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By J. E. Murphy

The u.s. Bureau of Mines investigated electrode designs for electrowinning lead metal from a LiCl-KCl-PbCI2 electrolyte at 4500 C. The major objective of this investigation was to decrease the energy requirement for lead electrowinning. Electrolysis was performed in a bench-scale cell using several graphite electrode assemblies. Such parameters as electrode spacing, current density, and chlorine gas removal from the anode were investigated in the bench-scale tests. An optimum electrode assembly, termed the sawtooth design, was scaled up and operated at 3,000 and 4,000 A. The sawtooth electrodes operating at 3,000 A produced lead for 0.66 kW·h/kg. The electrodes were constructed by cutting large triangular grooves in the electrode surfaces. The electrodes were placed together such that the triangular peaks of one electrode projected into the triangular valleys of the other electrode. Chlorine did not build up on the anode with the sawtooth electrodes.

Jan 1, 1991

By E. D. Calvert

This Bureau of Mines report discusses the electric-arc reduction of zirconium and hafnium oxides with carbon yielding a metal-metallic carbide mixture. The carbon to oxide ratio in the feed determines the metal to carbide ratio in the product. A sample of this product was produced -or testing as a feed for the deBoer iodide-dissociation process. A new technique for producing pure carbides is described, which uses the intense heat of the arc to volatilize the carbide. The condensed vapor form , crystals of nearly stoichiometric carbide, INTRODUCTION This research examines the preparation of refractory metal carbides in the controlled atmosphere electric-arc furnace.

Jan 1, 1962

By Richard A. Winters

There are no producing or developing mines or active mining claims in the Deschutes Canyon RARE II study area. Only two prospects were found; they have no identified potential for mineral resources. Thin diatomite deposits occur in the Pliocene Madras Formation. Development of sand and gravel deposits in the area could not favorably compete with similar deposits in the surrounding area which are closer to points of use. By mid-1982, active oil and gas lease applications covered about 25 percent of the area, a reduction from nearly 100 percent in early 1981. No holes were drilled for oil and gas exploration. INTRODUCTION Personnel of the Bureau of Mines, Western Field Operations Center conducted a mineral investigation of the Deschutes Canyon RARE II area during the summer of 1982. The area, about 10 mi (16 km) southwest of Madras, Oregon, covers 10,890 acres (4,407 ha) in the Crooked River National Grasslands (fig. 1). The Deschutes River has incised a deep canyon into the north sloping elevated lava plain near the transitional boundary of the High Lava Plains and the Deschutes-Umatilla Plateau geomorphic divisions (Baldwin, 1964, p. 20).

Jan 1, 1983

By Richard J. Mainiero, Michael J. Sapko, Marcia L. Harris

Since 1988, there have been 17 documented incidents in the United States and Canada in which carbon monoxide (CO) is suspected to have migrated through ground strata into occupied enclosed spaces as a result of proximate trench blasting or surface mine blasting. These incidents resulted in 39 suspected or medically verified carbon monoxide poisonings and one fatality. To better understand the factors contributing to this hazard, the National Institute for Occupational Safety and Health (NIOSH) carried out studies in a 12-foot diameter sphere to identify key factors that may enhance the levels of CO associated with the detonation of several commercial trenching explosives. The gaseous detonation products from emulsions, a watergel, and ANFO blasting agents as well as gelatin dynamite, TNT, and Pentolite boosters were measured in an argon atmosphere and compared with those for the same explosives detonated in air. Test variables included explosive formulation, wrapper, aluminum addition, oxygen balance, and density. Major contributing factors to CO production, under these laboratory test conditions, are presented. The main finding is the high CO production associated with the lack of afterburning in an oxygen poor atmosphere. Fumes measurements are compared with the manufacturer’s reported IME fume class and with the Federal Relative Toxicity Standard 30 CFR Part 15 in order to gain an understanding of the relative toxicity of some explosives used in trench blasting.

By Michael D. Fenton

Bauxite resources were primarily in Africa, Asia, Oceania, and South America. Only five countries combined, Australia, Brazil, Guinea, India, and Jamaica, contained most of the total world reserves available for extraction under current economic conditions and accounted for nearly 80 % of world production of bauxite. World bauxite and alumina production declined and prices for smelter-grade alumina remained below the $200/mt level during 1993 because of growing aluminum inventories on international markets and declining worldwide demand. The United States imported bauxite primarily from Australia, Brazil, Guinea, and Jamaica. U.S. alumina plant capacity remained essentially unchanged throughout 1993, but apparent capacity utilization decreased by the close of 1993. Chromium Most of the world's known resources and reserves of chromite are located in India, Kazakhstan, South Africa, and Zimbabwe. India, Kazakhstan, and South Africa accounted for 73 % of world production of chromite. The two largest producers of chromite, Kazakhstan and South Africa, were in the process of major economic and political change during 1993. South Africa's production and exports of chromite continued to fall during 1993, because of weak international demand and a flood of cheap metal from the former U.S.S.R. and China into world markets. Despite a significant increase in production, South Africa's ferrochrome producers continued to operate below capacity in 1993. Prior o the dissolution of the U.S.S.R., Kazakhstan was a major internal supplier of chromite ore to the U.S.S.R. consumer, but subsequent decline in demand led to a downward trend of chromite production in Kazakhstan and increasing exports to Europe during 1992 and 1993. The United States consumed, about 10% of world chromite ore production in various forms of imported materials. The United States imported nearly one-half of its required chromium contained in chromite ore and chromium ferroalloys and metal from South Africa; the remainder was from the minor producers Turkey, Yugoslavia, Zimbabwe, and others.

Jan 1, 1995

By R. S. Dean

"INTRODUCTION The idea of direct steel is by no means new. Although the work of Bessemer and Siemens provided simple and effective moans for converting pig iron into steel and established the ""blast-furnace route"" as the almost universal method of producing steel, metallurgists have not ceased to dream of direct steel. By direct steel is meant any process by which iron oxide in ore is reduced to Iron of the same or greater purity than the final steel or wrought iron. That is, carbon or alloying elements would be added as needed, not reduced in unwanted quantities into the iron and then removed more or completely by refining (Bessemer or open hearth) only to be readded in desired quantities.In general, direct-steel processes are ""sponge-iron"" processes, because reducing iron oxide without simultaneously alloying the iron with carbon, phcophorus, sulfur, and silicon present in ore and fuel succeeds only if the temperature is below the melting point of the iron. Such solid iron formed by reduction of iron oxide at relatively low temperature is sponge iron, which is butlery and porous. When the reduction proceeds at the higher temperature at which the particles of metal can weld together or finally even melt to yield pellets or balls that do not have the porosity and low-density characteristic of sponge iron, the product might preferably be called simply ""direct iron."""

Jan 1, 1945

By F. R. Lee

When the Bureau of Mines was established in July 1910, one of the problems immediately attacked by the new organization was the development of standard, for the design and testing of electrical equipment that could be used without fear of initiating fires and explosions in underground coal mines. Research and investigation by Bureau personnel, supplemented by the published results of similar work by European mining authorities, led to the establishment of standards or "schedules." which guide manufacturers ill the design of many types of electrically operated machines and devices used in underground coal Mining. By issuing these standards, Bureau personnel establish the requirements to be met by such equipment before it tan be approved by the Bureau of Mines as permissible for use in gassy coal mines. Every 2 years the Bureau of Mines publishes a list of equipment that leas been accepted as approved or permissible during the preceding 2 calendar years. This is done to inform the mining industry of the availability y of the latest equip¬ment for safe use underground.

Jan 1, 1964

By D. A. Paice

A portable calibrator to check tie trip setting of dc circuit breakers within an accuracy of +5% has been developed for the Bureau of Mines. It operates from a 300 volt dc trolley wire to provide controlled current pulses of 120 milliseconds duration and continuously adjustable from 1400 to 3600 A. These current pulses enable a breaker dc trip current to be determined and subject the contacts to full current rating. The equipment is simple to use and weighs 86 pounds. Connections are made with protected, clamp-on leads which are separately connected and weigh about 22 pounds. An accurate calibration procedure takes less than 5 minutes to complete.

Jan 1, 1978

By Ralph L. Rinehart, Wils L. Cooley

This paper summarizes recent experiments with grounding systems. Problems and potential hazards related to in-mine grounding systems are discussed. The monitoring of trailing cable ground conductors and testing of commercially available ground monitors are discussed.

Jan 1, 1975

By Fred D. Wright

A compressor and utility station, which is believed to be one of the largest mobile units of this type ever constructed, was placed in operation at the Bureau of Mines experimental oil-shale mine near Rifle, Colo., during. 1949. This mobile unit mounts two 770-cubic-feet-per-minute air compressors, a 2,500-gallon water tank, and a 200-cubic-foot air receiver. The mobile base of the unit is a 30-ton trailer 30-feet long and 12-feet wide. Prior to the construction of this unit, compressed air was supplied to underground workings through pipe lines connecting with a stationary compressor plant on the surface. The power consumed in supplying compressed air to underground drilling crews was 0.531 kw.-hr. per ton of shale broken. Use of the mobile unit has cut this figure to 0.421 kw.-hr. per ton of shale broken and, more important, has eliminated the cost of installing and maintaining underground air and water lines.

Jan 1, 1950

By Lawrence K. Requa

The property being worked by the Lewiston dredge of Placer Development (Ltd.) is on the Trinity River in Trinity County, Calif., about 9 miles north of the town of Lewiston (see fig. 1). The nearest rail point is at Rending, Calif., which is exactly 50 miles bar road from the dredge camp. Recently a very good section of State highway has been constructed from Redding to Weaverville, and it is now possible to use this highway for 35 miles of the distance between the dredging property and Redding. The remaining 15 miles, however, are over ordinary dirt road. No trouble is experienced in reaching the property except for a few weeks during the middle of the winter when snowstorms may make travel difficult but not impossible. At present the property consists of about 500 acres of patented land, which extends for about 3 miles along the main Trinity River and Stuart's Pork. It is being worked with one 7-cubic foot, Bucyrus-type dredge, which has an average monthly capacity of about 100,000 cubic yards. To the end of 1931 approximately 10,000,000 cubic yards of gravel had been dredged.

Jan 1, 1932

By Theresa Y. Schulz

It is interesting to study the noise standards that have been promulgated in the US over the last decade or so. These regulations are likely to have long-lasting impact. The Occupational Safety and Health Administration (OSHA) Hearing Conservation Amendment (March 1983) continues to have influence not only in the workplace but in the debate over new regulations. Both the Mine Safety and Health Administration (MSHA) and Federal Railroad Administration (FRA) regulatory preamble documents state the desire to be consistent with OSHA. An examination of Table 1, which compares the major components of the three regulations and the 1998 NIOSH “best practices” criteria, depicts the extent to which that intent is met. There has been some regulatory activity in the last decade which may give some hope for evolution and updating based on the wealth of science that has occurred during the last quarter of a century since the OSHA regulation was enacted. However there has also been some “back-sliding” toward more lenient standards. The MSHA noise standard made regulatory progress in September 2000 by emphasizing engineering and administrative controls, followed by personal protective equipment, in the hierarchy of noise intervention. MSHA’s requirement for technician certification (today only available from CAOHC) strengthened the training requirements for audiometric testing in hearing conservation programs and MSHA also added the requirement of dual hearing protection at 105 dB TWA. There were many subtle differences between OSHA and MSHA based on comments and a desire to clarify some of the vague aspects of the OSHA noise standard, and meet the needs of the regulated mining industry. One example pertains to the ceiling for exposures. OSHA says, “no exposures >115 dBA,” which is interpreted to mean no unprotected exposures above that level, giving credit for the assumed effectiveness of hearing conservation programs, hearing protection devices and administrative and engineering controls. MSHA specified that a “P” code1 violation be issued for any protected or unprotected exposures >115 dBA. The Federal Railroad Administration (FRA) noise standard for railroad operating employees, which went The Modern Evolution of Hearing Conservation Regulationsinto effect February 26, 2007, was expressly based on the OSHA standard but also uses MSHA for comparison. The preamble states that the FRA defers to OSHA as the “primary regulator of noise in the workplace,” but also acknowledges the need for some departure from the OSHA regulation (FRA Preamble II.B). As an example, FRA requires testing at 8000 Hz “because it will allow employers to identify hearing loss sooner.” The FRA rejected MSHA’s hierarchy of noise controls in favor of requiring specific engineering interventions and focusing on appropriate hearing protection which would still allow communication and audibility, and identification of excessive noise through employee-filed “excessive noise reports.”2 Where OSHA has no specific mandate requiring employees to take advantage of the employer-paid audiogram, it has been traditionally a condition of employment and is generally accepted that OSHA-covered workers require an annual audiogram. MSHA addressed this issue in its preamble; however, they made no significant change. MSHA employers are required to offer annual audiograms but MSHA stopped short of requiring employees to comply with annual audiometric testing. The MSHA preamble does allow that mine operators can also make audiometric monitoring a condition of employment. FRA requires employees to

By David A. Lipton

U.S. Bureau of Mines personnel examined mines, prospects, and mineralized areas to determine the mineral resources and potential of the Moses and Dennison Peak RARE II areas in Tulare County, California. These areas, along the west slope of the Sierra Nevada, are underlain by grarnitic rocks of the Sierra Nevada batholith and contain numerous metasedimentary roof pendants. Silver, copper, and zinc occur in contact-metasomatic deposits within the metasedimentary rocks. In the Moses area, the Powell Mine (fig. 1) contains an estimated 90,000 tons (82,000 t) of subeconomic silver, zinc, and copper resources. The King Solomon Prospect has 3,000 tons (2,700 t) of silicified phyllite containing zinc. On the Helen-Joyce Prospect, 44,000 tons (40,000 t) of gossan occur above a poorly exposed silver-zinc rich zone. Potential exists for additional mineral resources and occurrences at each of these properties.

Jan 1, 1983

By David E. Siskind

The Bureau of Mines recorded particle accelerations in the mine roof produced by three types of explosives in the Pilot Knob Pellet Co. mine, Pilot Knob, Mo. Examined were the effectiveness of cube root, square root, and two-thirds power scaling in grouping the underground blast vibration data, and the effects of mine geometry, rock type, explosive type, and charge size on blast vibration levels. A propagation law for this mine was determined. The scaling factor of the square root of the charge weight was developed from previous Bureau studies of vibrations from quarry blasts, and in under-ground blasting both square root and cube root scaling were found applicable for scaling particle vibration data. The vibrations from the Pilot Knob blasts were best grouped by a square-root scaling factor. The empirical propagation equation AW1/2 = 76,250 (R/W1/2)-2.61 where A is the peak acceleration in g's, W is the charge weight in pounds, and R is the distance from the blast in feet, may be used to describe vibration amplitudes from charges fired with zero delay caps or with a single cap at Pilot Knob. Statistically significant differences were found in the vibration levels generated by the different explosives. The Power Primer (75-percent weight-strength ammonia gelatin dynamite) produced levels of vibration of 1.7 to 2.4 times those of AN-FO and slurry explosives; the latter two are approximately equal.

Jan 1, 1973

By R. V. Ramani, V. T. Burgos, J. A. McClay

Introduction The Cost program was developed to provide the planning engineer with a tool to evaluate the cost implications of the technical mine design decisions. Direct costing methods are employed, where feasible, to provide greater detail and accuracy in the primary cost centers. Options have been provided in the cost computation, economic analysis, and output data subsystems to increase the flexibility of the system. Computer Program The program is written in Fortran IV for use in the IBM System 360/370 computers. i. Main - The main routine reads and stores input data from three sources, user input, Cost Data Library, and data transfer from the Master Design Simulator. Data is trans¬ferred to the appropriate subroutines, as they are called, by means of labeled common blocks. ii. Subroutine CSTCOM - is a data modification routine which computes the peripheral charges related to labor and supervisory costs. iii. Subroutine MANPWR - interrogates section data to determine the total labor and supervisory costs for each cost center. iv. Subroutine CAPCST - computes the total capital investment for each cost center, including the economic life and salvage value of each element. Capital costs are determined by user selection of quantities and models of equipment. Equipment costs are stored in the Cost Data Library for retriev-

Jan 1, 1975

By Jerry E. Olson

In 1984, the U.S. Bureau of Mines conducted a mineral survey of the Black Rock Desert Wilderness Study Area (WSA) (NV-020-620), which covers approximately 319,000 acres in Humboldt County, Nevada. About 90% of the WSA is underlain by Pleistocene desert playa sediments; the remainder is comprised of Jurassic-Triassic metamorphic rocks, a Cretaceous intrusive and Tertiary volcanic rocks. Most of the WSA is within a down-dropped fault block of the Basin and Range physiographic province. No mines or evidence of major exploration were identified within the WSA; but five claim blocks within or adjacent to the WSA and zones of anomalous character as defined by the Bureau of Land Management were examined. No mineral resources were identified, but anomalous gold, silver, and indicator element content of samples taken near Pinto Hot Springs indicate resources may exist. Lithium content of samples from near-surface sediments on the desert playa is too low for resources, out geologic conditions are favorable for higher concentrations at depth. Occurrences of zeolites are not considered to be of commercial interest. Approximately 27,000 acres are held under geothermal lease, and most of the WSA is of interest for oil and gas. No evaluation of these commodities was made by the Bureau of Mines

Jan 1, 1985

By L. F. Willmott

The Bureau of Mines at Morgantown, W. Va., has been investigating, on a pilot plant scale, various methods of gasifying bituminous coal with oxygen and superheated steam to produce synthesis gas, as part of the broader program of finding new uses for coal. Differences in the pressure gasification methods used have depended on differences in the manner in which the pulverized coal is fed to the gasifier. One of the methods of feeding the coal that was investigated was the continuous, integrated coal-water slurry system. Goal and water were first mixed to produce a slurry; then the slurry was pumped through a heated coil. to evaporate the water fraction; the resulting steam was superheated, and some of it was separated so as to adjust the ratio of the residual steam to the coal fraction and make the resulting mixture suitable for partial combustion with oxygen in a pressure gasifier. Both before and during this reported3 developmental work it was necessary to make an extensive literature search into the technology of aqueous slurries in order to establish design criteria for the pilot plant and to correlate results of various phases of the work with that of other investigators, The pilot work coincided with the commercial development of a long-distance pipeline for the transportation of coal as a coal-water slurry, and this fact tended to broaden the scope of the pilot plant work and the extent of the literature search. This bibliography is the compilation of the material that was collected.

Jan 1, 1963

The Bureau of Mines has developed test procedures and criteria for evaluating explosive reactivity of explosive-contaminated solid waste substances generated by U.S. Army ammunition plants. These substances are produced as explosive-contaminated sludge from wastewater treatment plants, residues from the burning of munitions and explosives on open ground, and residues from deactivation furnaces. The characterization of explosive reactivity is a prerequisite for disposal of such waste materials, which may be contaminated with primary explosives, propellants, or pyrotechnic materials. The Bureau has proposed two tests for this purpose. These tests were developed to evaluate the explosive reactivity as defined in Title 40, Code of Federal Regulations (CFR), part 261.23(a)(6) and (7). These are the Bureau's gap and internal ignition tests, which determine the sensitivity to shock and thermal stimuli, respectively. This report also includes gap and internal ignition reference data for typical blasting agents, high explosives, propellants, and marginally reactive substances. These reference data were used to establish test criteria. The Bureau has evaluated over 400 samples of contaminated soil, sludge, and burning residues using these two test methods.

Jan 1, 1988

By William H. Schiffbauer

The Bureau of Mines has developed a passive encoder for range knobs, a device that automates the task of obtaining the range settings from devices or instruments to be input to microcomputers. It is easily constructed and installed and will not disrupt the device to which it is being attached. It consists of a custom knob and a small printed circuit board that has light-emitting diodes and magnetic reed switches attached. A ribbon cable connects it to a microcomputer. This encoder eliminates one source of human error in an automated process.

Jan 1, 1983

By Thomas J. Fisher, John J. Sammarco, Gary L. Mowrey, Edward F. Fries

This report (Safety File 3.0) is the fourth in a nine-part series of recommendations addressing the functional safety of processor-controlled mining equipment. It is part of a risk-based system safety process encompassing hardware, software, humans, and the operating environment for the equipment’s life cycle. Figure 1 shows a safety framework containing these recommendations. The reports in this series address the various life cycle stages of inception, design, approval and certification, commissioning, operation, maintenance, and decommissioning. These recommendations were developed as a joint project between the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration. They are intended for use by mining companies, original equipment manufacturers, and aftermarket suppliers to these mining companies. Users of these reports are expected to consider the set in total during the design cycle. • 1.0 Safety Introduction.—This is an introductory report for the general mining industry. It provides basic system/software safety concepts, discusses the need for mining to address the functional safety of programmable electronics (PE), and includes the benefits of implementing a system/software safety program. • 2.1 System Safety and 2.2 Software Safety.—These reports draw heavily from International Electrotechnical Commission (IEC) standard IEC 61508 [IEC 1998a,b,c,d,e,f,g] and other standards. The scope is “surface and underground safety-related mining systems employing embedded, networked, and nonnetworked programmable electronics.” System safety seeks to design safety into all phases of the entire system. Software is a subsystem; thus, software safety is a part of the system’s safety. • 3.0 Safety File.—This report contains the documentation that demonstrates the level of safety built into the system and identifies limitations for the system’s use and operation. In essence, it is a “proof of safety” that the system and its operation meet the appropriate level of safety for the intended application. It starts from the beginning of the design, is maintained during the full lifecycle of the system, and provides administrative support for the safety program of the full system. • 4.0 Safety Assessment.—The independent assessment of the safety file is addressed. It establishes consistent methods to determine the completeness and suitability of safety evidence and justifications. This assessment could be conducted by an independent third party. • 5.0 Safety Framework Guidance.—It is intended to supplement the safety framework reports with guidance providing users with additional information. The purpose is to assist users in applying the concepts presented. In other words, the safety framework is what needs to be done and the guidance is the how it can be done. The guidance information reinforces the concepts, describes various methodologies that can be used, and gives examples and references. It also gives information on the benefits and drawbacks of various methodologies. The guidance reports are not intended to promote a single methodology or to be an exhaustive treatment of the subject material. They provide information and references so that the user can more intelligently choose and implement the appropriate methodologies given the user’s application and capabilities. [ ]

Jan 5, 2002