemically bound to the coadsorbing counterions. For the same reason, activated carbon is selective to metals that preferentially form neutral and singly charged cyano complexes, namely gold and silver.

Jan 1, 1990

By John H. Canterford

The adsorption of uranium onto Wyoming bentonite was measured in carbonate media over the range pH 8-11. Uranium was removed from solution onto the solids by a rapid reaction, proposed to be adsorption of the anionic uranyl tricarbonato complex onto edges of the clay platelets, and a slow reaction which may be precipitation of a hydroxide. The changes in uranium content of the aqueous and solid phases of a uranium ore carbonate leach slurry were also measured as the slurry was progressively diluted. There was an increase in the uranium content of the solids as the pH of the suspension was lowered, as was observed with the Wyoming bentonite. The results indicate the conditions that should be met with respect to pH control in order to prevent the problem of excessive uranium adsorption in the counter-current decantation washing circuit of a conventional leaching process, as well as in the leaching and restoration phases of carbonate solution mining.

Jan 1, 1983

By A. Pomianowski

A spectrophotometric study of xanthate solutions alone and their mixtures with equimolar amounts of alkyl trimethyl ammonium bromide (CnTAB) has established the additivity of ultraviolet spectra (190 - 400 my) for potassium ethyl xanthate (KEtX) and C12TAB. No obvious effect of C12TAB addition on the decomposition rate of KEtX was observed. The kinetics of collector abstraction by copper, nickel and sphalerite powders were studied in 10-5 - 10-3M solutions of KEtX alone and in equimolar mixtures of KEtX and C12TAB. Presence of C12TAB caused a 2 - 3 fold increase in the amounts of xanthate (equivalent to many monolayers) abstracted by copper and, nickel powders but had no effect on the abstraction of xanthate by unactivated sphalerite. The adsorption of C12TAB itself from the mixed solutions was very low, at most ore monolayer only, and was not influenced by the nature of the solid powder used. The results are interpreted in terms of molecular associations and synergistic action of xanthates and quaternary amines.

Jan 1, 1963

By Mengxiong Guo, Xuxin Shao, Yong Bao

In the paper, the adsorption properties of dissolved ions on the surface of collophane and dolomite are studied using zeta potential measurement, ESCA and UV adsorption spectrum both in distilled water and in the supernatant of each other. The effect of dissolved ions on the flotation separation of collophane and dolomite under SCO depressant and oleate is discussed on the basis of above analyses.

Jan 1, 1993

By Zhe Liu, Liping Xiao, Jichi Bai, Xuefei Luan

"In order to study the removal efficiency of Cu2+ from acid mine drainage by prepared bentonite-steel slag composite particles, adsorption experiment was carried out. The composite particles were characterized by X-ray Diffraction analysis technique (XRD), Scanning Electron Microscopy (SEM) and Fourier Transform Infrared spectrometer (FTIR). The results show that: the composite particles can release alkali to neutralize the acid of acid mine drainage; the adsorption and chemical precipitation of Cu2+ occurred in the whole reaction process; the removal amount of composite particles on Cu2+ was 9.88 mg/g when the reaction reached equilibrium; the FTIR spectra revealed the existence of surface complexation; the SEM micrographs suggested that the composite particles would continue to adsorb and coagulate Cu2+ after the composite particles surface adsorbing Cu2+ and forming precipitate, namely, there was synergistic reaction of adsorption and coagulation; the XRD patterns further showed the existence of cation exchange and revealed that the states of Cu2+ in the surface of the composite particles was Cu-Si-O mineral phase and CuO(Cu(OH)2) polymerization precipitation. The bentonite-steel slag composite particles which can play a role of adsorption-coagulation synergism are excellent multifunctional green environmental mineral materials to treat acid mine drainage containing heavy metal ions.Introduction It is reported (Zuo and He 2013) that with the rapid development of industry, the world demand for mineral resources is increasing, while the problem of mine environmental pollution is becoming more and more serious due to the large amount of mining. The pollution of mine wastewater has become a global problem, in which acid mine drainage (AMD) is one of the most serious waste water. It is also reported (Cong and Zhao 2003) that acid mine drainage containing high concentrations of heavy metals and having low pH value, causing serious negative influence to the mining production and ecological environment. Acid mine drainage is one of the most serious environmental pollution to the mining industry. In recent years, it has been widely concerned by scholars at home and abroad."

Jan 1, 2017

By Saul J. Esdalera

The flotation response to amine collector and its adsorption on the mineral surface was studied as a function of pH and collector concentration. The flotation response increased in the order anorthite + intermediate plagih clases + albite, while adsorption of amine obeyed the Freundlich equation r = A.Cn. This adsorption is proposg to be due to a covalent bonding between the AlOH surface pups of the plagioclase altered outer layer and the amino group of the collector. Finally, the study showed thatmtial dissolution of the solid phase provides the necessary conditions for amine attachment on the mineral particles and consequent flotation.

Jan 1, 1980

By L. Shevenell, L. Stillings

The Acid Drainage Technology Initiative-Metal Mining Sector (ADTI-MMS) has established a Pit Lake Committee to enhance the science and understanding for the long-term management of pit lakes. Participation in this new committee is from members of federal and state agencies, industry, and academia, including numerous individuals representing 10 states. Work has begun on a pit lake literature search and review, database, classification, and sampling and monitoring procedures document. Coordination with the International Network for Acid Prevention (INAP) has been established. Future work will include preparing a prediction and assumption verification document, a report identifying variables upon which water quality is dependent, and an applied remediation technologies document, including an evaluation of the effects of backfilling.

Jan 1, 2002

By Tamara Nestorovic, Luan T. Nguyen

"With the aim to mitigate excavation risks and reduce the costs caused by tunnel boring machine (TBM) stoppage when tunneling under uncertain soil conditions, prediction ahead of the tunnel face has become an increasing interest in the tunneling community. Our research topic is concerned with developing effective concepts for nondestructive identification of geological anomalies ahead of the tunnel face by waveform inversion of reflected tunnel seismic waves. The authors demonstrate that this new technique is promising in providing tunnel engineers with an accurate image of the geological situation that the TBM is going to encounter thanks to the waveforms’ rich information about the geological structure that affects propagation, reflection/refraction and mode conversion behavior of the elastic waves. By setting up a 2-dimensional numerical model for simulation of tunnel seismic wave propagation influenced by a dip layer change ahead of the tunnel face, the authors show that the waveform misfit to be minimized by the inversion process is highly multimodal and therefore propose a hybrid stochastic optimization method that can quickly and robustly converge to the global minimum. DEVELOPMENTS IN TUNNEL ADVANCE EXPLORATION Conventional site investigation by drilling boreholes helps to draw a general image of geological structures along the borehole axes but that image is likely to misrepresent the detailed geological structure due to limited sampled locations. Due to high costs and restricted boring space which deep tunneling and tunneling under urban areas encounter, many industrial and academic research groups have had great interest in developing nondestructive ahead of the tunnel face prediction systems. That means only excitation sources and receiving sensors, which are usually placed on the ground surface or on the side walls or on the cutter head of the TBM, are used for acquisition of the measurement data. The recorded signals in the form of seismic or electromagnetic/ electrical waves, which travel through the geological structure or are reflected back from it, hold the signature of the geological structure of concern, such as geological layer changes, fault zones, erratic rocks, boulders, construction remnants, etc., and therefore can be used to reconstruct the spatial and material properties of those hidden geological structures. Most common nondestructive ahead-of-tunnel investigation systems to date are based on interpretation of reflected elastic/ acoustic waves (seismic waves) and analysis of electromagnetic/ electrical resistivity signals (Mooney et al. 2012). However, due to insufficient penetration depth and spread of signals generated by radar and geoelectric sources, the use of seismic waves for ahead of the tunnel face prediction (tunnel reconnaissance) is more preferable (Kneib et al. 2000; Bohlen et al. 2007)."

Jan 1, 2016

By Trevor Ellis

The following is extracted from a report by the author to the International Valuation Standards Committee (IVSC), with minor modifications for the purpose of publication. The author represented the IVSC at the annual session of the Ad Hoc Group of Experts on Harmonization of Fossil Energy and Mineral Resources Terminology. This is a body organized by the United Nations Economic Commission for Europe (UNECE). This second session, held in Geneva, Switzerland, achieved an important agreement for advancement toward uniform global standards for the classification of minerals and petroleum reserves and resources. Attendees discussed the possibility of enhancing the United Nations Framework Classification for Energy and Mineral Resources (UNFC) for implementation globally as the classification standard for use in financial reports under the International Financial Reporting Standards (IFRS). Presently, there are between 100 and 200 mineral and petroleum resource classification (or definition) systems throughout the world — a similar number to what there are countries.

Jan 1, 2006

By Norman A. Nadel

Those of us who have directed our efforts toward the construction of tunnels have long maintained that tunnel construction is more closely an art than it is a science. We have spent time underground with hard-bitten, tobacco chewing shift bosses and superintendents who have made seat-of-the-pants decisions at the face which have been based upon their long experience underground coupled with uncanny intuition. The courage and skill of these men in the performance of their art is legendary. Without question, they have constituted the backbone of the tunnel construction industry. But just as John Henry, the steel driving man, despite his stout heart and dedication to his task, was supplanted by the steam drill, I fear that our tunnel stiff, at least as we have known him, will become an endangered if not extinct species. The reason for this is clearly that tunnel construction is slowly but inexorably making the transition from being an art into being a science, and more and more its performance is requiring the services of scientists as opposed to artists. The tunneling art has been undergoing change for many years, and yet until recently the changes have not been basic. We have improved the way we do the same old things. For example, John Henry would be flabbergasted if he saw the rock drills we use today. He would not have engaged in the legendary drilling contest with one of our modern drills, He would have simply conceded defeat.

Jan 1, 1970

By Dan Ifrim

Soft ground tunneling poses major challenges to the underground industry. Most of soft ground tunnels are in highly urbanized areas, often include limited cover, and include a strong trend of increasing diameters. Therefore, soft ground tunneling works can sometimes cause inevitable ground movements and settlements that may lead to damages to adjacent buildings, roads, structures or utilities; many of these being “lifeline” infrastructure assets. Tunneling operations, Tunnel Boring Machine (TBM) advance rates, and face pressure control can significantly increase or decrease such risks, depending on how well the TBM and operational parameters are applied to the ground conditions. Additionally, the risks of impacting existing infrastructure are heightened in many parts of North America because of cobbles and boulders. To date there is no standardized guideline that determines appropriate tunneling rates nor operator’s guidelines, to ensure safe tunnelling in soft ground. The paper analyzes tunneling records from completed soft ground tunnels to determine a relation between ground conditions, tunnel cover, TBM cutters maintenance and TBM advance rates. The records are discussed to draw several mitigation measures to be adopted during tunnelling, to reduce risks of settlements, over excavation or sinkholes.

Jun 13, 2021

By I. K. Kapageridis

Environmental management and planning requires the integration of large volumes of disparate information from many sources and the analysis of this information with efficient tools for assessment and evaluation. Effective methods of communication that allow interactive participation in the planning, assessment and decision-making processes are also very important. The VULCAN software package from Maptek (Pty) Ltd comprises a large number of 3D graphical tools within an interactive 3D interface called ENVISAGE. These tools are designed and developed to help engineers and scientists to identify and solve environmental problems. The combination of VULCAN 3D Software and the I-SiTE 3D Laser Imaging system leads to powerful solutions for environmental management. This paper presents the capabilities of this integrated system and its applications for environmental management.

Jan 1, 2002

By T. A. Griffin

Gentlemen: The subject of this paper is: ADVANCED APPLICATIONS OF BUCKET WHEEL EXCAVATORS AND RECLAIMERS. Against an urgent world wide energy crisis, the role of bucket wheel excavators and reclaimers in the surface mining of fossil fuels and other ores has been raised to new prominence. This paper will review the reasons for the expanded application of bucket wheel technology, its unique contributions, and other factors relative to volume, cost, versatility, and efficiency. Today, surface mining is faced with the twin challenge of (1), accelerating the rate of removal of massive quantities of overburden and ore, and (2), replacing comparable high volumes of overburden back into the mined-out portion of the pit. Optimum quantitites for - a single electrical power plant now range from 5 to 15 million tons of coal per year. The use of bucket wheels offers the best method for meeting this challenge at lowest possible cost. For example, an advanced application that also satisfies environmental concerns involves the simultaneous functioning of two bucket wheel excavators during surface mining operations. Working at spaced intervals and different levels in conjunction with a transfer conveyor and stacker, one excavator removes the ore while the other one transfers overburden to a stacker that replaces it back into the open pit. The result of this continuously operating cycle is: (1) removal of ore and replacement of overburden back into the pit in massive quantities, (2) at accelerated volume and extreme low cost that cannot be matched by conventional loading machines of any size, and (3) fulfills a basic environmental requirement which is to

Jan 1, 1974

By D. H. H. Quon, A. Ahamd, G. Pouskouleli, T. A. Wheat

An outline of the contributions of hydro- metallurgical techniques such as sol-gel processing, direct precipitation and hydro- thermal decamposition for the development of high-quality ceramics is given and examples drawn from recent work on both structural (engineering) and functional (electrical) ceramics are discussed.

Jan 1, 1990

By G. Luttrell, S. Keles, M. Eraydin, R. Yoon

The dewatering of fine particles is energy intensive and often requires costly capital expenditures. To address these issues, a series of advanced dewatering technologies have been developed at Virginia Tech. These include novel dewatering aids that enhance the performance of existing filtration equipment and an innovative hyperbaric centrifuge that utilizes both air pressure and centrifugal force for dewatering. The moistures obtained using these processes are 30-50% lower than those obtained using conventional methods. Another dewatering technology, known as the hydrophobic displacement process, can reduce product moistures to a level previously attainable only through the use of thermal dryers. This article presents test results obtained with these various advanced dewatering technologies along with estimates of the power consumption for each process.

Jan 1, 2007

By Ronald J. Doll, John Elkin, M. P. Evans

The application of "Alignment Free” right angle shaft mounted drive systems offers improved reliability and reduced costs for surface and underground belt convey- ors. Comparisons to conventional approaches will cover installation, operating, maintenance, and spares inventory cost savings. Various options for belt acceleration and load control on fixed and variable length (booster) belt conveyors will be reviewed for operating performance, reliability, and total cost. Lastly, a case study of a successfully operating installation will be highlighted.

Jan 1, 1996

By Karen L. Menna

At Digital Equipment Corporation, increasing demands on executive secretaries to share, track, and retrieve information prompted development of ALL-IN-1 System for Executive Services. Executive secretaries asked engineers to combine word processing and electronic mail with utilities for managing time; logging and tracking telephone calls, letters, and inquires; creating presentations; compiling directories; and archiving. The system, two years in development, now automates the president's and senior vice presidents? offices at Digital. It allows secretaries to interrupt any task with two keystrokes, and return later to the original task. The system has speeded customer response, enabled online information sharing, and increased professionalism and customer satisfaction.

Jan 1, 1989

By K. E. Harrison

Acid rain legislation as proposed by President Bush [1], if enacted, will immediately refocus current thinking on the economic decision-making as related to coal preparation facilities. Unit operations currently ignored because of their costs, will become mandatory to coal plant designers and operators to ensure maximum energy recovery and sulfur reduction in the entire coal stream. In anticipation of this need, the U.S. Department of Energy, The Ohio Coal Development Office, EPRI and others are sponsoring research in several areas of coal preparation, and coal plant designers are beginning to consider more innovative techniques as they configure their flowsheets for plants of the future. Preparation plants then will have recleaning

Jan 1, 1990

By K. E. Harrison

The acid rain legislation has passed into law. This new law has caused the power generation community to investigate alternative methods to obtain compliance with the new legislation. One thing all of the power companies have concluded is the answer is not easy. Do we switch fuels to burn all low sulfur compliance coal? Maybe possibly only partial desulfurization by means of a dry sorbent system? Or, finally, maybe a wet scrubber system? Whatever the choice, the power community needs to investigate all of the alternatives. In 1988, ICF Kaiser Engineers, Inc. (ICF KE) responded to a request by the U.S. Department of Energy for the engineering development of advanced physical fine coal cleaning. ICF KE responded and was awarded a contract to conduct a multi-task program to develop an advanced flotation system to eliminate pyritic sulfur and retain as much energy as possible. ICF KE assembled a team that included members of industry, academia, and industry research organizations to conduct this multi-task program. The program includes sixteen (16) tasks. This team had personnel to help solve some of the anticipated problems and to provide industry prospective on the viability and commercial potential for any concepts proposed. The primary team consists of a major coal producer, Babcock and Wilcox, Eimco Process Equipment Company, and Virginia Polytechnic Institute and State University.

Jan 1, 1992