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By Douglas R. Cook

Our present and future needs for base and previous metals are not satisfied by the present rate of new viable discoveries. This deficiency can be met by increasing the number of competent exploration organizations and by doing a more effective job of prospecting. My principal purpose is to show that new discoveries can be increased by improving the use of exploration techniques in a concept-oriented exploration program. Exploration techniques are defined and classified. The effectiveness of many exploration groups can be improved by better definition of objectives and thorough planning of the exploration program. The role of objectives, planning, and the use of techniques are discussed within the scope of the exploration framework. Common pitfalls in the use of exploration data are identified such as: inconsistency of geologic measurements, negative use of data, indiscriminate use of geo-surveys, collection of irrelevant information, and the unrealistic desire for exploration panaceas. Suggestions for improving the use of techniques include the use of multiple-working hypotheses, improvements in the quality of exploration data, use of geology in the selection, planning and interpretation of geochemical and geophysical surveys, and the recognition of variables and limitations affecting the interpretation of exploration data. The critical role of geologic mapping by Federal and State agencies is mentioned for satisfying the continual exploration demand for better geologic maps and filling many gaps that currently exist. The importance of imaginative and qualified exploration personnel is discussed as well as the maximum utilization of their exploration creativity. The problem of integrating field studies, research and training at universities and research institutions is identified. The need for high-quality research in economic geology is emphasized especially the importance of reducing the steadily increasing gap between basic and applied research.

Jan 1, 1968

By S. Maurigiannakis

In an effort to promote sustainability in the construction industry, the natural decorative stones that cover large external areas of buildings may be replaced with artificial stones. In this paper the physical and mechanical properties of artificial decorative stones are presented and are critically compared with corresponding natural stones. To test suitability for various applications, artificial stone specimens were subjected to weathering testing (freezing-thaw cycles in a climatic chamber). Mechanical characterization of these specimens was based on uniaxial compressive testing as well as non-destructive ultrasonic testing. Preliminary results show that artificial stones can replace natural stones, thus creating a sustainable development option for the construction industry.

Jan 1, 2003

By D. Belin

Treatment of dilute acid mine drainage and similarly polluted water is becoming increasingly complicated. The pressure of economics is now exacerbated by legislation which classifies as hazardous waste the precipitates from conventional lime treatment plants. Since acid mine drainage invariably contains sulfate ions, one solution is to use anaerobic Desulfovibrio type bacteria to reduce the sulfate into sulphide ions which could then be used to precipitate out the heavy metals. Results are presented for both batch flask cultures and continuous column tests. Compost was used as the bacterial substrate in the column test which simulated heaps. Conditions changed from aerobic to the required anaerobic deep in the columns. Polluted feeds (up to 700 mg/l zinc) gave effluent containing well below I mg/l zinc over extended periods. Direct transfer of sulphide ions through a stream from an isolated container of bacteria is a good alternative.

Jan 1, 1991

By R. L. Eppley

The Blacklick Creek Watershed Association was awarded a $158,000 Growing Greener grant from the Pennsylvania Department of Environmental Protection in 2002 for the design and construction of a sulfate reducing bioreactor (SRBR) cell to treat acidic discharge from the Judy 14 abandoned underground coal mine near Indiana, PA. The vertical flow SRBR was designed to treat 38 liters per minute of MIW containing elevated concentrations of aluminum and iron. Other treatment systems at this site plugged due to aluminum precipitates; this problem did not occur in the SRBR. The bioreactor has been periodically overloaded with flows up to six times the design rate. To date, the only maintenance performed on the unit has been the addition of hay to the surface of the unit in response to less than expected performance. The periodic hay additions appear to have restored the SRBR to nearly post-construction levels. Since construction, the SRBR has treated about 136,000 cubic meters (36 million US gallons) of MIW.

Jan 1, 2010

By J. Wagner, P. Eger

Although lifetime estimates for sulfate reduction based on total substrate carbon typically range from 20 to 30 years, field and laboratory experiments showed that rates of sulfate reduction decreased over time as readily available organic material was consumed. When the rate of acid input exceeded the rate of sulfate reduction, alkalinity was removed from the substrate, pH decreased and metals increased. Output pH increased from 4 to over 6 after the system was shut down for several weeks and the rate of acid input was reduced. Successful long term treatment requires a design based on the input pH and the long-term organic decomposition rate.

Jan 1, 2001

By J. Wagner, P. Eger

Although lifetime estimates for sulfate reduction based on total substrate carbon typically range from 20 to 30 years, field and laboratory experiments showed that rates of sulfate reduction decreased over time as readily available organic material was consumed. When the rate of acid input exceeded the rate of sulfate reduction, alkalinity was removed from the substrate, the pH decreased and metals increased. Output pH increased from 4 to more than 6 after the system was shut down for several weeks and the rate of acid input was reduced. Successful long-term treatment requires a design based on the input pH and the long-term organic decomposition rate.

Jan 1, 2002

By I. E. Zevgolis

A comprehensive critical review on the subject of sulfates-induced swelling behavior of lime-treated soils is presented in this study. Starting with the description of a well documented case study, the mechanisms behind the swelling behavior and the factors that affect this behavior are discussed. Then, the major experimental methods of sulfates content determination are briefly presented. Finally, an attempt is made to categorize sulfates level and equivalent risk for civil infrastructure. The paper indicates that limited work has been done, not only on identifying safe conditions for use of chemical stabilizers in presence of sulfate rich soils, but also on developing materials and methods to avoid, or at least mitigate, the problem.

Jan 1, 2008

By A. H. Kaksonen

Numerous reactor designs for biological sulfate reduction have been reported. Fluidized-bed bioreactors (FBR) can efficiently retain biomass and allow high mass transfer and reaction rates. This work reviews the development of various sulfate-reducing FBR processes for treating acidic metal- and sulfate-containing waters and recovering metals from bioleaching liquors. The FBR process performance was evaluated with continuous flow experiments under various operational conditions: fluidization rates, influent pH values, metal, sulfate and salt concentrations, hydraulic retention times, electron and carbon sources, and temperatures. Substrate utilization and sulfide inhibition kinetics were determined with batch FBR-kinetic experiments. An artificial neural network (ANN) model was used to predict the performance of the FBR. Sulfate-reducing bacteria (SRB) were characterized in FBRs with molecular and culture-based approaches with the aim to gain a better understating of the bioprocesses. Based on the studies, FBRs are well suited for the combined removal of metals, acidity and sulfate from water.

Jan 1, 2010

Because of the different types of reagents used for the flotation of sulfide and nonsulfide minerals, it is convenient to consider these two groups of ores separately. The metal sulfides and native metals are substantially all floatable with xanthate and similar collectors.

Jan 4, 1982

By Omar A. Muhtadi

Brohm Mining Corporation, in conjunction with Geobiotics, Inc. has nearly completed a pilot heap biooxidation test on sulfidic ore from the Gilt Edge Mine near Rapid City, South Dakota. Some results from the pilot testing have shown the correlation between the extent of biooxidation and the increase in cyanide gold recovery seen in the laboratory. Bench scale testing showed approximately a 1: 1 correspondence between percent biooxidation and percentage increase in gold recovery. The economics of large scale biooxidation were also evaluated in terms of increased gold recovery versus the time and cost of biooxidation. In the pilot test, the rate of biooxidation became limited by the acid water neutralization system. Later in the test, measures were taken to overcome this problem. Results from bench scale column bioleach testing showed that the Gilt Edge sulfide ore is quite amenable to biooxidation with a substantial increase in gold recovery with just partial biooxidation. Direct cyanide gold recovery of 51 % on ore crushed to -3/8" was enhanced to 82-85% after oxidation of37% of the sulfide as measured by iron. Laboratory experiments also showed that the slow rate of biooxidation of this ore could be accelerated by removal of metal sulfate build up from the leach liquor. The combination of these normally non-toxic metals became inhibitory to biooxidation if not removed by the neutralization circuit.

Jan 1, 1995

By John W. Shield

Oxide gold reserves are being rapidly depleted, especially in regions with long histories of gold mining, such as the Black Hills of South Dakota. However, these districts often have substantial additional deposits, where gold is refractory. It is not amenable to traditional cyanide extraction due to the presence of sulfide minerals that encapsulate or otherwise preclude the economic extraction of the gold. Several technologies have been developed to render refractory sulfide deposits amenable to traditional cyanide processing. These include roasting and pressure autoclaving. Unfortunately, these oxidation processes require substantial capital investment and incur significant operating costs. Microorganisms that obtain energy for their life processes by the oxidation of iron sulfides can be used to treat gold-bearing refractory sulfide minerals. As the bacteria convert the sulfide to sulfate, they expose any gold associated with the sulfide matrix. This makes the gold amenable to cyanide extraction.

Jan 1, 1996

By B. Derin

In this study, the Reddy-Blander model was applied to predict the sulfide capacity (CS) values of FeOx-CaO-SiO2, FeOx-MnOx-SiO2 and FeO-MgO-SiO2 ternary slags, which were experimentally studied in the literature within the temperatures between 1,673 and 1,923 K. As expected, sulfide capacity values of the slags increased with increasing temperature and decreased with increasing acidic content. The model was found to be in agree-ment for all slag systems at the temperature range of 1,773-1,923 K. However, a disagreement occurred when the basic content was relatively high, at 1,673 K for FeOx-CaO-SiO2 and FeO-MnOx-SiO2 slags. The effect on the CS of high amounts of Fe+3 and Mn+3 in the slags is discussed.

Jan 1, 2011

By D. S. Kimbal

The McCoy/Cove mine is located 48 km (30 miles) south of Battle Mountain, Nevada, USA, in the Fish Creek Mountains at an elevation of 1548 m (5080 ft), see Figure 1. Joseph H. McCoy first discovered gold at this location in 1914. This discovery led to the Gold Dome Mine which produced the first gold from this area in 1928. After the Gold Dome era, the land remained relatively dormant until Houston oil and Minerals Corporation purchased the claims from the Summa corporation and defined an ore body at the present day McCoy pit. In 1986 Tenneco Minerals (formerly Houston oil and Minerals corporation), sold the McCoy mine and adjoining claims to Echo Bay Minerals corporation. The Cove ore body was discovered soon after the sale to Echo Bay. Echo Bay expanded the heap leach operation and built the present mill which began processing ore in the fall of 1989.

Jan 1, 1993

By Lana Alagha, Fardis Nakhaei, Jose L. Corchado-Albelo, Noelia Munoz-Garcia, Michèle Heitz

Sulfide tailings from past and present mining activities are important hosts of critical elements and precious metals. This review paper presented a literature survey on the recovery practices of some critical minerals containing Te from sulfide tailings with a special focus on the physical beneficiation and hydrometallurgical separation methods. Finally, a conceptual framework and possible processing flowsheets were proposed. The findings of this review will be useful for the researchers in the field of geochemistry, mineral processing, and metallurgy to evaluate the separation processes for reprocessing of mine tailings for the recovery of critical minerals.

Feb 1, 2024

By Dale A. Shay, Roy R. Cellan

The Santa Fe Mine, located in west central Nevada, began leaching ore in 1988 and completed ore processing in 1995. Homestake Mining Company has completed final reclamation of the site, including remediation of bare surface soils resulting from the oxidation of sulfide minerals and migration of acidity in the mine waste repositories. The need to remediate oxidized sulfides and mitigate resultant acidity at the Santa Fe Mine emphasizes the economic, reclamation, and environmental advantages for understanding and pre-planning for management of potential sulfide wastes during mine planning phases. The lack of pre-planning by mining companies for sulfide waste management was common in the 1980's due primarily to mining of reserves characterized largely as oxide deposits and to the common opinion that low moisture regimes in arid or semi- arid climates would not allow for significant acid generation. Since the 1980's, operational experience has shown that sulfide wastes, deposited randomly in waste dumps and without adequate planning for final reclamation success, can create final reclamation problems that are very costly to remediate. While mine waste characterization, waste management plan compilation, and in-pit selective waste handling procedures add operational costs, the reclamation experiences at the Santa Fe Mine are indicative that pre-planning and management is worthwhile both in actual overall cost efficiency and in successful reclamation of the mine site. The reclamation program at the Santa Fe Mine shows Homestake's continued commitment to the successful management and reclamation of their mine sites.

Jan 1, 2000

By G. Wang

Industrial minerals processing has gained importance lately, not only due to its wide range of new and regular applications in processing different industrial minerals, but also due to the strict specs under which products are commercialized. Among the processes applied to industrial minerals, flotation is a leading technology. The laboratory study and commercial operation demonstrate that the sulfonated reagents are very effective collectors for industrial minerals. This paper compares synthetic petroleum sulfonate with fatty acid on iron reduction in glass sand processing and describes the effect of conditioning pH on iron reduction using synthetic petroleum sulfonate as collector, the effect of molecular weight of natural and synthetic petroleum sulfonates on their flotation performance and the enhancement made for certain products.

Jan 1, 2011

By R. Norman Holme

Sulfonate promoters and collectors were originally developed as relatively inexpensive anionic collectors to selectively concentrate the iron-bearing minerals in low grade iron ores and to remove iron and other mineral contaminants by flotation in the processing of glass sands, feldspar and other ceramic raw materials. The first reagents produced were effective collectors for such iron oxide minerals as goethite, hematite, limonite, magnetite and siderite. Further development has resulted in additional reagents with a broadened application to the selective flotation of a variety of nonsulfide and nonmetallic minerals. The products in this group are anionic sulfonate-type promoters, natural petroleum sulfonates, and synthetic modified sulfonates. Beyond their applications to iron-bearing minerals, the sulfonate collectors have gained commercial use in the flotation treatment of barite, celestite, fluorite, apatite, chromite, industrial garnet, kyanite, mica, rhodochrosite and cassiterite. in addition, extensive laboratory studies indicate their potential suitability for flotation of the following minerals: Anatase Anhydrite Bauxite Beryl Calcite Chlorite Some Copper Carbonates Corundum Dolomite Hornblende Huebnerite Ilmenite Lepidolite Magnesite Phosphate Minerals Rutile Scheelite Spodumene Sillimanite Talc Tourmaline Wolframite Zircon Sulfonate promoters are water soluble or dispersible liquids, syrups or pastes of varying viscosity with colors ranging from dark blackish-brown to clear. Customarily, they are fed to the conditioner or flotation as 5% to 30% water solutions or dispersions. In addition to their normal collector activity, certain of these products display notable frothing characteristics. Improved collector efficiency and adequate froth control can frequently be obtained by employing mixtures of sulfonate reagents, of ten with results quite markedly superior to those achieved with equivalent dosages of the individual promoter alone. Reagent requirements will vary with the type of mineral being treated; however, a general overall range of 0.13 to 2.0 kg/metric ton (0.25 to 4.0 lb/ton) of feed should cover most applications.

Jan 1, 1986

By C. B. Cecil

The sulfur content of United States coal can be assessed by using a variety of approaches. The sulfur content may be expressed in terms of total sulfur in the coal, pounds of sulfur per million Btu, or sulfur remaining after reduction by coal preparation. In addition, the sulfur content may be applied to the demonstrated reserve base or to coal resource estimates. Unfortunately current data bases do not allow for an integrated assessment at the National level. Although classification of coal resources and reserves according to sulfur content is arbitrary, preferential production of low-sulfur reserves will positively skew the total sulfur of the remaining coal resource.

Jan 1, 1986

By Milton E. Wadsworth, M. Ken Han

The kinetics of leaching of galena in hydrochloric acid solutions with sulfur dioxide gas have been investigated experimentally. The leaching method is then applied to complex sulfide concentrates to evaluate its selective leaching capability and to develop a new hydrometallurgical lead extraction process based upon the method. The leaching reaction follows a linear rate with an activation energy of 61.9,KJ/mole. The rate Is of first order with respect to the product [H+] [Cl-] . Excel lent selective leaching capability f s demonstrated and an attractive hydrometallurgical process flow sheet is proposed.

Jan 1, 1989

By John M. Dale

Now that the price of sulfur has reached unexpected high levels, it is little wonder that sulfur from surface ores is again receiving attention. In most instances, it is advantageous for an ore to be at or near the surface. However, it is a distinct disadvantage for sulfur ore to be close to the surface because it precludes the use of the Frasch process. The Frasch process depends on the presence of at least 180 m of uniform overburden to allow pressure injection of superheated water into the sulfur-bearing formation to melt the sulfur. In the Frasch process, sulfur separates cleanly from the gangue underground and comes to the surface in a very pure form. Surface sulfur deposits, particularly those in the Western Hemisphere, exist largely due to volcanic activity, and sulfur separation from the gangue is a formidable technical problem. None of the surface deposits are large compared to some of the Frasch deposits, but at the present sulfur price, they are certainly of economic importance. From the turn of the century until 1975, the price of sulfur was for the most part $18-$28/t. However, with the price of sulfur now over $154/t, there are a variety of technical alternatives to consider for sulfur surface ore separation that may not have been economically attractive a few years ago.

Jan 9, 1981