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By Toshiharu Teranishi

When we apply the Au nanoparticle superlattices to the future nanooptical and nanoelectronic devices, the control of not only the particle size but also the interparticle spacing and symmetry of superlattice are the essential problems to be overcome. First, we developed a novel synthetic procedure to precisely control the particle size of alkanethiol-protected Au nanoparticles in the range from 1.5 to 9.7 nm by the heat-treatment of the small Au nanoparticles in the solid state. Absorption and nonlinear optical properties of alkanethiol-protected Au nanoparticle superlattices were then elucidated. On the other hand, the hexagonal close-packed (hcp) 2D superlattices of small Au nanoparticles with the interparticle spacings from 1.9 to 3.6 nm were successfully prepared by using newly-synthesized ligand for single electron tunneling devices. Finally, various symmetric superlattices, such as chain (2-fold), quasi-honeycomb (3-fold), square (4-fold), etc., of Au nanoparticles could be produced by making use of interligand interactions or some templates.

Oct 1, 2003

By M. Meratian

The in-situ methods have been developed in production of aluminum matrix composites. A commonly adopted in-situ method involves reaction between a metal oxide and aluminum to produce alumina particles or whisker reinforcements. Aluminum-alumina particle composite was fabricated by in-situ method where alumina particles were produced from reduction of copper and silicon oxides by melting and casting aluminum. Aluminum matrix composites reinforced by Copper and Silicon alloying elements and alumina particles have been obtained. The size and shape of alumina particles were studied by scanning electron microscopy (SEM). The size of alumina obtained from mixture of SiO2 and CuO was bigger than the alumina particles obtained from CuO.

Jan 1, 2007

By Y. X. Li, L. R. Xiao, S. Gong, S. S. He

Porous copper and porous copper based alloys with controllable pore structure have been manufactured successfully by sintering evaporation process. This process consisted of mixing copper or copper based alloys with NaCl powders, hot pressing and final high-temperature sintering to evaporate the filler material of NaCl powders. NaCl was eliminated completely during vacuum sintering, and strong metallurgical bonding in the walls was achieved. The pores’ structural parameter (pore size, shape, and direction) and porosity can be controlled effectively. These porous copper and porous copper based alloys with controllable pore structure have great potential in many fields. Including heat dissipating materials, heat absorbing materials, chemical catalyst carriers, electromagnetic shielding materials, filtering materials, damping materials, silencing materials, battery electrode materials. INTRODUCTION The development of porous materials began in the 1960s. The research of activated carbon with high specific surface area made porous materials enter the stage of material research (Belyakov et al., 2008; Ferey et al., 2008). With the rapid development of science and technology, porous materials play an important role in material research, and gradually become an indispensable part of the material research field (Wu et al., 2012). The research of porous materials has gradually extended to metal, ceramics, plastics and glass and other fields. It has been successfully applied in many fields, such as functional materials, industrial production, aviation, medical materials, biochemistry and electronics, which fully shows that porous materials have considerable development prospects. Porous silicon, plastic porous materials and glass porous materials are the most widely used in the field of non-metallic porous materials (Capelle et al., 2012). Compared with non-metallic porous materials, metal porous materials have developed rapidly in the late 1980s and become new materials with good mechanical properties and excellent physical properties. Porous metal materials have many advantages, such as large specific surface, small specific gravity, good silencing effect, high stiffness, high electromagnetic shielding performance, good shock absorption performance, etc (Li et al., 1999; Ferey et al., 2008). Among its many applications, metal porous materials can be used as both functional materials and structural materials. In some cases, metal porous materials have dual functions and structures. It is a multi-purpose engineering material with excellent performance. At present, porous copper, porous aluminium and porous nickel are the most concerned materials (Chen et al., 2002; Yang et al., 2017; Liu et al., 2018). The preparation methods of porous copper and copper-based alloys mainly include self-propagating high temperature synthesis (SHS), capsule-free hot isostatic pressing (CF-HIP), spark plasma sintering (SPS) (Kvanin et al., 2008; Takahashi et al., 2008; Zhang et al., 2014). However, these methods can not accurately control pore structure parameters (including pore size, shape, orientation, distribution, etc.). In porous materials, pore structure plays an important role in the overall performance of materials. In order to control pore structure parameters accurately and optimize material performance, it is necessary to explore and develop new preparation technology. In this paper, the sintering evaporation process (SEP) was introduced for the preparation of porous copper and copper-based alloys. The core process of the preparation method is hot pressing and evaporative desalination. Hot pressing can make the pore orientation consistent. Evaporative desalination can ensure the complete removal of NaCl in the form of vapor in a short time, thus eliminating the corrosion of residual NaCl on the matrix metal (Gong et al., 2011).

Jan 1, 2019

This paper describes results of an investigation of fracture during tube expansion of 5052 and 5754 aluminum seam-welded tubes to optimize the forming of aluminum tubes during hydroforming. The tubes were produced in laboratory by press forming of tubular blanks and pilot-scale high frequency induction welding. The effect of property mismatch between the weld and base metal has been investigated. The material work-hardening was obtained by roll forming of sheet blanks in the 0-temper and H32 temper condition. The results showed that a significant work-hardening can be present in aluminum tube without causing weld fracture during tube expansion. The work-hardening increases the yield-strength mismatch between base metal and weld. Annealing reduces the hardness of base metal leading to more uniform deformation during tube expansion. As a result the occurrence of weld fracture is reduced. The study showed significant deformation of the welds during tube expansion. Weld thinning can be as large as parent-material thinning before fracture. To avoid fracture at the weld joint, good formability and high yield strength of the weld is needed. FEM simulation showed that minimizing the width of the weld joint can reduce thinning of the weld.

Jan 1, 2004

By AN. Kumar

Two fabrication stages in the manufacture of pipelines are identified as causing significant deterioration of the steel plates, namely cold bending and welding. The objectives of this work include quantitative assessment of the degradation of the quality of the steel plate by the loss of fracture toughness, and an estimation of the safe working pressure. The study was conducted on three API grade steels: X42, X46 and X60. After cold bending by the UO technique, various welding technique were employed for joining of the bend plates along the pipe length. A crack-tip opening displacement parameter (CTOD) was used at the onset of initiation and at the first load maxima as the criterion for assessing the toughness degradation under various fabrication stages and regime (such as WZ, HAZ and parent body). In addition, strength, hardness and impact energy values were determined to check the degree of degradation. Microstructural and microfractographic investigation of the fractured samples were also carried out in the scanning electron microscope (SEM). X60 grade steel plate suffers from CTOD toughness loss by around 38 and 55% after welding and cold bending, respectively, for the conditions studied. A combined effect of the two stages results in a loss in toughness by around 70% for the same steel. In X42 grade, the loss in impact energy ranges from 78 to 35 J due to electrical-resistance welding study (ERW). Crack resistance curves are also obtained for the steels to study the crack growth resistance behaviour and to supplement the information on crack initiation behaviour. The orientation of the pearlite banding, as observed on the fracture plane with respect to notch front and applied loading direction appears to have a strong influence on the microvoid-coalescence mechanism of fracture as well as the toughness values. An integrated analysis of the performance of pipelines, considering all these key factors, is discussed.

Jan 1, 2005

By A. N. Kumar

Two fabrication stages in the manufacture of pipelines are identified as causing significant deterioration of the steel plates, namely cold bending and welding. The objectives of this work include quantitative assessment of the degradation of the quality of the steel plate by the loss of fracture toughness, and an estimation of the safe working pressure. The study was conducted on three API grade steels: X42, X46 and X60. After cold bending by the UO technique, various welding technique were employed for joining of the bend plates along the pipe length. A crack-tip opening displacement parameter (CTOD) was used at the onset of initiation and at the first load maxima as the criterion for assessing the toughness degradation under various fabrication stages and regime (such as WZ, HAZ and parent body). In addition, strength, hardness and impact energy values were determined to check the degree of degradation. Microstructural and microfractographic investigation of the fractured samples were also carried out in the scanning electron microscope (SEM). X60 grade steel plate suffers from CTOD toughness loss by around 38 and 55% after welding and cold bending, respectively, for the conditions studied. A combined effect of the two stages results in a loss in toughness by around 70% for the same steel. In X42 grade, the loss in impact energy ranges from 78 to 35 J due to electrical-resistance welding study (ERW). Crack resistance curves are also obtained for the steels to study the crack growth resistance behaviour and to supplement the information on crack initiation behaviour. The orientation of the pearlite banding, as observed on the fracture plane with respect to notch front and applied loading direction appears to have a strong influence on the microvoid-coalescence mechanism of fracture as well as the toughness values. An integrated analysis of the performance of pipelines, considering all these key factors, is discussed.

Jan 1, 2005

The North Saskatchewan River flows southwest to northeast through a 22-km-long valley in the City of Edmonton, supplying the drinking water to dozens of downstream communities. During heavy rains, combined sewers occasionally overflow into the river, which has a significant negative impact on the water quality and the sensitive environment. The West Edmonton Sanitary Sewer (WESS) W12, a syphon connecting the Rat Creek Trunk to the Gold Bar Wastewater Treatment Plant across the river, was designed and constructed to take the overflow to the wastewater treatment plant. Due to the complexity of the project, various 3D technologies were applied to facilitate decision-making processes. 3D models were developed for design review and design conflict detection, while 4D models were established to help create a robust construction schedule. Construction sequencing animation was used to convey design intents and demonstrate construction stages to contractors and workers. The combined applications of 3D technologies helped the project team to identify critical issues, and assured effective communication among engineers, management, contractors, and other parties. Therefore, it provided more opportunities for the success of the project.

Aug 1, 2013

By K. D. Eng, W. T. Tierney

"During the past century, the development of vehicular transportation has benefitted tremendously from the performance improvement in engines in a situation where low-cost, plentiful fuel supplies were the order of the day. Engine advances were enhanced by and also dictated fuel modification to better adapt the energy source to the power plant.In discussing the several aspects of the change in approach from ""an engine and its fuel to a fuel and its engine"", the authors touch on the following areas:1. Description of an engine concept that provides the needed flexibility in fuel appetite at good efficiency to cope with future requirement s.2. The constraints placed on liquid fuel resource energy utilization efficiency by special engine-required fuel properties and the fuel efficiency of the various engine types available.3. Future vehicle engine fuel sources. This review will put into perspective the problem associated with the net energy available from future fuel sources under extensive research and development at present.4. A brief review of test data to show that fuel-tolerant and fuel-efficient engines are viable and that, in a fuel-resource-limited future, they can be a ""light at the end of the tunnel.""The Texaco Controlled Combustion System (TCCS)The TCCS is a unique means for stratified charge operation of an internal combustion engine in such a manner as to eliminate the requirement for octane or cetane number specification for the fuel. Octane rating is an empirical engine test method that evaluates a gasoline's resistance to spontaneous ignition or ""knock."" Cetane is based on a different engine test, which determines a diesel fuel's ease of spontaneous ignition . High cetane number enhances cold starting and permits high-speed diesel engine operation. As one would expect, the fuels in current use cover a band when the two values, octane and cetane, are plotted against each other."

Jan 1, 1982

By D. D. Tannant, H. Ozturk

Thin spray-on liners are increasingly being used as rock support in underground mines. The adhesive strength between the liner and the rock surface is an important design parameter. Adhesion tests were conducted to assess the impact on adhesion of the presence of oil, water, and dust on a substrate, and the roughness and grain size of different substrates. Other factors such as curing time, loading rate, and liner thickness were also considered. Adhesion was measured using a pull test of a 33 mm diameter elevator bolt attached to an over-cored section of liner with strong epoxy. Most tests were performed using Tekflex liner material, although five other liner products were also tested. Adhesive strengths of about 2 MPa can be achieved with Tekflex under optimal conditions. Long-term creep tests showed that the adhesive strength could drop by at least 50% when the liner carries load for about a month. Where the rock surface is contaminated with dust or the rock is weak in tension, it may be difficult to reach adhesion strengths of 1 to 1.5 MPa. As the thickness of the liner increases, the adhesive strength to a substrate appears to decrease.

Jan 1, 2007

By J. Paraszczak

Application of teleoperated and automated (or ?autonomous?) mobile equipment in underground metal mines represents a promising avenue for overcoming some of the challenges facing the industry. This paper addresses the overall effectiveness of autonomous loading and haulage equipment compared with conventional human-operated machines. Factors affecting availability, utilization, and production rate are explored, and an emphasis is placed on some problems and risks not present in conventional human-operated systems, as well as on the character and criticality of autonomous equipment. The need for a more in-depth analysis of factors affecting overall autonomous equipment effectiveness is stressed; these factors should be taken into consideration at the stage of feasibility studies. The paper concludes with recommendations and directions for future research.

Aug 1, 2010

By J. Paraszczak

ABSTRACT: Application of teleoperated and automated (or “autonomous”) mobile equipment in under-ground metal mines represents a promising avenue for overcoming some of the challenges facing the industry. This paper addresses the overall effectiveness of autonomous loading and haulage equipment compared with conventional human-operated machines. Factors affecting availability, utilization, and production rate are explored, and an emphasis is placed on some problems and risks not present in conventional human-operated systems, as well as on the character and criticality of autonomous equipment. The need for a more in-depth analysis of factors affecting overall autonomous equipment effectiveness is stressed; these factors should be taken into consideration at the stage of feasibility studies. The paper concludes with recommendations and directions for future research.

Jan 1, 2010

By Jacek Paraszczak

Application of teleoperated and automated mobile equipment in underground metal mines represents a promising avenue to overcome some of the challenges facing the industry. This paper addresses the issues of overall effectiveness of the autonomous loading and haulage equipment in comparison with conventional man-operated machines. It overviews and discusses the factors affecting availability, utilization and production rate. It puts an emphasis on some problems and risks not present in conventional man-operated systems, as well as their character and criticality. It stresses the need to analyze the factors affecting OEE of the autonomous equipment more in-depth than it has been done up to date and to take them into consideration at the stage of feasibility studies. The paper concludes with some recommendations and indicates the directions of the future research in this field.

Oct 1, 2009

By R. A. Bergman, C. A. Pickles, J. M. Toguri

"Black calcium cyanide is utilized mainly as a reagent for gold extraction. It is produced by reacting calcium cyanamide, sodium chloride and calcium carbide at temperatures in the range of 1200°C to 1400°C in a smothered arc furnace. The equivalent sodium cyanide content of the product is in the range of 45% to 50% and the calcium cyanamide conversion efficiency is in the range of 90% to 95%. Since black cyanide contains impurities such as salt and lime and also because the conversion efficiencies are below 100%, the product contains unwanted materials which significantly increase the shipping costs.The impurity content of the raw materials can not be lowered without increasing their cost and/or the processes to produce them, and therefore the present research was focussed on studying those factors which affect the cyanide grade. The major variables investigated were: the heating rate, the reaction temperature, the salt to cyanamide ratio, the nitrogen content of the calcium cyanamide, moisture additions and calcium carbide additions. It was found that each of these variables had a significant effect on the product grade. The highest cyanide content of the product was obtained for salt to cyanamide mass ratios of 0.55 to 0.60. The salt reduces the decomposition rate of the cyanide and, therefore, at low salt to cyanamide ratios and at higher temperatures, the product grade is decreased. It is likely that the salt evaporates at the higher reaction temperatures and this decreases the cyanide capacity of the melt. High heating rates minimize the residence time and thus salt evaporation is reduced and higher grades can be obtained. As expected, the cyanide content increased with the nitrogen content of the cyanamide. Calcium carbide additions resulted in an increase in the product grade. The presence of small amounts of moisture in the charge caused a significant decrease in the cyanide content of the black cyanide. An equilibrium reaction is postulated in order to explain the black cyanide process and in particular the effect of calcium carbide on the product grade."

Jan 1, 2002

By H. U. Ross

"INTRODUCTION Extensive studies have been carried on pure gold to determine the various factors that affect its dissolution in alkaline cyanide solutions. With the extension of milling to refractory ores more intensive investigations on the effect of impurities in the ore on the dissolution kinetics are needed. The present work describes experiments carried on refractory flotation tailings with the object to determine how the recovery of gold could be increased. The effect of arsenic and antimony in the ore and the excessive use of lime are discussed. Control of cyanide losses is also dealt with.MECHANISM OF THE GOLD DISSOLUTION REACTION In aqueous cyanide solutions, gold is believed to be dissolved by one of the following reactions:4Au + 8NaCN + O2 + 2H20 = 4NaAu (CN)2 + 4NaOH (1)2Au + 4NaCN + 2 + 2H20 = 2NaAu (CN)2 + 2NaOH + H202 (2)2Au + 4NaCN + H202 = 2NaAu (CN)2 + 2NaOH (3) The first of these, known as the Elsner Equation is supported by )4 3,2,1(several authors while others(5,6) support reactions 2 and 3 known as the Bodlander Equations. According to Habashi(7), the overall reaction for the dissolution process is as shown in equation 2. Most of the workers agree that hydrogen peroxide is produced in the course of the reaction."

Jan 1, 1973

By P. M. Huck, R. John

"The National Uranium Tailings Program was established in 1982 to develop, in part, a mathematical predictive model which would allow the assessment of the impact of uranium mill tailings on the environment and particularly on humans. . To achieve this , various studies were undertaken to establish the role played by key constituents of the tailings. This paper summarizes the findings of a study carried out under that program, to examine the leachability of barium-radium sulphate sludges produced in the treatment of uranium mill tailings decants. The investigators performed detailed chemical an alysis of the sludge, applied geochemical computer models to investigate sludge leaching behaviour, and conducted experiments to assess the impact of bacteria on leaching. The modelling showed that the redox state o f the sludge-leachant system was the most important factor. Substantial bacterially-mediated dissolutio n of the sludge and release of radium was demonstrated experimentally under suitable reducing conditions . INTRODUCTIONIn September 1981, Phillip A. Lapp presented the final report of the National Technical Planning Group on uranium tailings research to the federal government (Lapp, 1981). Lapp' s group had performed an in-depth survey of the status of uranium tailings research in Canada and, as a result, recommended that a national program be funded in the amount of $18 .6 million. Half of this fund ing was to come from the federal government, with the two producing provinces , Ontario and Saskatchewan, providing the balance. However , the provinces declined to support the program and the federal government decided to inaugurate a reduced program with $8.5 million o f funds .In late 1982, the formation of the National Uranium Tailings Program (NUTP) was announced by the minister of state for mines. A primary objective of this program was to develop a mathematical predictive model that would permit the assessment of the impact of uranium mill tailings on the environment, a nd particularly on humans. The program was to use existing information to the greatest possible extent, and then fund research to fill in gaps or substantiate data where necessary .The NUTP was established to administer this program of contract research over a five-year sunset life. By the end of the 1986-87 fiscal year the NUTP had completed about 100 contracts. One of those projects was to study the effect of placing barium-radium sludge ba ck within the tailings matrix. Th is paper gives the results of that study."

Jan 1, 1989

By L. M. Wang, G. P. Jiang, Y. Jiang, Liao. W. S.

ABSTRACT The authors measured porosities and permeabilities for cores from a low-permeability sandstone uranium deposit in Inner Mongolia. Features studied included fine pore structure, mineral composition, cation exchange capacity, granule appearance, and cementing features. In general, grading of the grains was relatively poor, which decreased the radii of the pore channels. The pore throat distribution was significantly heterogeneous. Pore channels ranged from small to large, but the lack of large pore channels led to low permeability. Cementation by calcite and clays, including montmorillonite, chlorite, and kaolinite, resulted in pore channel narrowing, further decreasing the permeability of the formation.

Jan 1, 2014

By Parissa Mirjafari, Ron Martel, Susan A. Baldwin, Luke Moger

Mine drainage contains metals and sulfate, which may be toxic to aquatic life at certain concentrations and should be removed to acceptable levels before release of any drainage to the environment. One method for treating mine drainage is passive treatment, which is increasing in popularity due to lower construction and operating costs. This method is based on the activity of sulfate reducing bacteria (SRB) respiring on sulfate while using fermentation products from decomposing complex organic materials. The product of this biological process is hydrogen sulfide, which reacts with metals in mine drainage and precipitates them as metal sulfides. However, in practice passive treatment systems are not always effective, reducing the reliability of this approach. In this study, a mixture of hay, cow manure and wood chips was tested in continuous flow experiments for efficacy at sustainable treatment of sulfate and selenium containing water from a mine tailings pond. Factors that contributed to a decline in performance included lowering of the pH due to acids leaching out of the organics, re-oxidation of sulfide back to sulfate and a reduction in dissolved organic compounds over time. In this paper methods are described to overcome these problems so that treatment is made more reliable.

Jan 1, 2011

By W. J. S. Craigen, G. E. Wittur

"In the context of today's continuously changing world, there are many factors which must be considered when attempting to assess the ability of Canada's primary copper producers to remain competitive in the face of increasing competition in world markets. In this paper, we have attempted to document those factors that will have the greatest impact on the future viability of Canada's copper industry, and to suggest possible strategies to fully utilize whatever inherent advantages Canada may have to enhance its competitive position. Technological factors related to the efficiency of precious and by-product metals recovery, energy type and utilization efficiency, production and sale of sulphur by-products, and control of 502 emissions are given high priority in this evaluation of Canada's future needs to remain competitive. Particular emphasis is placed on assessing the relative viability of hydrometallurgical versus pyrometallurgical processes for copper; to address uniquely Canadian conditions and problems. Due consideration is also given to the economic incentives required to allow Canada's copper producers to compete under anticipated world market conditions and to facilitate the continued development of Canada's copper resources. IntroductionWhen we try to assess the viability or competitiveness of any industry the bottom line is still usually, ""Can we produce a pound of product cheaper than the competition?"" Canada's copper industry is certainly no exception. However, as with most resource-based industries dependent upon exports, there are many factors which have a significant effect on the cost components which make up the total cost of producing and selling a pound of copper. It is desirable therefore to have as clear a picture as possible of the cost components, the major factors affecting them, and how they compare with the competition, particularly the third-world copper producers.In this paper we have attempted to provide a brief outlook for world copper markets and a brief overview of Canada's competitive position. We have also attempted to document those factors which will have the greatest impact on future production costs, and have suggested possible initiatives to utilize inherent Canadian advantages to enhance our competitive position. Special emphasis has been placed on technological initiatives designed to make full use of these ""advantages"", to develop superior beneficiation and extraction! refining technologies. Major factors considered in the present study are:"

Jan 1, 1986

By C. R. Fast, G. C. Howard

The loss of fluid to the formation adjacent a fracture governs the areal extent of the fracture and the success of hydraulic fracturing as a production stimulation technique. The three flow mechanisms which control this loss are the result of the viscosity of the fracturing fluid and the permeability of the formation to the fracturing fluid, its wall building properties, and the combined effects of viscosity and compressibility of the reservoir fluid. The effects of these flow mechanisms can be evaluated in terms of a fracturing fluid coefficient, the fundamental concepts of which are developed in the paper. The fracturing fluid coefficient, which may be used in calculating the areal extent of fracturing, affords a direct measure of the effectiveness of fracturing fluids. The area of hydraulically created fractures is in-creased as the coefficient is de-creased. The fifteen-fold variation noted in this coefficient for the commercially available fracturing fluids tested resulted in a six-fold difference m the calculated areal extent of the fracture system.

Jan 1, 1961

By J. T. Liu, G. H. Han, W. C. Chai, Y. F. Huang

"In beneficiation process, metal ions could adsorb onto clay mineral surfaces or interact with flotation chemicals, and then result in the flotation behavior changing of desired minerals. Al(III) is the dominating ion existing in the bauxite flotation system. In this research, the adsorption behaviors of Al(III) on two silicate clay minerals (including bentonite and kaolin) were investigated by means of UV-Vis spectra, zeta potential testing and scanning electron micrograph analysis. The adsorption experiment results show that the adsorption capacity of clays for Al(III) ions increases with the initial Al(III) concentration, contact time and solution pH. There are some different adsorption behaviours for two clays. Increasing the clay concentration decreases the adsorption capacity of bentonite, while increases first then decreases for kaolin. Higher temperature favours the adsorption of Al(III) on bentonite but goes against for kaolin. The adsorption capacities of bentonite and kaolin for Al(III) respectively reach 12.48 and 0.875 mg/g at initial solution pH 5. Zeta potential results show that the adsorption of Al(III) on two clays is characterized by electrostatic attraction mechanism.INTRODUCTIONIn beneficiation process, there is inevitably a wide variety of metal ions generated from mineral crushing, mineral dissolution and water chemistry conditions. Metal ions adsorb on the mineral surfaces or interact with the beneficiation agents, affecting the flotation efficiency of desired minerals (DiFeo et al., 2001; Parolis et al., 2008; Shackleton et al., 2012; Shengo et al., 2014). Therefore, it is necessary to have a detailed investigation on the adsorption behaviour of metal ions on clay minerals.Having good ion exchange capacity and negative surface charge, the clay minerals could take up various metal ions from the mineral-water system. Bentonite and kaolin are very common aluminosilicate clays in the mineral processing system. These two clays both hold a permanent negative charge, =X- on the basal surfaces, and a smaller variable charge, =SiOH on the mineral edges (Gu & Evans, 2008; (Gu et al., 2010). Adsorption experiments are usually used to study the adsorption affinity of metal ions for clay minerals (Sen & Bhattacharyya, 2012). The adsorption of Zn(II), Cu(II) and Pb(II) onto natural bentonite showed that the adsorption amounts of metal ions increase with contact time, solution pH and metal ion concentration, but decreases with adsorbent concentration and system temperature (Sen & Gomez, 2011; Melichova & Hromada, 2013). Cr(III) adsorption on bentonite was significantly pH dependent. The adsorption process followed pseudo-second-order model and the equilibrium adsorption was consistent with Freundlich isotherm (Lollino et al., 2015). The adsorption behaviours of Pb(II), Cd(II), Ni(II) and Cu(II) onto kaolin indicated that increasing pH favoured the adsorption of metal ions (Jiang et al., 2010). The adsorption of Cd(II), Cu(II), Pb(II) and Zn(II) onto kaolin showed that an ion-exchange reaction occurred at pH<7.0 and inner-sphere surface complexes were prone to form at higher pH (Srivastava et al., 2005)."

Jan 1, 2016