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By E. Salinas-Rodriguez, J. Hernández-Ávila, E. O. Ávila-Dávila, A. Romero-Serrano, M. Perez-Labra, G. Juárez-López

"Single phase rubidium jarosite was synthesized by precipitation from aqueous solution. X-ray diffraction and SEM-EDS analyses showed that the synthetic rubidium jarosite formed in subspherical particles with an average particle size of about 35 µm. The chemical analysis showed an approximate composition of Rbo9432Fe3(SO4)2 1245(OH)6. The decomposition behaviour of the jarosite in terms of solution pH was thermodynamically modeled using FACTSage by constructing the potential-pH diagram at 298.15 K. The E-pH diagram showed that the decomposition of jarosite leads to goethite (FeOOH) together with Rb+ and SO42- ions. The experimental decomposition of the Rb-jarosite was carried out in alkaline solutions with five different Ca(OH)2 concentrations. The decomposition process showed an ""induction period"" followed y a progressive conversion period where the Rb+ and SO42- ions formed in the aqueous solution. In contrast, calcium was incorporated in the solid residue and iron was transformed into amorphous ferrihydrite. The kinetic analysis showed that this process can be represented by the unreacted-core chemically controlled model. The reaction order with respect to Ca(OH)2 is 0.4342 and the calculated activation energy is 98.70 kJ mol-1. IntroductionJarosite type compounds are hydrous sulfate minerals containing alkalis and ferric ions, MFe3(SO4)2(OH)6, where M can be H3O+· Na+, K+, Rb+, Ag+, NH4 +, Tl+, ½ Pb2+ or ½ Hg2+. Jarosite-type compounds were formed by the natural ""in situ"" oxidation of pyritic ores leading to the replacement of the original iron sulfides and iron oxides (Dutrizac and Kaiman) [1]. The great interest in jarosites is due to its ability to eliminate or diminish the iron concentration of the acid leach solutions produced in the hydrometallurgical zinc process, with relatively low losses of divalent metals such as Zn2+, Cd2+, Cu2+ or Co . However, the losses of the metal values demand a careful study of the conditions under which the jarosite compounds are formed together with their chemical properties."

Jan 1, 2012

By R. L. Hopkins

Fifteen alkyl cycloalkyl sulfides and three dicycloalkyl sulfides were synthesized to provide reference compounds in the search for these classes of sulfur compounds in crude oils. In synthesizing sulfides by alkaline alkylation the order in which the reactants were added was shown to determine the yield and purity of the product.

Jan 1, 1966

By Donald R. Clark

"Drilled shafts are being used as foundation support for parabolic solar troughs at the Genesis Solar Project being constructed near Blythe, California. Three types of drilled shaft foundations are required for the project. At project build-out, there will be a total of 23,008 drilled shafts installed at the site. Preliminary designs for the axial and lateral capacity of the drilled piers were based on conventional geotechnical engineering methodologies and soil-structure interaction. The drilled shafts and subsurface conditions were modeled through the use of the computer program LPILE v6.0.Conducting lateral load testing of drilled shafts was considered appropriate to confirm or modify the geotechnical parameters used in the preliminary design. The lateral load testing program was conducted to provide site-specific test data that would allow the design engineers (both geotechnical and structural) to predict the actual performance and adequacy of the proposed drilled shaft foundations and improve the efficiency and hopefully reduce project costs.The lateral load testing was conducted within two solar fields at the site. Three pairs of drilled shaft foundations were installed in each field, instrumented, and laterally loaded to determine load-deflection response. A value-engineered option, proposed by one of the drilled shaft contractors, was also load tested. The results of the load-deflection data obtained in the field was used to modify the soil modeling used in the original L-PILE analyses and adjust the production drilled shaft lengths.Based on the results of the lateral load testing, the in-situ moduli of the subsurface soils were significantly increased over that assumed in the preliminary analyses. Based on the final soil-structure interaction analyses, the preliminary drilled shaft lengths were reduced by 2 to 2-1/2 feet. This resulted in an overall reduction of 55,654 feet of drilled shaft construction on the entire project, a savings of approximately 16.5% over the preliminary"

Jan 1, 2017

By Donald R. Clark

Drilled shafts are being used as foundation support for parabolic solar troughs at the Genesis Solar Project being constructed near Blythe, California. Three types of drilled shaft foundations are required for the project. At project build-out, there will be a total of 23,008 drilled shafts installed at the site. Preliminary designs for the axial and lateral capacity of the drilled piers were based on conventional geotechnical engineering methodologies and soil-structure interaction. The drilled shafts and subsurface conditions were modeled through the use of the computer program LPILE v6.0. Conducting lateral load testing of drilled shafts was considered appropriate to confirm or modify the geotechnical parameters used in the preliminary design. The lateral load testing program was conducted to provide site-specific test data that would allow the design engineers (both geotechnical and structural) to predict the actual performance and adequacy of the proposed drilled shaft foundations and improve the efficiency and hopefully reduce project costs. The lateral load testing was conducted within two solar fields at the site. Three pairs of drilled shaft foundations were installed in each field, instrumented, and laterally loaded to determine load-deflection response. A value-engineered option, proposed by one of the drilled shaft contractors, was also load tested. The results of the load-deflection data obtained in the field was used to modify the soil modeling used in the original L-PILE analyses and adjust the production drilled shaft lengths. Based on the results of the lateral load testing, the in-situ moduli of the subsurface soils were significantly increased over that assumed in the preliminary analyses. Based on the final soil-structure interaction analyses, the preliminary drilled shaft lengths were reduced by 2 to 2-1/2 feet. This resulted in an overall reduction of 55,654 feet of drilled shaft construction on the entire project, a savings of approximately 16.5% over the preliminary design.

By G. Demi

The biggest chromium mineral processing plant in Albania is Bulqiza plant. It has been in operation for more than 20 years, treating low-grade chromium ores grade 20 ? 26 % Cr2O3 and producing chromium concentrates grade 48 ? 50 % Cr2O3. About 2 million tons of tailings with 13 % Cr2O3 content are stocked in a dam close to the plant. Mineral processing of low-grade chromium ores with less than 16% Cr2O3 content is unprofitable because the mining expenses are high comparing with the current market prices of chromium concentrate. Recycle and enrichment of existing tailings is profitable, because there are no underground mining expenses in this case and because that this kind of raw material does not need expenses operation of crushing and grinding. The existing plant is in operation for more than 8 years treating existing tailings as raw material. Grade of concentrate in the value 40 % Cr2O3 and Cr2O3 recovery in the value 30-35% in the plant are considered low. The main reason of low concentrate grade and recovery is high content of particles under 100 microns, the slimes, in raw material. In the paper is described the study carried out to improve enrichment of the tailings, as well as analyses of existing process, raw material and products. It is concluded that majority of lost is present in the slimes which are not separated in existing spiral separators and shaking tables. Basing in the study is composed the new flow sheet of recycling and concentration of the tailings to produce chromium concentrate grade 41 ? 42 % Cr2O3 and recovery 60 %, decreasing in this way the concentrate production cost two times. In the paper are presented the tests and results of concentration of particle size fraction under 100 microns, using gravimetric, magnetic and flotation methods, as well as equipment and machines suitable for slimes treatment and concentration.

Sep 1, 2012

By Ramana G. Reddy, M. R. Bogala

Transition metal silicides have good potential for converting waste heat into electrical energy at higher temperatures. Transition metal silicides are used as thermoelectric alloys at higher temperatures because of their low toxicity, high natural abundance, good transport properties, and better thermal stabilities. In this article, thermodynamic, and thermoelectric properties of promising metal silicides are reviewed, calculated, and compared for waste heat recovery application. Higher manganese silicide (Mn4Si7) was produced from easy one-step self-propagating high-temperature synthesis (SHS) procedure of arc-melting technique. Characterization of the alloy phases were done using X-ray diffraction (XRD). In this study, lattice constants, Vickers microindentation hardness, and thermoelectric (TE) properties (Seebeck coefficient, electrical conductivity, thermal conductivity, and figure of merit) of Mn4Si7 alloy were experimentally determined, and compared with the reported literature values.

Mar 1, 2017

By Daniel R. Walton

A study to explore the potential of utilizing the transport time required to move coal miners to and from the working sections. Consideration was given to all forms of training and presentation media, taking into account such environmental factors as noise, dynamic interferences, visibility, physical constraints, and contaminants. Indications of managements? and workers' attitudes toward man-trip training were also assessed. The final product was a proposed prototype training system for man-trip training. Includes Bibliography.

Jan 1, 1979

By F. L. Wang

The purification process of water-mining carnallite and rough potassium chloride concentrate from Qinghai Salt Lake Industry Group Co. Ltd. are investigated by the preprocessing-reverse flotation technology respectively. The results show that the impurities such as calcium sulfate and sodium chloride can be effectively removed from water-mining carnallite ore and rough potassium chloride concentrate by the new technology, the low-sodium carnallite is obtained and the final potassium chloride product greatly upgraded. The content and the recovery of KCl in the low-sodium carnallite are 25.78% and 97.50%, meanwhile the content of NaCl, CaSO4 in the low-sodium carnallite are 0.56% and 0.24%, and the removal of sodium chloride and calcium sulfate in the low-sodium carnallite are 97.48%, 85.10% respectively. The KCl content and recovery of high quality potassium chloride product are 98.25%, 96.70%, and CaSO4 content is 0.40% with 83.24% calcium sulfate removed in the high quality potassium chloride product.

Jan 1, 2014

By Richard W. Hutchinson, Christopher Osterman

Abstract -The Selebi-Phikwe deposits are hosted by amphibolite to granulite facies gneisses of the Limpopo belt. The sulfide orebodies are generally stratiform and conformable to the foliation of the wallrock gneiss. Sulfide remobilization has occurred during metamorphism and has produced discordant sulfide veins, called piercement structures, which project into the hanging wall and foot­ wall gneisses. These piercement structures are compositionally similar to the stratiform sulfides, consisting mainly of pyrrhotite, pentlandite and chalcopyrite. However, texturally the piercement sulfides are coarse grained and inclusion-free, whereas the stratiform sulfides are fine grained and packed with tectonically produced wallrock inclusions. The piercement structure sulfides and adjacent stratabound sulfides were sampled and analyzed for major base metals and PGE's for comparative purposes. Most of the piercement structures were enriched in Cu, Ag and Au, whereas they were generally depleted in Ni, Co, Fe and PGE's. Changing elemental associations were observed from the stratabound sulfides and along the length of the piercement structures. This and the degree of depletion or enrichment of various major and minor elements in the sulfide piercement structures may reflect the relative mobilities of metals under metamorphic conditions. The similarities between sulfide piercement structures and the footwall Cu-POE veins in some Sudbury deposits are reviewed.

Jan 1, 1994

The pilot scale testing of Australian coals for their NO, emissions was carried out at the ACTC to investigate the influence of coal properties, furnace conditions and different NO,, control strategies on NO,, emissions. The NOx emissions for the Australian coals tested were found to vary over a wide range and primarily depended on combustion temperature and excess oxygen conditions. These coals did not exhibit any fundamental difference in NOx levels to other world coals. Under similar combustion conditions, the conversion of coal nitrogen to NO. was found to be best correlated with coal rank parameter, R, max per centage. The use of staged combustion as a control strategy was shown to reduce their NOx levels by 56 - 77 per cent.

Jan 1, 1991

By John J. Jonas, Hong Qin

Cylindrical samples of pure titanium were subjected to uniaxial compression at room temperature, leading to the formation of three generations of twins. Many primary contraction twins were observed as the initial texture was favourable for their formation. Numerous secondary extension twins formed within the primary contraction twins and some tertiary contraction twins within the secondary extension twins. The orientations of these three generations of twins were determined by electron backscatter diffraction techniques and their associated Schmid factors (SFs) were calculated. The formation of the twin variants selected in each generation and the absence of certain potential variants are accounted for by rotating the twinning displacement gradient tensor expressed in the twin system reference frame into the crystallographic reference frame of the relevant neighbouring grain. The presence of the observed primary, secondary and tertiary twins is explained in terms of the ease of imposing the required accommodation strains on the neighbouring grains. By contrast, certain first, second and third generation potential high SF twins were absent because their formation would have required accommodation by the most difficult deformation mode: pyramidal glide.

Jan 1, 2015

By M. N. Nabighian

Utilization of x-ray diffraction data for mineral identification has been well documented and accepted as an analytical tool in industrial and research organizations. However, the search for new methods to minimize errors affecting measured reflection intensities is being carried out by all concerned. Recent application of computer capability has greatly reduced the time required in handling data for mineral analysis and has increased the capability of accepting more data for greater precision. The purpose of this communication is (1) to describe the concept of cross-power in XRD analysis, and (2) to show that direct comparison analysis for multiphase systems has improved analytical accuracy when all available x-ray diffraction data are used in conjunction with high speed data processing by computer.

Jan 1, 1972

By L. C. So, S. Faucher, S. Mostaghel, D. Sauter, S. -Y. Oh, S. K. Lee

"Molten material from pyrometallurgical furnaces is tapped at high temperature, carrying a large amount of heat. Traditional handling methods of slow air cooling or water granulation do not allow for the recovery of heat from slag and matte. Furthermore, water granulation adds an inherent safety risk of explosions. Recently, there have been numerous studies into processes attempting to recover waste heat. However, most of them have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple dry atomization system that allows for heat recovery while eliminating the use of water. Comparisons of pilot and commercialized dry atomization and heat recovery technologies will be presented and challenges of these technologies will be highlighted.INTRODUCTION Slag has traditionally been regarded as an undesired waste product from smelting operations with slag management focused on removal and disposal of “waste”. Over 500 million tonnes of slag are produced per year, carrying with it ~220 TWh of energy (Barati, Esfahani, & Utigard, 2011). Depending on the process, the energy content of slag ranges from 10-90% of the total energy input (Barati, 2011, Rodd, 2010). There has therefore been great interest in recovering energy from slag. Slag handling methods can broadly be classified into three categories: (1) dumping and slow cooling, (2) wet granulation and (3) dry granulation. As discussed below, only dry granulation routes are amenable to heat recovery. Slag dumping involves the slow cooling of molten material and crushing of the resulting solid. In this process, slag is dumped on the ground directly from furnaces or transferred to slag pots that are moved by rail or haulers and then dumped on the ground. The molten material is left to cool and solidify until it can be broken and handled by heavy machinery."

Jan 1, 2017

By William Gleason

The Society for Mining Metallurgy and Exploration (SME) has a long and proud history of being the world?s leading resource for the dissemination for technical information regarding the fields of mining and mineral extraction and processing. That reputation was met, and maybe even exceeded, with the programming for the Society?s 2014 Annual Meeting in Salt Lake City, UT Feb. 23-26. The meeting drew more than 6,700 attendees to the three-day conference that featured more than 90 technical sessions with 670 presentations. These sessions covered the breadth of the mining and minerals industry, but it was the so-called ?softer issues? that were discussed in the keynote session that kicked off the meeting. The keynote session, ?Community Engagement: Building Partnerships for Mining,? brought together some of the leading voices from the mining industry, as well as some of the top voices from nongovernmental organizations (NGOs) that work in the mining sector. The common ground between the panelists was their dedication to working to ensure a social, economic and environmental balance in the development of mines. ?We wanted to bring these NGOs in to begin a dialogue to see how we can work together,? said SME President Jessica Kogel. ?This is a space that SME has not typically operated in, but one in which SME can bring a technical, scientific voice to the discussion. SME wants to play a leadership role in creating partnerships between the technical, social and economic areas that are crucial to the success of any mining project.? In today?s environment, finding mineral deposits and extracting the minerals in an economically viable manner is just one piece of an increasingly complex puzzle. Earning and maintaining a social license to operate requires careful consideration of local and global impacts. The industry often comes under intense scrutiny when a new project is proposed and, therefore, it must strive to meet the highest ethical and environmental standards. Success requires cooperation and collaboration between the industry, community and NGOs.

By M. S. Oudenhoven

The Bureau of Mines conducted an investigation to determine the theoretical stress distribution in the vicinity of explosively expanded rock bolt anchors independent of their bolts. Plane-strain solutions applicable to this problem were obtained by combining the field pressure with the uniform pressure that would be produced by vertically placed anchors having 2-, 3-, and 4-foot spacings. High rock stress which would be produced by an anchor was localized, as would be expected from St. Venant's effect, and increased as the field pressure decreased.

Jan 1, 1967

By Natal Nerímio Regone

Pelo processo de anodização forma-se uma camada de óxido sobre o substrato de alumínio através de um processo eletrolítico. Após a anodização do alumínio, pode-se colori-lo para obter um bom acabamento externo, aliado a maior durabilidade. O objetivo deste trabalho foi determinar as condições de anodização e colorimento por corrente contínua e pulsada no alumínio, e avaliar as vantagens da anodização e colorimento em função das propriedades do filme. A camada de óxido de alumínio e o revestimento colorido foram caracterizados por potencial de circuito aberto, polarização potenciodinâmica, e por espectroscopia de impedância eletroquímica. Pela solução utilizada na eletrodeposição obteve-se uma cor marrom sobre a camada anódica. As medidas eletroquímicas mostraram que a anodização e o colorimento processados por corrente pulsada tiveram melhores resultados de resistência a corrosão.

Aug 8, 2018

By F. Awotwe-Appiah, P. Koshy, J. Dankwah, J. R. Dankwah

This research investigates the generation of an effective carbonaceous material from waste ‘pure water sachets’ and their subsequent utilisation as reductants for the reduction of the Opon Mansi iron ore. Composite pellets of Opon Mansi iron ore and pulverised carbonaceous material generated from waste pure water sachets were heated from room temperature to 1200 °C in a gas fired furnace for seventy minutes. The reduced pellet was analysed chemically for its oxygen and carbon content using a LECO Oxygen/Nitrogen and LECO Carbon/Sulphur analysers, respectively. It was observed that nuggets of metallic iron were readily produced with the carbonaceous materials acting as an effective reductant and source of chemical energy. XRD analysis of waste ‘pure water sachets’ revealed that the polymer was semi-crystalline with peaks that were identical to those of high density polyethylene (HDPE). Gas emission behaviour of the iron ore-PWS pellet was studied in a horizontal tube furnace at 1200 °C using an infrared gas analyser; the results revealed an exhaust gas rich in the reducing gases CO and CH4 along with CO2.

Jan 1, 2015

By F. J. Gallagher

Some serious fires have occurred in bituminous-coal mines because of short circuits on direct-current power systems that do not have adequate circuit-breaker protection. The writer's observation of circuit-breaker installations in numerous coal mines leads to the conclusion that many persons am not properly informed as to the true functions, limitations, and operation of circuit breakers. Faulty protection results in fire hazards that endanger lives and property. Proper circuit-breaker protection would greatly minimize or, in many instances, eliminate the hazards; moreover, many operating advantages of proper application of modern circuit breakers would be gained. The purpose of this circular is to show why fire hazards exist in many mines despite the use of circuit breakers and how, the hazards may be overcome. A method is given for determining whether additional circuit-breaker, protection is required for a specific 250/275-volt direct-current distribution system, and, if so, the approximate locations and capacities of the required supplemental breakers.

Jan 1, 1951

By Earl C. Henry

Magnetic iron ore was mined in Essex County, N. Y., during the American Revolution; Benedict Arnold is said to have mined ore near Port Henry to secure iron for chains and spikes for the Lake Champlain fleet. Details regarding the operations prior to 1804 are not easily obtained but work on a commercial scale appears to have been started about 1838. The Witherbee, Sherman & Co. was established in 1849. The property of the district is held in fee almost entirely by the mining companies. The Mineville iron-ore district, as well as the entire Adirondack region, belongs to the pre-Cambrian complex. The readily identified rocks consist of gabbro, anorthosite, syenite, and granite, and are classed as igneous, eruptive, and intrusive. In addition, there is a great variety of gneisses, rocks with a variable mineral composition but all more or less distinctly foliated. The Grenville series are the oldest rocks in the district; this series consists of graphitic white limestones, graphitic sandstones, and quartzites and gneisses with or without graphite. The orebodies occur in the gneissic rocks and are comformable to the structure of the rocks. The typical occurrence of the ore in this district is in lenticular bodies with a parallel pitch to the southwest; this structure is best exemplified in the New Bed mine. The Harmony and Old Bed orebodies are faulted by two sets of diabase dikes, one set having a southwest strike and the other set an east-west strike. The ores occurring in the acid gneissic rocks are non-titaniferous. The ores occurring in the gabbros and anorthosites are high in titanium; these deposits are irregular, have no structural relation with one another, and are unquestionably of igneous origin. The origin of the gneissic rocks and the ores therein contained is not settled; both the sedimentary theory of ore concentration and the igneous theory of magmatic segregation have been advanced. The iron mineral in all the orebodies is crystalline magnetite; some very perfect and large specimens have been obtained. The gangue is

Jan 1, 1925

Madison Enterprises Corp. and Matu Mining are currently ex- ploring the Mt. Kare property in Papua New Guinea. The Mt. Kare gold prospect has had a short but very active history, since the first discovery of gold in the area in 1986 the property has sccn: a 3 year gold rush during which 10,000 alluvial miners re

Jan 1, 1997