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By J. A. Brierley, C. L. Brierley, R. C. II Blake, S. McGinness

A principal long-term goal of this laboratory is to achieve a detailed understanding at the molecular level of the microbial-dependent solubilization of minerals. Three recent advances in this research are summarized. (i) An in situ electrolytic procedure is described whereby large quantities of autotrophic iron-oxidizing organisms may be achieved for fundamental or applied studies. Over 600 grams wet weight of Thiobacillus ferrooxidans were harvested from a single 55-gallon growth vessel. (ii) A basis is presented for classifying some 70 different iron-oxidizing bacteria into one of 4 categories, depending on the type of redox-active electron transport proteins expressed during aerobic respiration on reduced iron. Comparative spectroscopic analyses indicated that different electron transport mechanisms exist in different genera and species of acidophilic bacteria that respire on iron. (iii) A method is introduced to investigate the binding interaction between bacteria and minerals, based on changes in the electrokinetic properties of the two species. Preliminary experiments indicated that the electrophoretic mobilities of pyrite and Thiobacillus ferrooxidans were both altered when the two colloid particles were mixed prior to the actual electrokinetic measurement. The need for more basic information regarding all aspects of the microbial-dependent solubilization of minerals is evident.

Jan 1, 1993

Halide media are considered as suitable alternatives to cyanide for extracting gold and have received much attention lately. The extraction of gold by iodide-iodine mixture has been patented and briefly studied without much attention given to the fundamental aspects of this process. This paper reports recent studies on the kinetics of gold extraction in iodide media, using hypochlorite, iodine and hydrogen peroxide oxidants. The kinetics of dissolution was found to be dependent on the solution pH, reagent concentration and most importantly the iodide- oxidant molar ratio. Without proper control, the gold surface can be passivated due to the formation of solid products. Thermodynamic modelling was carried out to determine the equilibria governing the dissolution process. The formation of AuI solid was also identified as a possible product during the dissolution.

Jan 1, 1992

The plan for establishing relations of American industry with national labor on a definite basis so closely follows the channels of the efforts of Engineering Council, principally in the classification and compensation work, that it is of special interest to the engineering profession. The principles laid down under the following headings are about to he submitted to a referendum vote of the membership of the Chamber of Commerce of the United States. These principles were prepared by a special committee of the Chamber of Commerce after a long period of study of the entire subject of industrial relations. 1. Industrial enterprise, as a source of livelihood for both employer and employee, should be so conducted that due consideration is given to the situation of all persons dependent upon it. 2. The public interest requires adjustment of industrial relations by peaceful methods. 3. Regularity and continuity of employment should be sought to the fullest extent possible and constitute a responsibility resting alike upon employers, wage earners, and the public. 4. The right of workers to organize is as clearly recognized as that of any other element or part of the community. 5. Industrial harmony and prosperity will be most effectually promoted by adequate representation of the parties in interest. Existing forms of representation should be carefully studied and availed of in so far as they may be found to have merit and are adaptable to the peculiar conditions in the various industries. 6. Whenever agreements are made with respect to industrial relations they should be faithfully observed. 7. Such agreements should contain provision for prompt and final interpretation in the event of controversy regarding meaning or application.

Jan 6, 1919

By J. Petersen, K. Shaik1, H. Kolev, Z. Cherkezova-Zheleva

Sperrylite is one of the most abundant platinum minerals globally, valued for its economic importance but also known for its highly refractory nature, making it difficult to process via the conventional route. This study explores the oxidative leaching of sperrylite using a cyanide–ferricyanide system, with a key focus on characterisation of the mineral and surface speciation under varied leaching conditions using x-ray photoelectron spectroscopy. The parameters investigated include the effect of sodium cyanide concentration, the use of potassium ferricyanide as an oxidant, copper sulphate pentahydrate as a catalyst, as well as the effects of temperature and particle size. A limited set of leaching tests was carried out to study the surface chemistry rather than optimising dissolution conditions. This approach identified mineral oxidation states and shifts in binding energies, prior to and post leaching. XPS analysis of sperrylite’s surface chemistry identified key species, comprising the bulk Pt(II)–As (≈73 eV) and As(–I)–Pt (≈41.8 eV) states, together with surface oxidation products Pt(II)–O (≈72 eV), Pt(IV)–O (≈74.5 eV), As(III)–O (≈43 eV) and As(V)–O (44.5 eV). Leaching led to the removal of pre-existing oxides on the ultra-finely ground sample, exposing the underlying bulk species. In contrast, the crystalline sample with an initial low concentration of oxides, generated higher amounts of fully oxidised species after leaching, reflecting greater surface reactivity.

Mar 6, 2026

By L Strezov, J Herbertson

Conversion of industrial waste materials to valuable resources would essentially take part in an ecologically sustainable future. There are still large amounts of undervalued biomass wastes generated from a diverse range of industries that are disposed in landfields. They have potential to produce valuable materials and fuels, such as charcoal, bio-oils and bio-gas through thermal upgrading. In order to enhance the efficiency of the thermal upgrading process, comprehensive characterisation of the raw biomass materials is essential. We have developed a novel thermal characterisation method that utilises computer aided thermal analysis incorporated with a gas analyser. The method was applied on two biomass materials, wood sawdust and bagasse. The paper discusses the results obtained with the novel thermal characterisation technique.

Jan 1, 2006

[Costs may be classified according to their source and behavior: Scale of aggregation - Total costs - Unit costs Time period for which the costs are charged - Product costs - Period costs Controllability and relevance for decision-making and control - Controllable costs - Noncontrollable costs - Sunkcosts - Opportunity costs Their basic source - Production costs (also termed manufacturing costs) - Nonproduction costs How the costs change with changes in activity - Fixed costs - Variable costs - Semivariable costs Traceability to individual units of production - Direct costs - Indirect costs Use in planning (budgeting) and subsequent control - Standard costs - Normal costs ]

Jan 1, 1999

By G. A. Irona

Solids injection into non-ferrous converters and furnaces is becoming increasingly important for concentrate injection, removal of impurities, and recycling of dusts and other waste materials. The fundamental design aspects of these technologies will be reviewed, including gas and particle trajectories, lance clogging, heat transfer, and mass transfer including reaction rates and mixing. The use of soda ash for removal of impurities such as antimony and selenium will be used as an example of versatility of powder injection processes.

Jan 1, 1993

By A. R. Oltrogge

WE have just seen? that resistance is a characteristic of an electric circuit that makes it difficult for current to flow; also, that if, by the application of voltage, we cause a current to flow through a circuit having resistance, heat is generated. This is the principle utilized in the production of heat by electric power in the arc furnace. In order to fully appreciate the problems of the arc-furnace electric circuit, let us examine the characteristics of some of the more commonly used materials that offer resistance to a flow of current and thereby produce heat. Usually the resistance material is a metal or a metal alloy, such as the nichrome ribbon in an electric toaster or the tungsten filament of an ordinary light bulb. These are the materials whose resistance-remains relatively fixed and which therefore permit the flow of a definite amount of current for a given impressed voltage. If we want more current to flow, we must either decrease the resistance or increase the voltage that is causing the current to flow. Such a resistive material has what we call a positive volt-ampere characteristic, which means that in order to get more current we must apply more voltage, and in order to reduce the current we must reduce the voltage. Such a volt-ampere characteristic can be represented by a line plotted on a graph (line B, Fig I).

Jan 1, 1947

By A. Chieregati

"A heterogeneity study was conducted at Erdenet Copper Mine in Erdenet, Mongolia, to determine the fundamental sampling error associated with blasthole sampling. Using a custom designed sector sampler, six large blasthole samples were collected to perform the test that was developed by Pierre Gy, to estimate the constitutional heterogeneity factor for several types of ore. The study investigated the entire sampling protocol, from mine site to analytical laboratory, and quantified the contributions to fundamental sampling error (FSE) of the various stages of sampling and sample preparation. The total relative standard deviation (RSD) of sampling error was determined to be ±32% and ±49.4% for copper and molybdenum respectively. A classical statistics analysis conducted on the data confirmed the level of RSD. About 95% of the sampling error was produced from only one step in the sampling protocol: when the 1 kg sample was reduced to 50 g sample for chemical analysis. Therefore, it is recommended that the 1 kg sample be reduced to 50g using a slightly different protocol to minimize the FSE. The 1 kg sample should be first crushed to 0.2cm size. A 250g split should then be taken and fine ground. A 50g split should then be taken from the 250g fine ground split. These two simple steps will reduce the FSE to ±7.9% and ±17% for copper and molybdenum respectively. The modified sampling protocol effectively reduces the probability of misclassification of low grade ore to zero. INTRODUCTION The Erdenet copper-molybdenum open pit mine is located in Erdenet, in Orkhon province, Mongolia. The Erdenetiin-Ovoo copper-molybdenum deposit is between 1.5 and 3 km wide, and about 25 km in length (Erdenet Mining Corporation, 2016). Chalcopyrite, bornite covellite and chalcocite are among the major minerals found in the deposit. The mine processes approximately 26 million tons of ore annually. A study was conducted to evaluate the fundamental error associated with the blasthole cuttings and sampling protocol at the mine. The open pit mine uses 215mm diameter Russian drills to drill 17.5m holes for 15m benches. The total weight of blasthole cuttings for a 215mm diameter hole and 15m bench height is between 1.5 and 2 tonnes. This amount of sample is difficult and time consuming to collect and analyze. Therefore, a sector sampler was designed for the Russian drills to collect large samples that were representative of the blasthole cuttings (Ganguli et al., 2016). In order to eliminate the delimitation and the extraction errors, researchers consider sector samplers to be ideal for sampling blastholes (Pitard, 2008; Chieregati and Pitard, 2009). This method was intentionally more rigorous than the blasthole sampling protocol at the mine to ensure that the blasthole cuttings were properly sampled. This study was part of a broader study that also looked at the relationship between particle size and grade. The samples collected by the custom designed sector sampler were very large (195 kg on average), and therefore, sufficient for both studies. The relationship between particle size and grade has been reported in Ganguli et al. (2016)."

Jan 1, 2017

By A. Chieregati

"A heterogeneity study was conducted at Erdenet Copper Mine in Erdenet, Mongolia, to determine the fundamental sampling error associated with blasthole sampling. Using a custom-designed radial sector sampler , six large blasthole samples were collected to perform the test developed by Pierre Gy to estimate the constitutional heterogeneity factor for several types of ore. The study investigated the entire sampling protocol, from mine site to analytical laboratory, and quantified the contributions to total fundamental sampling error (FSE) of the various stages of sampling and sample preparation. The total relative standard deviation (RSD) of sampling error was determined to be ±32 percent and ±49 percent for copper and molybdenum, respectively. A classical statistical analysis conducted on the data confirmed the level of RSD native to the mine. About 95 percent of the sampling error was produced from one step in the sampling protocol, that of reducing the 1-kg (2.2-lb) sample to a 50-g (0.1-lb) sample for chemical analysis. To minimize the FSE, the use of a slightly different protocol is recommended. The 1-kg sample (2.2-lb) should first be crushed to a 0.2 cm (0.08 in.) particle size. A 250-g (0.5-lb) split should then be taken and finely ground, from which a 50-g (0.1-lb) split should then be taken. These simple steps will reduce the FSE to ±7.9 percent and ±17 percent for copper and molybdenum, respectively. The modified sampling protocol effectively reduces to zero the probability of misclassification of low-grade ore. IntroductionThe Erdenet copper-molybdenumopenpit mine is located in Erdenet in Orkhon province, Mongolia. The Erdenetiin-Ovoo copper-molybdenum deposit is 1.5 to 3 km (0.9 to 1.8 miles) wide and about 25 km (16 miles) long (Erdenet Mining Corp., 2016). Chalcopyrite, bornite covellite and chalcocite are among the major minerals found in the deposit. The mine processes approximately 26 Mt/a (29 million stpy) of ore."

Jan 11, 2017

By Leon W. Dupuy

INTRODUCTION A BRIEF elemental discussion of the fundamental factors involved in diamond drilling often fills a need, particularly when a mine operator is contemplating for the first time an exploratory drilling campaign. Mr. James A. Barr, of the Mining Methods Committee of the Institute, has suggested that many engineers must undertake a drilling program of one kind or another and, in the case of diamond drilling, sometimes even are at a loss as to how to start correspondence. The Bureau of Mines has acquired much experience in managing exploratory diamond-drilling activities. Its activities in diamond drilling included exploring for potash in Texas, Utah and New Mexico 1-4 during the 1920's. The Strategic Minerals Exploration program was started in 1939 and was materially expanded during the war to include critical and essential minerals. At the peak of its war-time activity more than 200 engineers were employed, a majority of whom supervised diamond drilling. Many of them had little experience with such work prior to their employment with the Bureau, and it was necessary to instruct them in their duties. The purpose of this paper, therefore, is to present the fundamentals of exploratory diamond drilling from the viewpoint of management in such a way that they will serve as a basis on which those beginning exploratory diamond drilling may build an experience and acquire ability to direct exploration as they gain that experience. SELECTION OF METHOD OF DRILLING Selection of the method of drilling is governed by the type of material to be penetrated and by the type of sample needed to determine the quality and importance of a deposit. Types of drills that might be used for a given job include diamond drills, churn drills, hand auger drills, power auger drills, bucket drills, and rotary drills (sometimes called "seismograph rigs"). Each type has a specific field in which it is most useful. While the Bureau of Mines utilized all the types of drilling mentioned, diamond drilling was used on a majority of its exploratory projects. FACTORS GOVERNING SELECTION OF DIAMOND DRILLING The prime consideration in selecting a method of drilling is first to determine what results are desired and then to choose a method that will furnish reliable data in the ground to be penetrated. Use of diamond drills permits recovery of a core as well as sludge at a comparatively low cost. The core provides an excellent means of studying the formation being drilled and furnishes much information that would be difficult to obtain otherwise. Diamond drills will recover a satis-

Jan 1, 1947

By Leon W. Dupuy

SUPPLEMENT THESE tables should accompany Figs 6, 7, 8, 9 and 10, respectively. To follow Fig 6: TABLE 2[a]-Drill Rod [ ] To follow Fig 7: TABLE 3-Rod Coupling [ ]

Jan 1, 1947

By R. A. Jankowski, J. J. McClelland

Laboratory tests were conducted by the U.S. Bureau of Mines to determine the respirable dust reduction effectiveness of and interaction between face airflow and water sprays for a continuous miner. Exhausting face ventilation was varied from 3,000 to 9,000 cfm (1.42 to 4.25 m3/sec). Spray-water-flow was varied from 15 to 35 gpm (0.057 to 0.132 m3/min), while nozzle operating pressure was varied from 80 to 200 psi (5.62 to 14.06 kg/cm2). Results from gravimetric dust samples indicated that airflow had the greatest individual impact on reducing dust levels, with return and operator concentrations reduced by as much as 57% and 99%, respectively. Interactions between dust control parameters were found to be significant. Often, these interactions defined a level of application for a control parameter where further increases in that parameter failed to produce additional reductions in dust concentrations. In several cases, increases in a control parameter resulted in higher dust levels at the operator's location. These higher dust levels were attributed to additional rollback and/or airflow turbulence. Regression modeling indicated that increases in airflow to 8,400 cfm (3.96 m3/sec), water flow to 25 gpm (0.095 m3/min), and water pressure to 140 psi (9.84 kg/cm2) typically were beneficial at the operator and return sampling locations.

Jan 1, 1991

Based on experimental and computer simulation results from our group, we report a systematic, atomic level analysis of carbon dissolution from carbonaceous materials in molten iron. Experimental results on graphite / Fe-C-S system were obtained using carbon dissolution studies, XRD and FESEM investigations and were supplemented with Monte Carlo simulations. Three basic mechanisms, namely carbon atom dissociation rate, interfacial phenomena and mass transfer in the melt were found to be responsible for the overall dissolution process. While mass transfer in the melt is governed by the concentration gradients, melt composition and temperature; impurities present in ash play a significant role in the interfacial phenomena. For less ordered forms of carbonaceous materials, carbon atom dissociation rate depends strongly on the degree of long-range order and is an important rate controlling mechanism in the overall dissolution process. A systematic comparison of dissolution rates for a variety of coal-chars, natural and synthetic graphites has been carried out in an attempt to identify rate-controlling mechanisms. The structure of the carbonaceous material appears to be an important underlying factor in the carbon dissolution process.

Jan 1, 2003

Based on experimental and computer simulation results from our group, we report a systematic, atomic level analysis of carbon dissolution from carbonaceous materials in molten iron. Experimental results on graphite/Fe-C-S system were obtained using carbon dissolution studies, XRD and FESEM investigations and were supplemented with Monte Carlo simulations. Three basic mechanisms, namely carbon atom dissociation rate, interfacial phenomena and mass transfer in the melt were found to be responsible for the overall dissolution process. While mass transfer in the melt is governed by the concentration gradients, melt composition and temperature; impurities present in ash play a significant role in the interfacial phenomena. For less ordered forms of carbonaceous materials, carbon atom dissociation rate depends strongly on the degree of long-range order and is an important rate controlling mechanism in the overall dissolution process. A systematic comparison of dissolution rates for a variety of coal-chars, natural and synthetic graphites has been carried out in an attempt to identify rate-controlling mechanisms. The structure of the carbonaceous material appears to be an important underlying factor in the carbon dissolution process.

Jan 1, 2003

The SART (sulfidisation, acidification, recycle, and thickening) process is an effective way to separate copper and cyanide from each other in the waste stream of gold processing plants using cyanidation. Factorial experimentation has been conducted to create models of copper recovery, cyanide recovery, acid addition, and oxidation I reduction potential during SART. Economic analysis of the resultant models showed that SART is best operated with a sulfide to copper molar ratio of around 0.56, a pH of 4, and a minimised cyanide to copper molar ratio. The experiments also showed that thickening time may have drastic impacts on SART performance.

Jan 1, 2011

ABSTRACT The SART (sulphidization, acidification, recycle, and thickening) process is an effective way to separate copper and cyanide in the waste stream of gold processing plants using cyanidation. Factorial experimentation has been conducted to create models of copper recovery, cyanide recovery, acid addition, and oxidation/reduction potential during SART. Economic analysis of the resultant models showed that SART is best operated with a sulphide-to-copper molar ratio of approximately 0.56, pH of 4, and a minimized cyanide-to-copper molar ratio. The experiments also showed th0at residence time can have drastic impacts on SART performance.

Jan 1, 2013

By Maurice Bottiau

When dealing with displacement auger piling, some general and fundamental issues have to be considered, irrespective of the system. More than with other pile types, the interplay between the soil conditions and the design and execution is of outstanding importance. This paper intends to address these issues and to summarize some critical matters in terms of design, execution and control such as : ? Importance of a reliable soil investigation ; ? Summary of the design as it is addressed in Europe for this category of piles ; ? Criteria for a good choice and control of the correct asset of the piles ; ? Importance of the concreting phase; ? Relation between the power and the engine characteristics of the drilling equipment with the final bearing capacity. For each of these issues detailed examples will be given as well as results of load tests and in-situ control during execution.

Jan 1, 2003

By C. E. Mendenhall

THE word temperature has both a colloquial and a technical use. For everyday purposes of abusing the weather man, no very exact definition is necessary, but for the purpose of giving a simple summary of the physical laws that form the basis of practical pyrometry, something more precise is required. Beginning, therefore, with the common concept of "hotness" and "coldness," we must agree on a method of measuring differences in "hotness," on the unit to be used, and on the point from which measurements are to be taken. We shall then have a definite "scale of temperature," which can be used in all methods of pyrometry. But, as in many similar cases, it is much easier to define or describe something than it is to make practical application and use of the definition; so that much of our attention will be taken up with practical methods of realizing or applying the scale agreed upon. It was early observed that changes in temperature produced large and easily measurable changes in gases, which may be most simply separated into changes in volume (expansion and contraction) under conditions of constant pressure, and changes in pressure under conditions of constant volume. These changes are much the same in magnitude for the common gases oxygen, nitrogen, and hydrogen and also for the rarer helium and argon. This relative uniformity in behavior led to the suggestion of "the gas thermometer" and "the gas scale" as the basis for all temperature measurements. However, as methods were refined, differences appeared between different gases and different ways of using gases, so that Lord Kelvin introduced his more fundamental notion of the "absolute thermodynamic scale" of temperature, which he defined as follows: Given two bodies, say two tanks of water, at different temperatures to determine these temperatures on the "absolute thermodynamic," or Kelvin, scale, operate a thermal engine between these two temperatures, letting it take in heat from the hot body and give out heat to the cold, which therefore corresponds to the boiler and the condenser of a steam engine. The engine we may imagine as a cylinder and piston inclosing a gas and operating with the well-known Carnot or isothermal-

Jan 9, 1919

By O Ignatenko, A van Schaik

Environmental legislation for the process and manufacturing industries is frequently formulated without considering the fundamental limits of physics, chemistry and thermodynamics within process technology. Recycling of end-of-life goods is used in this paper to show how the limits can be evaluated on the basis of the theory of minerals processing and metallurgical engineering. This theory has been applied on European Union level to re-examine the legislation for automobile recycling in a recent stakeholder discussion involving the automotive industry (http://www.assurre.org). This theory and our models are finding their way into the computer aided design (CAD) tools of the automotive industry, developments that form part of a project to design the super light car of the future (http://www.superlightcar.com). Only such fundamental approaches will in future be able to provide the basis to argue and define realistic and sensible environmental legislation.

Jan 1, 2006