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By René G. del Villar, Jules Thibault, René del Villar

"Some key control variables of industrial processes, associated with product quality, often cannot be measured directly or frequently enough to establish adequate control. In such cases, it is possible to use available measurements to provide a prediction for these process variables and use them in a control strategy, thereby giving rise to what is now commonly called a softsensor.In some industrial grinding circuits, the on-line particle size analyzer is shared between various sampling points. Therefore, for a given location, the actual measurement is only available every 10 to 20 minutes, a delay which is unacceptable for automatic control purposes. To alleviate this problem, a softsensor based on an artificial neural network has been investigated. First, the structure of the neural network and different schemes for the training process are analyzed. Then, the performance of the neural network softsensor is compared with other inferential methods such as ARMA models and Kalman filters.IntroductionGRAHM, French acronym of the Research Group on Computer Applications in the Mineral Industry at Laval University, began in 1990 a research project on Knowledge Based Automatic Control (KBAC). This project, sponsored by a consortium of eight mining companies and the federal and provincial governments, seeked to screen advanced (knowledge-based) methods for data processing (filtering, mass balancing, etc) and automatic control (model-based) for their use in the mineral processing operations and the transfer of the project results to the sponsor companies.In parallel to more academic research work, a number of case-studies have been undertaken with the cooperation of partner companies. Among such works, a very successful one has been the design and installation of a new control strategy for one of the Kidd Creek (Falconbridge Ltd.) grinding circuits. This project was related to the evaluation of a number of control strategies and the implementation of one of them, as selected by the plant management, in the concentrator.A total of sixteen control schemes were evaluated on one of the dynamic phenomenological simulators developed at GRAHM, a trademark of this research group [ l]. The calibration of the simulator models was done based on industrial data gathered by GRAHM and Kidd Creek personnel. Then, the simulator was used to test the performance of various PID-based control schemes, designed to achieve the control objectives set by the Kidd Creek personnel. The best scheme proposed called for controlling the cyclone overflow particle size by manipulating the water addition rate to the cyclone feed box and the circulating load by manipulating the circuit ore feed. The particle size analyzer (PSI-200) available for monitoring the product size, was unfortunately shared (multiplexed) among various streams of the plant, which meant a 14 min delay between two consecutive readings for any particular stream. This induced the plant personnel to choose an alternative control strategy, one which controlled the cyclone feed density instead of the cyclone overflow particle size."

Jan 1, 1996

By Erik C. Westman

Knowledge of the orientation and relative magnitude of in-situ stresses at the mine scale is important for safe and efficient production from an underground mine. With this knowledge, stope location and scheduling can be optimized. Passive seismic tomography was used for imaging horizontal stress distribution at the mine scale. Microseismic measurements from the Creighton mine were used as input for the tomography calculations. The double-difference tomography algorithm was used, which provides the most precise results. The results clearly show a low velocity zone in the previously mined areas bounded by two high-velocity lobes located adjacent to the mined openings at locations consistent with those expected due to the horizontal stresses at the mine. The overarching goal of the research is to provide a tool that can augment both numerical modeling results and underground geotechnical measurements to allow the mine operator to produce in the safest and most efficient manner possible.

Jun 1, 2012

By A. J. Vivyurka

"This is a talk about the experiences that Rio Algom Mines Ltd. has had in the Elliot Lake uranium area trying to make the tailings more compatible with the surrounding environment. To get a better idea of the problem that we are associated with we have to go back to the location. The Elliot Lake uranium area is situated about half way between Sault Ste Marie and Sudbury and is about 20 miles north of Lake Huron. In 1950, uranium was discovered along the north shore of Lake Huron and by 1961 we had up to 9 mines operating in the area. Then the United States Atomic Energy Connnission withdrew their contracts so that at present there are only 2 mines operating. From all the mines that we had operating, we ended up with 7 tailings areas. From these 7 tailings areas we have 5 sites where we have active treatment or rehabilitation. There is the Pronto site where we are treating uranium tailings and copper tailings. There is the Lacnor-Nordic site which is located just out of Ellio Lake. The Milliken-Stanleigh site is in the Crotch Lake area. The Panel tailings is off the north end of Quirke Lake and finally there is the operating property of Rio Algom Mines at Quirke Lake.To understand fully the problem with this rehabilitation we have to look at the constituents of the ore. The ore body is a quartz conglomerate with uraninite and brannerite as the uranium bearing minerals in a fine ground mass of quartz, sericite and pyrite which separates the larger quartz pebbles. The approximate composition of the ore is: 80% quartz, 13% chlorite, 7% pyrite and 0.2% uranium minerals. The processing method also adds a few constituents to the final tailings."

Jan 1, 1975

By R. G. Rosehart, S. Y. Lee

"The current investigation concerns the removal of arsenic from waste waters using ion-exchange resin and activated carbon as sorption media. Use of certain weak and strong base anion exchange resins permits the removal of arsenic. Arsenic may be loaded on the weak base resin in the pH range of 2 to 3 and on the strong base resin above pH 5. The elution of arsenic is successfully achieved using 0.5 M NaCl or a mixture of NaCl and NaOH. The activated carbon investigated was less effective on loading arsenic, but the arsenic loaded was easily eluted by simple pH adjustments."

Jan 1, 1972

By H. H. Bleakney

THIS paper presents evidence that in 3 1/2% nickel steel, the published temperature for the Ac1 transformation, l,275°F., represents the completion of that transformation, and that its inception occurs approximately 275°F. lower, at about l,000°F. The formation of austenite within this range, especially at the higher temperatures, and its subsequent decomposition to martensite, results in considerable impairment of the properties of the steel. That the solid solution found to occur below l,275°F. is austenite has been questioned, but the evidence herewith presented, while not decisive, appears to be reasonably convincing. INTRODUCTION The February, 1939, issue of Metals Technology contains a very interesting paper by I. N. Zavarine, Associate Professor of Metallurgical Engineering at the Massachusetts Institute of Technology. In that paper, Professor Zavarine presented photomicrographs illustrative of the microstructures produced by heating nickel steels to a temperature slightly below the carbon change point, and holding them at that temperature for various lengths of time. His illustrations show that the structures found after such treatment do not consist merely of ferrite and carbides, but are characterized by the presence of a third phase, which he describes as a' 'sub-critical solid solution'. The occurrence of this third phase in increasing amounts is accompanied by an increase in strength and a loss of ductility and impairment of elastic ratio of the steel. Some years ago, one of the authors encountered the above-mentioned phenomenon in treating large forgings of 3.5% nickel steel. After normalizing and then drawing at l,250°F., very poor mechanical properties were obtained. Investigation of the steel disclosed no inferiority in quality. Eventually, after considerable waste of time and money, a draw temperature of l,150°F. was tried. This treatment resulted in a very great increase in elastic ratio, over 5 per cent increase in percentage elongation, and proportionate improvement in reduction of area.

Jan 1, 1941

By W. C. Risley

IN the year 1933, workings at the No. 12 colliery, New Waterford, of the Dominion Coal Company, Limited, had advanced to a point where additional ventilation would soon be required. Furthermore, development of the mine was being .made to practically double the output of coal. Consequently, authorization was given to sink a shaft to the workings. The location selected is on the west side of the mine, about one and a half miles from the slope mouth and on the Low Point shore, some 250 feet from high-water mark. The cliff at this point is 40 feet high, with the land rising on a slope of about 5 per cent to the shaft. Figure 1 shows the location with reference to the colliery workings. The strata through which the shaft was to be sunk were pretty well known from diamond-drill borings previously made, and it was believed that water would be encountered to a depth of at least 250 feet to 300 feet. It was planned, therefore, to seal-off the water by the pumping of cement grout under high pressure. This method was considered to be the most economical means of handling the water during sinking, and would also result in a permanently dry shaft. Figure 2 shows a cross-section of the strata. The permanent shaft hoist and fan were to be electrically driven, which would necessitate the construction of a transmission line between the colliery and the shaft; therefore, it was arranged that the sinking equipment would have electric drive. As all equipment, materials used in construction, and supplies were to be hauled by truck, a roadway 1,800 feet long was required from the main highway to the site, and as heavy loads would be hauled during the fall, winter, and succeeding spring, this road was ballasted with 18 inches of clinkered material obtained from a burned culm bank one and a half miles distant. Actual field work was begun by the Company's own forces early in October. Work preparatory to sinking-in addition to the roadway and trans-mission line-included the construction of the reinforced-concrete shaft collar and fan drift connection; the permanent timber headframe (which was to be used also as the sinking headframe); the permanent reinforced-concrete building to house the shaft hoist and fan drive; and the erection of temporary buildings and installation of all equipment for sinking and lining the shaft and for cementation.

Jan 1, 1936

By E. M. Córdoba

The effect of the Fe3+ lFe2+ redox couple on the chemical and biological dissolution of chalcopyrite was studied. All the tests were carried out in stirred flasks with 100 mL of a ferric/ferrous sulphate solution, in the absence or in the presence of bacteria (iron- or sulphur-oxidizing) and at low (35 DC) and high (68DC) temperature. The initial redox potential was controlled between 300 and 600 m V Ag/ AgCI and silver was used as chemical catalyst. The results showed that the oxidizing action of ferric ion on the chalcopyrite was controlled, in all cases, by nucleation and precipitation of jarosites on unreacted particles. The tendency of Fe3+lFe2+ solutions towards equilibrium favours the activities of both ions to be equal. Consequently, the dissolution rate was faster at relatively low redox potentials (between 400 and 500 mY) than at high values (600 mY). In this sense, the presence of ferrous ion in the system is a key factor to control hydrolysis and precipitation of ferric ion. Unlike jarosite, the elemental sulphur produced during dissolution of chalcopyrite was porous and did not act as a diffusion barrier.

Jan 1, 2007

By Scott Martin

This paper will discuss the challenges currently facing the mining industry. By sharing experiences gained in the CIM Leading in Mining Course, I will highlight what’s working, what’s not, what are the challenges, what are the concerns, what are the opportunities, what needs to happen. Specifically, I will discuss what is currently happening with leadership and leadership development in members’ own organizations, what skill sets are important to develop in different hierarchical groups and how comprehensive leadership courses like the leading in Mining course can help improve leadership within individuals and the industry. Leadership development is a process not an event.

Jan 1, 2014

By W. L. Thayer, K. A. Jonasson, R. D. Coleman, J. D. Hazlett, C. E. Capes

"Loss of coal fines in reject slurries limits the yield of coal cleaning operations. Difficulties in handling fines also limit the extent of physical cleaning in treating coals with finely-disseminated impurities. Selective oil agglomeration allows even extreme fines to be processed and offers some novel approaches for coal cleaning and utilization.The oil agglomeration process for the recovery and beneficiation of fine and ultrafine coal has now been commercialized by the Chemical Engineering Section/Chemistry Division of the National Research Council (NRC). This paper describes these activities to apply oil agglomeration and related fine coal technologies on an industrial scale. Pilot plant and large scale results are described, as well as aspects of agglomerate utilization in both wet and dry form."

Jan 1, 1988

By Claude Deveau

"With ever decreasing feed grades, finer mineralogy and increased demand for product, it became obvious that a major step in equipment performance was required to reduce operating costs and increase production. Offsite testwork indicated that a Centrifugal separator was capable of recovering fine tantalum and that the newly developed C Series Falcon concentrator would be capable of replacing many pieces of aging equipment and provide improved performance. Further investigation led to the rental and the purchase of a Falcon C20 concentrator followed by a C10 to maximize circuit performance.Falcon Concentrators Inc’ s practice of working with the customer mirrors Tantalum Mining Corporation of Canada’s (Tanco) philosophy of continuous product development. This synergy honed valve design for continuous operation in a highly abrasive ore environment.Tanco has recently purchased two more Falcon concentrators for the recovery of additional tantalum from its spodumene circuit. These new units have additional user friendly operating features partially based on developments made at Tanco.The Falcon C Series units have enabled Tanco to maximize recovery of tantalum that was otherwise lost while using the original conventional gravity circuit."

Jan 1, 2000

By G. K. Lee, E. R. Mitchell

Designers of combustion processes may select aerodynamic conditions which produce only superfine fly ash. Although it is not usually anticipated that this will create a problem, such as has been found to agglomerate in high-velocity gas streams, to plug mechanical dust separators in a short time, and to contribute to atmospheric pollution. The problem is a fundamental one, and may be approached in several ways. The authors, in the course of their combustion research program, had occasion to examine the agglomeration of ash, ranging from sub-micron to 17 microns in size, produced in a (coal and oil) dual-fuel-fired steam generator. Several theories, supported by extensive laboratory studies, have provided some understanding of a probable mechanism of agglomeration. As a result, certain precautions are suggested in the design and selection of combustion processes and equipment.

Jan 1, 1962

By L. E. Collins

"In western Canada, many new wells contain a significant fraction of H2S. As well, many older wells become increasingly sour over their operating lifetime. For these reasons, there has been increased demand for linepipe and casing for sour service applications in recent years. This paper will review the metallurgical factors which must be considered in designing steels for such applications. IPSCO’s development of linepipe and casing, and experience in fabricating products to meet test standards specified for sour service applications will be summarized. IntroductionWestern Canada produces the majority of Canada’s domestic crude oil and natural gas. A complex system of pipelines has been built to gather the oil and gas from the fields for transport to refining and/or cleaning operations. The gas carried in these pipelines can be either sweet or sour (i.e. containing no H2S or containing H2S) depending on the nature of the field from which it came. Many new fields contain a significant fraction of H2S and many older fields become more sour as their time in production increases. This uncertainty regarding product condition influences the user’s choice of materials for both casing and pipeline applications.It is well known (Merrick, 1989) that hydrogen induced cracking (HIC) will occur in steel when three conditions exist simultaneously: (1) the presence of H2S gas, (2) moisture, and (3) a susceptible material. Steelmakers can only address the latter of these factors. Development of steels to meet test requirements of sour service has been a major focus of IPSCO’s development work for several years."

Jan 1, 1998

By M. B. McClenaghan, O. P. Lavin, Ian Nichol

"Exploration in most areas of Canada has to contend with problems posed by glacial overburden. In many areas exploration for gold has been based on the sampling of tills, frequently by deep overburden drilling, and analyses of heavy mineral concentrates. Notwithstanding the significant role that till geochemistry has played in the discovery of some important gold deposits over the last few years, increased appreciation of the nature of the glacial history and stratigraphy and the character of gold within till has led to the recognition of a number of ways whereby the effectiveness of exploration can be improved upon.In order for till geochemistry to be useful in exploration, a number of conditions must be fulfilled, including:1. mineralization, or alteration halo related to mineralization, subcropping at the bedrock/overburden interface;2. glacial erosion and dispersal of a recognizable signature of mineralization into the glacial sediments;3. preservation of glacial sediments containing this geochemical component (trace metal or mineral) at positions subsequently selected for sampling (normally drill sites);4. correct identification of specific till units and associated ice movement history;5. collection of adequately large and representative samples;6. appropriate sample preparation and processing;7. appropriate geochemical analyses; and8. correct data processing and interpretation.While we have no control over the first two geological conditions, and only limited control over till availability, we can control the quality and thoroughness of sampling, sample identification, sample preparation, analysis and interpretation. In particular attention needs to be focussed on obtaining a large enough sample to be adequately representative, an unbiased sample must be collected, together with appropriate sample processing, analysis, data processing and interpretation. It is considered that by modifying or extending existing approaches to gold exploration the chances of exploration success can be increased. In particular, analyses of both the heavy mineral and minus 63 µ m fractions of till is recommended because gold in till may occur in different size fractions."

Jan 1, 1992

By Terry Braden

"Meeting probable world mineral demand in the years ahead will almost certainly require an ability to economically treat lower grade and more complex ores. Achieving this will require extensive research and technical development across the full spectrum of mineral processing.For mid-sized or smaller companies the most effective way to participate in such extensive programs - and gain access to the technology required to stay competitive - may be through collaborative research.This paper explores the recent history of collaborative research in mineral processing and in particular its ability to attract world-class multi-institutional research teams with sufficient resources to make step-change advances. It chronicles the advances achieved, but also explores the research architecture and administrative structures required to deliver research outcomes and technology transfer mechanisms to a range of often disparate sponsoring companies.INTRODUCTIONIn medieval times the dream of alchemists was to turn base metals into gold. We modern alchemists, of course, don’t waste our time on that sort of foolishness: we turn base metals into dollars. When I see the profit reports filed by some companies recently, I can only conclude that a lot of those present today must be pretty good at this.But the fact that we are here at this conference reminds us that an alchemist’s work is never done; turning base metals into dollars is not a one-trick wonder but an art that we must extensively refine year after year if we are to survive in a competitive marketplace.It is not that demand for metals is likely to slow; most people seem to think that China, India, Brazil and other emerging economies are still at the lower end of their demand curve. They will need significantly larger volumes of metals in the years ahead. The challenge for us as processors is that to supply increasing tonnages of those metals profitably we will almost certainly need to process more complex or lower grade ores and probably to do so with reduced energy inputs."

Jan 1, 2009

By R. A. Lunceford, K. C. Shaver

Acquired by Teck Corporation in 1990, the White Earth project, located in southwestern Colorado is the largest titanium resource in the U.S. Teck Corporation has conducted geologic, reserve, mineral processing, pre-marketing, and environmental baseline studies directed toward the economic feasibility of producing titanium pigment. The White Earth project is situated in a 31 km2 alkalic-carbonatite complex intruded into Precambrian granite and metamorphic rocks about 570 million years ago. Perovskite occurs in a 8 km by 1.2 km Acquired by Teck Corporation in 1990, the White Earth project, located in southwestern Colorado is the largest titanium resource in the U.S. Teck Corporation has conducted geologic, reserve, mineral processing, pre-marketing, and environmental baseline studies directed toward the economic feasibility of producing titanium pigment. The White Earth project is situated in a 31 km2 alkalic-carbonatite complex intruded into Precambrian granite and metamorphic rocks about 570 million years ago. Perovskite occurs in a 8 km by 1.2 km

Jan 1, 1998

By R. L. Bailey

"The Acheson D-3 Pool was discovered in August 1950, and contains 88 producing oil wells on 40 acre spacing. Initial oil-in-place was 118 million stock tank barrels and initial well potentials averaged 2,000 barrels per day.In early 1956 studies of hydraulic interference between the Acheson and Leduc D-3 Pools were conducted on the Carter Petroleum Reservoir Analyzer. These studies indicated that the natural water drive to Acheson would be incapable of replacing reasonable withdrawal rates over the life of the pool. To avoid shrinkage losses a scheme of pressure maintenance by water• injection was therefore instituted in March 1957.This pressure maintenance scheme is notable because pressure is being effectively maintained by high volume injection through one well located on the flank of the pool. Close control on reservoir behaviour is maintained by regular bottom-hole pres-sure surveys and observation of water cuts on producing wells. No evidence of pressure gradients or channelling of the injected water has been observed to date, and the water-oil contact has remained level over the whole field. It is possible to control the average reservoir pressure within very close limits by varying the rate of fresh water injection.Ultimate recovery estimated from the rise of the oil-water contact and calculated water influx to December 31, 1958, is 335 barrels per acre foot, or a total of 91.4 million barrels from the pool. This compares to 217 barrels Per acre foot or a total of 59.4 million barrels indicated from laboratory test data."

Jan 1, 1961

By Benjamin H. Clark

"For over 50 years, Derrick Corporation has been renowned for its innovative and durable fine screening equipment and screen surface technology. Derrick’s latest innovation, the patented Stack Sizer, offers mineral processors both high tonnage capacity and high separation efficiency on an extremely small footprint.The Stack Sizer is suitable for separations from 6.3 mm down to 75 microns (200 mesh). The Stack Sizer, coupled with Derrick’s patented urethane screen surface technology, offers an extremely economical alternative to hydraulic classifiers, hydrocyclones, and less efficient low volume wet screening systems. Stack Sizers have been used in feed preparation for flotation, spirals, and a variety of jigs. Mineral processors wishing to reduce grinding circuit circulating loads and generation of slimes due to over grinding, thereby enhancing the efficiency of flotation and gravity circuits, now have another technology at their disposal to perform this critical sizing and grade control function.Over 200 Stack Sizers have been installed in numerous mineral processing applications worldwide attesting to the rapid acceptance of this technology. Stack Sizers are currently screening ferrous and non-ferrous metal ores, mineral sands, silica sand, kaolin clay, feldspar, garnet, phosphate, aluminum dross, potash, coal, tantalum, spodumene, niobium, and other rare earth mineral ores.INTRODUCTIONDerrick engineers have long understood and demonstrated the importance of screen width in coupling both high capacity and high separation efficiency for fine wet sizing applications. As opposed to fine dry sizing, where the length of the screening machine is critical for high separation efficiency, introducing slurry feed to screens in a thin and even layer at minimal velocities across wider screen surfaces allows for high capacities and efficiencies, with maximum screen cloth life. This is due primarily to the combination of free liquid and high frequency vibration of the Derrick motors, which allow fine undersize material to pass through the screen apertures. Lacking either of these factors would be extremely detrimental to the screening process. Without the high frequency vibration of the motor, the screen is essentially a low efficiency sieve bend. Without the free liquid to carry fines through the screen openings, the screen is for all intents and purposes a glorified conveyor or dewatering unit, as little or no sizing takes place once the screen is devoid of free liquid. For optimal screening results, Derrick recommends feeding slurry to a screen at approximately 20% solids by volume. Figure 1 shows the Stack Sizer design concept. Note that a single feed point is used to evenly distribute the flow to the five separate feed points."

Jan 1, 2007

By R. Pressacco

"IntroductionAgrium’s history in fertilizer production and marketing goes back to 1931. Today, Agrium Inc. is a world leader in the production, distribution, and marketing of fertilizers and related products to the agricultural industry. Agrium is the largest North American producer of nitrogen fertilizers, a major producer of phosphate and potash fertilizers, and a world leader in fertilizer wholesale distribution and retail marketing. The mine at Kapuskasing is located some 40 km southwest of Kapuskasing, Ontario (Fig. 1). It has been developed to supply high-quality, low-cost phosphate rock to the company’s Redwater, Alberta facility, where it is an ingredient in ammonium phosphate fertilizer production. The Kapuskasing mine is the only phosphate mine in Canada and will rank as one of the highest-grade phosphate mines in the world (Clark and Duncan, 1999). Apatite is the principal ore mineral mined at the Kapuskasing Phosphate Operations.GeologyThe first record of exploration in the area was from a program executed by Continental Copper Mines in 1955 which evaluated the magnetic anomaly located in the Cargill and Cumming townships for its base metal potential. Intermittent exploration of the base metal potential of this magnetic anomaly continued in the following years, until the phosphate potential of the area was first examined in 1974 by International Minerals Corporation which recognized the presence of a layer of apatite sands overlying the carbonatite host rocks.The local geology consists of a core complex of multi-phased carbonatite rocks which are surrounded by a ring of pyroxenite, and have provided a U-Pb age date of 1907 Ma ± 4 (Sage, 1988). These two rock types are in turn situated within quartz diorite gneisses that form a large portion of the Kapuskasing Structural Zone (Fig. 2). The carbonatite host rock is sub-divided into two sub-types: sovite and rauhaugite. The sovite is a medium- to coarse-grained, white, banded rock in which calcite is the dominant carbonate species and it includes accessory minerals such as phlogopite, magnetite, clinohumite, apatite, olivine, pyrrhotite, and amphibole. Apatite can reach 15% abundance in this rock type (Sage, 1988). In sharp contrast to the sovite, the rauhaugite appears as a massive, fine-grained, dense, beige to tan-coloured rock in which dolomite is the dominant carbonate species. Phosphate values can range to 14% P2O5 in the rauhaugite."

Jan 1, 2001

By Kevan J. R. Ford, Chris A. Fleming, Robert D. Henderson

"Kinross Gold Corporation’s Maricunga mine in Chile presents an ideal opportunity to apply the SART process to a heap leach operation. Given increasing levels of cyanide complexed copper in current pregnant solutions from Maricunga heaps (over 300 ppm Cu), there is a need to reduce these levels and decrease cyanide consumption and cost. Additionally, a means of disposing of this copper is required, preferably as a saleable product. The well published SART process applied to gold-copper cyanide solutions was selected as it allows rapid precipitation of cyanide soluble copper as a relatively pure copper sulphide. The process also allows effective recovery and recycle of cyanide back to the heap leach operation.This paper reviews the SART process chemistry and presents a summary of SART bench-scale and pilot plant testwork completed by Kinross. Key design parameters and engineering aspects of the proposed plant at Maricunga are discussed. SART plant operating costs and net revenue analysis are included and illustrate the compelling economics of installing a SART process plant. INTRODUCTIONMaricunga OperationCompañia Minera Maricunga (CMM), fully owned by Kinross Gold Corporation, operates the Maricunga mine (formerly Refugio) which is located 120 km due east of the city of Copiapó at an elevation of 4,200m above sea level in the Andes mountains of northern Chile. Figure 1 shows a map of the location of the Refugio mine relative to other gold and copper mines in the region."

Jan 1, 2008

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, A. M. Elmahdy, Keiko Sasaki

"Seawater has been reported to depress molybdenite in a copper-molybdenum (Cu-Mo) flotation process at high pH due to the precipitation of Mg(OH)2. Meanwhile, to improve mineral recoveries, collectors are usually added into the flotation cells, thus adding the complexity to the mechanism of bubble-particle interactions involved in Cu-Mo flotation. Therefore, understanding the interaction mechanism in seawater flotation and in the presence of collectors is important to explain the minerals depression. The present work investigated the effect of kerosene on the bubble collision and attachment to pure chalcopyrite and molybdenite surfaces in MgCl2 solution as one of the seawater major components at pH 6 and 11. Mineral surfaces were characterized using atomic force microscopy (AFM). In addition, minerals floatability in the same system were tested in a column flotation. The study of bubble-particle interactions shows that following several collisions, bubble could displace the intervening liquid layer on the mineral surfaces, forming a three-phase contact (TPC). A TPC formed more rapidly in the presence of emulsified kerosene in a 0.01 M MgCl2 solution at pH 6 for both minerals. The reason is kerosene increased the surfaces hydrophobicity and destabilized the intervening liquid layer on the surfaces. Moreover, the average time required to form a TPC was shorter on molybdenite surface. This can be attributed to the effect of adsorbed kerosene on molybdenite surface and molybdenite surface roughness.INTRODUCTIONIn froth flotation, bubbles are used to separate hydrophobic mineral particles from hydrophilic particles. In this process, bubble-particle interactions (i.e., collisions, attachment, and detachment) are crucial with regard to mineral recoveries. The effectiveness of froth flotation depends on the formation of stable aggregates between the hydrophobic particles and the bubbles, allowing the bubble to carry the particles to the froth layer. To form such aggregates, the bubbles and particles must collide, and the intervening liquid layer must be drained below the liquid layer critical thickness, forming a stable threephase contact (TPC) (Ralston & Dukhin, 1999). Particles detachment may take place if the particles still have sufficient kinetic energy and the TPC is not formed. Previous studies of bubble-particle interaction in electrolyte solutions have been conducted using atomic force microscopy (AFM) (Assemi, Nguyen, & Miller, 2008), and by approaching the bubble using mica plate (Pushkarova & Horn, 2008), however, these studies did not focus on the bubble-particle collisions. Bubble collisions and attachment to hydrophobic (Teflon) and hydrophilic (glass) surfaces in a a-terpineol solution have been investigated by Krasowka et al. (2003)."

Jan 1, 2016