Search Documents

By C. A. Lavery

A DISCUSSION is presented of natural gas production and field processing equipment as now utilized in the gas producing areas of the United States, with reference to use of such equipment in Canadian gas areas. The scope of the paper is confined to a general description of various types and methods of using surface production equipment. The discussion is divided under two general groups: well-head production equipment, and field processing. The first will be concerned primarily with indirect heaters, separators, knockouts, and special versions of this equipment. The second major group includes the field processing equipment for handling natural gas. A delineation should be made here as to the meaning of field processing as used in this discussion. We will limit our term to mean such processing equipment as may be used in producing fields to process gas or its by products in a manner that does not require conventional plant practices either in operation or supervision. This covers such equipment as is necessary to complete preparation of gas for sale to pipeline and/ or is necessary to recover valuable components. Under this heading we will discuss glycol dehydration, solid desiccant dehydration, low-temperature separation, mechanical refrigeration, and desorbtion-stabilization. These are all processes involved in preparing gas for final sale or disposal. They do not include the more conventional and large-scale plant process systems.

Jan 1, 1956

By B. L. Moreau

Certain gas wells tend to form hydrates in the production tubing. This paper outlines a method developed and used by the Author's company to overcome the problem. The injection of glycol to control hydrates results in sufficient dehydration to allow the gas to be trans-ported through a field-gathering system b a treatment plant. Sub-surface injection of glycol also offers a method of introducing corrosion inhibitors into the gas stream. The major operating difficulties have been overcome and the system is now in use in the northeastern part of British Columbia.

Jan 1, 1958

By G. H. Agnew

When water floods are initiated after gas-oil ratios have increased, the transition period from the start of injection until" the gas-oil ratios are returned to the solution gas-oil ratio may be important for either economic or technical reasons. The transition period is longest, and consequently most critical in water floods where injection is equal to withdrawals. This paper describes a theoretical basis for predicting the behavior of such a system and outlines a procedure for making the necessary calculations. The calculation procedure is illustrated for two actual cases: a line drive water flood and a five spot water flood. In each case there is a reasonable similarity between the actual and calculated performance.

Jan 1, 1960

By Pieter van Nierop

Outline ? What is gasification? ? Gasification Technologies ? Gasification ?The early years ? Gasification ? The last decade ? The Alberta Situation ? The Importance of Gasification in Alberta ? Polygeneration ? Development ? Conclusion

May 1, 2004

By P. C. Richards

"Future Integrated Gasification Combined Cycle (IGCC) power plants will have superior environmental performance and unmatched efficiency.The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an IGCC plant. SCGP flexibility has been demonstrated for feeds ranging from bituminous coals to lignites and petroleum coke, and the process is ideally suited for combined cycle power generation, resulting in efficiencies of 42% to 46% (LHV).In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology is being built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N. V. Sep). The plant is scheduled to start up in 1993. IntroductionBasic ConceptShell's experience with gasification dates back to the 1950s, when the first Shell Gasification Process was commissioned with oil as feedstock. There are now over 140 SGP gasifiers licensed. The experience gained on oil gasification provided a firm theoretical and practical base for the start of coal gasification process development in 1972.At that time, there were serious concerns about the future availability and price of crude oil. Coal gasification (making carbon monoxide and hydrogen by the partial oxidation of coal) was considered to be an important option for refinery applications, because the synthesis gas (syngas) produced can be used as:• a chemical feedstock for making transportation fuels and chemicals;• a source of hydrogen (making use of the water gas shift reaction) for upgrading petroleum products; and• a fuel for heating process streams and/or generating electricity."

Jan 1, 1994

By A. M. Bell

"The property of Gaspe Copper Mines, Limited, is in the Gaspe Peninsula some 60 miles west of the town of Gaspe and 20 miles in from the north coast. The Copper Mountain deposit was first discovered in 1921 and first optioned and drilled by Noranda in 1938. The Upper Needle Mountain showings a mile south were found in 1938, but it was not until after a delay of 10 years that the more important deep ore at Needle Mountain was located by drilling. Production started in 1955, and the smelter commenced operation in December. Mining is by open stope methods with first production coming from the Lower Needle Mountain orebody, of which only a small portion has been exposed in underground openings.Stratigraphy and AlterationThe country rock is composed of limy siltstones of Devonian age. Away from alteration these are dark and generally carbonaceous. Throughout the drilled area numerous narrow layers of tuffaceous fragmental material occur, and such beds are found to provide excellent horizon markers by virtue of their uniform thickness and wide lateral distribution. These markers are valuable for stope control in mining the bedded replacement deposits.Intruding the sediments at Copper Mountain are porphyry dykes, and one drill hole encountered granite 1,400 feet below the valley. Solutions responsible for the rock alteration and ore deposits seem to have emanated from this intrusive centre.On the mine claims strong hydrothermal alteration has completely obscured the original character of the sediments. The unaltered formations are all very similar in appearance, but following alteration rocks that are very dissimilar in physical characteristics are produced, and such differences have an important influence on ore deposition. The alteration effects are known to extend over a vertical range in excess of 3,000 feet and have a surface area of two square miles. All known ore bodies are within the zone of alteration. In this, rocks are strikingly bleached to a white colour in contrast to the normal dark-coloured sediments, and are much harder and more abrasive, with bedding often obscured. The first effect of alteration is driving off of carbonaceous matter, followed progressively by silicification in the acid rocks and by the formation of lime silicates in the lime rocks, with an accompanying gain in silica and a corresponding loss in lime. Extensive analysis has shown that there is an actual addition of silica involved in the alteration."

Jan 1, 1949

By Ali M. Ghazi, Ronald J. Goble, Lowell S. Whiteside

"Geerite (Cu1.6S) is a rhombohedral copper sulphide which occurs naturally in epitactic replacement of sphalerite; cell dimensions closely approximate those of the host sphalerite.Geerite-type structures can be produced by leaching digenite (Cu1.8S) in ferric sulphate solutions. X -ray diffract ion and electron microprobe studies indicate that eight metastable geeritetype structures can be produced, depending upon the concentration of f erric sulphate solution used and the duration of the each. Although compositions cluster on or near values observed for natural phases, optical properties indicate that we are dealing with polymorphs of these phases. Leaching of chalcocite (CU2Sj in dilute f erric sulphate solutions produces similar results. In contrast, leaching of chalcocite in more concentrated solutions seems to produce true analogues of natural minerals.During froth flotation, sphalerite is activated with a monolayer of floatable copper sulphide with the composition, CuS, of the mineral covellite. However, covellite is not significantly more floatable than sphalerite, and has an incompatible structure because of the presence of covalently-bonded atoms of sulphur. Leaching ofdigenite was used to produce a polymorph of covellite with a geerite-type structure, compatible with that of sphalerite. This polymorph has a flotational behaviour similar to copper-activated sphalerite, suggesting that the monolayer has a geerite-type CuS structure. IntroductionIn an ideal close-packed sulphide structure the distance between sulphur layers, D, is equal to 2R 2/3, where R is the radius of the sulphur atoms. In sulphides with covalently-bonded sulphur layers, such as covellite (Fig. I), D will be an average of the number of covalentl y-bonded and close-packed sulphur layers, weighted as to the relative number of each type of layer. Both D and R are spacings which are readily identifiable structurally and on X-ray diffraction patterns. Goblel has shown that for copper-iron sulphides with metal-to-sulphur ratios between 0 and 2 and copper-to-total metal ratio s between 113 and I there are strong correlations between composition and measured D and R distances (Fig. 2). D can be represented by a single empirical equation relating interlayer spacing to composition; R must be represented by three equations relating the radius of sulphur atoms to composition. One of these equations (R, in Fig. 2) represents ideal close-packed behaviour, the other two represent sulphur radii greater than (R1) or less than (Rh) the ideal."

Jan 1, 1988

By G. C. McKerrow

"Mr. G.C. McKerrow, Assistant Manager of Noranda Mines and formerly Smelter Superintendent attended the meeting to answer questions as to why smelters imposed penalties for too much zinc in a copper concentrate or too much copper in a zinc concentrate, etc.D.W. Bridges -Mattagami Lake MinesWhat limits do you set on zinc and lead in a copper concentrate?G.C. McKerrow - At Noranda, we allow 5% zinc free and charge 25 cents for every unit above that. For lead, it is 1% free and 25 cents per unit above that. Lead is a much more harmful impurity than zinc because it tends to recycle more in the smelter circuit and creates a greater health hazard in the plant.E. Thornton - Sullivan GroupWHat harm does fluorine do in the smelting process?G.C. McKerrow - Fluorine usually does not occur in harmful concentrations in non-ferrous smelters. Fluorides are present in exhaust gases in the aluminum and phosphate industries. If these fumes escape into the atmosphere, they may settle out on forage grasses in concentrations that are harmful to livestock.Thorton - Sullivan GroupI have asked this question other places and have been told that it is hard on brick linings and causes gold and silver to be lost up the stack.G.C. McKerrow - Almost any volatile constituent in a smelter charge will aid in carrying other metal values. To this extent it may be harmful.E. Thornton - Sullivan GroupMr. Tait mentioned before a smelter where they have a copper-tin ore and they pay for copper, tin, bismuth and silver but object strongly to indium in the concentrate. Why would this be?G.G. McKerrow - 1 can't see why indium would be a serious impurity. It does tend to concentrate in flu dusts and if you get enough of it you can recover it and sell it but I have never heard of anyone putting a penalty on it.Question - I once ran into a small copper mine in Peru that had cadmium in the copper concentrate but no zinc. The copper smelter charged a penalty for the cadmium. Why would this be?"

Jan 1, 1971

"Chairman - To start this discussion off, I wonder if Mr. Dave Livingstone or Mr. Jeffrey of Granisle Copper would give a description of the crushing plant at Granisle since it is somewhat different from the usual plant, W. N. Jeffrey - Granisle Copper The main difference between the Granisle crushing plant and many others is the Livingstone method of putting the screens under the crushers instead of above them. This method allows a more compact arrangement and eliminates the heavy superstructure required to take care of the screen vibration when the screens are mounted above the crushers. There is a small surge bin above the tertiary crusher which takes care of the variation in circulating loads.All three crushers are gyratory crushers. There is no grizzly ahead of the primary crusher but the fines are removed from the primary crusher discharge at the first screen and sent directly to the fine ore bins. E, Thornton - Sullivan GroupDo you have any coarse ore storage outside?w. N. Jeffrey - Yes, there is about 6000 tons live storage, We have very little trouble with freezing even though it is open storage.E. Thornton - Sullivan GroupDoes rain cause any problem?w. N. Jeffrey - It sometime creates a problem because the storage area is on a slope. It is mainly a problem of keeping the drainage ditches open.Question – What is the size of the primary gyratory crusher and how does it work on run of mine size materials, in other words, do you have a problem with oversize material and how do you handle the oversize rock?w. N. Jeffrey - The primary gyratory is a 42 x 65 with a nominal open side setting of 61'. We do at times get a run of oversize material. For anything too large for the crusher to handle, we use what is known as the Esco hook, which is a type of grapple used to remove oversize rocks.The disadvantage with this equipment is that the crane is too slow. I am sure there must be better arrangements than the one we have,"

Jan 1, 1971

By R. L. Stanton

"The present contribution examines, in some detail, what appear to be the three outstanding features of the field occurrence of the conformable ""pyritic"" deposits. These are their association with fragmental volcanic rocks (and derivatives), their occurrence in sediments of near-shore formation, and their highly variable structural associations.In a recent paper it has been suggested that two such ""pyritic"" de-posits in New Brunswick may have originated as marine concentrations of volcanic base metal and sulphur compounds, and that many of their present features are the result of diagenesis, folding, and regional metamorphism. This is now put for-ward as a general explanation for the particular class of deposit considered.Such deposits should, on this hypo-thesis, be regarded quite simply as an integral part of the particular geological environment in which they occur -as a normal, though minor, sedimentarry type developed, char-acteristically, in near-shore and shelf facies of intravolcanic units formed along the margins of eugeosynclines. They should not be considered -as, for example, is required by the re-placement theory -as later features simply superimposed on a geological situation to which they are genetically unrelated. Where they are associated with folds and other structures, this may be attributed, from one in-stance to another, to mechanical migration during folding, weaknesses induced by pre-existing sulphides, and, occasionally, to fortuitousness.In the light of this postulated origin, it is suggested that the first stages in regional prospecting for deposits of this particular class should be broadly palaeogeographical. Later phases of the search should then be directed to the delineation of sedimentary facies and, finally, to the investigation of geological structure."

Jan 1, 1960

By R. L. Stanton

"The present contribution is complementary with a preceding one on the field association of the conform-able ""pyritic"" deposits. It considers the more important features of their mineralogical constitution and their microtextures, re-examines the present interpretations of these, and of-fer-some alternative explanations. The term ""pyritic"" for these de-posits is m many cases a misnomer, as two quite distinct ore types are inuolve. One is a banded pyritic sphalerite-galena-chalcopyrite ore (for which the term '•pyritic"" is in-deed quite suitable), while the other is non-banded and is composed essentially of pyrrhotite and chalcopyrite. In addition to these constitutional differences, each is distinctive in general appearance and texture. The occurrence of two such consistent but clearly distinguishable ore types is attributed -rather than to difference in source material and pressure-temperature conditions of deposition -to the contribution of similar source material to dissimilarly oxygenated environments of sedimentation. Textures in the banded ores generally thought to be indicative of replacement or of high-temperature exsolution are explained by slow, law-temperature segregation in situ during compaction, folding, and regional metamorphism."

Jan 1, 1960

By J. F. Wright

Introduction Previous to 1924 the mining fields of Manitoba and adjoining territory had not been prospected in detail, and the reports of the exploration of the mineral discoveries to that date had been discouraging. As a result of the apparent failure of all the mining operations, some considered that geological conditions in the country westward from lake Superior extending across western Ontario, eastern and northern Manitoba, and northern Saskatchewan, were different from those in the northeastern part of Ontario, where large gold mines had been developed. Discoveries of importance thus were necessary to renew interest in the mining possibilities of this part of the Canadian Shield, and the successful operations at Flin Flon and Howey in large part were responsible for the beginning of the present activity in what may be described as the part of the pre-Cambrian Shield within central Canada. In Manitoba, the more important developments at present are in the Central Manitoba, Gods Lake, and Knee Lake fields. The large area from west of Flin Flon east to Herb Lake, also, is being explored carefully for gold deposits of merit. A number of properties in Red Lake, Woman Lake, and Pickle Crow areas are being drilled and explored underground. Many of the mines of the Lake of the Woods area, that were producing gold 30 years ago, are re-opened, and new prospects in this field and in the country to the east are being explored. The recent development of Little Long Lac mine in an area near the railway, and considered by some to have been thoroughly prospected years ago, has stimulated interest in the areas formerly prospected. In the autumn of 1934, the belts of greenstone and sediments in the country east of lake Nipigon were staked, and deposits in these fields will be explored in detail this year. This paper is presented to discuss the general features of the geology and gold deposits of the various prospecting fields in Manitoba and adjoining territory. Details of a number of the areas and mines will be presented at this meeting in papers by Barton on Little Long Lac, Tanton on Sturgeon River, Baker on Gods Lake, and Brownell and Kinkel on Flin Flon. Although mining was not active in most of this territory previous to 1930, geologists of the various government departments continued field studies and interesting reports were issued.

Jan 1, 1935

By R. C. Hartviksen, B. H. Boyum

"The Sherman Mine, Temagami, Ontario, is an iron ore pellet operation rated at one million tons per year capacity. Mining is done from three open pits in two bands of Keewatin iron-formation intercalated in a 'greenstone belt' thought to be part of the Archean 'Abitibi Belt'. The bands of iron-formation are tabular and steeply dipping, averaging 75 degrees. The principal ore mineral is magnetite.Blast holes, 1214 inches in diameter, are drilled on 28-foot centers, each hole being sampled and assayed for both total iron and magnetic iron. Concentration tests are made in the laboratory to determine the anticipated concentrate grade. Two classes of ore are recognized -'liberating' or 'refractory'. Blending is done on iron con-.tent, degree of ease of liberation (i.e. grain size) and chunkiness. The latter is important, as primary milling is done in autogenous mills. Actual daily mill results are compared with predicted grade from blast holes, exploration diamond drill holes and pit inspection. Hourly mill samples are analyzed by the X-Ray Fluorescent Analyzer, with emphasis on silica grade. In 1969, the pellet grade was improved from 7 .01 per cent silica natural to 5.50 per cent silica natural."

Jan 1, 1970

By L. S. Beck

"IntroductionThe Beaverlodge District is an important mineralogenic province of pitchblende and occupies about 1300 square kilometres centred on Beaverlodge Lake near the north shore of Lake Athabasca in northwest Saskatchewan (Fig. 1). Uranium City is the main settlement of the area and is serviced by scheduled aircraft from Edmonton, some 700 km to the southwest, and from Prince Albert which lies a similar distance to the south.During the summer, boats and barges supply the area from the railhead to Fort McMurray via the Athabasca River and Lake Athabasca, a distance of about 550 km. For the past few years a winter road has been maintained across Lake Athabasca to Cluff Lake to connect with Highway 155.The topography of the area is typical of the Precambrian Shield with generally low relief and a disorganized drainage of numerous lakes separated by hummocky rock ridges, muskeg and drift-covered areas. Local topography in the area is, however, extremely rugged, particularly south and east of Beaverlodge Lake, where resistant rocks form prominent hills and ridges extending as much as 180 m above lake level. Rock exposures are abundant and form over 50 per cent of the land area.History of Exploration and DevelopmentEconomic interest was first aroused by Tyrrell (1896) who described an occurrence of iron formation at Fish Hook Bay; however, subsequent evaluation of the deposit indicated it to be uneconomic."

Jan 1, 1986

By Norman A. Grant

"Location and Transportation FacilitiesTHE BEAVERLODGE area of North Saskatchewan is on the north side of lake Athabasca, 500 air miles northeast of Edmonton.The main Eldorado operation and townsite are on the north •side of Beaverlodge lake, which is immediately north of lake Athabasca and is separated from it by only a mile long portage at Lodge bay. The once famous town of Goldfields. Saskatchewan, and the Box property of the Consolidated Mining and Smelting Company of Canada, Limited, are located on lake Athabasca nine mines from Beaverlodge townsite.Previously, all Eldorado freight was delivered by barge at the Lodge Bay portage, hauled across the portage, and across Beaverlodge lake by small Northern Transportation Company barges, which involved many handlings.In 1952 the port of 'Bushell' was established at Black bay. This is a particularly snug harbour, well protected from the main body of the lake and with good foundations for docking facilities. A Butler building, 300 ft. by 60 ft., and tank farms provide storage at the port. A •road from Bushell to the main Beaverlodge operation, a distance of twelve miles through rugged terrain, was built by the Saskatchewan Government. The cost was shared by the Saskatchewan Government, the Federal Government, and Eldorado and other mining companies.Along this road are located the properties of several enterprising mining companies and near the midpoint lies the ambitious budding town of Uranium. This road has made portaging unnecessary and palletized freight loaded at Waterways, Alta., is now loaded directly on trucks at Bushell and delivered to the point of consumption."

Jan 1, 1953

By D. A. Pirttinen

The promotion of improved coal quality for thermal generation can benefit our national economy. The construction of electric generating facilities in Canada is expanding at a rapid rate to satisfy the demands of a rising population and new uses for electrical energy. With remaining economic water power resources in the process of development, generation from thermal sources continues to grow. The increase in thermal capability has been somewhat arrested by a de-pressed economy, widening of inter-provincial and state transmission networks and decisions to exploit certain water resources before high capital investment is further in-creased by rising construction costs. The introduction of extra high volt-age transmission lines will further delay thermal generation planning, but in due course, when the effects of restrictive factors have been dissipated, steam-electric generation from fossil fuels will rise to considerable proportions. In time, nuclear sources will contribute a growing share to thermal power, but, it is doubtful if nuclear participation will ever displace conventional fuels for steam rising, unless it can be adapted to operate efficiently for variable outputs in peaking service. It appears certain that fossil fueled

Jan 1, 1961

By F. Awotwe-Appiah, P. Koshy, J. Dankwah, J. R. Dankwah

This research investigates the generation of an effective carbonaceous material from waste ‘pure water sachets’ and their subsequent utilisation as reductants for the reduction of the Opon Mansi iron ore. Composite pellets of Opon Mansi iron ore and pulverised carbonaceous material generated from waste pure water sachets were heated from room temperature to 1200 °C in a gas fired furnace for seventy minutes. The reduced pellet was analysed chemically for its oxygen and carbon content using a LECO Oxygen/Nitrogen and LECO Carbon/Sulphur analysers, respectively. It was observed that nuggets of metallic iron were readily produced with the carbonaceous materials acting as an effective reductant and source of chemical energy. XRD analysis of waste ‘pure water sachets’ revealed that the polymer was semi-crystalline with peaks that were identical to those of high density polyethylene (HDPE). Gas emission behaviour of the iron ore-PWS pellet was studied in a horizontal tube furnace at 1200 °C using an infrared gas analyser; the results revealed an exhaust gas rich in the reducing gases CO and CH4 along with CO2.

Jan 1, 2015

By Benedetto Corain

The production and dispersion of metal nanoclusters onto inorganic supports and amorphous carbon rest on well consolidated technologies belonging to the realm of industrial catalysis and of basic catalysis research (1). In spite of the existence of a variety of specific synthetic strategies, their very rationale relies on three main approaches i. e.: A: precursors of both the metal nanoparticles and of the relevant supports (or the support itself) are intimately mixed (even let to react) at ambient conditions and then thermo-reduced according to very controlled protocols (2); B: precursors of metal nanoclusters are let to be adsorbed onto suitable supports from the gas or liquid phase and subsequently thermally decomposed (3); C: metastable size-controlled metal nanoclusters are previously generated in a liquid medium and subsequently transferred onto pre-formed support particles (4). The production and dispersion of metal nanoclusters onto organic soluble supports is also a rather well documented academic praxis (5, 6, 7, 8) able to provide e.g. size-controlled Au0 nanoclusters of 4.4±1.7 nm (5). Our group started in 1997 developing (9) an innovative approach to the synthesis of metal nanoclusters dispersed inside insoluble, albeit accessible (see below) mechanically robust gel-type resins (10), which procedure was tested so far on palladium metal. Metal ions are previously dispersed upon ion-exchange inside of the polymer framework, followed by chemical reduction and by the aggregation of born metal atoms into nanoclusters, the size of which is templated (11, 12) by the three-dimensional intercommunicating meshes that build up the overall polymer framework (Figure 1).

Oct 1, 2003

By E. N. Durussel

"The Fox Mine has been producing copper/ zinc ore since 1970 at a rate of approximately one million tons per year, and until 1978all production was derived from longhole open stopes. In June 1978, a trial stope using bighole mining methods was started to eliminate the development of two sublevels between 400 level and surface. The trial proved to be successful, and bighole mining is now an accepted mining method for both stopes and pillars at Fox Mine.When production blasting was started in the first stope, the biggest problem encountered was the production of large amounts of sulphur dioxide gas as a result of secondary sulphide dust explosions. This gas generation resulted in lost production time and caused minor damage to underground installations to the blast level, and to the headframe. Sulphur dioxide generation has been noted in secondary drawpoint blasts and, on rare occasions, in drift rounds.This paper discusses the occurrence of the sulphur blasts and the practices and precautions used to prevent their reoccurrence at Fox Mine.IntroductionThe Fox minesite is located 30 miles southwest of Lynn Lake, Manitoba. With production startup in 1970, Fox Mine is owned and operated by Sherritt Gordon Mines Limited.The Fox orebody occurs as a large lenticular zone of semi-massive sulphides approximately 1,500 feet long and 15 to 100 feet wide running east and west. Dipping 70 degrees to the north, the orebody tends to bottom out at the 3200-foot level and reaches to within 15 feet of surface."

Jan 1, 1981

By J. P. Sims

Abstract - Ultramafic to mafic igneous intrusions of the Las Aguilas district form part of a belt of generally mafic plutonic bodies within medium- and high-grade early Paleozoic metamorphic rocks in the southern Sierras Pampeanas region, Province of San Luis. The intrusions host the largest known nickel sulfide resource in Argentina and contain significant Cu, Co and PGE mineralization (2.2 Mt at 0.5% Ni, 0.5% Cu, 0.035% Co). Sulfides at Las Aguilas Este, one of two principal mineralized zones, are hosted by a body comprising subvertically dipping units of predominantly orthopyroxenite and melanorite cumulate, with lesser dunite, harzburgite, norite, leuconorite, and amphibolite. The units are zoned horizontally from ultramafic to mafic compositions, representing primary magmatic zonation away from an original base or side of the intrusion. Intercumulus nettextured and disseminated aggregates of pyrrhotite-chalcopyrite-pentlandite are concentrated in the peridotitic zones and extend into melanorite. Whole rock major and trace element compositions, and olivine chemistry, indicate that the parent magma was gabbroic/basaltic with 100 (Mg/Mg+Fe) near 59, and resembles tholeiitic magmas generated in subduction-related arc, or back-arc settings. Unusually aluminous Cr-bearing spinel is compositionally similar to those in some synorogenic mafic/ultramafic plutons in magmatic arc settings. Relatively Ni-depleted olivines and low Cu/Pd ratios are indicative of magmatic sulfide segregation early in the crystallization of the magma. Early orthopyroxene saturation and virtual lack of clinopyroxene, in conjunction with sulfur isotope values up to +6.6 ‰, spinel compositions, and presence of graphite, phlogopite and magmatic hornblende, all attest to probable crustal contamination of the parent magma. Assimilation of crustal sulfur may have been crucial in the early attainment of sulfide saturation and resultant formation of magmatic Ni-Cu sulfide mineralization. Fabrics, textures and mineralogy of the intrusions and country rocks and U-Pb zircon dating indicate syntectonic-synmetamorphic emplacement at 478±6 Ma during the Famatinian (Ordovician) orogeny. Minor to locally significant recrystallization and deformation of mafic-ultramafic rocks and redistribution of sulfides and PGE occurred during and following the Famatinian orogeny. The Las Aguilas intrusion is one of several tholeiitic mafic-ultramafic intrusive complexes within an Ordovician arc - back-arc system in the Sierras Pampeanas. Aeromagnetic datasets and regional mapping suggest there is further potential for intrusion-hosted Ni-Cu mineralization along this eroded magmatic arc.

Jan 1, 1999