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By Henry H. Ginsberg

The Federal Bureau of Mines made pilot plant investigations of the process requirements necessary to produce heavy fuel oil by the liquid-phase hydrogenation of bituminous coal. The investigation was carried out in three separate series of experiments. The first series studied the effect of temperature and contact time on product distribution at 3,500 p.s.i.g. and 420° to 480° C. in the presence of 0.1 wt.-pct../ stannous sulfide plus 0.05 wt.-pct. iodoform based on gross coal. As a result of increased contact times and temperatures, the conversion-6/ and yield of hydrocarbon gas increased, the viscosity of product oil decreased, and elimination of oxygen, nitrogen, and sulfur from coal increased. The yield of oil did not indicate any definite trend with changes in temperature and contact time. The yield of oil ranged from 76 to 85 pct. for Pittsburgh coal and from 60 to 85 pct. for Rock Springs coal. Asphaltenes in the product oil ranged from 17 to 38 pct. of the total oil for Pittsburgh coal and from 12 to 22 pct. for Rock Springs coal. Fuel oils meeting Bunker C or American Society for Testing Materials (ASTM) Grade 6 specifications were produced with Rock Springs coal at 0.2- to 1.0-hr. contact time and 440° to 480° C. and with Pittsburgh coal at 0.3- to 1.0-hr. contact time and 420° to 460° C. In the second series of experiments tin, nickel, iron, and zinc were evaluated as catalysts for the hydrogenation of Rock Springs coal to heavy fuel oil at 3,500 p.s.i.g. and 460° C. Using the apparent conversion of coal as criterion of catalyst activity, at a contact time of 0.45 hr. tin was the most effective catalyst; nickel and iron were nearly as effective, but the use of zinc resulted in much lower conversion. When the contact time was increased to 0.80 hr., the apparent conversion of coal was essentially the same for each of the catalysts. When the yield of oil boiling below 3550 C. was used as criterion of catalyst activity, at 0.45 hr. the order of activity was tin, iron, nickel, and zinc; at 0.80 hr. tin was far superior and the others were essentially equal. The product oils contained from 8 to 20 pct. asphaltenes.

Jan 1, 1960

By G. L. Oldright

This paper is the second of a series that is to appear on smelting in the lead blast furnace. The objects of this investigation are to determine the conditions obtaining within the blast furnace by direct experimentation, and to correlate the behavior of the furnace at various times with the main factors governing the operation of the blast furnace, and metallurgical losses. The writers wish to express their appreciation to the management of the International Smelting Company at Tooele. Utah, for their kind cooperation which made possible the assembling of these data.

Jan 1, 1929

By T. S. Heah, S. T. Bishop

"The Lorraine property is located in the northern Intermontane Belt, north-central British Columbia. The property is underlain by intrusive rocks of the Duckling Creek Syenite Complex, an Early Jurassic, alkaline phase of the Late Triassic-Early Cretaceous Hogem Batholith. Two significant zones of copper-gold mineralization have been explored to date; the Main zone (historical Upper and Lower deposits) and the recently discovered Extension zone. A combined geological resource was estimated in 1975 for the Main zone deposits at 10 million tonnes averaging 0.7% Cu, and from 0.1 g/t Au to 0.34 g/t Au. The Extension zone, still at an exploration stage, is estimated to be considerably smaller than the Main zone.Copper-gold mineralization at Lorraine Mountain exhibits characteristics suggestive of both magmatic and hydrothermal origins, and may be related to orthomagmatic-hydrothermal fluid flow contemporaneous with magmatism and development of migmatitic fabrics. A depth greater than the depth of formation of classical porphyries may explain many of the variations displayed by mineralization at Lorraine. These characteristics distinguish Lorraine from other members of the alkalic suite of porphyry Cu-Au deposits in the Canadian Cordillera.IntroductionThe Lorraine prospect is located in the Omineca Mountains, at the headwaters of Duckling Creek, 56 km northwest of Germansen Landing (Fig. 1). The property is centred at latitude 55°55'N, longitude l25°26'W on NTS mapsheet 93N/14W. The area is typified by mountains of moderate relief, with elevations ranging from 1150 m in the valleys to peaks of 2000 m. Valleys are U-shaped and blanketed by glacial till which give way to steep, talus covered slopes and sharp ridges. Outcrop is generally limited to elevations above 1600 m (Fig. 2)."

Jan 1, 1995

By S. B. Christy

This report on the electrodeposition of gold and silver from cyanide solutions represents work that has occupied my time at intervals during the past 20 years. The investigation has been carried on simultaneously with my duties as professor of mining and metallurgy of the University of California. During shis long investigation I have been assisted in the details of the work by, a number of my former students, acting in turn as assistants. Particular mention in this connection is due W. H. Hilton, who graduated in 1900; C. T. Dozier, 1902; N. C. Stines, 1905; H. N. Herrick, 1907, and L. C. Uren, 1911. It is impossible to publish full details of the many thousands of experiments performed. Effort has been made to present only the essential data. Wherever possible, the results of the experiments have been expressed in diagrammatic form by curves showing the relation between the simultaneous variables of the experiments. It is necessary to show, as nearly as may be, the state of the art. This is difficult because of the meager literature on electrodeposition in the cyanide process; hence resort must be had to the specifications and claims of patents, most of which seem never to have been applied on a working scale. Such information consequently can not be taken at its face value. Expressing the essential ideas evolved in such specifications is no easy task. Clearly, in quoting from patent records it is not ·feasible to enumerate all of the specifications or the claims allowed the inventors. A statement of the chief contributions to the art in the patent cited must suffice. Legal details, of course, must be obtained from the original patent. In the study of patent literature, when one compares the ardent hopes of the inventors with the results realized from their efforts, it becomes clear that in the development of an art no one man contributes everything. Each subsequent inventor stands on the shoulders of the one who has gone before. It is only through the summation of the contributions of many inventors that the art as a whole prospers. On October 19, 1887, a British patent was granted to McArthur and Forrest for the use of dilute cyanide solutions for treating gold and silver ores. The rapid extension of this process, in various forms, all over the world, has almost revolutionized the treatment of ores containing precious metals. It is a remarkable fact, however, that long before this patent was granted there was issued, on February 5, 1867, to J. H. Rae, U. S. patent 61866, for an electrocyanide process. Thus a method of electrodeposition from cyanide solutions used for treating ores was invented 20 years before the McArthur and Forrest patent .was granted, although the process did not come into general use. On May 24, 1889, U. S. patent 403202 was granted to McArthur and Forrest for the use of zinc shavings for removing gold and silver from cyanide solutions. The use of finely divided zinc is still the standard method for recovering 'gold and silver from cyanide solutions. Since this patent was granted, many attempts have been made to replace the precipitation upon the zinc by methods of electrodeposition. It is the purpose of this report to give an outline of some of these methods, as well as to show the relative advantages and disadvantages of the zinc and the electrical methods of recovering gold and silver from cyanide solutions.

Jan 1, 1919

By Norman L. Wimmler

Active placer mining in Alaska began near Juneau in 1880, but the first gold rush did not start until 1896; then the discovery of the Klondike brought gold seekers from all parts of the world. A few of the newcomers were experienced miners, but the majority knew nothing whatever of placer mining. Even those who were placer miners of much experience found entirely new conditions, notably frozen ground, that presented many difficult problems. As a result, numerous methods of mining and of thawing frozen ground were tried. From these trials the practice described in this bulletin has been developed. All known placer fields in Alaska have been mined to some extent, and some have been virtually exhausted. In most districts, however, there remain large quantities of low-grade gravel and also some small isolated areas of comparatively rich gravels which could not be successfully mined because of adverse physical conditions. These districts are now the scene of most placer mining, including dredging, hydraulicking, drifting, mechanical methods of open-cut mining, and ground sluicing (or booming) followed by " shoveling-in."

Jan 1, 1927

By C. M. Harrer

The location, features, qualities, and extent of iron occurrences and the associated resources--limestone and dolomite, bentonite, coal-lignite, petroleum and natural gas, power, and water--are evaluated. The results of pioneer beneficiation tests on South Dakota taconite are discussed. In addition, pertinent features of taconite development, cost factors, the Western and Central United States trade area and markets are reported. The State's production of iron ores until 1963 has been small and for purposes other than the manufacture of iron. This investigation disclosed the probability of large resources of taconite in Pennington and Lawrence Counties. The average iron content is 29 percent, and a 65-percent or better iron concentrate might be produced. Ample resources are available for mining and processing taconite. An investment of at least $26 million would be required for a plant capable of turning out 1 million tons of agglomerated iron concentrate per year. The feasibility of such an enterprise is indicated, but intensive investigation and research must be completed to justify such an investment,

Jan 1, 1966

By Jr. Flynn

This U.S. Bureau of Mines publication is a compilation of fundamental cyanide chemistry data obtained through review of the scientific literature. It includes information on thermodynamics and chemical equilibria, ultraviolet-visible and infrared spectra, and the chemistry and photochemistry of cyanide, chemical species derived from cyanide, and metal cyanide species. It also includes guidance on the use of the data for solving practical problems in precious metals applications. This publication is intended mainly for use as a reference by personnel in the precious metals industry and regulatory agencies, and other cyanide users, to provide comprehensive information on cyanide chemistry. The document should assist in the formulation of effective policies for cyanide control in the construction, operation, and closure phases of precious metals mining and metallurgical operations. In addition, the data in this publication will be useful in other contexts, such as dealing with industrial cyanide usage, cyanide-containing wastes and associated environmental problems.

Jan 1, 1995

By A. E. Ketler

The Bureau of Mines Research Program has defined per coal miner's illumination needs. Due to similarity in the environment in which coal and Hardrock miners work, coal mine illumination technology has been applied to Hardtack room and pillar mines.

Jan 1, 1977

By Joseph L. Young, Richard A. Bohling

To keep Homestake's Bulldog Mountain silver and lead mining and milling operation in southwestern Colorado workable, natural ground water and decant water from the mine's sand backfilling operation must be continually pumped from the workings. Left untreated, this water exceeds maximum allowable levels for various contaminants that may be discharged to the environment. To comply with regulations, a National Pollutant Discharge Elimination System (NPDES) permit was obtained and a mine water treatment plant for heavy metals removal was constructed in 1977. Due to equipment capacity and operational problems, and the lack of on-site technical personnel and analytic equipment, the first water treatment plant could not consistently meet permit limits. In 1979, Homestake entered into a consent decree with EPA and the Colorado Department of Health, calling for the construction of a water treatment facility to meet NPDES permit limits. Initial construction began in the spring of 1980 and the plant now produces effluent acceptable for discharge.

Jan 12, 1981

By R. A. V. Raff

Although falls of roof, face and rib (or side) of coal mines were the third ranking cause of disabling accidents in 1966, the accidents from these falls resulted in the most serious injuries and accounted for approximately 50 percent of the total fatalities (I). Further breakdown of these statistics shows that 88 percent of the fatal accidents occurred within 100 feet of the working face and that 96 percent of the deaths were in bituminous mines, with only four percent taking place in anthracite workings. These figures demonstrated the need for improved reinforcement procedures in operational coal mines, and they provided ample justification for research in the area of accident prevention. The purpose of this project was to investigate the use of polymers and of related techniques to achieve rock bonding and reinforcement of coal mine structures, in order to obtain better or permanent ground support (e.g., drifts, entrees, coal and ore passes, galleries, tunnels and shafts) by the fill ing of fissures in the rock, thereby preventing or delaying the onset of serious rock degradation processes.

Jan 1, 1973

By Kevan J. R. Ford, Chris A. Fleming, Robert D. Henderson

"Kinross Gold Corporation’s Maricunga mine in Chile presents an ideal opportunity to apply the SART process to a heap leach operation. Given increasing levels of cyanide complexed copper in current pregnant solutions from Maricunga heaps (over 300 ppm Cu), there is a need to reduce these levels and decrease cyanide consumption and cost. Additionally, a means of disposing of this copper is required, preferably as a saleable product. The well published SART process applied to gold-copper cyanide solutions was selected as it allows rapid precipitation of cyanide soluble copper as a relatively pure copper sulphide. The process also allows effective recovery and recycle of cyanide back to the heap leach operation.This paper reviews the SART process chemistry and presents a summary of SART bench-scale and pilot plant testwork completed by Kinross. Key design parameters and engineering aspects of the proposed plant at Maricunga are discussed. SART plant operating costs and net revenue analysis are included and illustrate the compelling economics of installing a SART process plant. INTRODUCTIONMaricunga OperationCompañia Minera Maricunga (CMM), fully owned by Kinross Gold Corporation, operates the Maricunga mine (formerly Refugio) which is located 120 km due east of the city of Copiapó at an elevation of 4,200m above sea level in the Andes mountains of northern Chile. Figure 1 shows a map of the location of the Refugio mine relative to other gold and copper mines in the region."

Jan 1, 2008

By Geoffrey Birch

A skilled and efficient workforce is a pre-requisite for the success of modern construction companies. The drive for improved performance, innovation and best value must be matched by the enhanced skills of the construction personnel. Training has been accepted as one of the essential cost effective elements to achieve these goals. The foundation industry demands particular specialist skills and requires focused training for its dedicated operatives. The introduction and development of specific training qualifications for the foundation sector is providing significant benefits.

Jan 1, 2000

By D. Zhou, T. Hamano, Tsukihashi. F., W. -G. Seo

The thermodynamic properties for the CaO-CaF2and CaO-BaO systems were calculated by molecular dynamics (MD) simulation using Born-Mayer-Huggins type pair potential. The parameters of interatomic potential were obtained by fitting the thermodynamics properties of CaO, CaF2and BaO with the experimental data. The phase diagrams for the CaO-CaF2 and CaO-BaO systems were calculated by the thermodynamic properties obtained by MD simulation. The eutectic composition and temperature of the CaO-CaF2system calculated by MD simulation were about 28 mole per cent CaO and 1575K, respectively. The calculated eutectic point agrees very well with experimental data, which are about 22 mole per cent CaO and 1633K, respectively. Keywords: molecular dynamics simulation, thermodynamics, phase diagram, calcium oxide, calcium fluoride, barium oxide.

Jan 1, 2004

By S. B. Mishra

Ni-20Cr metallic coating was deposited on a Ni-based Superalloy (3Fe-19.5Cr¬0.3Ti-Balance Ni) by a shrouded plasma spray process; NiCrA1Y was used as a bond coat. Erosion studies were conducted on uncoated and plasma-spray coated superalloy specimens using an air-jet erosion test rig at a velocity of 40 m/s and impingement angles of 30° and 90°. The coating has been characterized for porosity, microhardness and microstructure and X-Ray Diffraction (XRD). An electron probe micro analyzer (EPMA) was used to obtain X-ray elemental mappings of the coating along the cross-section. Scanning electron microscope (SEM) with EDAX attachment was used to analyze the eroded surfaces.

Jan 1, 2005

By Louis R. Iverson

Patterns of species colonization, biochemical interaction among species, and competitive phenomena were studied in four reclaimed areas in western North Dakota ranging in age from one to four years after mining, along with a site from a native mixed grass prairie for comparison. Early successional changes in floristic composition and soil chemistry were quantified. The mined sites had been contoured, topsoiled, fertilized and seeded. Despite seeding of agronomic species, initial colonization was by fugitive species; analysis of the seed bank in topsoil showed that the most dominant colonizers immigrate after topsoiling. Of the 95 species encountered, Kuchia scoparia was the most dominant in the first two years following mining. Kochlo had relatively low densities in the first year (50-80 plants m-2), but was robust and attained heights of 88 cm with a biomass of about 400 g m-2 In the second year, the plant densities increased to over 10,000 plants m"2 but the height and biomass were reduced to 15 cm and 90 g m-2. However, during the third and fourth years Kochia density declined and was practically non-existent by the fourth year, while the planted Agropyron grasses had concomitantly increased. Other pioneers like Amaran thus retroflexus, Chenopodlum album, Helianthus annuus, Salsola spp. And Setaria spp. showed a less abrupt but similar decline. Chemical analysis of the soils over the same time period showed decreases in electrical conductivity (E.C.), and in the concentrations of P, Ca, Mg, Na, Li, Sr, and SO4 (due to leaching), while N increased. Field studies were conducted on the competitive relations between the dominant species - Kochia scoparia and Agropyron spp. - during early succession. It was found the Kochia acted as a "nurse" crop for several months during the first year of Agropyron spp. establishment, but then began to shade heavily by late July, thus reducing grass tillering. Field and growth chamber experiments on the intraspecific competition relations of Kochia demonstrated that its density and dry matter production, per plant and per unit area, conformed to several laws of plant population biology. Autotoxicity or the depression in growth of a species by its own degradation compounds, in Kochia, appears to be the main factor causing the decline in its growth. Results from a field experiment indicated that thinning dense second year Kochia stands to the density of first year stands did not alter the growth of Kochia, providing strong evidence for autotoxicity. Similarly, several growth chamber experiments demonstrated that small amounts of decaying Kochia leaves and especially roots were toxic to Kochia growth, but not Melilotus officinalis or Agropyron canlnum, Chemical analysis of the soils and plant tissues indicated nutritional im¬balances as shown by P/Mn and P/Zn ratios may be responsible for autotoxicity. In addition to Kochia, a bioassay experiment showed allelochemics to be important in several other colonizing species. Although our results indicate that later stage species generally have greater toxicities than first year colonizers, autotoxicity in the very initial stages seems to be accentuated by harsh habitat conditions. Several practices (mowing. fire, etc.) are used to manage grasslands. Mowing of the first year erect, annual, colonizing vegetation was shown to be beneficial in the growth and establishment of wheatgrasses after mining in western North Dakota. Plots containing Kochio predominantly were mowed in mid-and late-July, and in mid-August, during the first year of growth after recontouring, replacing topsoil. seeding and fertilizing. It was found the Kochia densities were reduced to two percent of the control and its biomass reduced to less than one-third when the area was mowed in mid-August. On the other hand, wheatgrasses showed increases of 23% in stem density and 860% in biomass production over the controls when mowed in mid-August. The mowing of Kochia just before seed-set apparently reduces interspecific competition between Kochia and Agropyron spp. during the following growing season. The method is highly recommended for use in hastening the establishment of planted grasses.

Jan 1, 1982

By Keith A. Heasley, John L. Ellenberger, Paul W. Jeran

In this paper, a state-of-the-art, three-dimensional, full waveform, microseismic system was used to analyze the rock failure around a deep (> 750 m (2500 ft) of cover) bump-prone longwall panel. The microseismic system consisted of both underground and surface geophones coupled through radio telemetry and a fiber-optic network to produce pseudo real-time detection and location of seismic events surrounding the coal seam. This was the first microseismic installation of this scope at a U.S. coal mine, and the system was intended to help determine the exact strata mechanics associated with the redistribution of stress and the associated gob formation at one of the U.S.’s deepest longwall mines. Overall, 5,000 calibrated seismic events were recorded during the mining of one panel, including a Richter magnitude 4.2 event which occurred inside of the array. Analysis of these events provides a number of notable insights into the rock mass behavior. For instance, the longwall panel was widened during the retreat process, and the mining-induced seismicity shows a distinctly different behavior between the start of the panel, the mining of the narrow part of the panel and the mining of the wider part of the panel. Also, in itself, the acquisition of the ML 4.2 event was a major milestone in geomechanical and bump research. This is the first time that such an event has been recorded with this detail and accuracy at a bump-prone coal mine in the U.S. The analysis of this single event has set distinct new limits on the relationship between mining seismicity and coal bumps.

By L. K. Sinclair

In situ leaching of copper has the potential to deliver low-cost recovery for soluble copper deposits of sufficient permeability. In order to provide key inputs for modeling of the in situ leaching process, bench scale test work can be used in conjunction with geochemical software to identify key leaching and precipitation reactions. A case study is presented in which a series of flow-through acid leaching tests were conducted on drill core sections from a porphyry copper deposit without crushing or grinding. Concentrations of copper and other key elements were monitored in the recirculating leach solution over several months. A geochemical model of each leaching test was prepared using Geochemist's Workbench using a combination of diffusion-controlled and reaction-controlled rate mechanisms. Key reactions included leaching of chrysocolla, iron oxides, and plagioclase. The model was able to simultaneously satisfy the evolving chemistry of the recirculating leach solution, mineralogy of the head and leach residue, measured acid consumption, and leaching rates for key minerals reported from previous laboratory studies. Opportunities and limitations for scaling up the model to simulate the commercial wellfield are discussed.

Jan 1, 2015

By Hiroaki Sakurai

Using batch reactors equipped with CO and CO2 gas sensor, CO oxidation over Au catalysts in room air has been investigated and compared with Pt catalysts. For both Au and Pt catalysts, the logarithm plot of CO concentration data during initial 10 min are well fitted by straight line, which mean the first order dependence on the CO concentration between 10 and 10,000ppm. The rate constant value (k) over Au and Pt catalyst generally decrease with increasing initial CO concentration above 100ppm. The value decrease especially rapidly between 100ppm and 1,000ppm over Pt catalysts, which should be due to the strong adsorption of CO on Pt. The k value over Au catalyst has become ten times or more as large as the Pt catalysts at 1,000ppm. Already for the initial concentration of 100ppm CO, the strongly adsorbed CO on Pt metal has been clearly observed by FT-IR during the reaction over Pt/Al2O3. A part of the strongly adsorbed CO has been remained on Pt after the disappearance of gas phase CO, and has gradually changed to gas phase CO2. Such strongly adsorbed species on Au has never been observed on Au/TiO2 under the same reaction conditions. These features of Au catalysts are favorable for indoor air purification.

Oct 1, 2003

By D. Harrington

For many years the Federal Bureau of Mines-in cooperation with other agencies-has been making investigations and compiling and publishing reports and statistics on accidents in the various branches of the mineral industry.4 Its assistance has been enlisted also in health, safety, and ventilation problems' incident to the driving of many large tunnels in the United States in recent years. As part of this work the Bureau has compiled considerable statistical and other information on accident experience in the tunneling branch of the heavy-construction industry. It has always been difficult to obtain up-to-date information on tunneling methods and tunnel accidents. Published accounts of tun¬nel construction furnish much interesting material of engineering, historical, or fiscal value, but usually little or no attempt is made to discuss and critically analyze the means taken to preserve the health and life of employees.

Jan 1, 1941

By Keith L. Harris

The performance of the world economy improved significantly in 1984. Real world output!/ grew 4.3% (compared with 2.6% in 19831, the highest since the 4.4% increase recorded in 1978 (table 1). The output of industrial nations rose 4.9%, while that of the developing nations rose 3.7%. The United States and Japan had the largest increases in output of the major industrial nations, with respective increases of 6.8% and 5.8% (table 2). The components of real output with the most significant growth in the industrial countries were gross fixed investment (9.2%), consumer expenditure (3.1%), and public consumption (2.5%) (table 1). Industrial output, as measured by industrial production indices, has returned to about the 1980 level for most of the major industrial nations (table 2). Exceptions to this were industrial production in Japan and the United States; Japan's industrial production rose steadily throughout the 5-yr period and is now more than 16% above the 1980 level, and the industrial production index for the United States reached 11 1.2 (1980=100.0). Real total domestic demand grew at 8.7% in the United States, more than double the rate of Japan, which, at 4.0%, had the second-largest growth. Average demand for all industrial countries was up 5.1%. During 1984 the U.S. dollar showed great strength on international markets, contributing to large current-dollar negative net exports of goods and services and even larger negative net exports of the merchandise sector. While growing U.S. imports helped spread the benefits of the recovery, they also led to a widening of current account imbalances and growing trade tensions throughout the world.3/, 4/

Jan 1, 1985