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By Charles W. Perry

The options of enhanced oil recovery, coal syncrude, and shale syncrude are compared by approximately equivalent economics. The physical constraints for the major enhanced oil recovery processes are described, followed by new estimates of cost. The range for all three options in terms of light syncrude equivalent are $22 to $40 per barrel in 1980 dollars.

Jan 1, 1982

By Walter Crafts, D. C. Hilty

The liquidus diagram for the iron field of the Fe-S-O system has been derived experimentally. The solubility of oxygen in molten Fe-S alloys has been measured at several temperatures and found first to decrease slightly and then increase rapidly with increasing sulphur content. IT is well-known that the types, distribution, and amount of inclusions in any given steel are closely allied with the oxygen and sulphur contents of the metal, so that the term "deoxidation" as conventionally applied in steelmaking refers not only to the control of oxygen and oxide inclusions but to collateral modification of sulphide inclusions as well. Inclusions commonly occur in steel as mixtures of oxides and sulphides, sometimes closely associated and sometimes apparently completely divorced. Their effects on the properties of the metal may vary widely depending on their types and distribution as well as on their quantity. The mechanism by which inclusions form, however, and the means for controlling it are exceedingly complex and not well understood. Nevertheless, as described by Benedicts and Lofquist' and by Wentrup' all oxide and sulphide inclusions, excluding mechanically entrained matter, must result from specific modifications of the basic equilibria of the Fe-S-O system. In an investigation of the mechanism of deoxidation and inclusion formation being carried out at the Union Carbide and Carbon Research Laboratories, it became evident that quantitative data for the fundamental Fe-S-O system were essential to a better understanding of the problem. Consequently, the liquidus surface of the portion of the Fe-S-O diagram of interest in steelmaking has been determined, and the solubility of oxygen in liquid iron containing sulphur has been measured. Fe-S-O Diagram The portion of the Fe-S-O diagram of specific interest in steelmaking is the Fe-FeS-FeO corner. Of the contiguous binary diagrams for this partial system, only those for Fe-FeO and Fe-FeS are known with reasonable certainty.3 Several attempts to derive the FeO-FeS diagram have been made, chief among them being the work of Giani as reported by Oberhoffer,4 and, more recently, that of Vogel and Fulling." Although both Giani and Vogel and Fulling published diagrams for the FeO-FeS system, their observations indicated that the oxide component approximated Fe3O4 rather than FeO, so that there is doubt whether the system is truly binary. Benedicts and Lofquist and also Wentrup published qualitative sketches of the ternary diagram based on the assumption that it was of the type described by Marsh for a ternary system in which two of the contiguous binary systems are simple eutectic systems and the third exhibits a solubility gap in the liquid. Apparently, however, the only previous effort to establish the diagram experimentally was that of Vogel and Fülling whose results are reproduced in Fig. 1. Although defining approximately the limits of the miscibility gap and the location of the ternary eutectic, point E in Fig. I, Vogel and Fülling's diagram must be considered only semiquantitative. It was derived from a limited number of observations mainly along two quasi-binary sections, and the directions of the tie-lines and the location of the critical point, K in Fig. 1, were estimated by computation. Experimental Procedure The experimental technique employed for the present investigation involved melting mixtures of ferrous sulphide and ferric oxide in contact with iron. Since it was considered that in this part of the system the vapor pressures of sulphur and SO, are so low that they would not affect the results significantly, the melting was carried out in a current of argon to sweep out products of any initial re-

Jan 1, 1953

By H. E. Strauss

The time-to-fracture test has been applied to pure platinum and to two alloys of platinum under the special conditions of small cross-sectional area of the specimens and of a test temperature above the annealing temperature. While the results are similar in character to those secured with large specimens of steel at temperatures below the annealing temperatures, two differences are noted: (I) an upward inflection in the curves for log stress vs. log time for the alloys, and (2) a sharp break in the curve for log stress vs. log time for pure platinum when single crystals filled the wire. The experiments showed that: (I) platinum and 10 per cent rhodium-platinum maintained their strengths at IIOO°C. better than did to per cent iridium-platinum, and (2) the rhodium-platinum after a time exceeded the iridium-platinum in strength at IIOO°C. Platinum alloys in their service at high temperatures encounter conditions somewhat similar to those that exist in the usual form of the "time-to-fracture"l test with steel. This paper is intended primarily to present results obtained by a "time-to-fracture" test under conditions approximating actual service for platinum (at the temperature IIOO°C. under oxidizing conditions) with three materials, pure platinum (99.99 per cent), a platinum alloy with 10 per cent iridium, and a platinum alloy with 10 per cent rhodium. The experimental procedure differed from that previously used in this type of measurement in that the samples were of small diameter (0.010 in.), were fully annealed, and were tested at a temperature definitely above their annealing points (600°C., IOOO°C. and 1050°C., respectively, for 60 per cent cold reduction and 15 min. heating time2,3). The experimental arrangement was similar to that previously described,' using as heating unit a small, horizontal, platinum-wound furnace, ½ by 12 in., maintained at constant temperature by an automatic controller. The samples were 0.010-in. wires, which had been annealed at 1200°C. by drawing them slowly through the furnace. The time-to-fracture was measured electrically. Elongation was not determined because of the difficulties inherent in the experimental arrangement. Life—that is, the time-to-fracture—was considered the important property in these first tests. No attempt was made to measure the reduction in area, but the types of fracture were noted qualitatively; in the text they are referred to as (I) the normal, plastic, or necked fracture, (2) the knife-edge fracture, and (3) the brittle or intercrystalline fratture with small reduction of area. Results for different constant applied stresses are plotted in Fig. I. In all cases at least two trials were made for each stress, although they cannot always be indicated separately on the curves. The breaking Stresses drop very rapidly to a small frat-286

Jan 1, 1943

By W. G. Pfann

In zone-melting, a small molten zone or zones traverse a long charge of alloy or impure metal. Consequences of this manner of freezing are examined with impurerespect to solute distribution in the ingot, with particular reference to purification and to prevention of segregation. Results are expressed in terms of the number, size, and direction of travel of the zones, the initial intermsofsolute distribution, and the distribution coefficient. IF a charge of binary solid-solution alloy is melted and then frozen slowly from one end, as for example in the Bridgman method of making single crystals,' coring usually occurs, with a resulting end-to-end variation in concentration. Such coring, or normal segregation, is undesirable where uniformity is an object. On the other hand, for certain systems, it can be utilized to refine a material by concentrating impurities at one end of the ingot.'. ' In the present paper a different manner of freezing will be examined with respect to the distribution of solute in the ingot. A number of procedures will be indicated which have in common the traversal of a relatively long charge of solid alloy by a small molten zone. Such methods will be denoted by the general term zone-,melting, while the process described in the preceding paragraph will be called normal freezing. It will be shown that, in contrast to normal freezing, zone-melting affords wide latitude in possible distributions of solute. Segregation can either be almost entirely eliminated or it can be enhanced so as to provide a high degree of sttparation of solute and solvent. A number of simplifying assumptions will be invoked which, while not entirely realizable in practice, nevertheless provide a suitable point of departure for more refined treatments. Moreover, our own experience with zone-melting has shown that, for certain systems at least, the analysis holds quite well. The present paper will be confined to a discussion of principles and a general description of procedures. Comparison with experiment is planned for later publication. Normal Freezing Before considering zone-melting, segregation during normal freezing will be reviewed briefly. If a cylinder of molten binary alloy is made to freeze from one end as in Fig. 1, there usually will be a segregating action which will concentrate the solute in one or the other end of the ingot. If the constitutional diagram for the system is like that of Fig. 2, then the distribution coefficient k, defined as the ratio of the concentration in the solid to that in the liquid at equilibrium, will be less than one and the solute will be concentrated in the last regions to freeze. If the solute raises the freezing point, then k will be greater than one and the solute will be concentrated in the first regions to freeze. The concentration in the solid as a function of g, the fraction which has solidified, can be expressed by the relation: C = kC0 (1-g)k-1 [I] where C, is the initial solute concentration in the melt. Eq 1 is based on the following assumptions: 1—Diffusion in the solid is negligible. 2—Diffusion in the liquid is complete (i.e., concentration in the liquid is uniform). 3—k is constant. Concentration curves representing eq 1 for k's from 0.01 to 5.0 are plotted in Fig. 3. This equation, in one form or another, has been treated by Gulliver,³ Scheuer,4 Hayes and Chipman5 for alloys and by McFee2 for NaCl crystals. It is derived in Appendix I. It should be pointed out that the k which is calculated from the phase diagram will be valid only in the ideal case for which the stated assumptions are correct. In all actual cases, the effective k will be larger than this value for solutes which lower the melting point, smaller for solutes which raise the melting point, and will probably vary during the beginning of the freezing process. For simplification it will be assumed that the ideal k is valid. Zone-Leveling Processes The processes of this part are designed to produce a uniform, or level, distribution of solute in the ingot. Single Pass: Consider a rod or charge of alloy whose cross-section is constant and whose composition, C2, is constant, although permissibly varying on a microscopic scale." Such a charge might be a rapidly frozen casting or a mixture of crushed or powdered constituents. Cause a molten zone of

Jan 1, 1953

IF you wish to make the acid that is vulgarly called common aqua fortis,* for parting gold from silver, you must first provide as many cucurbits and alembics, receivers, and materials as you wish, and then make a furnace that is long and conveniently wide for holding three or four pairs of cucurbits or as many as you wish. If you have to make this by art in order to work a large quantity, you could make several small furnaces for it seems that not more than three or four pairs are suitable for one. Prepare the places where the cucurbits are to stand with bottoms or covers made of potter's clay or tiles that are half round like the bottoms of the cucurbits and have a little rim around the top so that they can be built in. Proceed to build these in in pairs, one by the other with convenient spaces between, placing an iron support across to make this place stronger and more secure. In every corner and also in the middle a hole must be made as a vent for the smoke, as is done in all furnaces. You will see the form of this somewhat roughly drawn here. [Figure 25] Near this prepare a number of cucurbits which are made of glass, as clear and uniform as possible and very well formed. There must be no bubbles or other indentations in these, for they would be dangerous and uncertain for your work. Lute these with lutum sapientiae up to within three dita or less from where the neck narrows. This lute must be spread out well all over to the thickness of two threads or a little more. Then cover and make them strong with this well-made plaster, and finally dry it, taking care that there are no clefts or cracks such as clays are often prone to make even though they be well prepared. For greater security choose among these [64v] a clay that is lean and then mix it with at least a fourth part or more of wool-clloth clippings and about an eighth part of wash

Jan 1, 1942

By Earl S. Greiner, Eric R. Jette

The constitution of the iron-silicon alloys containing from 14 to 33.4 weight per cent silicon has been studied by a number of investigators, whose results have been reviewed in a monograph published by the Engineering Foundation1. In these previous researches, the solubility of silicon in iron was determined by thermal, microscopic or magnetic methods and the compound Fe3Si2 was reported to be stable at temperatures from 0 to approximately 1030' C. This paper describes the results of an X-ray investigation of the solubility of silicon in iron and gives data which prove that the Fe3Si2 phase is unstable below 825" C. In order to obtain the present results on the solubility of silicon in iron, the authors have utilized the lattice constants of the alpha-phase iron-silicon alloys given in a previous publication2, and also some additional data which will subsequently be described. Materials and Methods The alloys used in this investigation are listed in Table 1. They were prepared in 30 or 50-gram ingots by melting specially purified silicon and electrolytic or carbonyl iron in alundum crucibles under a pressure of less than 1 mm. of mercury. The purity of the silicon, electrolytic and carbonyl irons has been given by the authors in previous publications2, 5. The ingots were homogenized in vacuo at approximately 1000" C. for at least 96 hr. and then slowly cooled. The homogenized specimens were ground to powder in a hardened steel mortar. This powder was passed through a 150 or 200-mesh screen and sealed in evacuated quartz, Jena or Pyrex glass tubes and heat-treated as noted in the various tables. Specimens 23A, 24B, 33 and 35 and the specimens heated for one month at 700" C. were quenched by quickly removing the tubes from a horizontal tubular furnace and dropping them into water. The other specimens were quenched by means of a drop-quenching device, which has been described previously3.

Jan 1, 1937

By F. N. Rhines

STUDIES upon the sintering of metal powders, in the solid state, have led to the proposal that the surface energy of the powder particles provides the driving force that causes points of contact between pairs of particles to grow into broad welds which isolate the residual vacant space into pores that tend to spheroidize and gradually to diminish in total volume.' Investigators differ with regard to the mechanism of the movement of the metal, under the influence of surface energy, to accomplish these changes. One school asserts that there is a mass movement of the metal, referred to as a "viscous flow," while the other school prefers to view the movement as a self diffusion process, wherein individual atoms are, transferred without disturbance of the basic pattern of the crystal lattice. Extensive experimental studies upon the sintering of copper, conducted recently by A. J. Shaler,2 have been in- terpreted by their author as support for the viscous flow mechanism of transport, the theory of which was developed originally by J. Frenkel.3 Duplicating a portion of this work with minor changes, G. C. Kuczynski4 is led to the alternate view, namely, that the initial stages of sintering, at least, proceed as a self-diffusion process. Both of these investigations were designed to deal with an isolated unit of sintering, i.e., with the shrinkage of a single pore, or with the growth of a single point weld. It remains to ascertain the behavior of a typical metal powder compact composed of a large number of particles of varying size and sintering to a body with a multiplicity of pores. The observation of density changes alone during sintering is not sufficient in such a case; it is essential to know how the internal geometry of the compact changes. This has been the object of the present investigation, the results of which are used to support the self-diffusion mechanism of sintering. The present studies consist in the measurement of the number of pores as a function of size and time at temperature during the sintering of a copper compact made from a commercial copper powder lightly pressed and sintered in several different atmospheres. A brief survey was made also of the change in shape of the pores, under the influence of the same variables. All of this was done by direct observation with the microscope. Densities were measured on the same sample. It is found that, while the compact is exhibiting an overall shrink-

Jan 1, 1951

By T. Sterry Hunt

BUT little was known of the coals of Southeastern Ohio until the present survey of the State under Dr. Newberry began its work. The results of the geological investigations of Prof. E. B. Andrews in this region, and of the chemical investigations of Prof. T. G. Wormley, both of which appear in the reports of the survey for 1869 and 1874, and more recent special reports by the former, together with some data for which I am indebted to the kindness of Dr. Newberry, and my own limited observations, have served me for the preparation of the following notice of the coals lying on the western border of the great Appalachian coal-basin in the region drained by the Hocking River and its tributaries, and belonging to the Lower Coal-Measures. Some uncertainty exists as to the place in the succession of the lower coals to be assigned to the seams known and mined in the Hocking Valley. It is the opinion of Prof. Andrews that the inequalities of the original surface were such that we cannot identify in that region the lowest coals known in Northwestern Pennsylvania and the contiguous parts of Ohio, but that we must rather count from above downwards. These conclusions Dr. Newberry is not prepared to accept, and further researches will be necessary before certainty can be attained in this matter. Meanwhile it seems, from a study of its relations to the Pomeroy or Pittsburgh seam, that what is known as the great vein of the Hocking Valley, occupies the horizon of the Upper Freeport coal, E of the Pennsylvania survey, or No. 6 in Dr. Newberry's enumeration, counting from the base. This seam, in the region in question. assumes certain characteristics which, taken in connection with its geographical position, give it a great importance among the coals of the State. The area to be noticed includes the whole or parts of several townships in Perry, Hocking, Vinton, and Athens Counties, lying near the margin of the basin over which the vein in question assumes the character of a dry-burning or splint coal, and has a thickness varying from six to ten and even twelve feet. Its precise limit southward cannot at present be clearly defined, but it has been found as far south as the line of the Marietta and Cincinnati Railroad, with a thickness of six feet, and is mined at various points along the valley of the Hocking River, near Nelsonville, where it attains six or seven feet. To the northward, along the tributaries of this river, Sunday and Monday

Jan 1, 1874

By Michel David

One of the most important questions that arises in ore estimation can be stated as follows: What is the error when one extends the grade of a sample to a certain volume? The theory of regionalized variables, with the concept of extension variance, provides a response to that crucial question for any kind of sample extended to any volume. For the usual "extensions" encountered in current mining practice, some simple results can be derived from that theory which was initiated by Dr. G. Matheron. These results have been applied to a stratiform lead-zinc deposit for which several estimations of grade, tonnage and related precision have been made for a series of grid sizes such as might be used in a progressive exploration program.

Jan 1, 1969

By H. M. Woodrooffe

Three of the world's largest phosphate deposits are located in the USSR. These have an estimated reserve of 2,600 million short tons of elemental phosphorus. The best known lies in the Khibiny Massif, an alkalaic rock formation some 600 square miles in area with mountain peaks rising to an altitude of 3300 ft above the surrounding terrain. The Khibiny Massif is north of the Arctic Circle in the Kola Peninsula at a latitude of 67° 30' north and a longitude of 35° 30' east. It is connected by rail to Murmansk, 100 miles northwest, and Leningrad, 900 rail miles south.

Jan 12, 1972

By R. J. Wagner, Jim Douglas Jr., P. M. Blair

The calculation of the behavior of an oil reservoir during a water flood has long been an important problem to reservoir engineers. Buckley and Leverett derived the differential equation which describes the displacement of oil from a linear porous medium by an immiscible fluid, but this equation could not be solved by the methods of classic mathematics. Consequently, in order to integrate the equation over the length of the reservoir, they neglected the effects of capillary pressure. In the present paper, a numerical method has been developed for determining the behavior of a linear wafer flood with the inclusion of capillary pressure. The differential equation which was derived for the case of incompressible fluids is second order and non-linear. This differential equation was approximated by an implicit form of difference equation which is second order correct in both time and distance. An electronic digital computer was used to perform the numerical solution of the difference equation. INTRODUCTION The problem of calculating the flow and distribution of fluids in an oil reservoir subjected to a water flood has long challenged the reservoir engineer. The ability to solve this problem would provide a valuable tool for the design and study of field waterflooding programs. One of the first contributions in this field was made by Buckley and Leverett,'.' who developed a method of calculating waterflood performance in a linear reservoir. Their technique was limited by the practical necessity of excluding quantitative consideration of capillary pressure. It is the purpose of this paper to describe a method for calculating the behavior of a linear water flood with capillary pressure considered. This method, although limited to the linear case, should serve as a step toward the solution of the two- or three-dimensional waterflooding problem which would better describe actual reservoirs. The treatment of the problem has assumed that the reservoir is linear and homogeneous, that both oil and water -are incompressible, and that gravitational forces may be neglected, and that water is injected into one end of the reservoir and oil and water are produced from the other. Though these assumptions may not be directly applied to natural reservoirs, they are closely approached in many laboratory core tests. The physical problem has been represented mathematically by means of a differential equation and suitable boundary conditions. The inclusion of capillary pressure effects causes the differential equation to be second order and non-linear, and it is not amenable to solution in terms of known functions. Nevertheless, the problem may be solved by numerical methods. The authors have successfully calculated several cases from the start of water injection through to depletion of the hypothetical reservoir using realistic capillary pressure and relative permeability characteristics that were chosen so as to put the method to a test. DIFFERENTIAL EQUATION In two- or three-dimensional problems involving the two-phase flow of incompressible fluids through a porous medium, the equations describing the flow can be combined until only two dependent variables remain, the pressure in one phase, and the saturation of one phase. These variables appear in two simultaneous partial differential equations which are derived on the basis of the conservation of mass and Darcy's law as applied to two-phase flow. For a linear reservoir, this system of differential equations can be reduced to a single, nonlinear, second order, parabolic differential equation for one dependent variable, the saturation of one phase. For incompressible water and oil, it can be shown that the conservation of mass for the two phases requires that Where q, and q, are the water end oil flow rates per unit cross-section, s, and so their saturations, +, the porosity, and [ and T, dimensional space and time variables. Darcy's law, as extended to two-phase flow including the effect of capillary pressure,' is as follows:

By M. Albertson

At Cobalt, Ontario, Canada, a lake was drained to facilitate mining, by the Mining Corpn. of Canada, during the spring and early summer of 1915. Previous to pumping out the water, great quantities of sands and slimes from concentrating plants had been discharged into the lake and during and after the lake's drainage, its basin was a receptacle for tailing products. As the writer was at work along the shore line as the lake was being drained, he had a good opportunity to observe the changes that took place as the water was withdrawn. Some adjustments between the incoming sands and the mud in the lake had taken place before pumping was commenced. One of the most interesting results was the appearance of a small dome in a path the writer traversed twice a day for several months; he remembers distinctly the difficulty of crossing this. Cobalt Lake owed its existence to the gouging out of a rock basin by glaciation. The long axis of the basin closely follows the strike of a thrust fault of about 500 ft. (160 m.) vertical displacement. The lake was originally shaped somewhat as shown. The length was about 3000 ft. (914.4 m.), the width at the lower lobe was about 1000 ft., and the width at the narrows probably 400 to 500 ft. The original depth of water varied from 20 to 30 ft. (6.1 to 9.1 m.), near where the island later was formed, to 60 to 70 ft. (23.6 to 27.6 m.) in the widest part of the lower lobe. At the narrows, the depth was 30 to 40 ft. Above the bed rock was sand, with boulders near the bottom, and mud. During the building of the railroad in 1903, considerable filling was done along the right of way. With the commencement of mining operations, about 1905, waste rock and mill tailings were dumped into the lake. One of the mining companies operated a hydraulic giant to remove the glacial debris from several hundred acres of rock surface; much of the sand and clay from this operation was deposited in the lake. About 1,500,000 tons of mill tailings, composed of sands and slimes, were discharged into the lake's waters previous to 1915. Most of this material

Jan 1, 1921

By David R. Mitchell, R. B. Hewes

MANY processes for cleaning coal that are in use depend primarily on physical properties of coal and refuse other than specific gravity and surface conditions relating to froth flotation. These properties are shape, coefficient of sliding friction, resilience, friability, magnetic susceptibility, and electrical conductivity. In many of these processes specific gravity does have some effect and many separators are designed to utilize more than one of the physical properties cited. Although the processes described herein do not have a widespread application, yet for specific coals and specific conditions, they are economically important. A problem confronting many coal-mining districts is the marketing of the slacks or screenings and dust passing the final sizing screens. Processes in commercial use installed primarily to increase the form value, and hence the market value, of these slacks and dusts include briquetting, packaging, and low-temperature carbonization. MECHANICAL PICKERS Machines utilizing shape, frictional resistance, and differences in resilience of coal and impurities are usually called mechanical pickers. They require a closely sized feed, therefore their use is confined to the pea, nut, and egg sizes. Various types of these devices are described by Berrisford, 1, 2 Taggart,3 and Peele.4 Shape In general, coal differs in shape from its accompanying dirt throughout the range of commercial sizes. Coal, breaking into roughly cubical particles, contains a greater number of axes that are approximately the same length than does the dirt. The latter, consisting of pieces of slate and shale and lenses of pyrite, is flatter in nature. Further, flat coal often has a dirty, slaty appearance, even though of high quality. Mechanical pickers known as flat pickers, or "flatters," are widely used in the Pennsylvania anthracite region to remove flat coal .from the final clean coal. This practice greatly improves the appearance of the final market product. Flat pickers for removing impurities or flat coal ("flats") are usually installed on shaker screens, shaking conveyors, and chutes. In Fig. 1 three

Jan 1, 1950

By Frank L. Nason

The complete statistics of zinc-ore production in the United States for 1916 are not yet available. The following figures are, therefore, only approximate. The total production of concentrates for this year, including New Jersey and Tennessee, amounts to 1,280,000 tons. Of this tonnage, five mines produced approximately 536,000 tons, or about 42 per cent. The remaining concentrates came mainly from the "Valley States," Missouri, Wisconsin, Kansas, Oklahoma, and Arkansas. The 1,280,000 tons of concentrates represent about 25,000,000 tons of crude or run-of-mine ore. Of the five mines producing the 42 per cent., the dimensions of three are approximately 25 by 1500 by 2000 ft. (7.6 by 457 by 610 m.) or more: Four of the five mines are undoubtedly veins in the common acceptance of the term. They are located in great vein systems. The mines of "Valley States" have not, so far, been classed as veins; simply as "secondary deposits." The origin of these secondary deposits has been a warmly debated subject. Many geologists contend that they are the results of leaching from overlying and adjacent rocks carrying but traces of zinc, these traces leached out and deposited in favorable places. If this theory is correct, deposition is strictly limited to shallow depths. No volume of ore comparable to that of "true fissure veins" is to be expeeted. Just what this means to the future of zinc mining in these States is here indicated. The total zinc-bearing areas of these States amount to about 9124 sq. miles (23,631 sq. km.). Assuming that 10 per cent. of this total will be more or less productive, there are 912 sq. miles (2,362 sq. km.) of "mineral" ground. The average depth of the operated mines is something like 100 ft. or less. In Bulletin 606, U. S. Geological Survey (1915), p. 202, Siebenthal makes the following statement: "The writer is informed by William Waugh, one of the drillers of the Stone City well, that cuttings from other wells which he drilled in the vicinity of Pittsburgh, Kan., have shown galena and sphalerite taken from a depth of 591 ft. (180.14 m.) and that the showing of ore at some places would be considered good enough to justify the sinking of a shaft had it been found in the Joplin district and at shallower depths." Leaving out of the question the prohibitive cost of such a shaft, there is

Jan 1, 1918

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Jan 1, 1938

By R. J. Lytle

Geophysical exploration for engineering purposes is conducted to decrease the risk in encountering site uncertainties. Such studies are needed in construction of underground facilities. Current responsibilities, opportunities and challenges for those with geophysical expertise are defined. These include: replacing the squiggly line format, developing verification sites for method evaluations, applying knowledge engineering and assuming responsibility for crucial national problems involving rock mechanics expertise.

Jan 1, 1982

By Robert Goodrich

EXPERIMENTS ON A PORPHYRY COPPER ORE FROM BISBEE, ARIZ. THIS research was done partly in the non-ferrous laboratory of the Department of Metallurgy of Columbia University, under the direction of Dr. Edward F. Kern, and completed elsewhere. Acknowledgment is due to Prof. Arthur L. Walker, Dr. Edward F. Kern and Dr. William Campbell of the Department of Metallurgy, for their kind advice and for the inspiration derived from their instruction. This report is given under the following heads: Petrographic Description (Microscopic Study); Sampling and Preparing Ore for Treatment; Chemical Analysis; Treatment of Ore. PETROGRAPHIC DESCRIPTION Texture: Variable. Fine to medium mixed aggregate. Original structure: Obscure. Secondary structure: Fractured; healed.

Jan 8, 1915

By Zay Jeffries

IN this paper, it is proposed to outline a method for the determination of melting points of those metals and alloys having high fusion temperatures. The application of the method as used to determine the melting points of alloys of tungsten and molybdenum will be given. It will be seen from these results that tungsten and molybdenum form a completely FIG. 1.-PARTIAL SECTION OF APPARATUS USED TO DETERMINE MELTING POINTS OF TUNGSTEN AND MOLYBDENUM ALLOYS. isomorphous series. This is also verified by the accompanying photomicrographs. Tungsten and molybdenum have been found to crystallize in the salve system, namely, isometric, and the crystal units are cubes. These determinations were made by examining etching pits in the pure metals.

Jan 7, 1916

By W. C. Kerr

A brief sketch only is here intended, with a few illustrations, in order to give a general notion of the character and structure of these veins. I have stated elsewhere, several years ago, that these veins were wrought on a large scale and for many ages by some ancient peoples, most probably the so-called Mound Builders; although they built no mounds here, and have left no signs of any permanent habitation. They opened and worked a great marly veins down to or near water-level; that is, as far as the action of atmospheric chemistry had softened the rock so that it was workable without metal tools, of the use of which no signs are apparent. Many of the ladgest and most profitable of the mines of the present day are simply the ancient Mound Builders' mines reopened and pushed into the hard undecomposed granite by powder and steel. Blocks of mica have often been found half imbedded in the face of the vein, with the tool-marks about it, showing the exact limit of the efficiency of those prehistoric mechanical appliances. As to the geological relations of these veins, they are found in the gneisses

Jan 1, 1880

By T. Yoshioka, Paul A. Beck

SILICON, germanium, and tin occur with both the white tine-type structure and the diamond cubic structure. In the latter form these elements are semiconductors; in the former they are metallic. The metallic form of germanium and silicon is obtained only under high pressure.' For all three elements the transition from the semiconductor to the metallic state is accompanied by a decrease in the atomic volume of somewhat more than 20 pctily2 Table I. At such a large compression the widening of the s and p bands is sufficient to make the energy gap of 1.1 ev, or less, of the semiconductor disappear, giving rise to the metallic state.*

Jan 1, 1965