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Samples collected during the exploration phase of mining represent baseline conditions at the site. As such, they can be very important in forecasting potential environmental impacts should mining proceed, and can become measurements against which future changes are compared. Constituents in stream water draining mined and mineralized areas tend to be geochemically, spatially, and temporally variable, which presents challenges in collecting both exploration and baseline water-quality samples. Because short-term (daily) variations can complicate long-term trends, it is important to consider recent findings concerning geochemical variability of stream-water constituents at short-term timescales in designing sampling plans. Also, adequate water-quality information is key to forecasting potential ecological impacts from mining. Therefore, it is useful to collect baseline water samples adequate for geochemical and toxicological modeling. This requires complete chemical analyses of dissolved constituents that include major and minor chemical elements as well as physicochemical properties (including pH, specific conductance, dissolved oxygen) and dissolved organic carbon. Applying chemical-equilibrium and appropriate toxicological models to water-quality information leads to an understanding of the speciation, transport, sequestration, bioavailability, and aquatic toxicity of potential contaminants. Insights gained from geochemical and toxicological modeling of water-quality data can be used to design appropriate mitigation and for economic planning for future mining activities.

Jan 1, 2011

By F R. M Pires, R M. Carvalho

Supergene processes in banded iron formation (BIF) result in important dissolution, material transport and simultaneous disorder of the residual bands. The rock physical properties such as density, porosity and rheology change during the weathering attack. The itabirite, Paleoproterozoic metamorphic BIF from Quadrilßtero Ferrffero (QF) û Brazil, shows several weathered facies. Strong linking between topographic surface, rock density and iron grade occurs within the weathered zones. This linking is due to partial dissolution of silica and carbonate from itabirite and gravitational rotation and break of the remaining blades, generating kink-like slump structures. The original itabirite density, 3.7 t/m3, decrease at the first leaching steps, until 2.7 t/m3, and increase at the end of the leaching process until 3.6 t/m3. Iron grade increases from 38 per cent to 68 per cent and depressions (sinkhole), subsequently filled by Cenozoic basinal sediments, are developed over the enrichment zones. The formation of important supergene iron ore deposits of QF is intimately related to such a process. Several iron deposits at QF, such as Pico do Itabirito, Fßbrica Nova, Casa de Pedra, Tamanduß, -gua Claras, Cappo Xavier, etc., reveal the aspects related to the proposed evolution, implying that the formational process of the soft iron ores had a regional character. Granular medium model helped in the understanding of the development of the structure and the formation of the deposits. A numerical model has been developed in order to simulate a leaching system in a two-dimensional matrix, composed of two types of materials: leachable and unleachable. Equal volume proportion and vertical banding were considered. Drilling data was used as multipoint attractors to remove leachable matrix nodes.

Jan 1, 2002

By Minji Jun

Leaching of the surface-coated metals from waste acrylonitrile butadiene styrene plastics (WABSP) has been investigated in the ammoniacal solution. The ammoniacal leaching of WABSP (typically containing 4.1 wt% Cu, 1.3 wt% Ni, 0.03 wt% Cr) efficiently dissolved copper and nickel, leaving unleached chromium as fine particles. The results indicate that the anions of different buffer media for metals leaching follow the order: CO3 2− > Cl− > SO4 2−. A declined leaching with high NH4OH–(NH4)2CO3 ratio (8:1) and a steep rise in extraction with high pulp in solution revealed the influence of anion (CO3 2−) and cation (Cu2+) present in the system. The leaching performed in carbonate solution by maintaining 5.0 M total NH3 concentration as NH4OH–(NH4)2CO3 ratio, 4:1; pulp density, 200 g/L; agitation speed, 400 rpm; temperature, 20 °C and time, 120 min yielded the maximum extraction (>99%) of copper and nickel. The study reveals a plausible recovery of the surface-coated metals from the WABSP without altering the properties of polymer material that can be recycled separatel

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

By T. J. Ballard

The Ore Knob mine, in Ashe County, N.C., was one of the largest producers of copper in the eastern states during the 1870's. The ore occurs in a fissure vein, which strikes N. 64° E. and dips nearly vertical. The country rock is granite gneiss. Drilling indicated that the vein structure is approximately 200 feet wide and 1,500 feet long. The vein material shows evidence of replacement of the original gneiss by sulfides. Solution cavities in the vein were noted in some places. The ore minerals and pyrrhotite, chalcopyrite, pyrite, and minor quantities of sphalerite. The gangue contains biotite, magnetite, albite, calcite, and many silicate minerals.

Jan 1, 1948

By Mah Alla D.

Previously existing heat-of-formation values for the oxides of vanadium were rudimentary. They were subject to uncertainties of 1 to 5 kilocalories per gram-atom of contained oxygen. This fact has been the only adverse influence on the accuracy of thermodynamic calculations involving these substances, as the requisite entropy and high-temperature heat-content data are known with reasonable accuracy. This report presents new heat-of-formation data for four oxides of vanadium (VO, V203, V02, and V205), obtained by combustion calorimetry. It is believed that the uncertainties have been reduced to 0.1 to 0.3 kilocalorie per gram-atom of contained oxygen. The new heat-of-formation data were combined with existing entropy and high-temperature heat-content values to obtain free energies of formation of the four oxides at temperatures up to 2,000° K.

Jan 1, 1961

By M. J. Ankeny

This is a study of 58 fatal haulage accidents investigated by Federal coal-mine inspectors during the period January - June 1951. The information presented in this circular was obtained by analyzing fatal haulage accidents in 33 bituminous-coal producing counties representing 11 States. The physical conditions represent a cross section off producing coal beds. Mining and transportation methods vary, from those of small hand-loading mines to those of large modern mechanized operations. These data are thought to be representative of haulage conditions within the bituminous-coal mining industry and are submitted to follow up the Information Circular 7604 ?Analysis of Haulage Fatalities in Bituminous-Coal Mines - 1950.? Coal-mine haulage ranks second as a cause of coal-mine fatalities, and the problem of haulage safety is complex. It is subject to constant change and is comprised of numerous influencing variables, which are not always obvious. The solution to this problem will not come through the application of any standard formula or mechanical approach since the inherent factors are strongly influenced by the human equation, and the chain of circumstances is further affected by expediency.

Jan 1, 1951

By R. K. Dwari

The electrostatic beneficiation of coal is based on tribocharging characteristics of ash forming minerals and coal particles. The tribocharging of quartz, pyrite and coal particles contacted with various metals and polymeric materials have been measured and the charge acquisition is assessed through surface energy calculations from liquid contact angle data. The contact angles, before and after tribocharging of solids, are measured using Krüss tensiometer and Washburn?s method where the sample holders in tensiometer are specially constructed with tribocharger materials. The charge polarity and amount of charge acquired by quartz, pyrite and carbon with metal tribochargers were found in good agreement with the reported work functions of the contacting surfaces. The charge results with polymer materials differed from the work function values, presumably caused by surface contamination. The surface energy of quartz calculated by all the theoretical approaches in the literature showed that the tribocharging increases the surface energy. Both polar and non-polar components computed from Fowkes and Owens-Wendt-Rabel-Kaelble approaches dis-play that both these components increased after triboelectrification. However, the polar component divided into acid and base components, as in van Oss approach, manifest decreasing acid part and increasing base part. Since quartz charged negatively during tribocharging with metal surfaces and therefore accepted electrons, the determined acid and base surface energy components are consistent with charge transfer process. The results also elucidate an explicit correlation between the charges generated by powders and the surface acceptor (acid) and donor (base) electronic states and thereby the work functions. A novel fluidized bed tribocharger was designed and developed with internal baffle system for efficient contact electrification of mineral and maceral to produce high differential charging for efficient separation. The results achieved on coal with 45% ash content are presented and discussed.

Jan 1, 2014

By Kirsi M. Riihilahti

The oxidation characteristics of solid copper matte particles under simulated Kennecott-Outokumpu Flash Converting conditions are presented. The effects of feed matte grade, matte particle size, oxygen-to-matte mass ratio, oxygen content of the process gas and temperature on the particle oxidation rate, quality of conversion, particle size change and particle morphology were determined. The converting quality was highest (~68) with the 58% copper matte at 1100°C. At similar conditions, the 72% copper matte was more likely to produce copper oxides and leave unoxidized particles rather than directly produce sulfur dioxide at 1100°C, resulting in an average converting quality of 55. The quality of conversion was poorest for the 72% matte at 920°C (~45); the sulfur removal was extremely low even with a relatively high degree of oxidation. Fragmentation of the particles was significant in all cases with the 72% matte. A higher O2/matte .ratio and higher temperature, in general, resulted in increased fragmentation while oxygen enrichment had no significant effect. With the 58% matte, particle size was found to increase for the finest fractions rather than to decrease due to particle expansion.

Jan 1, 1998

By Jun Li, Lingling Zhang, Daqiang Cang, Guizhou Zhao

Pilot trial of direct modification of molten blast furnace slag and production of high acidity coefficient slag wool fibers were investigated nearby a blast furnace. Molten blast furnace slag discharged from blast furnace and then directly flow into specialized modification furnace and quartz was simultaneously added into the molten slag as modification agent. The modified molten slag was electric heated to 1500–1550 °C and then the melt was produced into slag wool fibers through high-speed centrifugation method. Melt with acidity coefficient of 1.2, 1.4, 1.6 and 1.8 were investigated and fibers with corresponding acidity coefficient were produced. Slag wool fibers with shot content of 5.5, 5.8, 6.2, 6.8% and average diameter of 4.5, 4.9, 5.6, 6.4 lm for four samples were successfully produced, respectively. Total energy consumption and production costs decreased by 50–70% compared to traditional cupola furnace method. This method provides an energy-saving and emission-reduction technology for the direct utilization of molten blast furnace slag.

Mar 1, 2018

By E. Z. Casassa

There has been a recent revival of interest in concentrated coal/water slurries as a substi¬tute for fuel oil or for coal/oil mixtures, particularly in electric power generation. The idea is not a new one. Coal/water slurries were transported by pipeline in the U.S. in the early nineteen-sixties, and the Black Mesa coal pipeline has been in operation for several years, while in Germany, coal/water slurries were being burnt for power generation in the early nineteen-seventies, as described by Merten and Höner (1972). Since coal is not a pure substance but a carbonaceous mixture, the different chemical and physical behavior of coal/water dispersions from different deposits must be understood in order to optimize the properties of the result¬ing slurry fuels. Since minerals which are minor constituents of coal may also strongly affect slurry properties, coal chemistry may vary considerably even within a single deposit. Thus it is unlikely that there will be a single formula for optimizing the slurry properties of all coals, and even the answer for coal from a single source may change with time.

Jan 1, 1983

By Leandro Miranda Nascimento

A maior parte da produção mundial de aço passa pela conversão de minério de ferro em grandes altos-fornos, tendo o coque como uma das matérias-primas. Por um lado, boas propriedades mecânicas a quente do coque, como o CSR e CRI, são necessárias para que o consumo de coque seja o mínimo, pois é também, junto com os óxidos de ferro, um dos maiores componentes dos custos variáveis do ferro gusa. As misturas dos vários tipos de carvões minerais utilizados exigem a participação de uma fração Hard, a mais cara e com maior poder de coqueificação, e de uma fração Soft, mais barata e inerte. Logo, quanto maior for a participação do Hard mais caro será a mistura a ser coqueificada. Uma maneira de aumentar a fração de Soft na mistura de carvões, reduzindo o custo da mistura, e ainda assim obter um coque com boa qualidade é aumentar a densidade a granel da mistura. Para isso alguns métodos já são empregados com sucesso, como o Stamp Charging e a Briquetagem Parcial. Este artigo apresenta um novo método, que consiste na densificação da mistura de carvões dentro do forno via dispositivos de vibração. Foram realizadas simulações físicas a frio e em escala reduzida para avaliar o potencial de aumento de densidade a granel da técnica. Os resultados mostram um ganho de aumento de 30% da densidade a granel da mistura.

Aug 17, 2017

By L Abrahamsson

This paper describes results from a gender study for a new mine in Pajala, a small community in northern Sweden. Using a gender perspective, the study examines migration, education, local culture, the labour market, and work organisation as problems and opportunities in the regional context for the planned mine. The most obvious ‘gender issue’ for the Swedish mining industry is the very low percentage of employed women, which is even lower among mining workers. To recruit the best people, a company actively needs to attract both women and men; however, the mining companies find it difficult to recruit women as cultural, labour market and educational traditions as well as the mining companies’ own cultures often make it difficult for women to find work in the mining industry.The Torneå river valley, the region surrounding Pajala, has a gender-segregated labour market and gender-stereotyped culture and few young women live in this traditional and oldish region. Many young people leave the region and this is especially true for women. Compared to the rest of Sweden, there is a low educational level, especially among the men. In the mining companies, as in many other male homosocial workplaces, the workplace culture has strong connections to a certain type of traditional masculinity (laddishness, a kind of ‘macho-style’) and for a long time this has excluded women. ‘Gender’, however, is not only a question of recruiting women to a male-dominated industry. An organisation that discriminates according to gender can become inflexible, hindering communication, learning, innovations and change processes. In mining companies, this can manifest itself in hesitant attitudes among the miners about safety as well as organisational and technological development.This study found that companies establishing a presence in this region should develop a strategy for how to deal with and manage the risks and opportunities in the surrounding society (the regional culture) as well as inside the company (the mining culture). This need to be strategic will also be required of future mining companies as they will face higher demands on safety, gender equality, and technology to become modern, efficient and lean organisations.

Nov 22, 2011

By D. M. Schubert

As a clean and renewable energy carrier, hydrogen is an important component of most alternative energy portfolios. Hydrogen combines very high energy content by weight with excellent environmental attributes. Since hydrogen reacts with oxygen to produce only water with release of energy, it can be used to power fuel cells, combustion engines, and turbines, without production of greenhouse gases at point of use. However, because of its low volumetric density, storing pure hydrogen is impractical. Thus implementation of hydrogen technologies requires materials that can safely store and release large amounts of hydrogen (1,2). In recent years, the U.S. Department of Energy (DOE) and other governmental agencies around the world sponsored extensive research on hydrogen storage materials, including those based on boron. These efforts have resulted in significant advances in hydrogen storage technologies. Boron materials stand out as leading candidates for hydrogen storage among the many options investigated. Combining excellent hydrogen densities, release rates, and safety characteristics, some boron materials can hold substantially more hydrogen by weight and volume than even pure liquid hydrogen (3-5).

Jan 1, 2010

By Paulo Sérgio Moreira

O tamanho de grão austenítico prévio é determinante na área de tratamentos térmicos dos aços, pois este parâmetro influencia sua microestrutura e propriedades. Para que o tamanho de grão possa ser medido, é necessário que antes se aplique métodos de contraste para sua revelação. A literatura relata, entre métodos desenvolvidos, dificuldades em se conseguir bons resultados em função deles serem susceptíveis a variações de composição química e histórico de processamento dos aços. Neste contexto, esse trabalho propôs métodos para a revelação dos contornos de grãos austeníticos prévios dos aços ABNT4340 e ABNT1030. Foram utilizadas duas técnicas: ataque químico e ataque térmico. Para a técnica de ataque químico, utilizou-se um reativo a base de ácido pícrico. Já na técnica de ataque térmico, as amostras foram austenitizadas de forma a promover uma oxidação controlada. Os resultados obtidos mostram o sucesso das técnicas, com destaque para o ataque térmico que se mostrou mais efetivo para o objetivo proposto. Foi possível mostrar que no ataque químico, o ajuste da concentração de HCl em função da composição química do aço é o ponto de maior importância, ao passo que no ataque térmico, a segregação química e a temperabilidade dos aços são relevantes para o sucesso da técnica.

Aug 17, 2017

By R. H. Knudsen

"In view of the chronic overcapacity problem in the world potash industry and Saskatchewan's recent emergence as a major producer, the long-term outlook for potash productive capacity and consumption is of importance and interest to both the Saskatchewan Government and the potash industry. This paper is based on a report recently published by the Saskatchewan Department of Mineral Resources on projected world potash productive capacity and consumption for the ten-year period 1970 to 1980. Potash productive capacity and consumption are estimated on a country and regional basis and projected annually to 1980. Tables and graphs are included which summarize projected capacity and consumption for the period and illustrate the impact of Saskatchewan's capacity upon the North American and world potash industries."

Jan 1, 1973

By R. Bhaskar

The results of an experimental study on the dispersion and deposition characteristics of fine coal dust in mine airways are presented. Experiments were conducted at various flow velocities using bituminous and semi-anthracite-coal dust which had a large proportion of dust in the respirable size range. Cross sectional variations in the concentration of dust at various points in the airway were also measured. Instruments used in the experiments included gravimetric samplers and impactors. Concentration measurements were made both for the respirable and total airborne dust. The experimental design, sampling procedures and results are discussed. The study is aimed at providing a better understanding of the temporal and spatial behavior of dust particles in underground mine airways.

Jan 1, 1986

High flotation of iron sulfide minerals at high pH values in copper ores is mainly due to the activation of these minerals by copper species dissolved from copper sulfide minerals during grinding. Several methods have been tested to reduce this copper activation during grinding and therefore to depress iron sulfide flotation. They include grinding the minerals at high pH values or with a less reactive medium such as high chrome, and addition of a thiol collector or copper complexant during grinding. The efficacy of these methods in the flotation of a copper ore was tested against more common methods of depression of iron sulfide flotation. The mechanism of iron sulfide depression in these methods was also investigated.

Jan 1, 2014

By Alexandre Furtado Ferreira, Fernando Paulucio Quinelato

A solidificação tem papel fundamental nas propriedades finais do material, uma vez que parâmetros como temperatura, composição química e cinética influenciam diretamente na micro e macroestrutura resultante. A solidificação dos aços no lingotamento contínuo ocorre através do crescimento dendrítico em direção ao núcleo da placa. A velocidade de crescimento interfere diretamente sobre a formação da micro e macroestrutura, bem como na formação das dendritas. Tais efeitos influenciam o perfil de microssegregação e macrossegregação finais. O objetivo deste trabalho é avaliar o comportamento dos espaçamentos dendríticos secundários em função da temperatura de lingotamento e da macroestrutura resultante, além de calcular, através do uso de equações empíricas, a taxa de resfriamento local. Os resultados mostraram que para menores superaquecimentos os espaçamentos dendríticos secundários apresentam-se menores. Foi verificada uma elevada correlação entre espaçamento dendrítico secundário e posição ao longo da espessura da placa para o intervalo de superaquecimento de 22°C e 34°C. Com a utilização de uma equação empírica, foram obtidas curvas que mostram o comportamento da taxa de resfriamento local em função dos espaçamentos dendríticos secundários. Os resultados obtidos são importantes para subsidiar estudos futuros e propostas de otimização de processo relacionadas a micro e macrossegregação em placas de aço.

Oct 1, 2019

By Joseph Newton

MUCH the same story can be told about the copper industry for the year 1944 as for the three preceding years. Operators report few or no technical changes at their plants and the main endeavor has been to maintain high production with existing equipment. No large new installations have been made to increase plant capacities and apparently over-all copper production has passed its maximum. The present decline in copper production results partly from the severe labor shortage. As is true of most industries; the outstanding fact about the copper industry during the past few years has been its tremendous and sustained production which has been maintained in spite of serious shortages in material. labor, and technical personnel. The figures in Table I give a concrete example of how production has been increased at one large smelter in the United States-the Garfield plant of the American Smelting and Refining Co. at Garfield. Utah. These figures, reported by W. G. Rouillard. superintendent. give the production of the Garfield plant for the five years 1940-44 inclusive. The total blister production

Jan 1, 1945