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By J. Bai, C. Zang, W. Yuan, L. Zhuang

"This study evaluates the efficiency of using mechanochemical reduction to assist the extraction of zinc from zinc ferrites by alkaline leaching. The transition of zinc ferrite into a metastable state after mechanochemical reduction with metallic iron contributes to the ready dissolution of zinc from the activated zinc ferrites in alkaline solution. Zinc ferrites were mechanochemically reduced under conditions of Fe:ZnFe2O4 mole ratio of 2:1, using 5 mm diameter stainless steel balls as the activation medium at a mass ratio of balls to raw materials of 25:1. Subsequent leaching in 6 mol/L NaOH solution at 90°C resulted in more than 70% Zn extraction. These results may be used to further develop a hydrometallurgical process for recovering zinc from zinc ferrites in alkaline solution.IntroductionZinc is an important nonferrous metal required for various applications in batteries, solder, dielectric materials, and piezoelectric materials. High-grade, easily concentrated ores are becoming scarcer: to meet world demands for zinc, it is necessary to develop economical and environmentally safe metallurgical technologies that use secondary materials such as leach residues of roasted zinc concentrates and electric arc furnace dusts. The zinc in the majority of these wastes occurs in the form of zinc ferrite (franklinite, ZnFe2O4), which is very stable and insoluble in most acidic and alkaline solutions (Langova and Matysek, 2009; Youcai and Stanforth, 2000).Several pyrometallurgical and hydrometallurgical processes (Jankovi et al., 2014; Langova and Matysek, 2010; Morcali et al., 2012; Shawabkeh, 2010) have been proposed for the treatment of zinc ferrites. Pyrometallurgical methods are costly owing to high energy consumption and their emissions of toxic gases are considered an environmental problem; hydrometallurgical methods are preferred for process economy and environmental reasons (Copur et al., 2004)."

Jan 1, 2016

By A. W. de Villiers

This paper explores the behaviour of methane in the goaf during longwall mining, together with some methods for the control of methane emissions into the goaf, the working face, and the ventilation system. Experimental work done at Twistdraai Colliery, Sasol Coal, is referred to, as well as the gas-drainage system being practised at West Cliff Colliery in New South Wales, Australia. Gas drainage is discussed briefly, and certain suggestions are made in regard to coal mining in South Africa.

Jan 1, 1989

By G. O. Rading, B. O. Odera, M. J. Papo, R. Couperthwaite

"Platinum-based alloys are being developed with microstructures similar to nickel-based superalloys for potential high-temperature applications in aggressive environments. Since the chemistries of nickel and platinum are similar, Pt-based alloys can be made with gamma prime ~Pt3Al precipitates in a gamma (Pt) matrix. Currently, the Pt-Al-Cr-Ru system is one of the bases for developing Pt-based alloys, where Al allows the formation of thePt3Al precipitate and also gives protection from the alumina scale formed, Cr provides oxidation resistance and stabilization for the L12~Pt3Al phase, and Ru provides solid solution strengthening in the (Pt) matrix. Four Pt-Al-Cr-Ru-V and two Pt-Al-Cr-Ru-V-Nb alloys were made, with compositions based on a quaternary alloy, ~Pt82:Al12:Cr4:Ru2, which hadpreviously been identified as having optimum properties. Four of the as-cast alloys had the targeted two-phase structure of ~Pt3Al and (Pt), and two were single-phase ~Pt3Al. Vanadium partitioned more to (Pt) than to~Pt3Al. There was an improvement in hardness compared to the quaternary alloys. The best addition of V was ~15 at.%; higher additions resulted in brittle intermetallic phases of the Pt-V system. The effect of Nbcould not be ascertained because of its high losses."

Jan 1, 2015

By D. S. Dihalu

A generalization of Gy?s model for the fundamental sampling error introduced the new ?parameter for the dependent selection of particles?, denoted as Cij. This allows for modeling deviations from the ideal situation where the selection of a pair of particles is composed of two independent selections. The generalized model potentially leads to more accurate variance estimates in the case of clustering of particles, differences in densities or sizes of the particles or repulsive inter-particle forces. A straightforward and practically applicable method is needed for the determination of this parameter for miscellaneous mixtures in industrial settings. In this contribution, the feasibility of using digital image analysis to determine this parameter Cij, will be demonstrated. Line transect sampling of a digital image was used to construct a transition probability matrix. A new algorithm to derive quantitative estimates for Cij will be presented and discussed. The applicability was verified by a photograph of zirconium silicate particles of sizes typical for industries dealing with pharmaceutical, food/feed, and environmental applications. Conditions affecting the practical applicability are identified and potential pitfalls will be discussed, including e.g. how a potential unrepresentative surface can affect the quality of the estimate of Cij.

Jan 1, 2010

By D. G. Hulbert, D. Tudors, M. L. Coetzee, I. K. Craig

The paper describes how a multivariable control scheme was developed and implemented for the run-of-mine milling circuit at a gold mine belonging to Vaal Reefs Exploration & Mining Company Limited. The key variables that are controlled are slurry level in the sump, mass of material in the mil, and product size. The control scheme has resulted in reliable control of the dynamics of the plant, and has provided a good basis for the optimization of plant operation by the selection of suitable set Points.

Jan 1, 1990

By M. P. Brungs, S. Haji Amini

Static dissolution of CaO into a CaO-SiO2-Al2O3slag and slags with additional fluxing agents (fluorspar, nepheline syenite and ilmenite) was studied. The slag was packed into dense CaO crucibles and heated to 1500ºC /1600ºC. After reaction, the crucible was air cooled and cross-sectioned. The development of the Ca2SiO4 phase and concentration profiles of various cations across the reaction zone were examined by Electron Probe Micro Analysis. At 1500ºC, a Ca2SiO4layer was found to form at the CaO/slag interface. No such layer was evident at 1600ºC. Ilmenite and nepheline syenite were found to be effective substitutes for fluorspar, increasing the rate of CaO dissolution.

Jan 1, 2004

By D. M. Meyer, K. Auerswald

The production of electrolytic manganese in South Africa by M. HARRIS, Pr. Eng., B.Se. (Eng.) (Fellow), D. M. MEYER, Pr. Eng., B.Se. (Meeh. Eng.) (Visitor), and K. AUERSWALD (Visitor) The decision to construct the first electrolytic manganese plant in South Africa was important and farreaching. After evaluating the results of the pilot plant operation, the first South African producer, Electrolytic Metal Corporation (Emcor), established a plant in Krugersdorp. Initially, there were many process problems that had to be InvestIgated, and, after these had been solved and many operating parameters had been established, manganese was successfully produced. When the Delta Manganese plant in Nelspruit was planned, cognizance was taken of the fact that, if peak efficiencies were to be maintained, the process must be operated between fairly narrow parameters. Instrumentation was therefore installed to control the process automatically wherever possible. The main features of the Delta Manganese operation are outlined, with a brief description of each stage of the process from ore milling through to electrowinning and packing of the metal. It is concluded that much benefit can be obtained from further research work into process improvements and into the exact effect of certain variables on plant and current efficiency.

Jan 2, 1977

By D. Duncanson, R. J. Davidson

The elution of gold from activated carbon using deionized water by R. J. DAVIDSON, M.Sc., Ph.D. (Rhodes) (Visitor) and D. DUNCANSON, H.N.C., B.Sc. Hons. (Strathclyde) (Visitor) The pretreatment of gold-loaded activated carbon with a relatively strong sodium cyanide solution prior to elution with deionized water at 90 to 125°Chas been shown to have a most beneficial effect on the elution of gold. The findings emphasize the important role played by the calcium cation and the hydroxyl anion in effecting efficient elution of gold. The elution of the relatively unstable complexes of silver and base metals with cyanide was also significantly affected by the ratio of the sodium cyanide to sodium hydroxide in the reagents used in the pretreatment stage. It was demonstrated that the use of 0,5 bed volume of a pretreatment reagent comprising 10 per cent sodium cyanide stabilized with I per cent sodium hydroxide for safety reasons resulted in a virtually 100 per cent recovery of adsorbed gold, silver, and base metals on subsequent elution with deionized water. The elution procedure takes a relatively short time, about 14 hours at 90°C (7 bed volumes) or 3 hours if pressure elution at 125°C (4 to 5 bed volumes) is used. Because the mechanism of elution after pretreatment entails the shifting of a physical rather than a chemical equilibrium, the higher the gold loading on the activated carbon, the more efficient is the elution procedure. When compared with other elution procedures, the proposed method appears to have several economic advantages.

Jan 7, 1977

By J. P. Beukes

The production of ferrochrome alloy from chromium bearing chromite ores is conducted at high temperature under highly reducing conditions. However, albeit completely unintended, it is impossible to completely exclude oxygen from all high temperature process steps, with the corresponding possibility arising for the generation of small amounts of Cr(VI) species. Certain Cr(VI) species are regarded as a carcinogenic, with specifically airborne exposure to these Cr(VI) species being associated with cancer of the respiratory system. With approximately three-quarters of the world?s viable chromite ore reserves located in South Africa, and annual ferrochrome production approaching almost half of total annual global output, aspects of Cr(VI) generation and control are of particular relevance and importance to the local industry, and naturally to the global industry at large. This paper seeks to examine theoretical and practical aspects associated with Cr(VI)generation (based largely on experience within the local South African industry, but considered to be generally encountered in the broader global industry context), together with mitigating measures that can be applied within the context of the production processes. From the discussions it is clear that significant improvements in various Cr(VI)-related aspects have been made by the South African ferrochrome industry. However, it is also evident that several areas of uncertainty still exist, which require further research in order to better quantify risks and enhance the efficacy of mitigating steps. Keywords Hexavalent chromium, Cr(VI), ferrochrome production, South Africa.

Jan 1, 2010

By P. J. D. Lloyd

The widely employed IPCC models for the release of methane from underground coalmining operations are reviewed, and put in the context of the South African National Communication on greenhouse gas emissions. Then attempts to calibrate the model via measurements on South African coalmines are described. These attempts failed because it rapidly became clear that the IPCC model, involving methane adsorbed by the coal and released (a) by the depressurization of the strata caused by mining, (b) from the broken coal and (c) from coal remaining in roof, floor, pillars or goaf after mining, was not valid. Instead, measurements showed that the methane release was very variable, sporadically falling to zero. Carbon dioxide concentrations were monitored at the same time as methane, and followed methane concentrations. An alternative model was developed, in which methane was largely displaced from the coal and held in fissures, cleats and pores, which, when intersected by mining, released methane into the ventilation stream. In a key test of this hypothesis, methane concentrations around a continuous miner were monitored both during operation and after shutdown. Even during operation, methane became undetectable. It is hypothesized that heating of the South African coal-seams during the emplacement of the igneous dykes that cut so many of the seams caused displacement of the methane from the coal into the pores. This fissure-held methane, or free methane, is released rapidly once a pathway through the coal into the mine atmosphere is established. In contrast, methane adsorbed in the coal, and measured as the seam gas, desorbs relatively slowly. Measurements suggest that on average about 50%of the adsorbed methane is lost one day after mining. By that time, the coal will have left the mine, so that the remaining seam gas will be released to the atmosphere outside the mine. Attempts to measure methane emissions from surface coal-mining operations showed very little detectable methane. Coal from surface operations, which was milled and exposed to atmosphere, adsorbed gas from the air. It is concluded that methane release from surface operations is probably less than 3Gg/a. It is estimated that the total methane release from the coalmining industry amounts to about 72 Gg/a, as opposed to the National Communication estimates of 323 Gg/a in 1990 and 317 Gg/a in 1994. However, there are large errors associated with these estimates, and it is recommended that the methodology outlined in this report be extended to as many mines as possible to reduce the errors that are inherent in the physical processes underlying the release of methane from South African coalmines.

Jan 1, 2005

By T. N. Moore, E. M. De Souza

This paper details a study conducted in Canada on the use of a drill with two different types of elastomer-covered handles in place of the standard steel handles. One type of handle was covered with a relatively stiff elastomer with a durometer of 70 (referred to as the plastic handle), and the other was covered with a more compliant elastomer with a durometer of 56 (refered to as the rubber handle). It was found that, compared with the steel handle, the overall acceleration at the interface between the plastic handle and the drill operator's hand was 2,5 times less, and that between the rubber handle and his hand was 3 times less. This reduction occurred predominantly in the frequency range above 500 Hz, and was greater with increasing frequency. However, an analysis based on the methodology of an international standard (which places greater importance on low-frequency vibration), indicated that the reduction in vibration levels was minimal. ~he driller himself felt that operation with the plastic and rubber handles was more comfortable, the rubber handle being preferred.

Jan 1, 1991

By A. Kapito

The ferrite-pearlite microstructure is the most popular microstructure for alloys used in structural applications, including railway wagon wheels. These alloys have been designed through alloying and thermo-mechanical processing to have a refined microstructure. Ferrite-pearlite alloys are low cost, weldable, have good fabricability, and are reliable under extreme conditions. Given these performance attributes, it seems unlikely then that their dominant position as structural steels would ever be challenged by alternative microstructures. One major achievement in the development of ferrite-pearlite steels has been in the refinement of their interlamellar spacing to very fine distances of the order of < 0.3 µm. A refined microstructure increases the hardness of the alloy, thus increasing its life under wear conditions. The interlamellar spacing in pearlitic steels has, however, been refined almost to its theoretical limit. The increasing demand for speed and increased axle loading on railway wagons requires the use of stronger, tougher, and more durable materials. This has opened the window for the development of novel bainitic steels. Bainitic alloys have a higher level of microstructural refinement than pearlitic ones. They have shown to have good wear resistance and rolling-contact fatigue resistance, and high toughness. This paper will discuss the progress to date on the development of bainitic railway wheel alloys. Four alloy chemistries have been chosen for possible further development.

Jan 1, 2012

Duties: The successful applicant will be responsible to the Planning Superintendent for long and short term Mine Planning. The current expansion programme requires production to be derived from new mines, using the most modern equipment. Considerable forward planning is required. Qualifications: Applicants should possess a degree or diploma in Mining Engineering. Experience: Five to eight years&apos; experience in hard rock mining is required of which some part has been spent on mine planning. Conditions: Salary to $7,000. Ample opportunity for further promotion exists in this expanding organisation. The person appointed will be eligible for benefits including discretionary annual staff bonus. An executive home will be provided in the new township with services at nominal rates. Primary schooling is available at Kambalda and the bus service operates for post primary students attending schools at Kalgoorlie. Reasonable relocation expenses within Australia will be met by the Corporation. Employment is conditional upon passing the necessary medical examination for admission to the Western Australian Mining Industry. Written applications, which will be treated in strict confidence, stating nationality, age, marital status and setting out qualifications and experience should be addressed to: The General Manager Operations-W.A., Western Mining Corporation Limited, Post Office Box 80, BELMONT, W.A., 6104. The envelope and application to be marked- "Attention: Senior Mining Engineer".

By D. J. de Clerk

Global trends stipulate the need to optimize existing assets while reducing environmental impacts. This paper illustrates the procedure that was followed to achieve such goals at one of the coal burning flash dryer units at an Anglo American smelter. An in-depth study of the process and related literature led to the development and installation of a revised control philosophy. This system includes modifications to the existing regulatory control structure as well as a hybrid rule-based and model-predictive advanced process control (APC) layer. Since commissioning of the APC, this flash dryer?s average throughput has increased by more than 6%, despite higher feed moistures. Furthermore, even though coal consumption has increased slightly, operating efficiency has improved by close to 5%. This was made possible by improving stability of the drying column outlet temperature by approximately 40%, which in turn enabled selection of a more optimal setpoint. Recent data has shown that APC utilization now exceeds 95%. This is indicative of a successful controller installation with good site acceptance. The same philosophy has therefore since been rolled out to most of the other flash dryers in the group.

Jan 1, 2012

By K. Tobór-Osadnik, M. Wyganowska, A. Manowska

"The behaviour of employees is an essential issue in the field of occupational health and safety. Safe behaviour is to a large extent determined by, apart from motivation and preventive actions, an employee’s attitude towards hazard. Thus, attention should be given to defining employees’ attitudes, and following that, to the possibility of correcting and shaping these attitudes in relation to hazard and obeying occupational health and safety regulations. The authors have focused on the analysis of employee attitudes to health and safety regulations in Polish coal mining companies, taking into consideration earlier research on the behaviour of selected employees. The paper presents the methods used to identify Z-type (passive) behaviour. Next, this behaviour is analysed to identify differences between a Z-type employee (enslaved) and other employees. To conclude, the paper presents a list of possible motivational tools that may be used to encourage occupational health and safety in Z-type employees. IntroductionThe technical state of equipment and conditions in the workplace greatly influence occupational safety. However, the deciding factor influencing the rate of accidents in the workplace is the frequency with which employees practise risky behaviour. Factors such as the social conditioning of conduct and motivation for organizing safe work conditions have been included in the notion of creating a positive culture of work safety. This notion has been approved as one of the main goals in management (Studenski, 1996).Safe behaviour is to a large extent, apart from motivation and preventive actions, determined by an employee’s attitude towards hazard. All actions undertaken in the field of occupational health and safety, including training, motivational systems, or imitation of behaviour resulting from a high culture of occupational safety in a given work environment, will not bring about the desire effects if workers have an inappropriate attitude towards occupational health and safety regulations."

Jan 1, 2017

By P. T. Wedepohl

The youngest technical programme committee of The South African Institute of Mining and Metallurgy- that on Physical Metallurgy - held its second colloquium on 18th September, 1984. The topic of &apos;Corrosion of Piping and Tubing in the Mining Industry&apos; was very appropriate since the date had been chosen to coincide with that of the Electra Mining Exhibition.

Jan 1, 1985

By A. Whillier

Recovery of energy from the water going down mine shafts by A. WHILLIER, Pr. Eng., Se. D. (M.I.T.) (Fellow) The influence of energy-recovery systems on the rise in temperature of water going down mines is examined. It is concluded that the, cost benefit of such systems, deriving partially from the reduced temperature rise in situations where cold water IS sent underground from surface, would more than justify the installation cost.

Jan 4, 1977

This paper summarises some observations regarding the way SAG and AG mills work based on the last ten years of pilot plant operation, grinding circuit design and operational reviews for various projects in Australia and overseas. The main purpose is to promote discussion on key factors influencing breakage in a SAG mill. The focus of the paper is on two questions: ? How do mill lifters and liners really work and have an effect on grinding? ? How does the mill charge composition impact on grinding performance? The focus of the paper is on observations of mill behaviour in both pilot plant trials and plant operation, particularly on Cadia ore. DEM, by others, and JKSimMet modelling of SAG mill performance have greatly assisted in forming the ideas expressed in the paper and both are valuable tools in developing our understanding of the comminution process. Put in the `extreme&apos; form the major observations and conclusions expressed in this paper are that: ? the main purpose of mill lifters is to reduce mill liner wear and not to promote rock breakage; ? the often promoted theory that balls impacting the ?toe of the charge? is a dominant form of breakage is incorrect; and ? fines production in a SAG mill is primarily a function of the rock load mass, with a secondary dependence on ball load for any given circuit configuration.

Jan 1, 2007

The Steering Committee for Minerals and Mining Policy convened two workshops during March 1996 to address the following topics: Business Environment- National and Provincial Powers, Administration and Regulation, Mineral Marketing, Beneficiation, Research and Development, Environmental Issues, Mining Impact on Surface Usage, Southern Africa Regional Issues. Human Resources: Elementary Residual Racism, Housing, Downscaling, Migrant Labour and Human Resource Development. Mineral Tenure: Mineral Rights, System of Access to Mineral Rights, Access to Exploration information, optimal Exploration, Trust Lands. Small-scale Mining. Development of Small-scale Mining, Artisanal Mining.

Jan 1, 1996

By D. Visser

This paper is based on the Townlands Ore Replacement Project whereby the concept of conventional sinking of one large diameter shaft was declined and replaced with three smaller raise bored shafts. A wire line geophysical survey was done and the results indicated that a single shaft larger then 4 m diameter unsupported would not be suitable. The shafts were placed 28 meters apart measured from centre to centre. To ensure that the skin to skin pillars between the shafts remained regular and to minimise any deflection, the pilot holes were drilled with the Rotary Vertical Drilling System. The different shaft sinking methodologies are discussed explaining the risk associated with each method.

Jan 1, 2009