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By Bolmerm R. L.

This information circular describes the application of modern methods and equipment in sinking a vertical, 916-foot-deep by 16-foot-diameter, concrete-lined access shaft for the Harold D. Roberts tunnel near Montezuma, Colo. Although the access shaft was merely a construction facility to expedite completion of a 23-mile water-diversion tunnel, a circular shaft of this type would be equally adaptable for mine development or other purposes. Comparable sinking methods and equipment could be used for similar shafts within a wide range of sizes and depths. SUMMARY In addition to excavation and support of the basic access shaft to tunnel grade, the overall sinking project involved initial preparation of a surface site and plant, subsequent construction of a tunnel-level station and loading pocket at the shaft bottom, and ultimate conversion of the basic shaft into a hoisting and access facility for tunnel operations. The sinking period for the basic shaft approximated one year. Actual tunnel operations through the converted shaft began on April 3, 1958, approximately 19 months after the project was initiated.

Jan 1, 1961

By R. S. Dean

T HE theory of hardening by heat treatment was, as usual, the most actively discussed phase of metal working theory and in spite of the fact that it is now ten years since the dispersion theory was proposed by Messrs. Merica, Waltenberg, and Scott, it still retains a dominating influence. It is being increasingly recognized. however, that in its simplest form, that is, the purely mechanical effect of very fine crystallites distributed through a groundmass, it is distinctly in- adequate. To explain the observed facts we are obliged to assume some well-defined intermediate stage between supercooled solid solution and conglomerate, however fine be the particles of the latter. This intermediate has been inferred by Gaylor and Preston to be "the rejection of the atoms of the dissolved metal from the lattice of the solid solution accompanied by the possible formation of molecules."' Perhaps this may well be designated as the formation of supersaturated solid solution. Some very definite evidence of such an inter- mediate stage has been found in the hardening of steel where it appears that the very hard martensite may be considered as a supersaturated solution of carbon in a iron. The X-ray spectrometry of drastically quenched steel shows a tetragonal lattice whose parameter changes by tempering at 100" until it coincides with the cubic lattice of iron.? The same gradual change of the tetragonal to the cubic lattice has been observed by Sekito when esamining layers on increasing depth below the surface of a quenched carbon steel.

Jan 1, 1930

By A. J. Farstad

Characteristics of metal/non metal mines were evaluated to determine the suitability of applying the U.S. Bureau of Mines electromagnetic location system to the problem of locating trapped mines in metal/non metal mines. Statistical distributions of mine depths and overburden conductivities show that the existing USBM EM system is inadequate for most metal/non metal mines. Alternate approaches to trapped miner location in deep mines were identified and subsequent field tests were conducted at six (6) mines to evaluate their feasibility. The approach considered to be the most promising is one which utilizes the existing manpack transmitting system, modified slightly for a dual frequency output, in conjunction with a sophisticated signal processing receiver on the surface. The main advantage of staying with a "through the earth" approach is that the underground equipment can be kept simple, easily maintained, light-weight and inexpensive.

Jan 1, 1979

By C. E. Augustine, B. A. Landry, P. Nicholls

"Wien bituminous coal is burned in a hand-fired up-draft boiler used for heating purposes it has a decided tendency to produce smoke. A design of furnace and a method of firing and attendance that are satisfactory for fuels low in volatile matter, as anthracite or coke, are not necessarily Satisfactory for bituminous coals. It is therefore becoming common practice to use a special design of furnace for bituminous coals, in order to facilitate the combustion of the volatile matter and soot. This is done by (1) providing a larger combustion space to give more time for the combustion, (2) construction that will produce a better mixing of the gases and secondary air supplied over the fuel bed, or (3) keeping the gases at a higher temperature by preheating the secondary air, as may be done by surrounding them with refractory surfaces, or causing them to pass through a fuel bed of hot coke. A furnace may be built to use any or all of these methods of smoke prevention.In Bureau of Mines Technical Paper 303, Blizard5 and others give tests on a large heating boiler when burning coke, anthracite, and bituminous coal. Certair alternative furnace arrangements were used, but there was no material change in the furnace design for the various fuels. Since that time the manufacturer has made modifications in design to adapt it for use of bituminous coal, and additional tests have been made to determine how this change affected the production of smoke and the efficiency of the boiler."

Jun 1, 1929

By R. C. Ruder, C. E. Birchenall

The method of decrease in surface activity was used to determine the rates of diffusion of Co" into cobalt and into nickel. Since the absorption curves for cobalt radiation were quite complex under the conditions of these experiments, the effects of geometry and surface preparation on the diffusion results were investigated. The cobalt self-diffusion coefficients obey the equation DCoco = e-61100/RT cm2 per sec. For dilute cobalt diffusing in nickel, DConi, == 1.46 e-/R' cm2 er sec. AS part of the general program to measure the self-diffusion and dilute-solution diffusion rates of the iron-group metals, the diffusion coefficients of cobalt into cobalt and nickel have been measured using the radioactive isotope Co"'. Self-diffusion studies in iron have been previously reported by Birchenall and Mehl.' The technique of measurement used was the decrease in surface activity method described by Steigman, Shockley, and Nix.' It has been determined that scattering of the measured beta radiation by the specimen matrix is significantly influenced by the condition of the surface and the counting geometry. Accurate diffusion coefficients can be calculated from the activity data provided that the specimens have plane diffusion surfaces and that the absorption properties of the emitted radiation are determined under geometrical conditions duplicating with external absorbers the absorption and scattering in a thin film at the specimen surface as nearly as possible. The cobalt used in this research was originally in the form of hydrogen reduced rondels 99.9+ pct pure. The nickel had been prepared by the carbonyl process and was found by spectrographic analysis to contain 0.03 pct Fe, 0.04 pct Co and smaller traces of other metallic elements for a balance purity of 99.9+ pet Ni. Both materials were vacuum melted and cast in rectangular ingots. Specimens 7/8x7/8x1/4 in. were machined from these ingots. The specimens were then ground to 4-0 emery paper and annealed in hydrogen for at least a day at 1200°C. Some of the specimens were used in preliminary experimentation after which their diffusion faces were machined to remove the radioactive material from the previous diffusion experiments. After grinding, the specimens were polished using an electrolytic lapping technique described by Mazia." This lapping was continued until at least 0.005 in. was removed from the diffusion surface. The final surfaces were metallographically smooth except for a few fine scratches caused by the glass cloth. A large percentage of the area was undisturbed as determined by microscopic examination. The grain diameters of the diffusion specimens varied from 0.1 to 5 mm. There were no effects due to grain boundary diffusion in the experiments

Jan 1, 1952

By Donald L. Everhart

The National Uranium Resource Evaluation (NURE) program since 1974 has been designed to accomplish a comprehensive coverage of the 48 conterminous States and Alaska to evaluate the total uranium resources of the USA. This resource base includes both ore reserves and potential resources. Techniques include airborne radiometric and magnetic surveys, by hydrogeochemical surveys, surface and subsurface geologic studies, and the application of improved geochemical exploration and resource assessment methods (Table 1). In brief review, the current status of each of the five basic NURE elements is as follows: In the Aerial Surveys, in the conterminous 48 states, the flying has been completed in 89 of the NTMS 10 x 2° NURE quadrangles, and is in progress in 39 more (Figure 1). Complete quadrangle data have already been open filed for 46 additional quadrangles, for a total of 174 for which data gathering is either complete or in progress. In Alaska, the flying is complete in 42 quadrangles, and quadrangle data have been open filed for 34 more, for a total of 76 (Figure 2).

Jan 1, 1979

By Dennis S. Kostick

Salt is a universal mineral commodity used by virtually every person in the world. Although a very common mineral today, at one time, it was considered as precious as gold in certain cultures. This study traces the material flow of salt from its origin through the postconsumer phase of usage. The final disposition of salt in the estimated 14,000 different uses, grouped into several macrocategories, is traced from the dispersive loss of salt into the environment to the ultimate disposal of salt-base products into the waste stream after consumption. The base year for this study is 1990, in which an estimated 196 million short tons of municipal solid waste was discarded by the U.S. population. Approximately three-fourths of domestic salt consumed is released to the environment and unrecovered while about one-fourth is discharged to landfills and incinerators as products derived from salt. Cumulative historical domestic production, trade, and consumption data have been compiled to illustrate the long-term trends within the U.S. salt industry and the cumulative contribution that highway deicing salt has had on the environment.

Jan 1, 1993

By Jr. Pitts

Elevation of surface charge density on colloidal particles in the presence of a high potential electrostatic field is demonstrated as a viable technique for preventing the accumulation of solids in solvent extraction circuits. The effect of the technique is manifest by relative turbidity measurements between pregnant leach solution and raffinate, by changes in the character of the sludge accumulations, by alteration of the zeta potential of particulates, and by a general reduction in the mass of solids.

Jan 1, 1992

The disasters between 1920 and 1979 in coal mines in Queensland and New South Wales due to underground fire, gas or coal dust explosion or to gas or coal outbursts, have been assessed. The evidence relating to disasters caused by gas explosion points strongly to divergence from safe mining practice as the main cause. There is a need for greater training and education of personnel, closer analysis of gas reports, better monitoring and testing procedures, improved ventilation standards and a policy where safe working practice is actively encouraged. Conditions in the New South Wales occurrences of gas explosion were similar to those at Collinsville, Queensland in that dykes, igneous sills, burnt out coal and faulting were common to all. Information on outbursts indicates that contributing factors were intrusions, depth of cover, fault zones and other geological disturbances, methods of work, pressure and type of gas.

Jan 1, 1982

By F. Sillers, R. T. C. Rasmussen

"INTRODUCTION This is the third report of investigations by the Bureau of Mines in cooperation with industry to establish the value of electrolytic manganese in the manufacture of ferrous and nonferrous alloys. The manganese was produced by the Bureau at its Boulder City pilot plant from domestic ores and by the process developed by it. 4/ The work was done under the direction of R.S. Dean, assistant director, Bureau of Mines, and R. G. Knickerbocker, chief, metallurgical branch. The first report dealt with the use of electrolytic manganese in the manufacture of stainless steels 5/ and the second with its use in acid electric or open-hearth low- and medium-carbon steel castings. 6/The present report treats of the use of electrolytic manganese in the manufacture of low—carbon rimmed and killed steels. A résumé of these three investigations and two others appeared in the magazine STEEL. 7/ Further reports will be published as tests are completed at some 70 industrial plants. All tests were made on full—scale heats or melts, and the resultant product was processed and used commercially."

Jul 1, 1945

By R. D. Parker

Location The Frood ore-body is expressed on surface as a prominent gossan ridge, with a total length of approximately two miles. The original Frood (the old No. 3 mine of the Canadian Copper Company) is at the southwest end of this gossan; adjoining it on the northeast is the Frood Extension (until 1929 the property of i:he Mond Nickel Company), while at the extreme northeast end is the Stobie mine. The first two of these divisions of the ridge form the Frood mine as it is known today.? This lies in lots 6 and 7 of the sixth concession, township of McKim, and is two and a half miles north of the city of Sudbury. The general elevation is 1,000 feet above sea level. The Ore-Body The Frood-Stobie parallel offset(l), as its name implies, has no connection in the field with the main mass of the Sudbury nickel eruptive-a norite. It lies one mile to the southeast of that body, and, in general, parallels it in strike. The ore occurs as a more or less tabular structure in what is known locally as the Sudbury series. They are the oldest rocks of the district, and have been placed by Collins(2) as earlier than the lower Huronian, of pre-Cambrian time. The series is comprised of sediments, volcanics (both acid and basic flows), tuffs, agglomerates, breccias, and basic intrusives, all highly metamorphosed, yet all forming a more or less regular picture. The controlling feature of the area has been the attitude of the sedimentary strata, from which has arisen the present sill-like character of the flow rocks, the basic intrusives, and the ore-body itself.

Jan 1, 1932

By Ingemar Hermansson, Thomas Bjerendal, Mattias Grävare, Carl-John Grävare

"AbstractHigh strain dynamic pile tests (HSDPT) on driven piles have been carried out on a routine basis in Sweden for more than 30 years. The Swedish Commission on Pile research established, in the early 1980s, safety factors based on the percentage of piles tested. The safety factors could then be reduced, creating economic incentives for the contractor to carry out testing.Energy formulas adopted by our neighbour countries, Norway and Denmark, were not accepted in Sweden as a reliable method since the dynamic testing method was considered to be a more scientific and reliable method. It has become almost the only in-situ method used to verify geotechnical bearing capacity on driven piles.The typical Swedish geology of soft soils overlaying very hard strata makes it possible to verify high design loads, typically 20 kN per cm2 of pile cross sectional area for steel piles and 1,5 kN per cm2 for concrete piles.Conventionally a certain percentage of the piles have been tested in Sweden. The EC7, on the other hand states a number of piles to be tested, regardless of the total number of piles. The Swedish NA (National Annex) states a maximum distance between tested piles, which results in better distribution of the test piles over the foundation.For shaft-bearing piles in soft clays, dynamic pile tests have to be correlated by static load tests.Historical backgroundOn a research basis stress-wave measurements have been carried out for a long time in Sweden. One example is a project in the city of Gothenburg, conducted by Fellenius and Pejrud (1964). Strain gauges were glued on the reinforcement bars in 60 m long, precast concrete piles at 3 m and 25 m above the pile tip respectively. Evaluation was done with different methods such as dynamic formulas,stress-wave measurements and in addition compared with static load tests.In the 1975 Building Code in Sweden, driving criteria for concrete piles based on stress-wave theory were introduced, as summarized in Table 1. The driving criteria are intended for 3 and 4 tonne gravity hammers. For hydraulic rigs, which have free-falling hammers, the drop height indicated should be reduced to 80 % of the values in the table. The criteria were considered to include a safety factor of 3,0. For 330 - 450 kN pile load, pile with a standard a cross sectional area of 235 mm x 235 mm was used. For 600 kN load, the standard cross sectional area was 275 mm x 275 mm."

Jan 1, 2014

By Yi Luo

The efforts to mitigate longwall subsidence influences on various residential and farming structures by many coal mining companies have been successful in the recent years (Luo, et al, 2003). The successes were largely dependent on the accurate subsidence predictions, correct assessments of potential influences, appropriate design and implementation of the mitigation measures. However, such efforts for protecting large industrial structures are still very rare. In this paper, the successful assessment and mitigation of the subsidence influences associated with a very intensive dynamic longwall subsidence process on a large workshop are presented.

Jan 1, 2005

The Kalgoorlie Golden Mile is proposed as an Archaean volcanogenic-type deposit, modified and redistributed along later-developed structures. Rich pyritctelluride and Green Leader gold mineralization is associated with the end phase of basic volcanism and, in a general sense, is confined to a broad interface zone between the products of marine basic volcanism and later acid volcanism. There is virtualIy no ore associated with the main body of acid volcanics.Green Leader is the local name of a type of ore that occurs at some igneous rock contacts in association with graphitic sediments and layered acidic tuffs. It is characteristicalIy green, of various shades, and commonly yields very high gold assays, the reasons for which are not apparent in hand specimen.Carbonates, carbonaceous shales, tuffites, rich gold ores, and acid and intermediate dykes, alI indicating a common heritage, are features common to the main ore hosts, viz. the Paringa Basalt (Calc Schist) and theGolden Mile Dolerite ("Quartz Dolerite Greenstone").Several probably related fracture systems have reconstituted most, but not all, of the original deposits into a large number of steep tabular lodes.Includes two sets of discussions and comments from later Proceedings volumes.

Jan 1, 1974

By W. T. Millar

"INTRODUCTION The purpose of the Star Lake project was to investigate, by geophysical surveying and diamond drilling, the magnetite deposits in the northwestern Adirondacks, the ultimate objective being to increase iron production in eastern United States,ACKNOWLEDGMENTSIn its program of investigating mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to the national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclu-sion. The Mining Branch, Lowell B. ""Moon, chief; conducts preliminary examinations, performs the actual investigative work, aid prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiation tests.The chemical and spectrographic analyses included in this report were performed at the Eastern Experiment Station of the Bureau of Lines at College Park, Md., under the general supervision of J. B. Zadra, chief, College Park Division, Metallurgical Branch, and under the immediate direction of Dr. Alton. Gobriel in charge of the laboratory service unit.The mineral exploration was under the general supervision successively of John D. Bardill, district engineer, and McHenry Mosier, chief, College Park Division, Mining Branch. The work was done under the immediate supervision successively of J. P. Ryan, N. A. Eilertsen, and W. T. Millar, project engineers."

Sep 1, 1947

By R. F. Favreau, L. C. Lang

"In modern blasting technology blasts are designed and analysed on an energy-mass-time relationship. The energy of the explosive is derived by computer analysis and the work potential of the available energy is expressed in numerical values. The mass involved in the blast is determined by the geometry of the blast and by the rock density. Time is also a relevant parameter, because time is required to complete the three basic stages of the breakage process.For successful application of the blasting parameters the basic mechanism of the breakage process must be understood.The physical-mechanical properties of the rock, local structural geology and the thermodynamic properties of the explosives can be brought together to create a computer model of a blast with which it is possible to predict separately the results of each parameter and to express the predicted degree of change in any parameter by actual numbers.A long-range project has started to create a ""bank"" of rock properties for as many Canadian and foreign mines as possible. A computer model has been successfully applied to predicting the effect of varying the ratio of spacing to burden at constant rock volume and significantly improved results are achieved, as the S/B ratio is increased up to about 2 to 2.5.High-speed photography has been applied to determine the time that has elapsed between zero time and the beginning of movement of the mass. The results assist in determining minimum and optimum delay time required for multiple-row blasting.The approach as described in the paper is now well proven and is clearly superior to previous methods based on powder factors and human assessment."

Jan 1, 1972

By Hiroyuki Matsuura, Fumitaka Tsukihashi

"Emission of CO2 gas from steelmaking industry covers more than 12 % of total CO2 emission in Japan. Though many efforts have been made to curtail energy consumption and high energy efficiency of Japanese steel production process has been achieved so far, further reduction of CO2 emission is strongly requested to develop sustainable steel production process and produce “green material”. Recently, authors have proposed the innovative hydrogen production process, in which water vapor is reacted with discharged steelmaking slag to produce hydrogen gas. This reaction can be achieved without any external energy source and operated by huge thermal energy associated with steelmaking slag and FeO or unrecovered Fe droplets that are relatively rich in the slag. In this paper, thermodynamic calculation results with various initial conditions in terms of hydrogen productivity were presented. Laboratory-scale experiments were also conducted to clarify the validity of thermodynamic calculation and the reaction rate in realistic conditions.IntroductionIronmaking and steelmaking process from iron ore through blast furnace and BOF is an essential steel production route for Japanese steel industries to supply high quality steel products in large quantity to society stably. Blast furnace – BOF process requires huge amount of fossil fuels such as mainly coal, resulting the emission of considerable amount of CO2 gas. Since the emission of CO2 gas from steel industries, about 147 Mt (FY2011), accounts for approximately 12 % of domestic CO2 gas emission in Japan (FY2011),[1] it is an urgent issue for steel industries to develop environmental-friendly ironmaking and steelmaking process and reduce CO2 emission. Various kinds of gases and by-products generated from ironmaking and steelmaking processes have been recycled as much as possible at present. Enormous thermal energy is also generated from processes and released to surrounding atmosphere as various forms such as sensible heats of gases, molten steels or by-products, and as heat losses. However, these energies are not utilized before final dissipation to atmosphere. Although various technologies to utilize thermal energy from ironmaking and steelmaking processes have been attempted to develop, practical application of these technologies has not been achieved because the thermal energy is not always useful as an energy source. In steelmaking process by BOF, fluxing agent such as CaO is added during reefing and thus about 100 kg/t-steel of steelmaking slag are generated. Since the steelmaking slag is discharged at temperature range between 1873 and 1923 K after discharge of refined molten steel, it also has large thermal energy. Amount of generated BOF slag is 11.0 Mt/y (FY2012) in Japan.[2] Assuming the amount of steelmaking slag is 10 Mt/y and its average heat capacity from room temperature to 1923 K is 1 kJ/kg·K,[3] unutilized heat is estimated to be 16 PJ/y, which is equal to annual energy consumption of 420 thousand families in Japan.[4]"

Jan 1, 2014

By H. Lyn Bourne

This is the fourth annual tabulation that gives mineral royalty information. The table presents previous information plus about two dozen new entries. In addition to the royalty information, some entries show the cost of purchased reserves. Last year's tabulation appeared in two issues, to accommodate all of the information. This year the format has been changed slightly so the table can be printed in one issue. This year's table presents the commodities in the same sequence as last year. Sand and gravel information appears first, followed by: crushed stone for aggregate; other stone; industrial sand; other industrial minerals; energy minerals (coal, oil shale, uranium); and finally metals. As always, a caveat relates to factors that influence the reserve values. The data should serve only as a general reference. The table is not intended to present an absolute scale of reserve costs. Several factors influence the value of mineral commodities. These factors include: • location and transportation costs (especially significant for most industrial minerals); • market conditions for both the commodity and the company acquiring the right to mine it; • quality or grade of the deposit as it reflects the amount of processing and beneficiation necessary to produce the finished product; • and legislative restrictions and conditions for mining a given material at a given site. These and other factors will influence reserve costs of reserves. The table shows the range of royalties and the variations in the basis of computing the fees. In a few instances, it gives the cost of acquired reserves based on purchase price and quantitative estimates of the material in place. The table lists the commodity; the location (either by state, US geographic area, or Canadian province); the cost (R for royalty and P for purchased cost); and the year in which the lease or purchase agreement occurred. The last column offers either comments or gives a footnote number for more information. The cost column requires more explanation. The units may refer to cubic yards (/yd), cubic feet (/cuft), tons (/T) (2000 lbs) or acres (/A). 1 cu yd = 0.76m3 1 cu ft =0.28m3 1st = 0.9 t7 1 acre = 0.40 ha or m2 In several cases the royalty is a percentage of the finished products, sale price and is levied against either the amount produced or the amount sold. We thank those who contributed information for the table: J. Dunn, T. Eyde, K. Loda, L. Morgan, F. Nix, H. Sorenson, and L. Williams. Several people have said they would like this to be an annual tabulation. That can happen if new information comes to the writer. What appears in the table is only a very small fraction of the cost information relative to the various commodities and the geographic areas for which there is royalty information. If you find this column of interest and possess information write or call: H. L. Bourne, c/o Neyer, Tiseo & Hindo, Ltd., 38955 Hills Tech Dr., Farmington Hills, MI 48018, (313) 553-6300. Only with new information can this become an annual and current source of reserves costs.

Jan 8, 1986

By K. A. Lapakko, D. A. Antonson

Fourteen samples of pyrite-bearing Archean greenstone rock (d < 6.35 mm, 0.04% < St < 1.22%) were characterized (particle size, chemistry, mineralogy) and subjected to laboratory dissolution testing. The only sulfide and carbonate minerals identified were pyrite and siderite, respectively. Quartz, chlorite and sericite typically comprised 90 to 98 percent of the mineral content. For the first 60 weeks, seven samples with sulfur contents less than or equal to 0.16% produced drainage pH values exceeding 6.0. Over this period, six of the seven samples with sulfur contents greater than or equal to 0.20% produced drainage pH below 6.0, with minimum values ranging from 3.2 to 4.7. The seventh sample (0.72% S) had a siderite content of 18%. Small amounts of magnesium and, to a lesser degree, calcium carbonates present in the siderite apparently dissolved to neutralize acid and maintain drainage pH above 6.0. Sulfate release rates generally increased as sulfur content increased, and the rates of pyrite oxidation estimated for individual samples were roughly half to five times that reported in the literature for the abiotic oxidation of pyrite by oxygen. Observed neutralization potentials ranged from 0.2 to 2.0 g CaCO3/g rock.

Jan 1, 2002

By Z. Jin, D. DePaoli, P. Zhang

"Phosphorite, or phosphate rock, is the most significant secondary rare-earth resource. It contains high amounts of phosphate-bearing minerals along with low contents of rare earth elements (REEs). In Florida, about 19 Mt of phosphate rock are mined annually and most are used to manufacture fertilizers using a wet process, in which sulfuric acid reacts with phosphates to produce phosphoric acid and phosphogypsum. In the wet process, REEs are also leached out into solution and eventually get lost in the leaching residue and phosphate fertilizer. Recovering REEs from Florida phosphate rock in the wet process will be beneficial to broadening rare-earth availability, improving the quality of phosphoric acid product and protecting the environment.This study focuses on the influences of wet-process operating conditions on REE leaching efficiency. The results indicate that REE leaching efficiency increases with phosphoric acid addition in the initial pulp. At a temperature of 75 °C, a stoichiometric ratio of sulfuric acid (H2 SO4 ) to calcium oxide (CaO) of 1.05 and a weight ratio of liquid to solid of 3.5, REE leaching efficiency reached a relatively high value of 52.82 percent. The trends of REE leaching efficiency were similar to those for phosphoric acid (P2O5 ). Extensive tests on the leaching residue showed that during leaching, about 90 percent of the REEs were released from the phosphate rock but only 52.82 percent ended up in the leaching solution. This phenomenon can be attributed to two factors: (1) the effect of phosphate ions (PO4 3-) in the solution, which caused REE ions to form REE phosphates and be precipitated into the leaching residue, and (2) the influence of large amounts of anions such as sulfate (SO4 2-), dihydrogen phosphate (H2 PO4 -) and hydrogen phosphate (HPO4 2-) anions as well as the polar molecule H3 PO4 , which surrounded the REE cations and formed an ion atmosphere that prevented the PO4 3- from contacting and combining with REE cations. Interaction of these two opposite effects determined the REE distribution between leaching solution and residue."

Jan 1, 2017