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By J. R. Levin, E. J. Schelter

"We present some of our recent efforts in the development of predictive, directed oxidation chemistry of cerium(III) complexes under non-aqueous conditions. The electrochemistry of cerium(III)- alkali metal heterobimetallic aryloxide complexes is reported and compared with cerium aryloxide complexes that are kinetically stabilized by hydrogen bonding cations that span between the complexed aryloxide ligands. Comparative electrochemical measurements reveal differences between the heterobimetallic complexes and the hydrogen-bonded complexes.INTRODUCTIONThe rare earth elements comprise the lanthanides, La–Lu, and the element yttrium (Aspinall, 2001). Rare earth ores such as monazite, LnPO4, and bastnäsite, LnFCO3, typically bear mixtures of light rare earths: La–Sm while monazite, LnPO4, contains mixtures of heavy rare earths (Eu–Lu) (Cotton, 2006). Pure rare earth elements typically are isolated using a liquid-liquid separations process.(Bautista, 1995) The hydrometallurgy of these elements is a difficult problem because the separation factors between neighboring rare earths, which are predicated on the small differences in the sizes of the trivalent ions, are quite small (Cox, 1992). The element cerium, with its 4f1 electronic configuration in the trivalent state, is unique among the rare earth elements due to a relatively accessible 4f0 electronic configuration. The accessibility of the 4f0 configuration underlies the chemistry of cerium(IV), the only rare earth ion with molecular chemistry in the tetravalent oxidation state (Cotton, 2006). Cerium is trivially separated from mixtures of light rare earths by making use of its unique oxidation chemistry. In an effort to extend separations chemistry by oxidation reactions to other rare earth elements such as terbium and praseodymium, the solution electrochemistry of well-defined cerium complexes is of interest."

Jan 1, 2012

By W. Dingley, G. R. Hoey

"Thirteen Canadian sulphide ore mines were surveyed for corrosion control. The mines visited were a small, yet representative, proportion of this segment of the Canadian mining and metallurgical industry. Information on metallic corrosion and methods used to control it in underground workings and mills was gathered (a) by discussing corrosion problems with company personnel, (b) by examining equipment and structures during under-ground and mill tours, (c) by photographing corrosion sites, and (d) by collecting and analyzing mine water samples.The corrosion survey, which is summarized in the re-port, leads to the following general conclusions. Mine environments are corrosive, particularly when the mine w1a-ter is acidic. Because of a lack of good corrosion control measures, excessive deterioration of equipment due to corrosion occurs in mines. Mill environments are also corrosive, but in some cases good preventive measures are being taken to effectively control corrosion losses.Ways to reduce corrosion losses in sulphide ore mines and mills are discussed. The main areas for more corrosion research and development are selection of materials of construction, protective coatings, cathodic protection, inhibitors, equipment design, and mining and milling practices."

Jan 1, 1971

By Rick Wilkins

The stability of steep embankments is a major safety issue in open pit mining, highway passes, and earth filled dams. A failure in any one of these situations could mean a loss of very expensive equipment, a long term inconvenience, and more importantly, a loss of life. These possible catastrophes could be avoided by installing a reliable real time monitoring system. Robotic total stations (RTSs) give one possible cost effective solution to creating a near real time monitoring system. Repeated surveys at predetermined time intervals can automatically generate warnings if slope movements exceed a preset tolerance level. The variation in atmospheric refraction, combined with possible instabilities in reference targets, can make a monitoring system based on RTSs produce false alarms. A methodology has been developed at the Canadian Centre for Geodetic Engineering (CCGE) for reducing these systematic error effects. The methodology has been realized in the creation of a software package that has been successfully implemented at large earthen dams in California and at an open pit mine operation in British Columbia.

May 1, 2002

By Geoffrey C. Streeton

A continual objective of mine operations is to reduce ground control costs without compromising the overall safety or performance of the installed ground support. Any change in the ground support regime must not result in a less secure or safe workplace. The due diligence required to implement a change in rockbolting practice is extensive, particularly when the new bolting system has not been used at any other mining operation. Factors such as yield, shear strength and embedment strength must all be investigated to gain an understanding of how the rockbolt can be expected to perform. This paper also discusses the substantial cost reductions and efficiency gains which can be achieved through the introduction of the Jumbolt rockbolt.

May 1, 2001

By Andrew Cormier

"The Early YearsThe Grand Lake coal fields in New Brunswick undoubtedly can claim the distinction of being the first part of North America from which coal was mined and exported. The diaries of the Governor of Massachusetts during the first half of the 17th century clearly establish this fact. There is also a reference in the Massachusetts Colonial Records which indicate that coal exports to New England were carried on as early as 1639.It has generally been believed that Cape Breton mined and exported the first coal; but no account has yet been found to show that this took place earlier than 1676. Both at Grand Lake and Cape Breton the coal was near the surface and removed by hand.When the country passed entirely into British control, Joseph Garrison, a grantee of Maugerville in 1765 moved to Jemseg. While surveying the north side of Grand Lake he discovered outcroppings of coal on the shore of the lake and further inland along the banks of streams. It was he who named Newcastle Creek in reference to Newcastle in England, which was widely known for its coal mines. Joseph Garrison died in 1783, the same year that an influx of United Empire Loyalists increased settlement in Newcastle Creek in the area now known as Minto. Many Loyalists also settled on the shores on both sides of Grand Lake.At a number of points where streams cut channels through the overlying strata, the coal seams were exposed and it was at such outcroppings that the early operations were carried on. A tunnel was driven in the seam from the foot of the bank, affording both an outlet for the coal and natural drainage from the workings. The coal was loaded into boxes and wheeled over wooden tracks to a point on the surface where it could be dumped into wagons and hauled either direct to destination or to where it could be loaded into boats and conveyed via Grand Lake, Jemseg and Saint John river to points of distribution.In the latter part of the 18th century and first years of the 19th century, farmers were undisturbed by mining the coal found on their lands. This was soon to change and resulted in many years of contention between landowners and the Legislative Assembly.New Brunswick became a separate province from Nova Scotia in 1784 and the seat of government moved from Saint John to Fredericton in 1788. The new province had its first priorities; the establishment of counties, the building of roads, and the development of its natural resources. From 1805, records of coal and land development are fairly complete. These records show the increasing interest of the Province in developing the coal fields. This interest resulted in the granting of coal leases to many friends of the government, without any regard for the wishes of the farmers who owned and had occupied the land for many years. The farmers fought back with lawsuits and other forms of dissension but with little success. By the end of the 19th century there were very few farm operators left in the area."

Jan 1, 1992

By R. Kong, X. W. Zhang

"High pressure (up to 50 MPa) isotropic compression tests were performed on marble, gneiss and sandstone specimens, of which represents the typical rocks, to investigate isotropic compression deformation characterization at room temperature. Experimental data with respect to volume change in loading and unloading are presented. An apparent volume change inflection point (sensitive stress) was observed at a lower pressure range for porous sandstone, indicating that the elastic-plastic behaviour arising in the isotropic compression stage, but for tight crystalline rock, the sensitive stress is much higher, not probed prior to 50 MPa. The irrecoverable volumetric strain in the unloading can be seen for sandstone as well. The anisotropic deformation was discussed in terms of the axial and radial strain measurement. It was found that essential features of mechanical anisotropy are the irreversible in deformation range. The deformation feature in the isotropic compression tests is a very complex issue due to the factors concerning the stress history, unloading in sampling and in-situ stress. INTRODUCTIONThe isotropic or hydrostatic compression condition that stress is compressive and has the same magnitude for all direction, which is expressed as s1=s2=s3 in principal stress space. A yield locus of soils subjected to the isotropic and anisotropic compression was widely known, for instance Cam Clay model, which forms a closure cap model. However, the similar isotropic compression yield curves for rocks, especially for hard rock, was not established due to the geo-stress in the rock mass is much less than the socalled isotropic yield stress. And hence, the previous experimental studies on the hard rock have been made tend to on the stress-strain-strength relationship (Handin & Hager, 1957; Edmond & Paterson, 1972; Menéndez et al., 1996). Perhaps the yield curves related to an increasing in the hydrostatic pressure is not forced to construct for hard rocks, undoubtedly, the deformation data in this processing is valuable to assess the bulk module (Fabre & Gustkiewicz, 1997), anisotropy (Niandou et al., 1997), field stress (Hakala et al., 2007). Furthermore, many rocks store much elastic volume strain energy link to the hydrostatic pressure exerted, following a deviator stress applying, to drive the unstable brittle fracture for hard rock. Latter was studied to interpret the incentive of rock burst. However, volume change characteristic in the isotropic compression behaviour have been scarcely studied experimentally to our knowledge, less application related to the fracture in hard rock as well. The mechanical behaviour in the isotropic compression of hard rock is notably affected by the original structure anisotropy, stress history and stress condition before sampling, all of which need reasonably assess. It is also a useful understanding to study isotropic compression that elastic and plastic volume change in the isotropic loading and unloading, and the micro crack evolution throughout it."

Jan 1, 2015

By A. J. W. Law

"This paper deals with the organization of the central office technical areas and the role played during the feasibility studies, construction and operating phases of Les Mines Selbaie.HistoryThe Engineering Department was originally formed as a part of the Exploration Department, to examine the feasibility of advanced exploration prospects being brought to the company. In 1968, with the discovery of the South Bay property in northwestern Ontario, the department became part of a Mining Division and was expanded, so that it could provide more advanced mine feasibility studies, control of construction engineering and procurement and initial mine design. As is generally the case, the mine design function was handled with in-house capability, while plant, mill and const ruction functions used outside consultants.The 1974 discovery of the Selbaie deposits, started a period o f growth in the capabilities o f the department. The complex nature of these deposits, required that skills were added in the mining, metallurgical and plant areas. During the early feasibility study period these skills were provided by the engineering company of the parent group, but when it was realized that production from the deposits was likely, permanent staff was added."

Jan 1, 1990

By T. Hofbauer, M. J. Dry, G. B. Harris, C. W. White

"Urban Mining is a term that is increasingly being used, and represents an appreciable source of secondary materials for the metals extraction industry, a source that does not incur mining costs, but does, at present, incur considerable disposal costs. Electric Arc Furnace Dust (EAFD) is probably the most common of these materials, with an estimated global production of 8 million tonnes annually, of which 1 million tonnes is generated in North America. The contained annual metal value in EAFD at current prices is of the order of $6 billion, yet, apart from the zinc, virtually none of this is recovered.Despite many attempts over the years, with pyrometallurgical, hydrometallurgical or hybrid processes, currently the only commercially viable method of treating these materials is smelting in a Waelz Kiln (or a Rotary Hearth Furnace), which essentially recovers only the zinc, in an impure oxide form, and generates a secondary slag waste, which is still toxic and requires disposal. This paper describes the development of a chloride-based treatment process to recover all components of the EAFD in a marketable form, which centres around the novel hydrochloric acid recovery and recycle operation. Laboratory, miniplant and pilot plant data are presented, leading to the definition of a viable process flowsheet enabling the recovery of pure iron and zinc products (the principal components of EAFD), together with secondary products such as copper, silver, lead, cadmium, magnesium and manganese. A rigorous mass-energy balance is used to examine the preliminary economics involved."

Jan 1, 2014

By E. C. Morton

The Western Australian School of Mines (WASM) has developed a facility for the static testing of large scale ground support elements. The samples are loaded using a mechanical screw feed jack. Instruments measure the displacement and the load being applied. Methods have been developed for testing of mesh, shotcrete and membranes. Mesh samples are restrained on all sides and loaded centrally. A new large scale punch test method has been developed to evaluate shotcrete and membranes. These products are sprayed on to a sandstone substrate containing a centrally located isolated disc. The sprayed product is loaded by displacing the disk. The different test methods are described in detail. The test program involved two types of mesh, several shotcrete mix designs with different curing times and one membrane product. The force-displacement responses are used to directly compare the products. The implications for implementation of the different ground support products are discussed.

May 1, 2009

By N. C. Clarke, T. Wu, M. le Page, K. J. Henley

In 1994, Gold Mines of Australia acquired the rights to the historic Mt. Lyell copper mine, and commenced a feasibility study into expanding production. The ore was shown in laboratory tests to be amenable to single-stage, fully autogenous grinding (FAG) of underground primary crushed ore, and this route offered the maximum cost savings. Flotation performance was expected to be enhanced. However, batch flotation tests done on pilot-scale autogenously ground ore showed an unexplainable recovery loss of between 1% and 3% Cu. A second pilot plant trial was set up, with the ground product feeding banks of continuous flotation cells. Single-stage FAG, FAG/pebble and FAG/ball circuits were tested. Results confirmed a loss of about 3% recovery with single-stage FAG milling. The FAG/ball circuit eliminated the loss. Analyses showed that autogenous milling probably produced more chalcopyrite/pyrite composites and that recovery of these composites was lower than with ball milling. In size fractions below about 53 microns, where chalcopyrite is well liberated, copper recovery was less affected by milling method and flotation selectivity. It was concluded that for the Mt. Lyell situation, a FAG/ball circuit was preferable to single-stage FAG.

Jan 1, 2002

By Francis Chachula, Niel Erasmus

"In 2002, Titanium Corporation Inc. focused its attention on the development of a process for the recovery of valuable heavy minerals, including zircon and titanium bearing minerals from oil sands froth treatment tailings. The development of a process flowsheet to recover the titanium and zircon minerals from the Athabasca oil sand tailings has evolved through many laboratory, bench and pilot scale iterations.Initial development work focused on so-called ‘beach sand’ material, which is tailings material deposited over a period of time close to the tailings pipe discharge. The derived process flowsheet primarily consisted of gravity concentration stages, which is typical of all mineral sands operations. Titanium Corporation’s business plan calls for the utilization of tailings directly from the tailings pipeline – the process developed around the beach material is therefore risky as it differs from the live tailings in a number of aspects, with the effects on the process unknown. Titanium Corporation successfully obtained an intermediate product through a ‘bulk sampling plant’ coupled directly to an Oil Sands operator’s froth treatment tailings pipeline, during the summer of 2005. Subsequent further processing of this material resulted in poor separation or concentration of the heavy minerals due to a number of reasons. A more effective process flowsheet had to be developed.The newly derived process is basically a marriage between mineral sands technology and oil sands technology that can economically concentrate and recover the heavy minerals and entails the incorporation of a flotation process that takes advantage of the entrained bitumen in the feed to separate the heavy mineral fraction from the quartz gangue This paper will describe the newly derived process as well as the successful results of a subsequent on-site concentrator pilot campaign completed during the 3rd Quarter of 2006."

Jan 1, 2008

By G. Cordingley, A. Mwanza

Lumwana is an open pit Copper mine located in the Northwestern Province of Zambia approximately 80 km west from the provincial capital of Solwezi, approximately 300 km northwest from the Copperbelt and 700 km northwest from the national capital of Lusaka. The mine has two major Copper deposits: Malundwe and Chimiwungo. Copper mineralization includes Chalcopyrite, Bornite and Chalcocite. In addition to Copper, these deposits also contain the undesirable element Uranium contained in vein hosted and disseminated Uranite. The processing plant was designed using conventional technologies: semi-autogenous grinding (SAG) and ball mill for grinding, and mechanical cells for rougher and cleaner flotation. Soon after commissioning in early 2009, it was recognised that two stages of conventional cleaning were unable to produce plant final Copper concentrates with the desired Uranium grades. Studies have shown that a significant quantity of liberated and fine Uranium particles (up to 80-90%) is recovered with the concentrate by entrainment. Lumwana Operations sought the use of the Jameson Cell technology after observing successful implementation at other sites in rectifying similar issues. In late 2009, Jameson Cell pilot-plant test work was conducted at the site and this quickly led to the installation of a full-scale B5400/18 model into the existing cleaner circuit. Inclusion of the Jameson Cell resulted in the plant being able to effectively produce clean and saleable concentrate with Uranium contents consistently below acceptable levels. Initially designed to be used as a cleaner scalper cell at the head of the existing conventional cell circuit, subsequent operational issues with the existing recleaner cells forced reconfiguration of the cleaner circuit and reintroduced the Jameson Cell for the recleaning duty. This paper reports the Lumwana Operation from the first two years of operation where it struggled to produce a saleable concentrate with Uranium grades below 150 ppm, which is the maximum allowable limit set out in the smelting contracts, to steps taken in the subsequent years to implement a satisfactory solution. The plant can now consistently produce a clean Copper concentrate with Uranium grades well below 130 ppm and the overall improvements implemented at site have seen the overall plant recovery improve by 1.3%.

Jan 1, 2014

By Michael L. Free, Shukla. Abhijeet

The short-circuiting tendency of a copper electrowinning cell (EW) based on the roughness of cathode deposits was investigated with varying parameters such as Cu concentration, guar concentration, current density, and temperature. A bench scale EW cell was set up to produce copper under conditions similar to industrial Cu EW. In addition, a statistical analysis and finite element analysis were performed to analyze the deposited thickness, surface roughness and maximum feature height. Interaction data for the cathode deposits suggest that current density and Cu concentration together affect the roughness of deposit more than the combined effect of guar and temperature. Model predictions of roughness were similar to experimental values. The predicted time to short-circuiting was similar to the measured time. This study provides an industrial relevant baseline against which new operating parameters can be compared.

Jan 1, 2014

By S. A. L. Read

"The intact rock constant, mi, is one of the three basic input parameters required for the widelyused Hoek-Brown failure criterion. Values for the constant should ideally be determined by statistical analysis of laboratory test data. In this paper the influence of the inclusion or exclusion of tensile test data on derived values is discussed. We firstly investigate the relationship between direct tensile strength (DTS) test values and Brazilian tensile strength (BTS) test values based on a literature search, finding that the correlation between the two test types is DTS = 0.9*BTS, independent of the lithology being tested. Secondly, using the shear strength database of Douglas (2002), we examine the influence of confining pressure range and the inclusion or exclusion of DTS and BTS test values on calculated values of mi.Chief amongst the influences was the exclusion of tensile data in the calculation procedure, particularly when the Hoek triaxial confining stress range requirement (?3?max = 0.5?c) was not satisfied. Based on a reasonable 1:1 relationship between R (the ratio of unconfined compressive to tensile strength), use of actual tensile data in the calculations for the Hoek brown failure criterion is considered to be a simpler and more robust approach to the use of a tensile cutoff based on empirical criteria such as that of Fairhurst (1964). We advocate the fitting a failure curve using compressive and tensile test data as the most reliable means of calculating mi, while at the same time satisfying requirements as originally advocated by Hoek relating to the appropriate triaxial confining stress range (?3?max = 0.5?c) and sufficient (>5) evenlyspread data points. In the absence of triaxial data the use of R provides a practical means of obtaining estimates of mi that are more robust than guideline values."

Jan 1, 2015

By Alf Hartling

"Most of the Paleozoic section of the Williston Basin is a thick accumulation of numerous carbonate to evaporite, shallowing upward, cyclic sequences. These sediments were deposited in broad epeiric seas, and the deposition of the evaporite facies marked the final stage of each cycle. Many of the sequences display a pervasive replacement dolomite in the uppermost portion of the carbonate units. This secondary dolomitization is, at least in part, an early diagenetic event, synchronous with evaporite deposition.The inception of evaporite precipitation resulted in the seepage of a dense, Mg-rich brine into the underlying sediment. The heavy brine moved down the gentle regional dip displacing the more normal marine interstitial pore fluid and dotomitized the primary calcitic sediments en route. The supply of Mg-ions decreased away from the source, and correspondingly, the degree of dolomitization decreased and larger crystals formed because of slower nucleation at fewer sites.The seepage refluxion of dolomitizing brines gave rise to the frequently observed textural variation of cryptocrys talline, impervious dolomite grading into a finely sucrosic, permeable dolomite down-dip. This diagenetic facies change provides the critical up-dip barrier for potential hydrocarbon reservoirs. The lateral pool boundaries are controlled by either structural relief or a similar diagenetic facies change. The reservoirs are capped by the tight evaporites.Hydrocarbon production is attained from diagenetic traps in the Mississippian Oungre Zone and the Ordovician Red River 'C' Zone . Reservoir creation and the pooling mechanism are the result of dolomitization by the seepage refluxion of dense, Mg-rich brines beneath restricted, hypersaline lagoons. When formulating an exploration/ exploitation program for these oil prone horizons, it is essential to understand the complete geological history in order to establish where the reservoirs will be found and to define the areal extent of each accumulation."

Jan 1, 1984

By C. Chapman, P. Cowx

"INTRODUCTIONTetronics Research and Development Co. Limited has installed several plasma torches for steel heating in continuous caster tundishes. An extensive demonstration program on a 14 tonne tundish reported the following advantages of plasma heating.• close control of steel temperature to ± 5°C;• a reduction of the furnace tapping temperature of up to 20ºC, leading to savings in energy and refractories costs ;• improvement in steel quality, to produce a slab product with an equi-axed crystal structure and a reduced number of large sub-surface slag inclusions;• the virtual elimination of oxygen pickup in the tundish; and• the capability of making ferroalloy trim additions to the tundish to permit a change of steel grade during casting, greatly decreasing inventory costs.The Need for Tundish HeatingIn the continuous casting of steel, the function of the tundish is to transfer the molten metal between the ladle to one or more continuously fed casting moulds. Figure I shows a typical temperature profile of molten steel in the tundish over the first cast cycle. It is observed that a rapid drop in temperature occurs both at the start of the cast, due to the tundish refractories absorbing heat, and also during ladle changeover. In addition, as a result of thermal losses through the ladle sidewalls, there is a gradual decline in the bulk steel temperature over the entire heat cycle. Consequently, in normal tundish operation, it is necessary to cast with a high superheat (25°C to 30°C + above steel liquidus temperature) in order to prevent freeze-up of the strand. Problems of high temperature variation and the potential of the steel solidifying in the tundish are greater for small caster units of low thermal mass . A high steel superheat increases the steelmaking vessel process time and refractory wear and prevents the formation of a uniform equi-axed solidification structure in the cast steel, resulting in centre line segregation and porosity. The large drop in the casting temperature that occurs during unsteady state operation causes an increase in the number of sub-surface inclusions, reducing the value of the product. Accordingly, plasma heating may be employed to maintain the molten steel at an optimum temperature to produce a slab of consistent quality."

Jan 1, 1989

By B. A. Monkman

"IntroductionONE OF :THE most effective methods by which the construction industry is combatting mounting building costs is by making increased use of lightweight materials, thus reducing the dead load to be carried •by structures. This applies to non-metallic materials as well as to metallic ones, and particular attention has been given to developing lightweight aggregates for use in concrete.The use of lightweight aggregates is not new and, in fact, dates back to the Roman Empire, when pumice was used in the walls and domes of the Roman buildings. More recently, and up to a decade or so ago, the demand for these aggregates was met from deposits of volcanic cinders, pumice, scoria, etc., and from the by-products of blast furnaces and coal burning boilers. However, these sources of supply are no longer sufficient to meet the demand, for transportation costs pretty well restrict the use of the natural lightweight aggregates to the western cordillera regions where the deposits of these materials occur, and the use of expanded slag aggregates to the areas neighbouring the plants where slags are produced. As for cinders, the supply has been greatly reduced by the conversion of industry to fuel oil, natural gas, and powdered coal, and the large stockpiles which existed previously have been pretty well exhausted.Industry's approach to the problem of a decreasing supply, in the face of an increasing demand, has been characteristically direct. The solution has been to construct plants whose sole .purpose is to produce economically an acceptable light-weight aggregate from materials close at hand."

Jan 1, 1955

By E. M. Cameron

Reconnaissance radiometric and geochemical data have been obtained for an area on the western shore of Wollaston Lake that includes the Rabbit Lake uranium deposit. The study area is extensively drift cover ed. The geochemical data were obtained by analysis of center-lake sediments and surface waters for a variety of elements and other constituents. The airborne radiometric data comprise measurements of eU, eTh and K obtained with a .50,000-cc NaI (Tl) detector at a mean terrain clearance of 120 m and 5-km flight-line spacing. Uranium in lake sediments and uranium in waters are the most effective geochemical indicators of uranium mineralization; the other elements measured are not notably anomalous. A sample site density of one per 1 8 km 2 is more than adequate for identification of the mineralized area. Because many water samples contain close to or below the current analytical detection limit of 0.05 ppb U, the use of sediments is generally favoured. for broad-scale reconnaissance in the region. Uranium in these lake sediments appears to be little influenced by variations in the organic or iron and manganese content. The most effective radiometric indicator of the mineralization is the eU/eTh ratio. This parameter is less influenced by environmental variation on the ground beneath the flight line than eU alone . The eTh/K ratio is anomalous under the Athabasca Formation unconformity where, in places, the uranium mineralization is localized.

Jan 1, 1977

By M. B. Kime

"A set of experimental batch leaching tests studied the effect of pH, time, temperature, and stirring speed on the relative Cu, Co, Ni, and Fe leaching yields of an oxidized copper-cobalt ore sample in an aqueous hydrochloric acid solution. The results were statistically analyzed and modelled using the structural equation modelling method. Models showed that Cu, Co, and Ni leaching yields were strong functions of the leaching time and leaching temperature, whereas the Fe leaching yield depended on the leaching temperature, stirring speed, and pH. Under optimum leaching conditions yields were 99.8% Cu, 82.4% Co, 91.3% Ni, and 30.6% Fe.RÉSUMÉ Une série d’essais expérimentaux de lixiviation en bâchée ont été menés pour étudier l’effet du pH, de la durée d’attaque, de la température et de la vitesse de brassage sur les rendements relatifs de lixiviation du cuivre (Cu), du cobalt (Co), du nickel (Ni) et du fer (Fe) d’un échantillon de minerai de cuivre-cobalt oxydé dans une solution aqueuse d’acide chlorhydrique. Les résultats ont été analysés et modélisés statistiquement à l’aide de la méthode de modélisation par équation structurelle (SEM, de l’anglais structural equation modelling). Les modèles ont montré que les rendements de lixiviation du Cu, du Co et du Ni dépendaient énormément de la durée d’attaque et de la température de la lixiviation ; le rendement de lixiviation du Fe, quant à lui, dépendait de la température de la lixiviation, de la vitesse de brassage et du pH. Dans des conditions optimales de lixiviation, les rendements étaient de 99,8 % pour le Cu, de 82,4 % pour le Co, de 91,3 % pour le Ni et de 30,6 % pour le Fe."

Jan 1, 2017

By C. J. Edmonds, R. Bland, W. C. Ferguson, R. Whitehead

"In 1969, the Environmental Science Division of James F. MacLaren Limited received authorization from The International Nickel Company of Canada, Limited to carry out a water quality monitoring program in the Lake Shebandowan region of Ontario, where a new base metal mining and milling complex was expected to go into operation in 1972. The objective of the program is to establish base-line water quality characteristics. Fully realizing their corporate responsibility to minimize the effects of the proposed activities on the environment, Inco decided that it would be desirable to establish a program by which any change in the quality of environmental waters will be detected before detrimental conditions ensue, permitting prompt corrective measures to be taken. The program has been in progress for over two years. The waters are sampled and analyzed four to six times per year. Sampling stations are located in Lake Shebandowan and on the adjacent Gold Creek - Matawin River system. On-site analyses and measurements are made of flow, dissolved oxygen, temperature and pH. Samples also are collected for later analysis in the laboratory. These samples are analyzed for a wide range of chemical and biological characteristics. The paper discusses the extent of the sampling program, the techniques utilized and the value of such programs in maintaining the quality of the environment."

Jan 1, 1973