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By B. Rezai, Z. Pourkarimi, M. Noaparast, S. Chehreh Chelgani

Nanobubbles (NBs) flotation separation can be an indicator for improving the efficiency of fine particles through the conventional process. Since flotation reagents such as frothers can reduce bubble size, they can potentially be used for the generation of NBs and develop a selective NB flotation separation. This study explored the flotation separation of fine phosphate particles from their associated minerals in the presence of NBs, which were generated by using a phosphate flotation reagent (Flo-YS: collector-frother). The results of flotation tests showed that in the presence of NBs, the flotation efficiency was significantly improved. However, in the presence of NBs, surface chemistry analyses (Fourier Transform Infrared Spectroscopy and High-Performance Liquid Chromatography) illustrated that the collector adsorption on the surface of phosphate particles decreased. A comparison between outcomes of various phosphate flotation conditions indicated that increasing the flotation efficiency in the presence of NBs may be due to the aggregation of fine particles by the generated NBs, and also selective adsorption of NBs (hydrophobisation) on the surface of particles. In other words, generating NBs by selective collectors may increase efficiency and decrease the collector consumption of a flotation process. Keywords: Phosphate, selective separation, fine particles, collector-frother, efficiency, mechanical flotation cell

Jan 1, 2020

By Nicolle Krusberski

Potential errors in XRF analysis are discussed and investigated with specific reference to the analysis of ilmenite samples. A selection of ilmenite samples was chosen and prepared using two XRF preparation techniques: pressed powder pellet and unroasted fusion bead. The merits of the two methods have been discussed in this paper for ilmenite analysis by XRF. Recommendations have been made regarding the use of pressed powder pellets especially with regard to the mineralogical effects that were evidenced during this investigation. The fusion bead technique was found to be far more accurate and able to meet short turnaround requirements provided the calibration methodology used is specific to the grade of samples analyzed.

Jan 1, 2014

By J. L. Broadhurst, S. Rumjeet, S. T. L Harrison, T. Chimbganda

Post-mining land use for the production of industrial crops has the potential to mitigate environmental and socio-economic impacts of mine closure and stimulate post-mining economic growth. Fibre-rich plants are of particular interest due to their multi-product potential. In the South African context, where there are many abandoned and end-of-life mines near human settlements, an opportunity presents to assess the feasibility of transforming post-mining land into productive land and building resilient communities through the development of multi-product value chains from fibre-rich plants such as kenaf, hemp or bamboo. This paper provides an overview of the plant selection criteria, phytoremediation potential and the downstream options for the recovery of products and value from bast fibre plants (hemp and kenaf) and bamboo. Based on findings from a comprehensive review of the published literature, as well as interviews with relevant experts within South Africa, it appears that bast fibre plants are the best downstream option for producing ‘green’ textiles and high-end niche products, whereas bamboo is more suitable as a replacement for conventional timber. Although fibre plants have the potential to extract metals from soils, high concentrations may inhibit plant growth and affect the quality of the final fibre product. Further site-specific studies would thus be required to select the best route for both land remediation and optimal product recovery. Keywords: Bioremediation, bamboo, kenaf, hemp, multi-product value chains, sustainable postmining land use

Jan 1, 2020

By K. C. Corin, M. Tadie, R. M. Manenzhe

The near depletion of high-grade ores, among other factors, has necessitated the consideration of alternative PGM sources. Various factors in the metallurgical processing of ores result in valuable minerals being lost to the tailings, and hence, PGM tailings are a possible alternative PGM source. However, as the value residing in PGM tailings remains unquantified and uncharacterised, there is a challenge in knowing the recoverable fraction of value contained in PGM wastes. This paper outlines the in-situ techniques of oxygen uptake and EDTA extraction for their possible use for determining the recoverable value in PGM tailings. Both methods have shown efficiency in determining the weathering of sulphide minerals and sulphide-bearing ores. Keywords: PGM tailings, tailing retreatment, oxidation, oxygen decay, EDTA

Jan 1, 2020

By M. Gaula

"Gold bearing deposits of the Witwatersrand basin are generally less than 2m thick and require conventional narrow-reef mining methods for extraction and employ explosives as a means of rock breaking. Optimal utilization of explosives is dependent on the overall design of the blast. The under-utilization of explosives arises when shot-holes are drilled inconsistently, overcharged, and when tamping is absent. This can be rectified by emphasizing the importance of good drilling practices as part of induction programmes and refresher courses. The project was aimed at determining whether or not explosives are being optimally utilized at project site. This was investigated through a study of the properties of explosives, mine standards, and recommendations for usage. Underground observations were made to determine whether or not mine standards were being adhered to. Historic data was obtained to establish the historic relationship existing between the quantity of explosives used (kg) and the production output (m2). This was then compared to the quantity of explosives the mine expects to use per unit of production. The results obtained were analysed to determine the presence and extent of over- or under-utilization. It was found that explosives are being under-utilized at the mine. More explosives are ordered than expected per unit of production. The explosives’ properties are not thoroughly exploited during blasting, thereby requiring the use of more explosives than prescribed. Paper written on project work carried out in partial fulfilment of BSc. (Mining Engineering)"

Jan 1, 2015

Models are used in engineering to reproduce reality as faithfully as possible so that the expected response of a system for given actions or inputs can be determined. In the field of rock engineering, both empirically based and numerical models are widely used to determine the likely response of the rock surrounding excavations. Many of the empirical models are developed from statistical analysis of case histories or from direct observation; however, empirical models are limited because they should be used only within the range of conditions of the observational database. Synergy exists between empirical and numerical models, because empirical models can be used to calibrate and validate numerical models. The empirical approach can benefit from the capability of numerical models to investigate specific mechanisms, which would not be possible using observations alone. Two cases are presented in which the synergy between empirical and numerical models is demonstrated. The first case examines the analysis of discontinuity effects on the strength of slender pillars in limestone mines, and the second case evaluates the effects of stress orientation on coal mine entry stability. It is concluded that numerical model calibration and verification comprises an important first stage in the successful application of models in rock engineering design. Application of numerical models allows mechanisms and interactions of various parameters to be analysed, greatly improving the understanding of the system. The improved understanding can be used to extend the application of empirical design methods, resulting in improved safety and efficiency of rock engineering designs.

Jan 1, 2014

By T. Tholana, P. N. Neingo

"A mineral resource constitutes the principal underlying asset of a mining company, and must be exploited and managed in such a way that maximum value is derived from it. Various asset management frameworks applicable to physical assets are available. This paper focuses on the extension of an asset management approach, particularly the Publicly Available Specifications (PAS) 55 asset management framework and the International Organization for Standardization (ISO) 55000 series of standards, to mineral assets. It is concluded that PAS 55 and the ISO 55000 series of standards can be extended to manage mineral assets, resulting in an integrated approach to sustainably optimize value from the company’s mineral assets. The benefits include improved returns on mineral assets, maximum mineral asset utilization, creation of an organizational culture focused on quality and continuous improvement, and assurance to stakeholders that the mineral assets are being efficiently managed over their entire life-cycle. In the context of this paper, a ‘mineral resource’ refers to both Resources and/or Reserves as classified by the SAMREC Code. IntroductionMining involves the extraction of valuable mineral resources from the Earth’s crust. A mineral resource is unique among natural resources in the sense that it is a wasting asset, which means that its value depreciates continuously with extraction. In addition, it is often impaired from time to time as commodity price changes (Macfarlane, 2011a). Since a mineral resource is a wasting asset there is a single opportunity available to optimize value from its extraction. Mine planning involves identifying a strategy to exploit the mineral resource in a way that maximizes value at an acceptable risk level throughout the life of mine (LOM). This optimum extraction strategy changes as economic conditions change, particularly commodity prices, as well as with improvements in orebody knowledge as mining progresses. It is the mineral deposit that competitively distinguishes two different mines and dictates the location of a mine; hence the adage ‘the orebody dictates’. Therefore, a mineral resource is the primary tangible asset possessed by mining companies and must be managed in such a manner that maximizes its value at an acceptable risk level (Macfarlane, 2011a)."

Jan 1, 2016

Novel flotation reagents were developed to improve the flotation of coarse particles. Laboratory tests conducted on an anthracite coal sample from Kyung-Dong Coal Company, Korea, showed that the reagents can successfully clean 2?3 mm top-size materials. Pilot-scale tests conducted on a 1.41 mm x0 coal gave substantially better results than those obtained using kerosene as collector. The pilot-scale test results were used to develop a flowsheet, in which the 1.41 mm x0 fraction is cleaned by flotation and the 4 x1.41 mm coal is cleaned by single-stage spirals. The performance of this circuit was compared with another flowsheet, in which the 0.5 mm x0coal is floated using the conventional flotation reagent, with the 4 x0.5 mm material being cleaned using two separate spiral circuits. The performance of the two flowsheets was compared by computer simulation. The results showed that the flowsheet consisting of the coarse particle flotation circuit can give substantially higher yield sat a given product grade. Keywords: coal flotation, coarse particle flotation, collector, spirals, computer simulation.

Jan 1, 2002

The Modified Zincex® Process, developed by Técnicas Reunidas, is highly flexible dealing with a wide range of pregnant leach solutions. No matter if those solutions are produced from primary or secondary raw materials, and/or are based on conventional leaching, pressure leaching, heap leaching or bio leaching the result is always high-purity zinc product. The zinc solvent extraction unit within the process is a very effective barrier for impurities and a buffer for the composition of the pregnant liquor. This unit achieves an extremely pure aqueous extract that can be converted into different final products. All of them are characterized by fulfilling the highest purity standards. Also, there is the possibility to adapt the global process to a wide range of pregnant liquor compositions and various production capacities up to a zinc production limit over 150 000 t/a with a single solvent extraction plant.

Jan 1, 2002

[Consider the situation where we wish to estimate the value of a block of ore W from the values of n samples wt (i = 1, 2.... n). The samples can be located anywhere inside or outside W. The blocks and the samples can have any size or shape (Fig. 8.1). We define ws as the set of all the samples wi: WS = Iw1; W2; W3.. . wn and we wish to estimate the block W using the samples ws. Let xi be the value of the ith sample and µw the unknown average value of the block. We can estimate µw from the average value of all the samples. Let µw be the estimator of µw. As the samples need not be of equal size, the sample average is: µw = wi xi/~ wi. (8.1) The mean squared error made when estimating µw by µw is known as the variance of estimation of W by ws. It is the error made when giving the value of the sample set ws to the block W and is written o2E (WS to W). By definition: o2E (ws to W) = E [(µw - µw)2]. (8.2) If n = 1, this error is known as the extension variance. Since the sum of the weights given to the sample values is equal to 1,0, the estimator µw is unbiased (the question of the absence of bias is studied in more detail in Chapter 9): E [( µw - µw)1 = 0. (8.3) The error (µw - µw) has zero mean and a variance o2E = E (W8 to W). If we assume that this error is normally distributed, we can define confidence limits for µw. Let tP be the value of the standardized normal variance t such that the probability that t is less than tP is p: (t,) = .\/27T f exp (- t2/2) dt = p (8.4) The probability that µw is larger than µw + t1-P oE is p. The probability that µw is smaller than µw- t1-P oE is p. The following approximation formulae are often used to calculate 2p central confidence limits for the block value: 68% central confidence limits (p = 16%): µw - o2E, and µw + o2E. 95 % central confidence limits (p = 2,5 %): µw - 2 oE, and µw + 2 oE. Tables of the function 0 can be found in any textbook on statistics (for example, Fraser, 1958, p. 388) (see Table 7.2). [ ] The last line of Table 2.2, corresponding to f = 00, also contains the value of tP for p = 80, 90, 95 and 97,5 %.]

Jan 1, 1978

By M. Kuchta, A. Newman

LKAB’s Kiruna Mine, located above the Arctic Circle in northern Sweden, is the second-largest underground mine in the world today. The orebody is a world-class high-grade magnetite deposit, from which three raw ore products are extracted. We use mixed integer programming to determine a production schedule, i.e., which production blocks to mine, and when to start mining them, so as to minimize deviation from planned production quantities while adhering to the operational constraints of the mine. The resulting model contains thousands of binary variables and a commensurate number of constraints, precluding us from obtaining a schedule in a reasonable amount of time. We describe a method that builds on prior, related work, to expedite solution time. Keywords: underground mining, production planning, optimization, integer programming

Jan 1, 2003

By D. C. Oliver

Paper written on project work carried out in partial fulfilment of B.Sc. (Eng.) (Metallurgy and Materials) degree Corrosion in exhaust systems can occur on both the interior and exterior surfaces. Chloride-containing de-icing salts on the roads in colder countries greatly increases the rate of corrosion on the exterior surfaces. This paper investigates the relative exterior corrosion resistance of three alloys?two ferritic stainless steels( AISI Types 409 and 441) and an aluminized mild steel. The exhaust system is split into two categories?the hot end and the cold end. A test for each of these ends was designed?the standard ASTM G85test was modified to create a simulated driving cycle. The cold end test samples were exposed to ten driving cycles, and the hot end test samples were exposed to five driving cycles. A driving cycle constitutes the car being started from cold, driven until the operating temperatures are reached, and switched off and allowed to cool. Pitting corrosion is the primary corrosion mechanism occurring at the cold end of the exhaust system. The aluminized mild steel was the most resistant alloy in this test, and Type 409 the least. However, once the protective aluminium layer degrades, corrosion will occur rapidly. At the hot end of the exhaust system, spalling of the surface oxide layer is the primary corrosion mechanism occurring. Type 441 was the most resistant in this test, and the aluminized mild steel the least resistant. Potentiodynamic tests were performed on the alloys?the results agreed with the results obtained in the exposure tests.

Jan 1, 2003

By G. Akdogan, C. Dorfling, L. Bumhira

Hydrometallurgical recovery of rare earth elements from phosphors obtained from end-of-life fluorescent lamps involve leaching followed by extraction of dissolved metals from solution. The similar properties of rare earth elements make selective recovery of individual elements challenging. The aim of the paper was to investigate the extraction of primarily Ce and Tb from a hydrochloric acid leach solution also containing other REEs (Y and Eu) as well as impurity metals (Ca and Al). Batch solvent extraction tests were performed with di-(2-ethylhexyl) phosphoric acid (DEHPA) at various extractant concentrations, pH conditions and organic-to-aqueous ratios. Extraction isotherms and separation factors for the range of conditions tested in the project are presented in the paper. Separation of individual REEs was not possible at the conditions investigated, but a mixed REE product can be obtained in a single extraction stage operated at a pH of 0.5 using 1 M extractant at an O/A ratio of 1; these conditions resulted in complete Y and Eu, 95 % Ce and 99 % Tb extraction with Ca and Al coextraction below 7 %. A better quality mixed REE product can be produced by operating at lower pH and extractant concentration conditions, but this would require a larger number of extraction stages. Keywords: Cerium, fluorescent lamps, phosphors, rare earth elements, solvent extraction, terbium

Jan 1, 2020

By M. H. Dehghanpoor, M. Zivdar, M. Torabi

"A hydrometallurgical route was developed to extract metals such as gold, silver, copper, and selenium from anode slime from Sarcheshmeh Copper Complex in Iran. For the extraction of copper by leaching, the anode slime was heated and stirred with 4 M sulphuric acid in the presence of oxygen. Optimal conditions for recovery of copper were temperature 80°C, mixing time 5 hours, and oxygen flow rate 2 L/min, resulting in a copper recovery of 94.47%. Silver and selenium were dissolved by leaching anode slime from which the copper had been removed with nitric acid. For gold extraction, anode slime was heated with aqua regia at 90°, and the gold then extracted with 2-ethyl-hexanol at a concentration of 0.5 M and phase ratio of 4. The extract was then stripped with soda solution at pH=10.5 and a phase ratio of 5. Finally, gold was recovered by precipitation with oxalic acid at a ratio of mass to volume 10 g/L. Total gold recovery was 80%. IntroductionDuring the electrorefining of copper, some metals are accumulated in the byproduct anode slime, which is an important source for recycling and recovery of these metals (Petkova, 1994). In this paper, a hydrometallurgical route is described for the recovery of precious metals from copper anode slime of Sarcheshmeh Copper Complex, which is located in southeastern Iran .Copper anode slime is black or gray powder with a particle size less than 200 mesh. Approximately 2 to 20 kg of anode slime is produced per ton of copper cathode. The slime is characterized by higher amount of Ag, Se, Pb, and Cu compared to other metals and a very low Au content (Khaleghi and Ghader, 2013).The copper anode slimes are composed of 11.69% selenium, 3.93% copper, 5.26% silver, 0.13% gold, and 45% barite, plus lead, tellurium, antimony, sulphur, and silica with small amounts of nickel, iron, zinc, and bismuth. Gold is one of the most important noble metals due to its wide applications in industry and economic importance, so recovery of gold from slime is more appealing than that of other metals. According to the World Gold Council (2013), the demand for gold has increased during the last decade. This increase is due not only to the increasing demands of the jewellery market, but also to the increasing demand for gold in industrial as well as medical applications (Ranjbar et al., 2014)."

Jan 1, 2016

By J. Rajala

The Kupol mill facility processed a high grade free milling gold/silver ore containing 28.2 g/t Au, 324.8 g/t Ag and approximately 0.5% pyrite during 2008 operation. Gold predominantly occurs a selectrum in the ore and silver is predominantly present in the forms of acanthite, stephanite, pyrargyrite and proustite. Mill start-up was in mid-May 2008 and the mill reached the design throughput of 3 000 tpd in October. The ore was ground to approximately 70%?53 microns. A Knelson Concentrator recovered 9.8% gold and 0.5% silver. The gravity tails reported to a cyanidation circuit that has 14 hours pretreatment and 116 hours leaching. The slurry from cyanidation was then processed by counter current decantation (CCD) thickening to wash and separate the leach residue from the pregnant leach solution. Precious metals are recovered fromthe pregnant solution using the Merrill-Crowe process. The washed CCD leach residue slurry is treated with calcium hypochlorite to destroy cyanide and then sent to the tailings impoundment. Leaching is performed with a new technology called ?CELP? (CANMET Enhanced Leach Process). The Kupol mill overall gold and silver recoveries for 2008 were 95.4% and 85.6% respectively, which were 2.8% and 7.5% higher than targets. Gold and silver extractions in the leach circuit were 94.2% and 84.5% respectively. Leach profiles indicated that gold extraction reached a plateau in the 4th tank while minor silver dissolution occurred in the 5th tank. With the CCD circuit included, total gold and silver extractions increased to 95.4% and 86.6%, respectively. Optimization of the leaching strategy made it possible to reduce sodium cyanide concentration to as low as 410 ppm without compromising precious metals extractions. Silver was effectively leached from the refractory silver minerals because CELP produced more oxidized mineral surface relative to the conventional cyanidation leached mineral surfaces. The average cyanide consumption for 2008 was 1.3 kg/t. The new leaching technology proved to be very robust and performed efficiently even with changes in feed grade and ore mineralogy. Laboratory experiments produced results that were indicative of plant performance. The robustness of the technology and the laboratory test work contributed to the success of the Kupol mill start-up.

Jan 1, 2009

By R. A. Wildenboer, R. F. Sandenbergh

Rare earth elements (REE) are present at concentrations of approximately 0.36 % in phosphogypsum stacks located in Phalaborwa, South Africa. The REE are present in the phosphogypsum in solid solution in the gypsum and as fluorine and aluminium rich precipitates. Recovery of the REE offers opportunities for valorization and reducing the environmental impact of the phosphogypsum waste. This paper presents the results of investigations into the leaching behaviour of rare earth elements and other impurities from phosphogypsum using aqueous sulfuric acid. The effects of acid concentration, temperature, residence time, and the influence of impurities were evaluated for their impact on the solubility of rare earth elements in a sulfate medium. It was found that a significant fraction of the REE can be leached from the phosphogypsum in a range of conditions much less severe than traditional hard rock rare earth processing conditions. The REE were leached at a sulfuric acid concentration of 110 g/l, temperature of 30°C – 40°C and a residence time of approximately 8 hours.

Nov 6, 2024

By T. C. Alex, K. M. Godiwalla, R. K. Jana

Manganese nodule, available in ocean beds, is a potential resource of the future for copper, nickel and cobalt. Recovering only these metals, containing less than 3% by weight, will result in the generation of large amount of residue. In addition to the material losses, several environmental and ecological problems arise out of this. The present study has been aimed at reducing the environmental and ecological problems associated with massive generation of this residue together with utilization of the resources. Presence of ~ 20% manganese and ~16% silicon in the residue has prompted us to check its suitability as a raw material for silicomanganese production. Lower manganese content and lower Mn/Fe ratio of the residue than that required for silicomanganese production has been corrected in this study by suitable blending. The efficacy of blending and its thermodynamic aspects using FACTSAGE software are discussed. The studies conducted indicate viability of bulk utilisation of the residue through silicomanganese production and thereby reducing the burden on environment to a great extent.

Jan 1, 2007

By J. Bai, C. Zang, W. Yuan, L. Zhuang

"This study evaluates the efficiency of using mechanochemical reduction to assist the extraction of zinc from zinc ferrites by alkaline leaching. The transition of zinc ferrite into a metastable state after mechanochemical reduction with metallic iron contributes to the ready dissolution of zinc from the activated zinc ferrites in alkaline solution. Zinc ferrites were mechanochemically reduced under conditions of Fe:ZnFe2O4 mole ratio of 2:1, using 5 mm diameter stainless steel balls as the activation medium at a mass ratio of balls to raw materials of 25:1. Subsequent leaching in 6 mol/L NaOH solution at 90°C resulted in more than 70% Zn extraction. These results may be used to further develop a hydrometallurgical process for recovering zinc from zinc ferrites in alkaline solution.IntroductionZinc is an important nonferrous metal required for various applications in batteries, solder, dielectric materials, and piezoelectric materials. High-grade, easily concentrated ores are becoming scarcer: to meet world demands for zinc, it is necessary to develop economical and environmentally safe metallurgical technologies that use secondary materials such as leach residues of roasted zinc concentrates and electric arc furnace dusts. The zinc in the majority of these wastes occurs in the form of zinc ferrite (franklinite, ZnFe2O4), which is very stable and insoluble in most acidic and alkaline solutions (Langova and Matysek, 2009; Youcai and Stanforth, 2000).Several pyrometallurgical and hydrometallurgical processes (Jankovi et al., 2014; Langova and Matysek, 2010; Morcali et al., 2012; Shawabkeh, 2010) have been proposed for the treatment of zinc ferrites. Pyrometallurgical methods are costly owing to high energy consumption and their emissions of toxic gases are considered an environmental problem; hydrometallurgical methods are preferred for process economy and environmental reasons (Copur et al., 2004)."

Jan 1, 2016

By U. S. Kusel

Extractive metallurgy in Iron Age South Africa U. S. KUSEL, B.A. Hons. (Pta) (Visitor) The finds relating to the metal-working of Iron Age Bantu tribes are reviewed, the following metals or alloys being considered: gold, tin, copper, bronze, brass, and iron. Most is known about copper- and iron-working, but even this is very little, and no one has successfully been able to demonstrate how iron was smelted in the primitive furnaces that have been found.

Jan 1, 1974

By Y. Z. Ma

This paper presents a matrix formulation of factorial kriging, and its relationships with simple and ordinary kriging. Similar to other kriging methods, factorial kriging can be applied to both stationary and intrinsic stochastic processes, and is often used as a local operator. Therefore, the concepts of intrinsic random function and local stationarity are first briefly reviewed. Kriging is presented in a block matrix form in which the kriging solution is useful not only for understanding the relationships between simple and ordinary kriging methods, but also the relationships between interpolative kriging and factorial kriging. When used as a signal/noise-filtering method, factorial kriging is especially useful for multiscale modelling. Examples for general signal analysis and geophysical data signal filtering are given to illustrate the method..

Jan 1, 2014