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By A. W. Henderson

The growing importance of halide metallurgy for preparing high-purity metals has stimulated research to extend halogenation reactions to the direct extraction of metals from low-grade sources. This Bureau of Mines investigation involves a pioneering study of chlorination reactions in the presence of a fluorine donor. Tin slags containing tantalum and columbium and a zircon concentrate containing a relatively high ratio of hafnium to zirconium were studied. Direct chlorination of these materials at 500° C. yields only a 5-percent conversion of tantalum and columbium or zirconium and hafnium to anhydrous chlorides. This investigation showed that small additions of calcium fluoride to the reaction increased the recovery of tantalum and columbium to 95 percent and the recovery of zirconium and hafnium to 27 percent. These results were achieved with ratios of calcium fluoride to mineral or slag of only 0.2. Silica, the major impurity in the materials studied, was found to be converted to silicon tetrafluoride during chlorination in direct proportion to the quantity calcium fluoride added to the charge. However, large additions of calcium fluoride decreased the volatility of the resulting halides of tantalum, zirconium, and hafnium. Smaller amounts of calcium fluoride also favored recovering minor metal constituents in the zircon concentrate (uranium, thorium, and rare earths).

Jan 1, 1962

By Wilbert J. Huff

The organization of the Explosives Division has been outlined in two preceding publications., The activities of the various units for the fiscal year 1939 are described hereafter: I. INFLAMMABILITY OF GASES AND VAPORS DETERMINATION OF EXPLOSION HAZARDS OF COMBUSTIBLE GASES AND VAPORS IN MINES AND INDUSTRIES (a) Determination of Limits of Inflammability of Gases and Vapors The following hitherto unpublished limits of inflammability were determined during the past fiscal year.

Jan 1, 1939

By W. J. Kroll

Despite the fact that barium minerals are plentiful and widely distributed in nature, this element is one that we do not yet know how to prepare cheaply in metallic form. This is due to its chemical activity, as evidenced by its great affinity for fluorine, chlorine, oxygen, nitrogen, hydrogen, and sulfur. Furthermore, it forms a very stable subchloride and subfluoride, which prevents isolation of the metal by fusion electrolysis from a halide bath. A good survey of the metallurgy of barium calcium, arid strontium has been made recently in Light Metals (54,55).3/ Metallic magnesium (46), calcium (83), barium, and strontium (27) reduce each other's oxides. Proof of this can be found in the activation of BaO after reduction with Mg, which leads to the formation of so-called "Maquenne" mixtures (58) used for absorbing gases. However, it is impossible to extract the reduced metal- from the residue, a fact that Guntz (25) attributed to the formation of barium suboxide. There is no necessity for presuming the formation of such a compound, as it has boon established that in the reduction there is always formed an alloy of the alkaline-earth metal with the magnesium, which is capable of producing hydrogen when brought into contact with water. The reduction of alkaline earth-metal oxides with aluminum was observed by Mallet (57) in 1877, but recent investigations have shown that the end product of the reaction is an alloy of aluminum with the alkaline earth metal (1,2). Silicon also has been suggested as a reducing agent, and the results obtained are the same (84,85).

Jan 1, 1945

By W. W. Adams

Rock dust, as a preventive or limiting factor in explosions of gas and coal dust in bituminous-coal mines, was used in larger quantities in 1939 than in any other year except 1937 since annual figures first became available in 1930, Reports from mining companies to the Bureau of Mines revealed that 144,430,000 pounds of rock dust was applied to underground nine workings in mines that produced 126,635,677 short tons of coal during the year. This quantity of rock dust applied averaged 1.14 pounds for each ton of coal produced. Rock dusted mines were the source of 39.7 percent of the total production of bituminous coal from underground mines; 33.2 percent of the total number of underground workers were employed at rock-dusted mines, and 35.8 percent of the total number of man-hours worked underground at all bituminous-coal mines in the United States during 19719 can be accredited to mines so treated. Rock dust was employed chiefly in the larger mines, which numbered only 431 out of 6,016 underground mines in operation in 1935, according to reports from mining companies. The mines in which rock dust was used had an average of 288 underground employees per mine, whereas mines in which rock dust was not used averaged only 62 underground employees per mine.

Jan 1, 1940

By Philip A. Holland

The Bureau of Mines has developed a method for determining helium in water for use in sampling and analyzing surface and subsurface waters for geochemical survey work. The accuracy of the analytical method is within ±10 percent for samples containing above 20 x 10-8 cm3 He (STP)/cm3 H20. The minimum detectable helium-in-water concentration is calculated to be 2 x 10-8 cm3 He (STP)/cm3 water. Water samples are collected in 500-cm3 stainless steel cylinders. The dissolved gases are extracted into a cylinder of equal volume containing a known quantity of neon. The resulting gas mixture is subsequently analyzed for helium and neon-21 by mass spectrometry. The volume of helium in the sample is calculated from the mass spectrometric determination of the helium-to-neon-21 ratio, the known quantity of neon used, and the extraction efficiency of helium.

Jan 1, 1981

To provide cooler air to miners working in hot areas of mines, particularly new deep hardrock mines. Approach Air supplied to hot working areas of mines is cooled by passing it through a series of water sprays. How It Works Water nozzles mounted inside a section of ventilation tubing release cooling sprays of water into the air being blown through the tube. The prototype of the water spray cooler consists of six evenly spaced water sprays located inside a 10-ft. long section of 16-inch-diameter fiberglass ventilation tubing. See diagram. This section of rigid tubing is installed into one of the positive pressure ventilation tubing lines that conduct fresh air into working stopes. The intake manifold to the six water sprays is connected to the mine?s cool water line, and the water valve on the manifold is opened. Warm ventilation air being supplied to the stope passes through the water sprays, and is cooled by the lower temperature water.

Jan 1, 1979

This study presents a reservoir modeling approach to investigate the relative effects of different coalbed parameters on the migration of methane into development entries. A base coalbed reservoir model of a three-entry development section, where grids were dynamically controlled to simulate the advance of mining at a constant section advance rate, was created and calibrated for a Pittsburgh Coalbed mine in the Southwestern Pennsylvania section of the Northern Appalachian Basin. The values of coalbed parameters were varied to evaluate their effects on predicted methane emissions for various development distances. The results of these parametric simulations were then used to derive linear expressions relating these parameters to methane emissions into the workings. These models were analyzed to assess their significance and adequacy for predictive purposes. This work shows that coupling reservoir simulations with linear modeling yield a technique that can be applicable to different coalbeds. The reservoir parameters used by the linear models (coalbed thickness, pressure, sorption time constant, Langmuir parameters, permeability) can be determined by running relatively simple laboratory tests, such as adsorption equilibrium and permeability determination, on coal samples obtained either from the mining operation or from the exploratory boreholes drilled ahead of mining.

Jan 1, 2008

In the United States water pollution resulting from mining activities has long been recognized as a major environmental problem Mine drainage pollution results from many types of mining activities and includes both physical (i e , sedimentation) and chemical (i e , acidification, metal contamination, etc ) pollutants Active and abandoned surface and underground mines, mineral processing plants, mine and processing plant waste disposal areas, haulage roads, and tailing ponds are typical sources of mine related water pollution (130) One of the most serious pollution problems arising from mining activities is acid mine drainage resulting from the chemical reaction of sulfide minerals (commonly iron sulfides) and air in the presence of water Acid mine drainage is commonly associated with coal and hard rock mining areas in the United States In general the more serious and extensive acid mine drainage problems exist in the more humid coal regions east of the Mississippi River (11) In 1964 the U S Department of the Interior, Fish and Wildlife Service, reported that acid mine drainage adversely affected fish and wildlife habitat in 9,477 kilometers (5,890 miles) of streams and 6,062 hectares (14,967 acres) of impoundments in 20 states in the United States (64) Of the total affected waters, coal mining operations accounted for 97 percent of the acid mine drainage pollution reported for streams and 93 percent of that reported for impoundments In 1970 more than 19,308 kilometers (12,000 miles) of streams in the United States were reportedly significantly degraded by mining related pollution (130) Of the total affected kilometers, 16,920 kilometers (10,516 miles) or approximately 88 percent were located in the Appalachian coal region (Pennsylvania, West Virginia, Ohio, eastern Kentucky, Tennessee, Maryland, and Alabama) In addition, more than 965 kilometers (600 miles) of streams reportedly were degraded by coal mining in states in the Illinois, Western Interior, and Rocky Mountain coal regions The remaining portion of the stream pollution resulted from the mining of (1) copper (california, Montana, Nevada, New Hampshire, Tennessee, Virginia, and Wyoming), (2) lead and zinc (Colorado, Idaho, Kansas, Missouri, Montana, Oklahoma, and Tennessee), (3) uranium (Rocky Mountain States), (4) iron (Lake Superior iron region), (5) sand and gravel (all states), (6) phosphate (Florida and other states), (7) gold (Alaska), (8) bauxite and barite (Arkansas), and (9) molybdenum, gold, and other metals (Colorado) Abandoned mines and abandoned mine waste disposal areas contribute a large portion of the total pollution resulting from mining activities Numerous abandoned underground mines are located throughout the United States and many are discharging mine drainage pollutants In 1966 the U S Bureau of Mines estimated that more than 88,000 inactive and abandoned underground mines were in existance (126) A listing of these mines by state is presented in Table 1 0-1 More recent estimates indicate that this list is incomplete In Colorado alone there is

Jan 1, 1975

By S. R. Zimmerley

[In the course of a flotation investi£ation, a siliceous gold ore was ground in a'ball mill to ':1inns 300-meeh. It wa. found that the small amotIDt of _Ius 300-mesh material had a gole.. assay approximately twice that of the oriGinal ore, &~d that this overs.ize nroduct also contained much abrac..ed iron. .,Joreove I the gold assay of the abraded iron t which was !1epnrated ma§metically', ~iVFl.£ eight ti;nes that of the are. These facts suggested that some r31aticnship ex?...,ted between the abnorma11y high gold content an the prese:1ce of brA-cit)" iron. It was decided, therefore, to investigate furt~er th~ Fl.Gsociation of the bold ~ith the iron abraded from the balls during sri~Qing ]

Jan 1, 1937

By E. J. Matson

Under the investigation for critical and strategic minerals the Kaiser mine, formerly the Baxter fluorspar property, in northeastern Mineral County, Nev., was explored. The work comprised excavating 32 trenches averaging 90 feet in length, 8 feet in width, and 1 1/2 feet in depth. The trenches were excavated across the strike of the ore body to enable the engineer to spot the diamond-drill holes; 7 such holes were drilled, aggregating 3,276 linear feet. A total of 20 core samples and 107 sludge samples was taken. The work under this program indicated that the fluorspar southwest of the deposit extended laterally and also at depth at least 250 feet below the 400-foot level. INTRODUCTION The Kaiser fluorspar deposit is in the northeastern portion of Mineral County, Nev. Mining was begun about 1928, and the property has been a consistent producer of both Acid- and Metallurgical-grade fluorspar. The mineralized zone has been developed along a strike length of about 2,000 feet and to a depth of over 700 feet along the dip.

Jan 1, 1957

By Richard A. Allwes

The Bureau of Mines conducted an in-mine case study on two consecutive three-entry gate road systems designed in accordance with the stiff-yield pillar design concept. This Bureau study was conducted in order to further develop technology that will improve the health and safety aspects of longwall mining. Support loading and strata activity were monitored to determine the effects of retreat longwall mining on the gate road ground control system. Analyses of pillar stress and roof bolt loading histories revealed that headgate roof support elements ex-perienced cumulative loading throughout the life of the longwall panel. Tailgate pillar loadings had significantly different histories from the loading histories of the headgate pillars. Stress relief occurred in the tailgate pillars following the passage of the longwall face. More-over, the stiff-yield pillar design, with the abutment pillar placed adjacent to the working panel when part of the headgate system, provided effective ground control in that no major roof falls or roof problems were experienced in the headgate or tailgate systems during longwall mining.

Jan 1, 1985

Provide a means to (1) rapidly disconnect a multifunctioning signal channel from a multichannel data collection system, (2) protect electronic devices from damage while causing the minimum amount of data collection disruption, and (3) operate electronic devices under gassy mine conditions. Background Data collection system instrumentation and cables are often located in hazardous areas of underground coal mines. As a result, frequent damage to the instrumentation cables occurs from roof falls, heavy equipment, and the relocation of air, water, and power lines. A similar problem exists in surface areas where cables and instrumentation can be damaged by animals and by vehicle traffic. Without a circuit-breaking feature, the damaged cables could cause instrumentation to be ruined, cause power supply failure, and otherwise disrupt data collection in some situations the lack of a circuit-breaking feature might cause an ignition in a methane atmosphere.

Jan 1, 1990

By K. P. Wang

SIGNIFICANT general developments took place in the Far East during 1964, with far-reaching repercussions on the mineral and industrial economies of individual countries and the region as a whole. Japan, during this, "the Year of the Open Door," ushered in the era of industrial maturity, greater independence in economic policy, and expanded technical assistance to less developed countries. Symbolic of its dynamic economic growth is the fact that Japan out-produced the Federal Republic of Germany in steel during 1964 to take over a third-ranking world position. Mainland China, recovering from the "Leap Forward" debacle, made significant gains in industrial output. Mainland Chinese trade with Japan was on the upswing, and discussions were held between the Chinese and the Soviets for possibly resuming Soviet aid in industrial and mineral development. Meanwhile, United States aid to Taiwan was being phased out because of progress achieved. Rapprochement between South Korea and Japan was imminent late in 1964, a factor which may well affect South Korean mineral development. The Indonesian-Malaysian confrontation created economic difficulties in both countries. The war in Viet-Nam seriously disrupted industrial activities, particularly in the south.

Jan 1, 1966

By J. L. Konchesky

The technical feasibility of gasifying powdered, noncoking, low-rank coal with steam in an externally heated tube has been demonstrated. The tube, 112 ft. of alloy-steel tubing shaped into a helix, served as an electrical conductor of electricity used for heating. The effects of the following variables were studied: Residence time of coal in reactor, average reaction temperature, steam concentration, and rank or geologic age of coal. Reaction pressure was maintained in the range 19-26 p.s.i.a. High carbon conversions and large yields of synthesis gas were obtained with low-rank coal. In one test, for example, about 88 pct. of the carbon in a subbituminous C coal was gasified at 1,910* F. with a residence time of 1 sec. The gas contained 58 pct. H2, 19 COD 15 CO, and 3 CH4; the yield was 30 cu. ft. (at 32' F. and 14.7 p.s.i.) of synthesis gas (CO + H2) per pound of dry coal.

Jan 1, 1960

By Robert A. Jankowski, Ellsworth R. Spencer, Jay F. Colinet

Longwall mining is the most productive method of under- ground coal mining in the United States (U.S.), and record levels of production have been reached in recent years. These ever-improving production levels have the potential to generate significantly higher quantities of respirable dust. Consequently, the longwall industry continues to struggle with controlling dust liberation and maintaining compliance with the federally-mandated respirable dust standard. In response, longwall operators have increased the application of primary dust controls, airflow and water flow, in an effort to improve respirable dust control and reduce worker exposure. Pittsburgh Research Center (PRC) personnel conducted dust surveys at 13 longwalls operating throughout the U.S. and collected information to: identify current operating practices on these longwalls, identify the types of dust controls in use, document the levels at which these controls are being applied, and measure the respirable dust levels present. This data was analyzed to quantify the dust levels generated by the major sources on the longwall section and to evaluate the relative effectiveness of the control technologies in use.

By William H. Schiffbauer

This paper details the computer hardware and software integrated to provide computer-assisted control and monitoring of four different coal mining machines. The backbone of each system is a U. S. Bureau of Mines integrated distributed microcomputer control network called BOM/NET. The network provides connections for intelligent sensors and systems that provide for navigation, diagnostics, and computer control. Many different computer systems using various operating systems (including RMX I, UNIX, VXWORKS, DOS and DCX51) have been connected to the network and each have had complete network functionality. A description of the network's integration to Joy' 16CM, a Joy 14CM, a Jeffrey 102, continuous mining machines, and a custom built auger machine is provided. The networks for the Joy 16CM, the Joy 14CM, and the Jeffrey 102 have been installed and extensively tested at the Bureau's surface test facility. The Jeffrey 102 system has also been tested in a highwall coal seam. The Joy 14CM will soon be tested underground.

By J. F. McIlwain

The Bureau of Mines investigated fumes generated by selected welding materials used in mines in order to help determine their relative hazard potential. The initial phases of the study have been completed. A welding-fume generation and collection apparatus was designed, assembled, and calibrated. Five brands of coated, AWS-type E308-16 stainless steel electrodes were tested. Total fume generation rates of 0.39 to 0.51 g/min were measured. Quantitative chemical analyses were conducted for all of the principal firms constituents. Two analytical schemes were used to determine levels of the Cr6+ and Cr3+ species contained in the welding fumes; comparable results were obtained. The Cr6+ was found to be the most hazardous constituent, leading to a maximum allowable total fume exposure of 1 mg/m3. Fume generation rates and fume constituent analyses will be derived for other groups of welding electrodes using similar procedures.

Jan 1, 1983

By C. Özgen Karacan

Degasification and methane control in underground coal mining is an important area augmenting conventional ventilation in order to prevent possible fires and explosions due to excessive methane emissions. Coal bed reservoir engineering has been applied for many years to coalbed methane production. In recent years, modeling the flow and draining methane, not only from coal bed itself but also from the overlying strata, have been recognized as important areas of expertise for supplementing underground ventilation. This paper demonstrates the applications of coal bed reservoir engineering and modeling techniques for optimizing and controlling methane emissions in longwall and continuous miner sections. Practical applications and some considerations are presented for reservoir modeling, borehole performances, and face emission predictions for various coal bed and borehole configurations. A section on field reservoir studies and well bore log analyses for methane control are also presented as a complementary way of controlling methane and optimizing ventilation.

Jan 1, 2009

By R. S. Warfield

The Kasna Creek copper deposit near Lake Kontrashibuna in the Lake Clark region, Alaska, was the object of an investigative project by the Bureau of Mines during the fall of 1948. Recessed because of inclement weather, it was completed in 1949. This project was a part of the Bureau of Mines program in Alaska for the development of critical and strategic minerals. The ore bodies are contact-replacement deposits in limestone. Mineralization is mainly specular and micaceous hematite associated with chalcopyrite, calcite, chlorite, quartz, and amphibole. The deposit, on the right limit of Kasna Creek approximately 2 miles from the shore of Lake Kontrashibuna, is composed of two mineralized zones that range in altitude from 2,350 to 2,650 feet. This report contains a brief history of the prospect, description of the physical setting of the property, its geology, and the factual results of the Work performed by the Bureau of Mines.

Jan 1, 1951

Eliminate the need for roof bolter operators and their helpers to work under unsupported roof while setting or removing temporary supports before or during the roof bolting cycle-a task that annually accounts for approximately 20 percent of all roof fall fatalities. Approach The Bureau of Mines designed, built, and field tested an auto-mated temporary roof support (ATRS) that can be carried from place to place on the drill head of a single, fixed-head roof bolting machine (squirmer) used in low coal seams (less than 42 inches thick). How It Works The ATRS is designed for installation on any streamlined squirmer. It consists of a ten? foot-long, steel, wide-flange beam supported by two double-acting, telescoping hydraulic cylinders. A steel sleeve, mounted on the bottom center of the beam, is designed to fit over top of the

Jan 1, 1983