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By T. L. Joseph

The size and accessibility of the Minnesota manganiferous iron ore deposits make them attractive as a potential source of erromanganese, which is essential in the production of steel. For several years the Bureau of Mines has been conducting experiments to determine the feasibility of producing ferromanganese from these ores by a three-step process which involves (1) the smelting of the ores in the blast furnaoe to produce a high-phosphorus spiegel; (2) the treatment of the spiegel produced from step 1 in an electric or open-hearth furnace to separate the manganese from the phosphorus and the iron; and 3) the smelting of the high-manganese slag from step 2 to produce forromanganese. The details of the first two steps of the process and the results of tests with the experimental furnaces Lave been given in previous reports.5 The m$ or part of the experimental work on the second step has been conducted in a half-ton open-hearth furnace. Some preliminary tests showed, however, that the electric furnace has some distinct advantages over the open hearth for producing, from high-phosphorus spiegel, a slag containing from 45 to 55 per cent manganese and phosphorus and iron in amounts required for ferro-grade ore. The electric furnace tests described in this paper were made to get more information as to the possibilities of the electric furnace in connection with this problem and to study the fluxing effect of alumina on high-manganese slags. Herty, Conley, and Royer have reported' results of laboratory tests which showed that slags containing from 60 to 75 per cent MnO, from 8 to 10 per cent S102, and small amounts of CaO MgO, and FeO, were sufficiently fluid at 1,450° to 1,550° C. to pour readily if 12 to 14 per cent alumina was present. With a normal A1203 content resulting from the A1203 in the

Jan 1, 1931

By C. Melvin Lepper

The Bureau of Mines has developed an improved earth resistivity field system which employs a novel technique for obtaining null measurements. The instrument is designed to operate reliably in high-noise environments such as those found in the vicinity of operating mines. The system consists of a low-frequency transmitter, a sensitive receiver and an external battery pack, each in its own case to provide protection from the elements. The receiver and transmitter units have self-contained recharge-able batteries to supply power to the circuitry and separate built-in battery chargers that operate on standard 115 Vac power. The system is portable and simple to operate. Measurement accuracy, reliability, and dynamic range are superior to most commercially available equipment even though less time and effort is required to make null readings. Unlike some commercial systems, long integration times are not required to enhance signal-to-noise ratio in areas of high background noise.

Jan 1, 1974

By Daryl R. Tweeton

The Bureau of Mines compared the effects of surface-active chemicals with those of pure water on core-drilling rock and quartz and on fracturing quartz. The objectives were to determine if these chemicals assist drilling and fracturing rock and if zeta potential control was worth pursuing as an aid to full-scale drilling. All tests were performed in the laboratory. No significant increases in drilling rates were observed for 1 to 10,000 ppm Al (as AlC13) in flushing water when drilling microcline or serpentine, nor for 1 to 10,000 ppm Mg (as MgC12) when drilling microcline or marble. Concentrations near those giving a zero zeta potential were used with microcline and marble. A 50-pct rate increase was observed for drilling quartz in 0.7 ppm oleylammonium acetate, which gave a zero zeta potential. No other concentrations were used. No effect on the tensile strength of quartz thread in 0.05 ppm Al (as AlC13), which gave a zero zeta potential, was observed. Heptanol, reported to give a zero zeta potential on quartz, did not reduce the bending strength of small quartz bars below that in water. These generally negative findings raise doubt about the usefulness of zeta potential control in full-scale drilling. The results, combined with previous studies, suggest that controlling physical properties of drilling fluids, such as viscosity, is more useful than altering chemical properties.

Jan 1, 1976

By Sam S. Taylor

In most oil fields, natural gas is the major source of energy causing flow of oil to the well. The amount of gas produced With the oil generally exceeds actual energy requirements, so that in time the gas reserve of the field becomes seriously depleted and the oil production nest be stimulated by some auxiliary means. One of these is to repressure the oil formation with natural gas; or, where a gas supply is not available, often air is used. Although air is a cheap and convenient repressuring medium, its use sometimes is attended with several disadvantages. First, the return air-gas mixture decreases rapidly in fuel value, often until it can be used no longer as a source of power. At the same time, explosive mixtures may result if recycling is used, causing hazards to life and equipment. Second, some fields experience considerable trouble with the formation of emulsions which become increasingly difficult to treat. Although there is no definite proof that air repressuring always causes these emulsions, many operators are convinced that this is the case.

Jan 1, 1934

By W. W. Adams

[S,1.1.8'"' of explordves -permissible explosivos,21 other high explosives, and black blasting povrder -in the Uni ted States during the caJ.endar yenr 1937 reached a ~ombined total that slightly exceeded the quantity sold in 1936. A larger output was re orted. for permisAiblA and other hig! explosives but asmal-ler for black po~~er. Production of the three classes of explosives totaled 404, 744,294 pounds, more than 3 pel'CGnt over 1336. The total qrumti ty produced included 49,579,441 pounds of perminsibles, 2~8,924,253 pounds of other high ex-plosives, 36,403,950 pounds of black powder in pellet form, and 29,836,65q pounds of bla~k powder in granular form.]

Jan 1, 1938

By Robert T. Langland

The Bureau of Mines, at its Denver, Colo., research center, has developed a computer program to solve nonlinear regression problems. The program is written in a general form so that, regardless of the functional relationship assumed, the unknown parameters may be evaluated by the Newton-Raphson method of iteration. Variances and covariances of the parameters are derived, based on the propagation of errors. A creep function is established from shale test data as an example of program utility. Program accuracy is compared to the accuracies of other programs in present day use.

Jan 1, 1974

By Terry G. Montgomery, Eric S. Weiss, John E. Going, Kenneth L. Cashdollar

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted joint research on dust explosions by studying post-explosion dust samples. The samples were collected after full-scale explosions at the PRL Lake Lynn Experimental Mine (LLEM), and after laboratory explosions in the PRL 20-L chamber and the Fike I m3 chamber. The dusts studied included both high- and low-volatile bituminous coals. Low temperature ashing for 24 h at 515 °C was used to measure the incombustible content of the dust before and after the explosions. The data showed that the post-explosion incombustible content was always as high as, or higher than the initial incombustible content. The MSHA alcohol coking test was used to determine the amount of coked dust in the post-explosion samples. The results showed that almost all coal dust that was suspended within the explosion flame produced significant amounts of coke. Measurements of floor dust concentrations after LLEM explosions were compared with the initial dust loadings to determine the transport distance of dust during an explosion. All these data will be useful in future forensic investigations of accidental dust explosions in coal mines, or elsewhere.

By George J. Conroy

This Bureau of Mines publication describes several fault locators and methods, including time domain reflectometers, a frequency domain reflectometer, tone generators, an infrared method, the Murray loop method, and high-voltage "click" methods. The Bureau of Mines has been conducting research into these methods for several years, to improve mine safety and facilitate production through rapid, safe location of trailing-cable faults. The problems encountered in practical applications are discussed, and schematic diagrams of several instruments fabricated by the Bureau are presented. Since no present single method of locating trailing-cable faults is universally applicable, a kit composed of several of the more promising fault locators is advisable.

Jan 1, 1978

By Richard G. Sandberg

Sphalerite concentrates prepared during processing of Missouri lead ores contain small percentages of cobalt and nickel which adversely affect zinc electrolysis. The Bureau of Mines has evaluated solvent extraction and precipitation techniques to remove and recover cobalt and nickel from zinc sulfate solution prior to zinc electrolysis. Prepared zinc sulfate solutions containing about 190 gpl of zinc and 50 ppm of both cobalt and nickel were treated using various combinations of complexing reagents, solvent, pH, concentration, time, and temperature. The following complexing reagents gave the best results: a-nitroso-ß-naphthol, ß-nitroso-a-naphthol, 1,2 cyclohexane dione dioxime (nioxime), di-2-pyridyl ketone oxime, and dimethylglyoxime. These reagents in suitable solvents lowered the cobalt and nickel levels to <0.1 ppm. Stripping the complexed reagents from the solvents was not possible except for nioxime. Direct addition of the appropriate reagent to the prepared zinc sulfate solution resulted in the precipitation of cobalt and nickel. Several possible flowsheets are presented for the removal and recovery of cobalt and nickel. Good zinc deposits were successfully electrowon from zinc sulfate solutions purified by solvent extraction and precipitation.

Jan 1, 1978

By Charles Vaught, Kathleen Kowalski

Emergency personnel, like all workers, carry out their duties within an environment composed of a set of discrete elements. First, there is the emergency itself. Whether a forest fire in France, a tornado in the American Midwest, or a mining disaster in Russia, the emergency imposes certain exigencies upon the responders. Second, a social structure exists with specific social units, rules, and forms of association. An emergency response, therefore, takes place within a context of prescribed behaviors, expectations, and value judgments that are sometimes in conflict with each other. Third, there is a technology that must be understood in order to accomplish group goals. If the technology itself is implicated in the emergency, the entire emergency environment may be impacted. Clearly, a breakdown in any of these elements could result in worker injury and might heighten responder stress. This paper discusses how emergency workers not only get injured but may come to experience bum-out, post-traumatic stress syndrome, or impaired work and family relationships, even though their normal work setting (the emergency) is expected to be &apos;abnormal&apos;. The authors suggest areas in each of the three environmental elements that, deserve further inquiry.

By R. C. Ellman

This report presents results of a series of tests on grindability of lignites and factors that influence grindability determination. All grindability tests in this investigation were made in the standard Hardgrove test apparatus. In addition to tests on standard samples of equilibrium moisture content, grindability determinations were made on air-and oven-dried samples of lignite representing the complete range of moisture content from normal bed moisture to nearly moisture-free conditions. Grindability index for all tests was calculated both by standard method and by an alternate or "corrected" method of calculation based on directly measured weight of fine-particle material produced in the grindability test. The second method of calculation allows more satisfactorily for loss of moisture during testing of high-moisture samples.

Jan 1, 1955

By John A. Johnson

[Tests were conducted at the Mount Weather testing adit of the Bureau of Mines4/ on the effectiveness of spraying water along the outside of the drill steel as compared with standard wet-drilling practice. The spray equipment used in the tests was designed primarily for the control, in quarries, of dust from dry drilling with solid type drill steel. EQUIPMENT Spray equipment is made in sizes to fit different drill steel but is alike in design, the only difference being in the diameter of the ring and the number of spray holes. The device is made of cast steel and has a coating of Stellite on the inside edge that comes in contact with the drill steel. It looks like a garden spray, except that the spray holes point in only one direction.]

Jan 1, 1939

By T. T. Campbell

Studies were conducted by the Bureau of Mines to develop a process for preparing thorium-magnesium master alloys or pure thorium metal by magnesium reduction of thorium tetrachloride in a semicontinuous reactor. Thorium tetrachloride was prepared in a fluidized-bed reactor by chlorination of thorium oxide or thorium oxalate. Conditions were established for producing a suitable thorium oxide feed for a fluidized-bed reactor. Thorium tetra-chloride was purified by vacuum sublimation and subsequently reduced by magnesium in a semicontinuous reactor to form thorium-magnesium alloys. Relatively pure thorium was produced by removing magnesium from the alloys by vacuum sublimation. Close to 100 percent of the thorium fed into the reactor was recovered either as metal (~93 percent) or as thorium oxide (~7 percent). The oxide can be recycled directly into the process.

Jan 1, 1971

By Bill M. Stewart, Phil W. Patton, Curtis C. Clark

Back injuries from handling materials in underground mines continue to be a major safety problem. In spite of the ingenuity of many people and the development of numerous mechanized aids, the number of materials-handling injuries remains second only to the number of roof fall injuries in underground coalmines. Relocation and repositioning of electrical cable, conveyor belt parts, and roof bolt sup-plies in particular are the sources of significant numbers of back injuries. To help reduce such injuries, researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health are examining Mine Safety and Health Administration accident data to determine correlations between materials-handling tasks and the number of back injuries. Also being investigated are new technologies used in underground mines in the United States. Equipment is being developed or modified that would replace the necessity of doing lifting tasks manually. A Coleman manipulator was tested, and modifications were made to make it more suitable for underground mine use. To reduce or eliminate the need to manually clean off materials that commonly plug grizzly openings, a track-guided pincher arm device was developed. Oversized rock can be broken with the pincher arms in the up position, and the arms can be lowered to grab and remove debris. The arm can also be used in a sweeping action to remove cohesive fines that may bridge grizzly openings.

"Fire fighting in metal mines under the best of conditions is a dangerous, a slow, and a difficult task. Certain gases generated from combustible material burning in restricted areas are poisonous, even in small quantities, and can not be breathed without serious and often fatal results. In addition to poisonous gases, smoke is given off which obscures the vision of the fire fighter and frequently prevents him from gaining access to the fire area. Many fire-fighting crews have had to turn back because their vision was so impaired by the dense smoke that the fire area could not be located and there was danger of them becoming lost in the mine.In mines having mechanically controlled ventilation - that is, mines not dependent entirely upon natural air currents - the gas and smoke can be forced ahead of the fire-fighting crews, thereby facilitating exploration of the mine and saving the time, energy and oxygen of the mine rescue apparatus crews.Where currents of fresh air can be circulated up to points near the fire without danger of seriously spreading the fire, fresh air bases can be established in the immediate vicinity, and a more intelligent campaign for fighting or controlling the fire can be mapped out.Positive air currents through forced ventilation may also result in saving the lives of miners who otherwise might have been trapped in smoke and poisonous gases.It is generally known that comparatively few metal mines have attempted to regulate or control air currents, with the result that when a fire occurs underground, the normal ventilation may be reversed, short circuited, or the air current may be in one direction one minute and in the opposite direction the next; or, generally speaking, the ventilation can not be depended upon, and smoke and poisonous gases may accumulate in any part of the mine or ""drift"" on the fire-fighters or on the miners endeavoring to escape."

Apr 1, 1921

By M. B. Shirts

Bench-scale studies were made on a reductive hydrometallurgical procedure to convert chalcopyrite flotation concentrate to copper metal or a readily leachable sulfide. Reductive conversion of chalcopyrite and dissolution of iron and sulfur were accomplished in hydrochloric or sulfuric acid solution by the addition of metallic copper, iron, or lead. Use of metallic copper as the reductant enabled extraction of 95 and 46 percent of the iron and sulfur, respectively. The products were ferrous iron, hydrogen sulfide, and a copper sulfide. Use of metallic iron or lead as the reductant enabled extraction of 95 percent of both the iron and sulfur. The products obtained with metallic iron or lead were ferrous iron, hydrogen sulfide, and metallic copper.

Jan 1, 1974

By Deno Pappas, Chrisropher Mark, John Rusnak, Linda McWilliams

Mine planning for a new reserve is based on information obtained from exploratory coreholes. A critical component of an exploration program is the geotechnical evaluation. Poor assumptions about roof conditions greatly add to the risks of mining. Rock mechanics testing is central to a geotechnical exploration program. Typically, 3 to 5 uniaxial compressive strength (UCS) tests are made to characterize a particular roof unit at a given corehole. The average (mean) of these tests is taken as “The UCS” for that location. Isopach contour maps are then used to show spatial trends in roof strength. Two issues are raised by this traditional approach. The first is due to the large variability in UCS values that is typical even within a single unit from a single hole. The average UCS might be higher at Corehole A than it is at Corehole B, but the difference may not be statistically significant. The second issue is whether widely spaced coreholes can identify valid spatial trends in rock strength. The answer depends upon whether rock strength changes over distances that are longer or shorter than the corehole spacing. This is a classical geostatistical problem. While geostatics have been used to investigate many coal quality parameters, they have seldom been used to evaluate rock strength. This paper describes an extensive investigation of these issues conducted by the National Institute for Occupational Safety and Health (NIOSH) in collaboration with Peabody Energy. The study employed the Peabody Rock Mechanics Data Base which contains more than 10,000 individual test results. Data from four important roof units were subjected to statistical analysis: • Brereton Limestone above the Herrin 6 seam (Illinois) • Turner Mine Shale above the No. 9 Seam (Kentucky) • Sandstone above the Eagle Coal (West Virginia) • Shale above the Eagle Coal (West Virginia) The study did not find significant spatial trends in rock strength in any of the cases. Perhaps there are none, or perhaps the exploration coreholes were just too far apart to see them. These results have valuable implications for the design of geotechical exploration programs.

By John Gross

The modern practice of grinding ores so that often 80 per cent or more of the product is finer than 200 mesh makes it desirable to supplement sieve sizing so as to extend considerably the range of sizing. Moreover, the fact that the material finer than sieve size represents the major part of the work done in grinding emphasizes thick need in can investigation of crushing efficiency. A method based on the settling rate of particles in grater appeared to be most practical for sizing; finely ground ores. There are two possible methods of utilizing this principle: one based on free settling or sedimentation; and the other on separation by means of a rising; current of water, or elutriation. In sedimentation, mechanical entanglement causes material at the start to settle in a mass, and this persists throughout. As this feature is largely eliminated by elutriation, which permits a comparatively clean separation of the various sizes, the elutriation method was adopted.

Jan 1, 1929

By C. H. Fisher

[Mxny methnhs of ,analyzing tpr oils fnr thoir tar acid ~nd base cnntent hava boon employL~d in connection mith both ac~d,.mic and. industrial investigs- tions. Mnst of thznu nnalyticel proc?durn~s aro bpsed nn th; diminution in volums caused by extract lon sit5 alkali 5 minL+ra,l acids (cantrsction rn,>thod) , although othrr mr~thrids havu &apos;sL<on ?q~lnglt 8 . In many instmccs th-: donti ti on of RT~ m~lytic~l m ithod was not ;r.:c ~d~d by ~d.jqunt9 study, and, ns 3 cone+ qucnce, tha lit .,ratur ? on thls sub,jr:.ct is consoScuous for its cnntr~dictnry . claims and rocnmmondatinna.. 1.t tiR.s b9~n shoyn in th;, cnsn of c.lrtn.in synth?tic solut innsfi/ thnt larg~ jr-orn sny rcsult if th2 ,mnlysis is c~rri~d out by sim~la extraction wi.th alidi r.nd min 3rd ncids.]

Jan 1, 1937

By J. W. Paul

This paper deals with the second phase of an extensive research on coal-mine ventilation factors. A comprehensive report of the entire work is in course of preparation, but abstracts of the various chapters are being prepared in order to make the results public as rapidly as possible. Part 1 dealt with the resistance of unobstructed entries and was issued as Serial 2621 of the Bureau of Mines, in July 1924. Description of tests. After the resistance of an unobstructed entry to flow of air had been determined by tests in the Experiment mine, mine cars were; run into the test section in various arrangements and the increase in resistance was determined. The cars used were of the wooden type with loose end gate, and would hold about one ton of coal, level full. They were 7 feet long. 4 feet 2 inches wide above the wheels, 3 feet high, and had a cross-sectional area of approximately 10 square feet. The average area of the entry was about 57 square feet, the ratio of unobstructed to total area being about 17.6 per cent. The track gage was 42 inches and the wheel-base 20 inches.

Jan 1, 1924