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By V. A. Chanturiya

In Pt- and Au-keeping complex ores processing, about 10% ~ 15% of noble metals are lost with true tailings that are due to low floatability of Pt- and Au-keeping minerals by the conventional collectors. With the aim to achieve the effective recovery of noble metals at flotation of Pt-Cu-Ni and Au-keeping ores organic complex reagents keeping electron-donating atoms of nitrogen, oxygen, sulfur or phosphorus may be offered as selective collectors for the indicated minerals. These rea-gents tend to form complex compounds with PGM. Besides this, Cu-Ni-Pt and complex Pt and Au carbonated mica ores are characterized by finely disseminated (up to nanometer size) mineral forms of Pt in multivalent states. In this connection, the use of a combination of the strong ionic collectors with nonionic reactants that are capable to derivate complex compounds with multivalent PGM seems to be expedient for this type of ores. In the research new complex reactants were tested such as cyclic alkylene-trithiocarbonates, oxyalkyl butylxanthogen acid ethers, a combination of the collectors ? mercaptobenzothiazole (MBT) and dialkyldithiophosphates (DTP). Sorption and flotation tests were made with monomine-ralic samples of chalcopyrite, pentlandite, pyrrhotite, pyrite, and Pt-Cu-Ni sulfide ore samples. Sorption properties were examined by the extractive UV spectrophotometric method and potentiometric measurements. To indicate a structure of modified xanthate solutions the method of a thin-layer chromatography (TLC) was applied. The chromatographic behavior of the basic components of modified xanthate solution ? ButX, cyclic propylene-trithiocarbonate (PTTC), diethyl-dithiocarbamate (DEDC) and the product of its modification ? oxypropyl-S-ether of dithiocarbamatic acid was studied on plates ?Silufol UV ? 254?. The composition of organic solvents and its ratio in a mobile phase was deter-mined for simultaneous chromatography of the main components of a reaction mixture. It was found that operating selectivity of MBT, DTP and cyclic alkylene-trithiocarbonates incorporated in modified xanthate in relation to Pt-Cu-Ni and Au-containing sulfide minerals might be explained by an electoral sorption of this nonionic collector on a surface of the minerals studied. It was demonstrated that the application new reagent modes with the use of a combination of designed complex reactants helped to increase the extraction index of Pt- and Au-keeping minerals from complicated ores.

Jan 1, 2014

By József Faitli, Barnabás Csoke, Károly Solymár, Zoltán Hatvani, Dimitri Papanastassiou

In most cases, the sizing of dry or wet mills for ore processing is primarily based on the determination of the Bond grindability index, using the Bond-Kjos-Rowland relations. In several cases, grinding takes place under conditions different from these and the grinding conditions have a great influence on the postgrinding process. This is particularly true for the grinding of bauxites where grinding takes place in alkali, often in higher temperature in alkali Liquor. So it is necessary to develop a testing method providing a reliable grindability index even under these special circumstances and allowing a more precise mill sizing. Therefore we surrounded the grinding crucible of the Hardgrove mill with a crucible furnace to heat it. The new heated mill is suitable to determine the grindability index under temperature-controlled circumstances, in liquids (water and alkali) with different temperatures. The required heating power is 2000 W. In the implemented equipment we installed four 230V/500W electric heating wires made from heat-resistant alloyed material and surrounded by ceramic insulators. The temperature and temperature-gradient are measured by four PT100 platinum thermal resistors. The data acquisition and control program written in the C language in the Lab Windows CVI program environment measures the voltage proportional to the temperature. Determining the grindability indices of hungarian and greek bauxites experimentally, first dry grinding tests were carried out under standard conditions. During wet and alkaline grinding, to 50 g of dry bauxite 85.5 g of industrial alkali with a concentration of about 200 g/l was added. As grinding aid 2 g of CaO (4 % of dry bauxite) was dosed. From the data it can be concluded: - The tested bauxites show a similar behaviour against temperature change. However, the extent of grindability change is different for different bauxites. - Soft Hungarian boehmitic bauxite can be ground in a high-temperature alkaline medium better than hard Greek one. The increase of grindability according to the high-temperature Hardgrove indices: (kHT = Dry o HT,alkaline H /H ): for hard Greek and soft Hungarian boehmitic bauxites: kHT = 1.7 and 2.4 respectively; according to estimated Bond indices (kB,HT =Wi,dry/Wi,HT, alkaline ): kB,HT = 1.6 and 2.1. - The increase of grindability is the most important factor the reaction of kaolinite with caustic liquor and lime and the loosing of the textural structure at 80 ºC and especially at 100 ºC.

Jan 1, 2003

By F. Y. Kang

Graphite with layers structure is easily to form graphite intercalation compounds (GICs) by means of intercalation reactions due to the weak cohesion force among carbon layers, van der Waal?s interactions. By controlling the oxidation-intercalation, high quality exfoliated graphite with low residual sulfur content and MClx-GICs (M=Fe, Co, Ni, Cu, Zn) powder for electromagnetic wave absorbing and shielding materials have been invented. The expansion volume of expandable graphite can be larger than 160 mL/g while the residual sulfur content is less than 800 ppm. The MClx-GICs powder can shield infrared ray and laser completely up to 15 min. We have also in-vented exfoliated graphite for heavy oil adsorption and mild-expansion exfoliated graphite for anode materials in lithium ion battery by controlling the intercalation/de-intercalation. The exfoliated graphite can adsorb heavy oil up to 80 g/g, it also exhibits better performance than commercial active carbon in sewage treatment. The mild-expansion exfoliated graphite as anode material shows high capacity of 370 mAh/g and good cycle performance.

Jan 1, 2014

By C. H. Zhou

Cryogenic grinding of Printed Circuit Board will bring less pollution, reduce energy costs, smaller particles, regular particle size, efficient process, separation various materials due to different fracture toughness. Systemic studies of recycling discarded Printed Circuit Board (PCB) by low-temperature modification and cryogenic grinding have been made in this paper. Firstly test mechanical property of PCB at different low-temperature, including impact strength, flexural strength, and shear strength. Do experiment on the power consumption of different cooling temperature, The results show that the average power consumption is lower between -30? to -60? and the average power is decrease in evidence at -30?. Use ZKB type double roll shear crusher to crush PCB to 20mm×20mm particle size, in a temperature range of -10 ~ -30? Used R type mill to grind sample to minus 3mm under different working condition, the average power consumption is decrease in evidence from -10 ? to -30 ?, power consumption is the lest at rotational speed is 1180rpm.

Jan 1, 2014

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, A. Abazarpoor

"The morphology of pellet feed is known to influence several properties of iron ore pellets, including drop number, compression strength and reduction properties. The effect of grinding method on the particle size, specific surface area and particle shape of an iron ore concentrate has been studied. Grinding methods considered were ball mill and high pressure grinding rolls (HPGR). 5 different samples (Blaine= 1800, 1900, 2000, 2100 and 2200 cm2g-1) were used to compare the size, shape and specific surface of particles for each grinding methods. Particle size was meticulously examined by sieve analysis, laser sizing and image analysis. In samples ground by ball mill, it has been observed that the fraction of particles <10µm increases from 39% to 46% as the Blaine number increases from 1800 to 2200 cm2g-1. For HPGR samples, corresponding figures are 41% and 49% respectively. It is evident that for samples ground by HPGR, the fraction of fine particles is higher than that of those ground in the ball mill. To measure the specific surface area of particles, Blaine and BET were used. A higher real surface area was observed from HPGR treatment in comparison to ball mill grinding, provided by a higher porosity, cracks, roughness and new surfaces. Shape factor of particles was determined using three descriptors: circularity, roughness, and aspect ratio. It was also observed that particles produced by HPGR were more elongated, less circular, and rougher than those processed by the ball mill. 1. INTRODUCTION Particle size and shape are important parameters that can significantly affect mineral processing plants and pelletizing plant performances (Brozek and Surowiak, 2007). It has also been proposed that green pellet quality is directly related to the amount of fine particles in a pelletizing plant (Dwarapudi et al., 2008; Umadevi et al., 2008; Gul et al, 2014; Van der Meer, 2015). Particle size distribution and specific surface area (SSA) are also key factors that can control the quality of green and fired pellets. Processing circuits generally reduce the fines fraction to lower than the required specific surface area (SSA). It is therefore necessary to regrind concentrates to produce suitable pellet feed for further treatment in the balling and firing steps [1, 2]. Two main methods are used for re-grinding of concentrate; high pressure grinding rolls (HPGR) and ball mill. Given the different forces used to reduce size in these methods, it is expected the shape of particles will be different (Pourghahramani and Forssberg, 2005)."

Jan 1, 2018

By Vladko Panayotov, Marinela Panayotova

"Recently, in order to extract metals, the industry is trying to process old metallurgical slag. The material requires very fine grinding that results in enhanced slime-formation. This in turn leads to problems in the course of the flotation process and to a loss of metal. In addition, it causes difficulties in the wastewater treatment aimed at water reuse. The aggregation and separation of the fine particles and their further subjecting to mineral processing would result in more efficient use of raw materials. Closing the water cycle also would be facilitated. The paper presents results from studying sixteen flocculation reagents, commercially available for treating municipal wastewater, including products based on nanotechnology, for their ability to rend the production wastewater in suitable for reuse in the flotation. It turned out that, from all studied reagents, the cationic C-587 is suitable for the purpose. Some of reagents were studied for their ability to flocculate selectively, in presence of coke fines, rich in copper fines which are produced at grinding of a slag from lead-zinc metallurgy. Most promising reagents are chosen, based on the chemical analysis of the flocculated materials. Open-cycle rough copper flotation experiments with the flocculated fines and recycled wastewater gave encouraging results."

Jan 1, 2014

By I. Ngoma, Marijke Fagan, Susan Harrison, Rebecca Chiume

"Heap bioleaching is an unsaturated hydrometallurgical extraction process which is commonly applied to the recovery of copper from low grade sulfide ores as well as for preparatory treatment of gold ores. The leaching reactions occur in the liquid phase, catalysed by iron and/or sulfur oxidising micro-organisms. Contact of the mineral grains with the leaching solution is consequently essential for metal recovery. Additionally, the liquid is responsible for the transport of the liberated metal out of the heap under gravitation-driven flow. However, the highly inhomogeneous structure of the heaps coupled with low irrigation rates cause the flow to vary between being gravitationally and capillary dominated, resulting in non-uniform wetting of the ore. In this study a 132 kg agglomerated ore ‘slice’ is used to examine the effect of liquid distribution on microbial colonisation and mineral recovery in a long term bioleach (> 500 days) when irrigation from a single drip emitter source is employed. The novel setup enabled sample collection from ports positioned along the length and height of the ore bed, so that 2D maps of the degree of wetting and microbial colonisation could be generated at different times in the leach. Lateral movement of the liquid increased with bed depth; the majority of flow was below the irrigation point while the top corner of the bed that was not irrigated remained the driest region of the heap throughout the experiment duration. The lowest cell numbers were also recorded in the driest regions. Specifically, cell numbers in the top corner of the bed, 400mm from the irrigation point, remained at undetectable levels until the 283rd day measurement, in line with typical heap operation durations. This indicates that slow colonisation of the heap in the regions between irrigation points may be a significant issue in heap optimisation."

Jan 1, 2014

By Duong Huu Hoang, Nathalie Kupka, Urs A. Peuker, Martin Rudolph

"The froth ability, froth stability and the froth structure are strong influences in flotation process i.e. on water recovery, bubble size, entrainment of gangue particle, flotation rate constants, grade and recovery. The labscale flotation of rich apatite ore with a high mass pull leads to significant changes in pulp and froth properties over time. The froth stability decreases with increasing the flotation time. These changes can be related to different solid contents, reagent concentration, froth heights and bubble size distributions. This study presents the results from froth studies and discussions on the particle size of fully liberated silicates and degree of entrainment based on automated mineralogy size-by-size analysis. The change of entrainment in a rich apatite ore batch flotation with time will describe more precisely by measuring froth properties using a Dynamic Foam Analyzer. It is concluded that the degree of entrainment is not only dependent on particle size but also the pulp density due to its effect on particle settling and also froth properties in varying resistance to particle drainage. Furthermore, entrainment models are applied to predict the effect of size, flotation time on entrainmentINTRODUCTIONFroth flotation belongs to the group of heterocoagulation separation techniques. Froth flotation is classically divided into two active zones, the pulp zone (where particle collection occurs) and the froth zone. A schematics drawing of the interaction between both zones is plotted in Figure 18 (Yianatos and Contreras, 2010). In froth flotation, the collision probability in the collection zone is governed by the physics of the process or hydrodynamics (Wills and Finch, 2016). The true flotation event in the pulp occurs when the hydrophobic valuable mineral particles collide with bubbles and formation of a stable particle-bubble aggregates moving upwards against gravity to the froth phase (Yianatos et al., 2009)."

Jan 1, 2018

By Cheng Wei

Fly-ash was used as adsorbent to remove butyl xanthate from aqueous solution in this study. Adsorption kinetics investigation reveals that the adsorption process abides by the Lagergren-second-order Kinetic Model, and fine fly-ash prepared by grinding has a higher second-order adsorption rate as 1.25 g/mg?min and a higher saturated adsorption amount as 10.92mg/g. Four influencing factors as adsorption temperature, solution pH, consumption of fly-ash and adsorption time were investigated. Testing results indicate that butyl xanthate removal rates declines slightly with the temperature increase within the range of 15-50?, increases slightly when pH rises from 7.27 to 8.01 and then declines from 99.65% to 98.25% when pH rises from 8.01 to 11.10. An enhancement of removal rates can be observed by increasing the consumption of the adsorbing agent or prolonging the adsorption time. Thermal desorption was adopted to regenerate the used fly-ash, and test results show that fly-ash possess good regeneration performance and could be used as adsorbent repeatedly with little influence on the adsorption capacity.

Sep 1, 2012

By L. Tavares

The significant capital and operating expenditure of size reduction operations have maintained comminution on the spotlight of mineral processing research during the last century and, more recently, the concerns about the impact of these operations on the sustainability of the minerals industry, will remain to do so in the 21st century. One of the most popular approaches that have been used to deal with these challenges is the application of simulation both to reduce the uncertainty in the design and improve the operation of size reduction operations. From the initially purely empirical approaches, including the energy size reduction ?laws? and the phenomenological approaches, of which the traditional population balance model is, arguably, the best example, comminution modeling now reached a point in which more fundamental and mechanistic models are sought. The paper analyzes some of the advances that now make multiscale modeling of comminution processes realizable. On the microscale, greater understanding of the phenomena involved in fracture and fragmentation of single particles under different stressing conditions now exists. Particle breakage testing methods are currently used in a routine basis by industry and good quantitative descriptions of different breakage mechanisms are now available, although research is still required to develop appropriate models for a couple of them. On the macroscale phenomena, the discrete element method (DEM) has been successfully used not only to provide insights but also quantitative information on the transfer of mechanical energy from the machine to the grinding media in mills and to particles in crushers, while smoothed particle hydrodynamics (SPH) and computational fluid dynamics (CFD) to describe fluid flow. The paper also analyzes the importance of modeling mesoscale phenomena in size reduction, which is the interaction of particles forming assemblies or beds of particles, demonstrating some of the areas requiring further attention. Examples of application of the multiscale modeling approach to the inadvertent comminution of ore lumps during handling, to the comminution in vertical impact crushers and tumbling mills are demonstrated. Keywords: comminution modeling, DEM, SPH, CFD, multiscale modeling approach

Sep 1, 2012

By G. Dodbiba, T. Fujita, M. Kawata, S. Yamasaki, K. Mitsuhashi, J. Ponou, Y. Iwazaki, T. Atarashi

"The grade of copper ore and concentrate is recently decreasing and it will continues decrease further in the future. The effective liberation treatment for low grade copper ore and the removal of arsenic from copper concentrate is becoming even more important. In this work, the magnetic separation of copper concentrate by heat treatment and the flotation of low grade copper ore by microwave irradiation was studied. The heat treatment of copper minerals in the air atmosphere, the magnetization of most copper minerals increases and especially the magnetization of chalcopyrite shows the largest magnetization, after being heated at 500 oC. The wet HGMS of copper concentrate has been studied and the results have then been compared with the ones when calcined concentrate was used instead. The microwave treatment before ball milling increased the degree of liberation up to 100%, especially when compared with the case when only ball mill was applied to the as-received ore. The flotation of ground copper ore after microwave irradiation showed that the grade copper minerals such as chalcosite and bornite in froth part is much larger than that of tailing part.INTRODUCTION The copper has been used many kind of technological fields and will be more important for the future technology. The global copper production from mine is predicted as shown in Figure 1 (Northey, S. 2014). The copper production peak will be appeared in 2030 and the demand peaks in 2040. In the future the recycling of stocked copper and copper alloy will be necessary to satisfy the demand (Yoshimura, A. 2018). Changes in the grade of copper in copper concentrate, exported from several countries are shown in Figure 2. The copper grade in copper concentrate after mineral processing is gradually decreases every year and it is less than 30% nowadays. On the other hand, the copper ore grade change and prediction are shown in Figure 3. The grade of copper ore is also decreasing to less than 1% in 2010 (Northey, S. 2014). In the future the copper grade gradually decreases, reaching to less than 0.5% in 2080 and the energy to produce the copper metal will increase. The effective liberation treatment for low grade copper ore and the removal of arsenic from copper minerals become more important, nowadays. The microwave irradiation of copper ore for the liberation, energy etc. has been reported by several researchers (for example, Batchelor, A.R. 2017). The magnetization change of copper ore by heating has been reported to remove the arsenic (Sawada, M 2015). In this report, the magnetic separation of copper concentrate by heat treatment and the flotation of copper concentrate by microwave irradiation are discussed after the characteristics of secondary copper minerals are investigated by these treatments."

Jan 1, 2018

By Takashi Furuyama, Sukeyuki Mori, Takafumi Okuma, Norio Hashiguchi

"In order to achieve a high recovery of particles finer than 10µm, three types of dry Tower Mill (VD-1, KD-1, KD-2 and KD-3) have been developed. These mills differ from each other in the size of the comminuting part, the inside diameter and shape of the classifying part and the system involved in the collecting process. The last version (KD-3) of tower mills in which the comminuting and classifying operations has been separated, can produce particles finer than 10µm from a limestone ore sizing from 420 to 3360µm. In this tower mill, products in comminuting section are blown up and transported into the classifying column, made of an inverted cone on top of a cylinder, before they agglomerate and settle down. Fine particles are deported and recovered in a cyclone with a central spiral ribbon.Previous studies on the grinding efficiency of the tower mill KD-3 have shown how the maximum size of collected products increased with the airflow velocity, disturbing in the same way a smooth regulation of the grinding operation with the tower mill KD-3. A complete knowledge of factors that influence the maximum size of collected products is needed, therefore, to increase the efficiency of the grindingclassifying operation and ensure a better control over the collected products. The present study deals with this issue and, assuming that the structure of the classifying column could be one of these factors, its internal structure was modified (insertion of vertical plates, cone or horizontal nets) before carrying out comminution tests that would establish a relationship between the inward shape of the column and the maximum size of collected products. It was found that the weight of products collected in the cyclone decreases when a cone or some horizontal nets are inserted inside the column. At the same time, the weight of products collected in the column increases. This is due to the fact that coarse particles blown up from the comminution section collide with the base of the cone or the nets and settle down the bottom of the classifying column. Therefore, the cone and some horizontal nets inserted inside a classifying column, have the particularity to stabilize the maximum size of particles (15.1-17.5µm and 8.4-11.3µm) in the cyclone even when the airflow velocity in duct increased. These tools could of great help in the production of particles of definite size to fit for instance the paper industries requirements (production of limestone material sizing - 10µm as paper filler)."

Jan 1, 2003

By Francis Pitard

"The optimization of metallurgical processes requires an in-depth understanding of the heterogeneity carried by any constituent of interest. It emphasizes that knowledge of the Theory of Sampling (TOS) is the necessary step to ensure that valuable and valid research programs, pilot plants, feasibility studies, plant design and plant operations have been set on solid foundations. Too many publications today are solely based on the properties of the sample, with no mention of how this sample relates to anything in the environment where it was collected. Unfortunately sampling is an error-generating process that leaves no apparent tracks of its shortcomings. Indeed, it is easier to track down analytical errors than sampling errors. Consequently, bad sampling practices plague the scientific community and the industry and are responsible for severe money losses, unsatisfactory science and processing, and sometimes litigation. A point-by-point strategy is presented addressing sampling problems in early stages of a project. Sampling system requirements for metallurgical accounting and process control are listed. The use of Chronostatistics is suggested to determine if sampling systems are performing satisfactorily and to identify the various types of process variability that may not be easily detected by a conventional inspection of available chronological data. This strategy will help engineering firms, manufacturers, managers and supervisors to provide, install, use and maintain key sampling systems located at very important points in a process. Equipped with the appropriate sampling and statistical tools it becomes easier to minimize reconciliation problems with the mine, with suppliers and with clients. Contrary to the beliefs of many people, good sampling systems are not expensive because in the long run they help to reduce hidden cost and better regulate plant productivity; they most certainly minimize the number of unnecessary meetings looking for solutions where there are none. The suggested strategy will help specialists to extract maximum information from the available data, as large investments and crucial decisions depend on it."

Jan 1, 2014

By B. Y. M. Bueno

Biosorption of heavy metals can be an effective process for the removal of heavy metals ions from aqueous solutions. In this study, the adsorption properties of Rhodococcus opacus biomass for Pb(II) and Cu(II) ions was investigated. The effects of initial pH, initial metal concentration and biomass concentration on biosorption efficiency were studied in a batch system. Results showed that the initial pH would play an important role in the Pb(II) and Cu(II) ions removal by R. opacus and affected the zeta potential of R. opacus. The equilibrium adsorption was reached with 60 min. The Langmuir and Freundlich models were used for describing of adsorption isotherm data. The maxi-mum adsorption capacities of biomass were determined as 94.3mgg-1 and 32.2 mgg-1 for the Pb(II) and Cu(II) ions, respectively. The experimental data fitted to pseudo second order kinetic model. Adsorption capacity of Pb(II) ions was found to be reduced by the presence of the other competing metal ions in the system. The FT-IR results of R. opacus biomass showed that biomass has different functional groups and these groups are able to react with metal ions in aqueous solution.

Jan 1, 2014

By Gjergj Dodbiba, Toyohisa Fujita, Li Pang Wang, Masashi Yamane

"The platinum-group metals (PGMs), are currently receiving worldwide attention as they have major industrial uses. PGMs, i.e. ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), and platinum (Pt), are widely used as catalysts in petroleum and chemical processes. In addition, they find wide applications in automotive exhaust-gas control converters and are of immense importance to the electronic industry. Broadly speaking, PGMs are extracted in minute quantities from a limited number of ores, found mainly in South Africa and Russia. As the PGMs are both costly and almost indestructible, they are usually recycled from various forms of scrap. In other words, the recycling of the PGMs is an essential factor in the overall management of the PGM economy. In addition, the ever-increasing user areas have created renewed interest in the search for new sources or deposits of PGM, which in turn requires an in-depth knowledge of its characteristics. In this work, the emphasis is placed on the need to analyze the composition and microstructure of blast-furnace slag for recovering PGM metals. In other words, chemical composition, surface analysis and microstructure analysis of the DC arc furnace slag have been carries out. The aim is to provide a detailed analysis of this material for anyone with an interest in gaining further knowledge of its specific content for recovering PGMs."

Jan 1, 2014

By S. Vimalnath

The bioremediation capability of Pseudomonas aeruginosa cells was investigated for the biosorption of lead ions from aqueous solution. The various parameters such as pH, kinetics, biomass loading and concentration of lead affecting the biosorption process were studied. Complete bio removal of lead could be achieved for an initial concentration of 12.4 mg/L at pH 6.2, corresponding to typical industrial effluents. The biosorption isotherm followed Langmuirian behavior and the Gibbs free energy (?G) was determined to be-30.8 kJ/mole, indicative of chemisorption between the functional groups of the bacterial surface and lead. The biosorption kinetics adhered to a pseudo-second order model. The possible mechanisms of interaction of lead with the bacterial cells are discussed. A carbon paste electrode with a coating of biomass was developed for lead ion detection in aqueous solution using cyclic voltammetric technique. Concentrations of lead up to 5x10-5 M could be successfully detected using cyclic voltammetry, which could be improved to a detection limit of 1x10-8 M adopting differential pulse anodic stripping voltammetry (DPASV). Keywords: Pseudomonas aeruginosa, bioremediation, lead, voltammetry

Sep 1, 2012

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, M. Zare

High Pressure Grinding Roll (HPGR) plays a major role in increasing specific surface area of iron ore concentrate for producing pellet feed. HPGR grinding mechanism implies that material be compressed between the two rolls, therefore layer of material must be able to resist required pressure for achieving suitable grinding conditions. In this study for determining a simple relationship between material pressure resistance ability and HPGR main design parameters, piston press tests were performed on different iron ore concentrate samples along with HPGR Blaine increasing tests. Piston press tests results showed that by decreasing moisture content, material pressure resistance increased and in constant moisture content this parameter will change based on material specifications. HPGR Blaine increasing tests results showed that by decreasing moisture content, HPGR specific throughput and working gap increased and in constant moisture content this parameter will change based on material specifications. For all of the studied samples at worst condition, we got the results including: HPGR delta gap equal to zero, specific throughput lower than 200 ts/hm3.According to the tests results, HPGR Applicability Index (HAI) can be introduced at four different class types from 1 (weak) to 4 (excellent). This index determines achievable specific throughput and possibility of using HPGR according to material specifications, i.e. for HAI 1-4 the pressure resistance is <90, 90 to<125, 125 to <150 and = 150 bar, respectively. Similarly for HAI 1-4 specific throughput is <200, =200, =220 and =250, respectively. So based on design moisture content, if concentrate HAI is 3 or 4, HPGR is a correct choice. For HAI 2, HPGR can also be used. But for a material with HAI equal to 1, HPGR is not a good solution. As a result in order to apply HPGR for HAI 1, material condition such as moisture or slime content should be decreased.

Jan 1, 2018

By R. Chowdhury

Axis House manufactures and supplies alkylhydroxamate reagent of various carbon chain lengths for application in flotation of oxide copper and other minerals. As part of reagent performance improvement the structural factors of hydroxamate are examined by various analytical tools in particular with X-ray diffraction of single crystals. In a recent publication, the structure of n-octylhydroxamic acid and its corresponding potassium salt are presented with findings of hydroxamic functional group geometric preference, H-bonding, keto-enol tautomerisation, acid-salt aggregation and alignment of carbon chain. In this paper an example of branched alkylhydroxamate 3, 5, 5-trimethylhexylhydroxamate will be presented and compared with the result of linear alkylhydroxamate.

Sep 1, 2012

By G. Aguilera

The mineral suspensions do not present a newtonian behavior as their continuous phase; they can be pseudoplastic, dilatant, or both. The viscosity becomes as the most important rheological variable because the different industrial processes involve a wide variety of rheological scenes, with a specific rheological behavior for each one. Some authors have tried to model the viscosity of suspensions considering the volumetric fraction of solids and others have also kept in mind the size of the particles (Einstein, 1906; Batchelor, 1977; Jinescu, 1974; Krieger and Dougherty, 1959; Tangsathitkulchai and Austin, 1988). Others consider the shear rate (Cross, 1965; Hershel-Bulckley, 1926; Bingham, 1916, etc). However, none of the models is able to simulate the viscosity involving the physical, chemical and mechanic factors at the same time for crowded suspensions. A new model based on Neural Networks is presented, taking into account all the variables of ceramic clay suspensions and chemical additives. Keywords: viscosity, clay minerals, neural networks, simulation, mathematical function

Sep 1, 2012

By Rogerio C. Guimarães, Antonio E. C. Peres

The production of phosphate concentrates (phosphate rock) from slimes represents a challenge to the phosphate industry worldwide. In Brazil, this challenge is particularly relevant due to the consistently low P2O5 grades and the igneous origin. The first industrial experiences of producing phosphate rock from slimes (-44µm or -325#) fraction started at Arafertil, currently Bunge Fertilizantes SA, in Araxá, in the 1980.s. This production corresponds, nowadays, to 35% of the total production of concentrates in the company (830,000t/year) in a circuit consisting of desliming in 40mm microcyclones and concentration in flotation columns, corn starch and fatty acids being utilised as reagents. The performance of slimes flotation and the process control, at Bunge´s concentrator, were improved after the introduction of column flotation technology, in the first half of the nineties. The column flotation technology for slimes recovery was expanded to other Brazilian concentrators still in the nineties: Ultrafértil (Catalão - GO), Bunge (Cajati - SP), Fosfértil (Tapira - MG) and Copebrás (Catalão - GO). At present the Brazilian production of phosphate rock is approximately 4.5Mt/year, with a strong trend for a market increase. Genuinely Brazilian technology is utilised for the processing of slimes, the concentrates representing 11 to 13% of the overall production. The production of apatite concentrates from slimes was relevant to increase phosphate recovery and reduce costs, contributing to the growth of the fertilisers industry.

Jan 1, 2003