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By M. Olper

The zinc recycling is assuming more and more importance. A lot of zinc secondaries and wastes are ready to be collected and converted to zinc metal. The impurities present in these materials and the technical and economical problems that some traditional ways of treating these materials are facing, call for new technologies. The EZINEX Process, a fully hydrometallurgical process industrially proven to convert oxidised zinc bearing materials directly to zinc cathodes, is an innovative process that can deal with any kind of zinc waste/secondaries in a very powerful way. In this paper the highlights of this process will be shown and discussed to demonstrate the robustness of the process and its economic viability.

Jan 1, 2008

By E. J. Y., G. J. McLachlan, E. Amini, Koha

Inferring individual component flotation rates from recovery-time data of ore complexes is important in optimising and designing minerals processing plants. However, existing two-component first-order flotation models are computationally intensive to solve using conventional non-linear least squares regression. In this paper, a Convolutional Neural Network (CNN) is used to approximate the inverse function which predicts the two-component first-order model parameters using recovery-time data. This paper compares the accuracy and computation speed of the proposed CNN against traditional non-linear least squares regression on 1 million generated data based on a known two-component firstorder kinetic model. It is shown that using a CNN is possible to approximate the inverse function for the non-invertible two-component model with recovery-time as an input matrix for convolution operations. The CNN method is 450 times faster to compute than the Trust-Region (TR) non-linear least squares regression algorithm. However, the CNN model is less accurate compared to the TR algorithm overall. Keywords: Flotation kinetics, convolutional neural network, inverse problem, modelling and simulations

Jan 1, 2020

By J. Cilliers, R. Seitz, D. Drinkwater

Mineral processing produces a saleable product from high-cost ore. The Mineral Processing Engineer must constantly improve the separation to create the most value from the ore and reduce the associated costs. Graduate Metallurgists (or Chemical Engineers) have had the university theoretical training required, but often are illprepared to perform their plant roles. The in-work Metcelerate programme was designed specifically to develop the practical skills that Mineral Process Engineers require, by combining three key elements: 1. Knowledge transfer through self-paced, on-line training; 2. Practical skills acquisition through assessed, practical plant exercises; 3. Skills development through online tutorials. A final process improvement project adds significant value to the operation that far exceeds the training cost. Experience from Metcelerate clients has indicated improved staff retention, greater confidence, and pro-active process intervention.

Jan 1, 2023

By Mark Van Kleek

CONTENTS ?The Falcon C ?Data from a Production Trial ?Methodology ?Scale-up ?Test Results ?Circuit Configurations ?Conclusion

Jan 1, 2006

By D. Seke

Metal inventories are usually reported in financial statements of mining companies. However, the value of these inventories can be reliable only if the metals in stock are measured within acceptable tolerances. Reliable metal balancing requires accurate mass measurement, sampling, and chemical analysis. Many mining companies are usually unable to validate the accuracy of metals in inventories at the end of their financial year. This is mainly due to poor mass measurement, sampling, and chemical analysis practices. This has an adverse impact on metallurgical accounting and metal valuation. In addition, it puts a lot of stress on external auditors, who have the duty to recommend the approval of the financial statements to the board of directors. Although a full value chain of metal reconciliation includes the accuracy of Mineral Reserve definition and grade control at the mine, this paper discusses the implementation of best practices for mass measurement, sampling, and chemical analysis at processing plants. This is an important aspect of sampling and reconciliation that is required in order to improve the reporting of inventories in the financial statements of public mining companies. Keywords metallurgical accounting, corporate governance, sampling, analysis.

Jan 1, 2014

The influence of Harold Hotelling?s work in the field of mineral economics is both unusual and outstanding. In the 66 years since its development, theory surrounding the economics of exhaustible resources has only been significantly researched since the early 1970s. At that time a wave of research into the economics of exhaustible resources arose from the threat of global resource scarcity and continued into the late 1990s. Current East Asian and global demand for natural resources as well as mineral and metal commodities, has stimulated interest in the optimal and sustainable exploitation of exhaustible resources to the point that the subject is worthy of review. Hotelling?s theory and the assumptions that he made in establishing a model for the optimal exploitation of mineral resources at the industry level and at the level of the individual mine owner, are examined. He showed that the rate of increase inexhaustible resource prices should be equivalent to the market rate of interest and that in a market with rising prices the rate of extraction should be constant. In markets where demand is stable optimal exploitation requires that the rate of extraction should decline over time, while in a monopoly market he showed that the rate of extraction is retarded. In addition, the effects of cumulative production on costs and prices, the uncertainty associated with estimates of the resource stock, the impact of exploration and issues of intergenerational equity are examined. An analysis of the optimal price path, extraction costs and mineral rents at an industry level is presented as a model. An analysis of the rates of production and optimal benefits at the individual mine level including total, average and marginal costs on the optimal rate of production, is considered. Optimal extraction rates for a mine with a clearly defined concave positive cost equation vary according to the position on the marginal cost curve. The influence of discount rates and the size of the ore reserves on the rates of mineral extraction are also examined and could define the frontier of usefulness for the ?economics of exhaustible resources?.

Jan 1, 2007

By G. A. Matthrsuis, R. N. Morris

The paper identifies two zones in a Leeds flotation cell. The ratio (13)of the dissipative forces and the interfacial tension force acting on a bubble and a solid particle are shown mathematically to be proportional to the square of the particle diameter for the quiescent zone and inversely proportional to the particle diameter for the turbulent zone. To locate the range of operation, correlations were established for the bubble diameter through photography and bubble counts. 13was found to be fairly constant in the particle size range 38 to 150 ",m, and the level of turbulence unlikely to affect the bubble-particle attachment and hence the beneficiation efficiency. This was verified in a series of flotation runs with a standard Leeds cell and a modified cell of twice the height to increase the capacity of the quiescent zone. A series of tests on the size range 300 to 600 ",m showed that the turbulence level had a marked effect on the cell performance through a relative improvement in the beneficiation efficiency due to the increased height of the cell. To identify the significant variables in the size range 38 to 150 ",m, a factorial design was carried out. Promoter dosage and particle size were found to be significant, aeration rate and impeler speed being insignificant at the 95 per cent confidence level. Multiple regression correlations were established for the recovery of organic material, mineral rejection, and beneficiation efficiency.

Jan 1, 1988

By D. Mesa, J. Karvonenb, A. López, P. R. Brito-Parada, R. Grau, D. Davoise

The froth zone in flotation cells plays an important role in determining metallurgical performance. This is even more critical as cell sizes increase, since larger bursting surface areas can easily result in poor froth transport and even stagnant froth zones, which are detrimental to recovery. Generating additional overflowing lip length by adding internal launders and reducing surface area (while also directing the froth to the overflow) by adding crowders are well established design strategies to enhance froth mobility. However, comparative experimental studies of froth zone design modifications at industrial scale are scarce and often lack detailed froth characterisation. In this work, we present the results of two experimental campaigns that were carried out at Atalaya’s Riotinto concentrator in order to determine the effect of a new froth zone design on the flotation performance of a TankCell® e300 cell that operates as the first cell of the rougher bank. These campaigns provided a unique opportunity to assess froth phase phenomena and metallurgical performance before and after changes in design. The original cell design had an internal peripherical launder and a froth cone, while the new concentrate launder technology adds a centre launder and an adjustable froth crowder to the existing launder design. The new concentrate launder arrangement reduces significantly the froth area as well as the froth transport requirements, aiming to improve froth recovery and, consequently, enhance flotation performance, allowing copper recoveries in the TankCell® e300 cell to increase dramatically. In addition, radial profiles of froth height and froth velocity at the surface were determined, which provide valuable insight into the effect of design changes on froth stability and mobility. Keywords: Flotation performance, enhanced recovery, launder, crowder, froth stability

Jan 1, 2020

By L. Ozdemir, B. Asbury, T. G. Rozgonyi

A new type of bit, that has been developed and is being evaluated, shows great potential in expanding the range of rock strength that can be cut by continuous miners and roadheaders. This new style of bit is called the frustum. The tools tested in this program were developed, manufactured and patented by Briese Industrial Technologies, Inc. The frustum derives its name from the unique geometric shape of the cutter, or cutting insert. The frustum shape cutting tool has previously been proven as an effective cutting tool for machining metals, metal matrix composites and polymers. The frustum rock bit has a very dense carbide frustum shape tip mounted on the end of a steel body similar to the conical bits typically used on continuous miners and roadheaders. In between the carbide frustum cutting tip and the steel body there can be a bearing that allows the frustum to rotate around the bit axis. When the bit is forced into the rock at a skewed angle, the frustum tip rotates as it travels. This rotation greatly reduces the cutting forces acting on the bit when compared to the current state of the art conical drag bits. This cutting force reduction, derived from the frustum’s cutting action, allows for much harder and more abrasive rock to be cut without quickly wearing out the bit. Full scale laboratory cutting tests have been performed with the frustum bit in direct comparison to the current state of the art conical bits. Field trials of the frustum bit are currently being planned. Test procedures, results and findings are presented.

Sep 1, 2001

The FSPE Award for Services to the Engineering Profession was awarded to Or Francis George Hill at a ceremony held in January of this year by the Federation of Societies of Professional Engineers. The following is an abridged version of the citation made by Professor A.N. Brown, President of FSPE, and of Or Hill?s reply. Achievements. It is indeed fitting that such a distinguished group of people have gathered on this special occasion to honour and pay tribute to Or Pinkey Hill

Jan 1, 1988

By A. R. Miller

A fuel cell locomotive incorporates the advantages of its competitors, namely catenary-electric and diesel-electric units, while avoiding their disadvantages. It possesses the environmental benefits, at the vehicle, of an electric locomotive but the higher overall energy efficiency and lower infrastructure costs of a diesel locomotive. The natural fuel for a fuel cell is hydrogen, which can be produced from many renewable sources or via nuclear energy, and thus a hydrogen-fuel cell locomotive will not depend on imported oil. Hydrogen produced from renewable primary energies or nuclear energy would provide a totally zero-emissions vehicle, that is, with zero carbon in the energy cycle. A project partnership among Vehicle Projects Inc of the USA, and South African partners Anglo American Platinum, Ltd, Trident South Africa, and Battery Electric, has designed and is launching a series of five prototype fuel cell-powered mine locomotives.

Jan 1, 2012

By S. Moolla, R. Lynch, S. Brijraj

A reliable method to locate microseismic evets is an important objective for routine mine seismic monitoring. We developed an algorithm that can automatically and reliably locate an event from a single uniaxial trace. Signals created by microseismic events are recorded as seismograms that consist of direct P- and S-waves as well as the waves reflected off the underground excavations. We take advantage of the extra complexity these reflections introduce as they make the signal more unique. In our investigation we cross-correlated unaltered synthetic seismograms against trial waveforms created from a linear combination of appropriate waveforms from a library of numerically calculated strain Green’s tensors. We use a single uniaxial synthetic seismogram to invert for the source location, six moment tensor components, and frequency. The resulting cost functions are constructed as maximal correlations at each node in the mine grid through the true source x-planes. This function is maximized by differential evolution to simultaneously yield the source parameters. Sensitivity tests such as shifting the mine plans and altering the background velocities of the media are investigated to test the robustness of the method. We contaminate the data with 40% white noise to test the resolution against simulated real recorded seismograms. The method is demonstrated using synthetic data calculated with a realistic underground 3D velocity model.

Jun 10, 2024

By T. Nyakudarika

The Unki Platinum Mines concentrator, employing an MF2 circuit configuration which includes fully-autogenous primary milling of run-of-mine (ROM) ore, was commissioned in November 2010. The project was Anglo American Platinum?s first PGM concentrator in Zimbabwe and would form a significant contribution to the group?s platinum production. The project financials demonstrated that the project was operating-cost sensitive. After reviewing the metallurgical testwork, mineralogical examinations, and the history of similar operations, it became apparent that the Unki ore characteristics rendered it amenable to autogenous milling. The primary ball mill, structurally designed for 30 per cent steel load, could be operated at the required initial phase throughput with fully-autogenous primary milling, realizing savings in both power requirements and grinding media consumption. The original mill sizing had been done with fully-autogenous milling in mind, but allowing for flexibility and mitigation in case of varied mining fragmentation. Since attaining steady state, target grinds have been achieved. This paper looks at the Unki ore characterization programme, design considerations, and the operational and control philosophy for a successful comminution circuit, and discusses the design to produce a flexible, low opex, mitigated comminution and overall MF2 flowsheet that is easily expanded in line with the potential for optimum exploitation of the orebody.

Jan 1, 2012

By B. J. Coetzee, P. W. Sonnendecker

The quality control of a two-stage coal washing process involves several complex components that need to be modelled accurately, to enable autonomous control of the process. The first objective is to develop a method to track the material through the washing process, while ensuring accurate washing prediction models are used. This was achieved through a digital twin model of the Grootegeluk 1 coal processing plant. The model is the amalgamation of manipulating and combining of data-sets from the plant historian, geological wash tables, and mining dispatch servers. This information is then used to control and set the processing medium densities of all 15 modules on the plant, 10 modules in the primary wash and 5 modules in the secondary wash. This controller has been successfully implemented and controlled the plant for 10 days.

Aug 2, 2022

By Y. H. Hatzor

ABSTRACT: A fully dynamic, two dimensional, stability analysis of a highly discontinuous rock slope is demonstrated in this paper. The studied rock slope is the upper terrace of King Herod’s Palace in Masada, situated on the western margins of the seismically active Dead Sea Rift. The dynamic deformation of the slope is calculated using a fully dynamic version of DDA in which time dependent acceleration is used as input. The analytically determined failure modes of critical keyblocks in the jointed rock slope are clearly predicted by DDA at the end of the dynamic calculation. It is found however that for realistic displacement estimates some amount of energy dissipation must be introduced into the otherwise fully elastic, un-damped, DDA formulation. Comparison of predicted damage with actual slope performance over historic time span window of 2000 years allows us to conclude that introduction of 2% kinetic damping should suffice for realistic damage predictions. This conclusion is in agreement with recent results of Tsesarsky, Hatzor and Sitar (2002) who compared displacements of a single block on an inclined plane subjected to dynamic loading obtained by DDA and by shaking table experiments. Using dynamic DDA it is shown that introduction of a simple rock bolting pattern completely stabilizes the slope. RÉSUMÉ : On présente dans cet article une analyse bidimensionnelle complète de la stabilité d’une pente rocheuse très fracturée. La pente rocheuse étudiée est la terrasse supérieure du Palais du roi Hérode à Massada, située sur la rive Ouest du Rift sismiquement actif de la Mer Morte. La pente est constituée de blocs de dolomite raide présentant une stratification sub-horizontale et des joints sub-verticaux. La déformation dynamique de la pente est calculée en utilisant une version entièrement dynamique de l’Analyse de Déformation Discontinue (DDA) où l’accélération dépendant du temps est utilisée comme donnée. Les modes de rupture déterminés analytiquement des blocs clés dans la pente rocheuse fracturée sont clairement prévus par l’approche DDA à la fin du calcul dynamique. On trouve cependant, que pour obtenir des estimations réalistes du déplacement, il faut introduire un facteur de dissipation énergétique sans lequel la formulation DDA serait totalement élastique et sans amortissement. En comparant l’endommagement prévu avec les caractéristiques de la pente sur une période historique de 2000 ans, nous pouvons conclure que l’introduction d’un amortissement cinématique de 2% suffit pour obtenir de prévisions réalistes. Cette conclusion est conforme aux résultats récents de Tsesarsky, Hatzor and Sitar (2002) qui ont comparé les déplacements d’un bloc isolé sur un plan incliné sous chargement dynamique obtenus avec l’analyse DDA et à partir d’essais sur table vibrante. ZUSAMMENFASSUNG: En utilisant une modélisation DDA dynamique on montre que l’introduction d’un système simple de boulonnage stabilise la pente.In dieser Veroeffentlichung wird eine vollstaendig dynamische, zweidimensionale Stabilitaetsanalyse eines hoechst diskontinuierlichen Steinhangs dargestellt. Der untersuchte Hang ist die obere Terrasse des Herodespalastes in Massada, welche in den westlichen Randgebieten des seismisch aktiven Toten Meer Grabens liegt.Die dynamische Deformation des Berghangs wird mit Hilfe einer vollstaendig dynamischen DDA-Version berechnet, in welcher als Input die zeitabhaengige Beschleunigung eingegeben wird. Die analytisch bestimmten Versagensarten kritischer Schluesselbloecke in diesem zerkluefteten Steinhang werden durch Anwendung von DDA am Ende der dynamischen Berechnung klar vorausgesagt. Es zeigt sich jedoch, dass fuer realistische Dislozierungs-Abschaetzungen ein gewisses Mass an Energieverlust in der sonst vollstaendig elastischen, ungedaempften DDA-Fassung einbezogen werden muss. Der Vergleich des vorhergesagten Schadens mit dem aktuellen Verhalten des Berghangs waehrend einer historischen Zeitspanne von 2000 Jahren erlaubt uns zu schliessen, dass ein Zusatz von 2% kinetischer Daempfung fuer eine realistische Vorhersage des Schadens ausreichen sollte. Diese Schlussfolgerung steht im Einvernehmen mit neuen Ergebnissen von Tsesarsky, Hatzor und Sitar (2002), welche die Dislozierung eines einzelnen Blocks auf geneigter Ebene unter dynamischer Belastung – unter Anwendung von DDA und “shaking table”-Versuchen – verglichen. Mit Hilfe der dynamischen DDA wird gezeigt, dass der Steinhang durch Anwendung einer einfachen Steinschraubenstruktur vollkommen stabilisiert werden kann.

Jan 1, 2003

By S. Tu, Y. Yuan, H. Wei, Z. Chen, M. Jia

"To reduce production costs and increase efficiency in ageing coal mines, a system that utilizes two shearers in a fully mechanized longwall working face is proposed. Using theoretical and engineering experience, three issues pertaining to the system were determined: (a) the two-shearer mining technique; (b) matching and modifying the equipment; (c) and coal-cutting task allocation for each shearer. Two mining processes are proposed, with the two shearers travelling in either the same or opposing directions. To avoid breakage of chains and pan extrusion of the armoured face conveyor (AFC), the length of the AFC ‘snake’ was controlled. To ensure continuous cutting and transporting of coal, the cross-sectional dimensions of the AFC were checked and the shearer closer to the head drive was modified. Based on the assumption of equal cutting times for each shearer, the meeting position of the two shearers was obtained by using a theoretical model of mining task allocation. Application of this technique at No. 2 Jining Mine, China, has shown remarkable benefits: daily production capacity was increased by 54% and personnel efficiency was improved by 33 t/d per person. IntroductionAll coal mines aim to increase the unit output of the working face to reduce mining costs and improve the economic efficiency of the operation. To achieve this goal, a production model known as one mining face of the mining area has been adopted by most Chinese coal mines (Hu, Meng, and Zhu, 2008; Zhang, Zhang, and Wang, 2000). Under these conditions, the main technical approaches to maximize the output are increasing the width of the working face (Qu, Xu, and Xue, 2009) and accelerating the advancing speed (Robbins, 2000). In coalfields with shallow seams, the width of a fully mechanized face exceeds 300 m (Ju and Zhu, 2015; Fu, Song, and Xing, 2010); in coalfields with deep seams, the width of the face is usually greater than 240 m (Liu et al., 2016; Li et al., 2013). The term ‘super-long working face’ was proposed to describe working faces with a width of over 240 m (Zhao and Song, 2016; Xu et al, 2007) in China. To support these long working faces with rapid advancing speeds, high-powered mining equipment is required (Kulshreshtha and Parikh, 2001, 2002; Tu et al., 2009; Mishra, Sugla,and Singha, 2013). This is easily achieved in newly built mines, but is not a good choice for ageing mines because of the low return on a high investment on account of the limited remaining resources. It is therefore difficult for ageing mines to significantly increase their unit output with the existing mining equipment. This study focused on this problem: two shearers were applied to a longwall fully mechanized working face (LFMWF) to achieve increased unit output."

Oct 1, 2018

By Taylor K. Kruger, A. H. Basson , S. Fataar

The mining industry remains heavily reliant on mineworkers, whose working conditions are typically more arduous than in most industries. With recent technological developments in mining and other industries focusing on the digitalisation of workspaces, mineworker safety should be at the forefront of the digital transformation. Underground mines should be viewed – and developed – as human cyber-physical systems, where digital technologies are integrated with human roles to enhance safety and coordination. Contributing to this vision, this paper presents a set of functional requirements to guide the development of human cyber-physical systems that improve the safety of mineworkers in underground mines. The formulation of the functional requirements is informed by an analysis of the current context of underground mines and an exploration of opportunities for improved human-system integration within such environments. The functional requirements are related to the real underground mining context through an illustrative example, which demonstrates how a human cyber-physical system could monitor mineworker and environment states, perform predictive safety analyses, and coordinate operations. The proposed functional requirements serve as a starting point for the development of human cyber-physical systems within complex underground mining environments; however, further research (supported by real case studies) is required to refine and obtain specific target values for the functional requirements, and to formulate accompanying performance requirements.

Jul 3, 2026

By J. N. Van der Merwe

In the process of pillar extraction, pillars are seldom if ever extracted completely. The pillar remnants, or snooks, play an important role in the extraction process. At the working face, they need to be stable to provide a measure of support in the immediate area. Further back, they have to fail in a controlled manner to prevent undue load build-up on the pillars that have not yet been extracted. The stability condition at the working area is the result of interaction between the stability of the pillar and that of the roof rock. It is shown that the primary mode of roof layer failure is by bending induced tension. Direct tension can be excluded in most practical conditions, and only in exceptional cases will the first failure be in shear mode. Panel spans required to cause the first goaf to be formed, predicted using analytical considerations, are of the same order as has been observed in practice. Once the first goaf has formed, the horizontal stress is reduced and failure will occur at more frequent intervals. It is shown that bending induced tension is the most likely mode of failure in an unjointed roof layer. In roof layers with a high frequency of weak or uncemented jointing, failure can be expected to occur at spans equal to the joint spacing. In this context, failure will occur at the smallest of the spans required to induce tensile roof failure and the joint spacing. A fundamental procedure to evaluate the likely roof layer failure in a stacked beam system is developed. This can to be used to estimate the loading condition on snooks. It is shown that snooks assist in stabilizing the immediate roof beam. The sizes and positions of the snooks relative to the position of the next pillar to be stooped, control the magnitude of the contribution to stability. The further the snook is from the next pillar, and the larger it is, the greater the contribution to the stability of the immediate roof. Under the condition of loading by the immediate, continuous roof beam, the position and size of a single snook controls the load acting on it. The closer it is to the nearest solid, provided that the roof overhang extends beyond the snook, the greater the load on it. However, once the immediate roof beam fails, the loading conditions change. The snook is then loaded by the tributary area load. A procedure is developed to assess the condition of snooks for different situations. Using the fundamental considerations developed in this paper, snooks can be designed to be stable during the active mining phase in their immediate vicinity, but to fail once the next line of pillars has been extracted.

Jan 1, 2005

By J. Petersen, K. Shaik1, H. Kolev, Z. Cherkezova-Zheleva

Sperrylite is one of the most abundant platinum minerals globally, valued for its economic importance but also known for its highly refractory nature, making it difficult to process via the conventional route. This study explores the oxidative leaching of sperrylite using a cyanide–ferricyanide system, with a key focus on characterisation of the mineral and surface speciation under varied leaching conditions using x-ray photoelectron spectroscopy. The parameters investigated include the effect of sodium cyanide concentration, the use of potassium ferricyanide as an oxidant, copper sulphate pentahydrate as a catalyst, as well as the effects of temperature and particle size. A limited set of leaching tests was carried out to study the surface chemistry rather than optimising dissolution conditions. This approach identified mineral oxidation states and shifts in binding energies, prior to and post leaching. XPS analysis of sperrylite’s surface chemistry identified key species, comprising the bulk Pt(II)–As (≈73 eV) and As(–I)–Pt (≈41.8 eV) states, together with surface oxidation products Pt(II)–O (≈72 eV), Pt(IV)–O (≈74.5 eV), As(III)–O (≈43 eV) and As(V)–O (44.5 eV). Leaching led to the removal of pre-existing oxides on the ultra-finely ground sample, exposing the underlying bulk species. In contrast, the crystalline sample with an initial low concentration of oxides, generated higher amounts of fully oxidised species after leaching, reflecting greater surface reactivity.

Mar 6, 2026

By V. M. Lovell, N. P. Finkelstein

The concepts involved in flotation research are discussed and aims are presented. Three different methods of investigation can be used, all of which are applied at the National Institute for Metallurgy (N.I.M.), and these are the empirical, trial and error method, the chemical engineering method, and the physicochemical approaches. This paper is devoted to the last of these. Because of the complexity of the physicochemical interactions involved, the work has, to a large extent, been concentrated on only one aspect, viz. the interaction between the mineral surface and reagents in solution, which was considered of major importance in the understanding of the process. The aspects on which work has been done are the concentration of uranium, the reaction between salt minerals and fatty acids, mixed xanthate-cationic collector systems, and the reaction between sulphide minerals and thiol reagents. Selected problems from the first two of these are discussed in some detail and deal with the agglomeration flotation of uranium and the chemical control of the flotation process for phoscorite. A detailed discussion is also presented of the progress made in the understanding of the interaction between sulphide minerals and thiol reagents, which is of more general application. Finally, an indication is given of the future direction of physicochemical research at the N.I.M.