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By G. Hanko, A. Lebleu, M. Sibony, J. Lecadet

The New Jersey distillation process is today the most important pyrometallurgical method for the production of zinc of very high purity. The flexibility of the pyrometallurgical zinc production process, especially its ability for recycling, makes it competitive, although it is energy intensive. A deeper knowledge of the New Jersey process is necessary to further increase its technical performance by ensuring its global safety. A project, integrated in the European research program EUREKA, has been started in order to define the process chemistry of distillation. Experimental measurements have been carried out with a column at the laboratory scale, and the results, linked with industrial measurements, support the development of a model based on material and thermal balances. The first conclusions indicate that the key parameters for process optimization are the column geometry and the distribution of the thermal losses.

Jan 1, 2000

By A. Robles

The main goal of the present work is to propose a viable alternative for selective arsenic elimination from copper smelter flue dust without the need of a global leaching scheme for all the individual components of the flue dust. Using this alternative, the inherent copper recovery problems are avoided. Arsenic precipitation is also considered for regenerating the solution and completing the process cycle. The experimental results for arsenic extraction and precipitation are satisfactory. Concentration of NaOH used was relatively low. The main reason for succeeding in high arsenic extraction and low NaOH consumption is due to the previous water washing of the flue dust. Water washing dissolves much of the iron and copper that are present in certain percentage as sulphate.

Jan 1, 1999

By P. Stantke

In recent years the CollaMat process has been used successfully worldwide in a number of copper electrorefining tankhouses as an instrument for measuring the glue concentration and optimizing cathode quality. Owing to its measuring principles the CollaMat can be used not just for measuring the concentration of active glue but also the activity of other substances, which have an impact similar to glue on the copper deposition. In SX-EW plants guar is frequently used instead of glue as a levelling additive. In our laboratory the effect (activity) and the decomposition rate of guar in copper electrolyte was examined. As expected, the results show that guar has an effect similar to glue on the copper deposition. However, at the same temperature, a greater quantity of guar is required to achieve the same results. As with glue, the decomposition rate (due to hydrolysis) of guar is strongly dependent on the temperature. Therefore, in practice, its on-line monitoring is necessary to guarantee the same guar activity at any time.

Jan 1, 1999

By Ximena Massone

Chile is the most important copper producer in the world and the mining sector plays a key value in its economy. However, at present the country does not have a satisfactory set of regulations about closure and restoration of mining operations. In our country many mining operations will, in the near future, shut down their activities, therefore, it is of utmost importance to elaborate and enforce a set of regulations to prevent risks and to protect the environment. The present study is focused on reviewing and analyzing the existing national regulations about the closure of mining operations and preparing a comparative analysis with other international regulations of countries with mining experience. The final results of the study will be a legal proposal to regulate the closure of mining operations in Chile, aiming at minimizing the potential environmental adverse impact, internalizing the social costs by the relevant operators and defining all aspects of liability for the environmental damage.

Jan 1, 1999

By Claire A. Chanenchuk

Catalytic Extraction Processing (CEP), a technology commercialized by Molten Metal Technology, Inc., a US.-based company, can convert industrial, household, and government wastes into commercial resources. CEP is an innovative elemental recycling technology that uses a molten metal bath to completely dissociate hazardous or toxic components of a feed and convert them to valuable products. The catalytic action of the molten metal bath converts the feed to its elemental constituents and the reducing atmosphere prevents the formation of any dangerous byproducts (NOx, SOx, dioxins, furans, etc.). Selective reactant addition allows engineering of valuable products from otherwise unexploited resources. Synthesis gas is generated from hydrocarbon feeds, ferro-alloys from metallic wastes, and ceramics from select inorganic species. Commercial-scale processing of multiple wastes and waste surrogates has been carried out at a destruction and removal efficiency exceeding 99.9999 wt.%, validating theoretical predictions. Unlike conventional hazardous waste treatment technologies, CEP offers resource recovery, minimal byproduct generation, and the potential for closed-loop recycling.

Jan 1, 1994

By G. Achurra

The products of the smelting of copper concentrates in an El Teniente Converter (CT) are a high grade matte, analyzing 74-76% Cu; and a highly oxidized slag, typically containing 15-20% Fe3O4 and 4-10% Cu. The El Teniente Division of CODELCO¬CHILE has developed a slag reduction-cleaning process, that is practised in a tilting, horizontal furnace, to recover copper from these slags. The El Teniente slag cleaning process has been successfully implemented at the El Teniente Caletones smelter and various other smelters in Chile: Today, eight such slag cleaning furnaces, each with a capacity of 800-1000 tonnes/day, are in operation in Chile. This paper discusses basic laboratory research and industrial tests that led to substantial reductions in the slag cleaning cycle time and the specific consumption of fuel and reductants. Simultaneously, the slag cleaning off-gas quality was improved. Based on the experimental results, recommendations were made to improve the practice of the El Teniente slag cleaning process. The recommended modifications have been fully implemented at the Caletones smelter.

Jan 1, 1999

By Alim Ullah

Process, quality and management control are necessary in order to produce DRI of required quality and at minimum cost. Although the characteristics of the two (2) principal inputs, that is, iron oxide feed and natural gas (for gas-based DRI plants) can affect the operation of a DRI plant significantly, they are outside the control of plant operators, at least in the short run. The quantity of reduction gas, its composition and reduction gas temperature are some of the key process variables. Statistical Process Control (SPC) can be used in a DRI plant to minimize the production of off-grade material and costs, as well as to improve the overall operation of the plant. One of the key quality variables to be measured and controlled is percent metallization, defined as FeM/FeT*100 where, FeM and FeT respectively are metallic iron and total iron in DRI. Control charts are used to monitor the quality of DRI produced and, when necessary, corrective actions are taken to bring the product back within the control limits. Management control can consist of essentially following how well the plant performs against some pre-established standards of parameters like daily production, downtime, consumption of material and energy, etc. In this respect, it is suggested that yield, defined as theoretical consumption/actual consumption of iron oxide feed, be used to monitor the consumption of feed material. Similarly, instead of using natural gas per ton of DRI produced, a better criterion would be efficiency, defined as theoretical natural gas consumption/actual natural gas consumption.

Jan 1, 2006

By Jafar Safarian

A new kinetic modelling technique has been applied to study the rate of MnO reduction from slags by dissolved carbon in liquid iron. Based on a consideration of the fundamental reaction kinetics, a general differential equation for the slag reduction process has been formulated, which then is solved analytically for certain special cases. By re-writing the solutions in a dimensionless form the poorly known kinetic constants are eliminated, which makes the model both flexible and applicable to a wide range of experimental conditions. For example, changes in process parameters such as temperature, metal composition, slag composition, gas composition can readily be captured along with variations in the crucible geometry. Based on a comparison with a series of experimental reduction curves being reported in the literature, it is concluded that the predictive power of the model is surprisingly good, yielding outputs that are both reliable and physically reasonable. An attractive feature of the model is that it provides an alternative way of calculating the activation energies from experimental reductions curves. For example, it suggests that the activation energy for the reduction of MnO by dissolved carbon in liquid iron is about 90 kJ/mol, which is different from the previously reported activation energies. The model also suggests that the crucible geometry, which affects both slag the volume and the resulting slag/metal interfacial area, has a significant influence on the overall reduction kinetics. This design parameter is a key to further optimisation of the process on an industrial scale.

Jan 1, 2006

By Roger Wilmoth

Exposed, open pit mine highwalls contribute significantly to the production of acid mine drainage (AMD) thus causing environmental concerns upon closure of an operating mine. Four innovative technologies were evaluated under the U.S. Environmental Protection Agency?s, Mine Waste Technology (MWTP), Prevention of AMD Generation from Open-Pit Highwalls Demonstration Project. This project is funded by the U.S. Environmental Protection Agency (EPA) and jointly administered by the EPA and the U.S. Department of Energy (DOE) through an Interagency Agreement. The objective of the field demonstration was to evaluate the technologies ability to decrease or eliminate acid generation from treated areas of the highwall in comparison an untreated highwall area. The field demonstration was performed at the Golden Sunlight Mine (GSM) a subsidiary of Placer Dome U.S., located near Whitehall, Montana. GSM is an operating gold mine. The highwall at GSM was divided into five plots measuring 15.24 by 15.24 metres (m) and each technology was assigned a plot with the fifth plot being used for comparison as a background control plot. The four technologies were spray-applied. The applied insitu treatment technologies included: 1) A modified, furfuryl alcohol resin sealant, utilizing wood and agricultural by-products to coat the rock surface. 2) EcobondTMARD, a phosphate based process that forms a stable, insoluble compound, coating the rock surface. 3) Two ARD passivation technologies, magnesium oxide and the Dupont technology developed to create an inert layer/coating on the pyrite, preventing oxidation. The technologies were evaluated using the following methods: 1) ASTM D 5744-96, Accelerated Weathering of Solid Materials using a Modified Humidity Cells, 2) mine wall residual wall rinse sampling, 3) microscopy, and 4) core drilling followed by water injection testing.

Jan 1, 2003

By V. Bojarevics, K. Pericleous

"A number of different methods have been developed for noncontact electromagnetic treatment of liquid metal and to investigate the melting/solidification processes. Applying AC magnetic field in terrestrial conditions, along with the buoyancy and thermo-capillary forces, results in turbulent flow. The use of a homogenous DC magnetic field allows damping both of the turbulence and the large scale flow at different rates leading to surprising results at some stages. The dynamic interaction of the turbulent flow with the oscillating interface needs to be accounted if it is required to levitate liquid metal of up to few kilograms without the contact to container walls. At the high values of magnetic field some oscillation modes are damped quickly, while others are modified with a considerable shift of the oscillating droplet frequencies and the damping constants from the non-magnetic case. Numerical models are used to investigate behavior of liquid metal suspended in high DC magnetic fields providing microgravity-like conditions with laminar viscosity and heat transfer to the surroundings.IntroductionSince the early Electro Magnetic (EM) levitation experiments [1] in AC magnetic field it became apparent that the levitated liquid metal is prone to oscillation and instability. The EM and electrostatic levitation experiments with liquid metal droplets show difficulties related to confinement stability and a need for complex correction functions to establish a correlation between the measurements and the droplet material properties [2,3]. Intense internal fluid flow is visually observed, apparently being in the turbulent regime for earthbound conditions."

Jan 1, 2012

By José Sancho, Julia Ayala, Purificación García, Begoña Fernández

"A study is carried out to see the adequacy of using flying ashes coming out from a Power Station to eliminate the copper present in waste cyanide waters that are generated in gold mines.Tests were carried out to see how effective the use of ashes taken from two Power Stations could become. Later, the tests are made using ashes coming from Narcea Power Station as this station is near the mine under study.The work is centred on looking for an economically adequate solution to close the waste decanting ponds of the mine. After several tests, a solution is reached through filtration in static layers.IntroductionThe use of coal to adsorb some water-soluble substances has been widely studied [1,2,3,4,] both in the treatment of drinking waters and in determined stages of selective detachment of cyanide gold complexes in cyanide lixiviation processes [5]. Flying ashes sent to the atmosphere by Power Stations as a sub-product of the combustion of this combustible are generally made of more of a 70 % of a vitreous aluminosilicated material and of an active residual material which may be changeable making them potentially useable as adsorbents. Nevertheless, the properties of each kind of ashes depend on the characteristics of the Power Station, of the combustibles being used, of the combustion system, etc.The aim of this work is to demonstrate the adequacy of flying ashes to eliminate the copper present in cyanide waters coming from gold mines either by adsorption or precipitation of the metal. For this study, tests are carried out with Asturian ashes which have a low quantity of lime. The results obtained in the tests demonstrate the effectivity of the method used. To be absolutely concrete, the work is carried out to establish the use of these ashes in the closing of Asturian installations of cyanide lixiviation"

Jan 1, 2008

By Yukihito Sasaki

Sumitomo Metal Mining Co. Ltd. planned an expansion program for the Toyo smelter and refinery in order to increase the production capacity of electrolytic copper to 450,000 tpy in 2007. Regarding the flash smelting furnace, a drastic increase in the average concentrate smelting capacity from 2,300 tpd to 3,950 tpd was required to achieve the plan. It was necessary to examine the performance of the Sumitomo concentrate burner when the feed rate was considerably increased. The authors developed a mathematical model to describe the combustion phenomena in the Toyo flash smelting furnace. This model was developed incorporating the fluid flow, heat and mass transfer, and chemical reactions of the copper concentrate and ancillary fuel. The copper concentrate was considered to mainly comprise chalcopyrite (CuFeS2). The reaction of CuFeS2 was assumed to consist of two steps, namely, the decomposition of CuFeS2 and the oxidation of the resulting pyrrhotite (FeS) and sulfur (S). The combustion phenomena in the furnace at the increased feed rate were predicted using this model. It was found that the Sumitomo burner was capable of enhancing the smelting capacity. This is attributed to the wide dispersion of the concentrate particles caused by an increase in the particle mass and a long residence time in the reaction shaft; this is due to the low temperature of the reaction air. However nonuniformity of the reaction in the reaction shaft was enhanced with the increased feed rate. In order to improve the nonuniformity of the reaction, an increase in oil-burner oxygen and an enlargement of the diameter of the dispersing cone were useful. By combining the expertise of the Toyo smelter staff and the calculation results, the concentrate smelting capacity of the Toyo smelter has been stably increased to 3,600 tpd thus far, and further improvements of the smelting performance are still being carried out.

Jan 1, 2006

By Ivanildo Hespanhol

"DALYs are a measure of the health of a population or burden of disease due to a specific disease or risk factor. It evaluates the time lost because of disability or death from diseases compared with a long life free of disability in the absence of disease. DALYs are calculated as the sum of years of life lost by premature mortality (YLL) and years of healthy life lost in states of less than fully health, i.e., years lived with a disability (YDL), which are standardized by means of severity weights, thus: DALY=YLL+YLD.WHO has established for wastewater use in irrigation (1) the same reference level of health protection as established for drinking water quality (2), i.e., the additional burden of disease from consuming water irrigated food should not exceed 10-6 DALY(Disability-Adjusted Life Years) loss per person per year (pppy). This level of risk means that a single additional case of disease may occur in a population of 1 million, during a life time (70 years). In a individual basis is equivalent to the occurrence of a mild disease during about 31,5 seconds.Such a restrictive risk is almost impossible to be attained in most developing countries which may not be able to afford the cost of wastewater treatment and of other protective measures, even for restrict irrigation.This paper presents proposals to adapt the reference level of risk to local technical, cultural, economical and social conditions of developing countries on the basis of a risk benefit approach."

Jan 1, 2008

By Bob Drew, Alfred Spanring, Kirschen. Marcus

"Increasing material conversion and energy efficiency, and decreasing carbon dioxide emission levels are crucial for sustainable production processes in the aluminum, cooper, and steel industries. RHI supports these targets by providing a diverse range of solutions including high quality refractory linings, optimum lining maintenance, and process improvements. In this paper examples are provided of process improvements and increased energy efficiency in copper refining, potential energy savings during electric arc furnace and ladle operations in the steel industry, and increased energy efficiency by improved heat transfer in anode baking furnaces in the aluminum industry. In all cases, RHI’s expertise in close collaboration with the customer resulted in an improved performance of the reactor lining and the actual high temperature process with a positive impact on the material conversion and energy efficiency and as a result a decrease in specific carbon dioxide emission levels.IntroductionRefractory linings play an important role in heat transfer during high temperature processes in for example the aluminum, copper, and steel production industries. Due to constantly increasing energy prices worldwide and the increasing demands for environmental and climate protection, improving the energy efficiency and decreasing emission levels of these energy intensive production processes is of significant importance. In this paper, the contribution of modern RHI lining technologies to energy saving measures and the corresponding reduction of specific carbon dioxide emission are described. The type of current refractory solutions for energy intense processes are illustrated with four examples: Optimization and increase of material conversion and energy efficiency in copper refining, energy saving potentials in both electric arc furnace and transport ladle operations in the steel industry, and heat transfer improvements during the carbon anode annealing process in the aluminum industry. These examples focus on particular production processes operating with a high proportion of recycled copper, steel, and carbon anodes. Increased energy efficiency directly decreases the specific energy related carbon emission levels whereas improvements to the metallurgical processes aim to increase material conversion efficiency and, therefore, decrease specific process related carbon emission levels. Significant energy savings can be achieved by maximizing the refractory campaign length through a combination of appropriate refractory material selection, grade zoning, correct installation, careful preheating, and effective maintenance strategies. Besides the efforts to improve the performance and energy efficiency of customer high temperature processes, RHI continuously promotes the development of new low emission carbon-containing refractory bricks and unshaped products."

Jan 1, 2008

By Thomas Schuman, Jaan Kers, Lucas N. W. Damoah, Xiangjun Zuo, Lifeng Zhang

"Rapid technological innovation has propelled the use of electronic equipment leading to the generation of more and more waste electrical and electronic equipments (WEEE). Printed wiring board (PWB) is a component made of one or more layers of insulating material with electrical conductors. To investigate an environmentally friendly process to recycle PWBs, PWB samples with and without additives were pyrolyzed. Liquid, gas and solid products were achieved with different conversion fraction. Analysis of the exhaust gases from the experiments using GC-MS and MS showed that without CaCO3 additives poisonous gases such as C6H6 and HBr were produced which were adequately controlled if CaCO3 was added.IntroductionPyrolysis is one of the best methods for treating complex mixtures of waste polymers and to recover the material and energy content. The process consists of thermal decomposition at moderate temperatures in total absence or small amount of oxygen in which the structures of polymers break down into smaller intermediate products "". The decomposition temperature of a substance is the temperature at which the substance breaks up into smaller substances or into its constituent atoms 2). Thermal treatment of PWBs were reported using DC Arc Plasma furnace 3), and fixed bed reactor 4). One drawback in dealing with thermal treatment of PWB scraps is the likely production of super-toxic halogenated dibenzodioxins and dibenzofurans from the bromine containing structures. Pyrolysis of organic materials contained in waste PWBs leads to the formation of gases, oils, and chars which can be used as chemical feedstock or fuels ""'. Dehalogenation of the pyrolysis product of electronic scraps is essential to make it commercially acceptable. It would be obviously the most advantageous solution as pyrolysis and dehalogenation are carried out simultaneously. Reported pyrolysis investigations are at experimental stage and have been carried out in vacuum, molten salt, fluidized bed, rotary kiln, entrained, stationary, and moving bed reactors 7). Comparing to the incineration and combustion of PWBs, the pyrolysis process has several characteristics: 8'"">) 1). Converting the organic solid substance into fuel gas, fuel oil and carbon-black as storage energy; 2) Emitting toxic substances such as sulfur, bromine and heavy metals in wastes; and 3) Keeping metals from being oxidized. Although many researches into the pyrolysis of PWB wastes have been reported, most of the works have been carried out using analytical pyrolysis techniques or very small batch reactors ""~'5). Also, most of the works for the pyrolysis of PWBs haves concentrated on the composition of the organic products, particularly the brominated organics. The current study is to investigate the pyrolysis of PWB powders in a small TG-DTA scale and a 50-gram tube furnace scale."

Jan 1, 2011

By Kiichiro Hayashi

"Indonesia is one of the world leaders in palm oil production. Palm oil industry is an industry to be considered when it comes to environmental impacts. This paper utilizes three step approaches. First, a material flow analysis of palm oil related industry was conducted in Indonesia. Second, a factory visit survey was conducted for getting information on environmental impacts of plantation and CPO mills. Third, a LCA study was made for a model Indonesian CPO mill in several bio-waste treatment options. Main findings were that, first; over 70% of FFB was bio-wastes generated from CPO mills. Second, some mills introduced a zero emission bio-waste policy. However, untreated bio-wastes in the zero emission policy, such as, CH4 from POME ponds, may have potential to reduce more impacts on the environment. Introduction Indonesia is one of the world leaders in palm oil production with approximately 12.4 million tons of crude palm oil (CPO) production in 2005 and with the plantation area 5.6 million ha spreading out in 19 provinces [10]. The expansion of palm oil cultivation in Indonesia and its export oriented industry heavily relies on the strong world market demand for food. Currently, there are 320 CPO industries in Indonesia [10]. These include plantations and palm oil related factories. Among them, there are six biggest players in CPO business in Indonesia: PT. Perkebunan Nusantara (PTPN) consisting of 9 PTPN, Sinar Mas, Raja Garuda Mas, Astra Agro Lestari, Minamas Plantation and Indofood. They are managing more than 50% of plantation estate in Indonesia and are leading the Indonesian palm oil business.Palm oil industry is an industry to be considered when it comes to environmental impacts. Unfortunately, there is not so much available information related to the performance of each CPO on environmental impacts. There are reports which provide information on environmental impacts of CPO mills in South East Asian countries, but are limited to, for instance, Thailand’s cases [4 and 5] and Malaysia’s cases [1, 3, 6, 7, 9, 11 and 12]. On the other hand, similar studies on the Indonesian’s case are not well established in academic literatures. And also there is limitation on Indonesian palm oil industrial information from plantation to consumption and disposal in academic articles. There is no literature related to material flow analysis focusing on the whole Indonesian palm oil related industry. One way to describe and present the environmental impacts is through a life cycle assessment (LCA). The LCA could be used to estimate the impacts of CPO production including the stages of plantation, transportation and milling [5, 8 and 11]. However, studies on Indonesian CPO production process were not well established in academic articles. The purpose of this paper is thus to clarify environmental impacts of palm oil industry in Indonesia especially by focusing on plantation and CPO mills with consideration to various bio-waste treatments."

Jan 1, 2008

By N. J. Rarmrez, C. Perez, J. D. Calderon, L. Lopez

"Among the thermal characterization of any material, one of the variables to know is the coefficient of thermal conductivity because this value can tell how much heat passes through the material and if the material could be used as an isolator. In order to determine this parameter is required some kind of special equipment and controlled conditions which implies high costs in the development of tests. The present paper proposes a design of a low cost measurement system in order to determine this coefficient with the lower possible error. This equipment was thought for companies or labs where they do not have the economic resources or the infrastructure (environmental controlled labs, heat flux transducers, human resources with specialized knowledge) to do this kind of tests.The system is based on ASTM C 518 - 04 [l] and integrated by two plates (one that contains a thermal resistance and which temperature is controlled by a closed loop controller and the other one with a route of water flow). The thermal resistance is actuated by a relay and a supervisor system checks the total time the relay is on in order to determine the effective power applied to the system. The contact faces of the plates contain a group of temperature sensors connected to a data acquisition system that process and record the temperature in each measurement point.With the power applied to the system, the measurement of temperatures and a process of calibration is possible to determine the coefficient of thermal conductivity. IntroductionWithin the thermal characterization of a material of known variables is the coefficient of heat transfer, since this value can know the amount of heat the material is capable of transferring or isolating. To determine this ratio requires specialized equipment and controlled conditions, which implies high costs in the development of a test. This article proposes a design of a low cost machine to allow closer this coefficient with the least possible error. This equipment was done thinking about companies that do not have the infrastructure (laboratories, controlled environment, heat flux sensors, human resources expertise) and financial resources to conduct these tests."

Jan 1, 2011

By S. V. Ketov, V. P. Menushenkov, V. S. Shubakov

"The glass samples were obtained by melting of the oxides mixture SrO-Fe2O3-B2O3(Al2O3) at 1200-1250°C with subsequent quenching of the melt on quickly rotating steel roller. Submicronsized Sr(Fe,Al)12O19 particles were formed in glass-ceramic matrix during the crystallization aging of glass. The aging temperature Tag varied in the range 650-950°C. The submicron-sized hexaferrite powder was obtained by removing of the matrix phases using etching. The samples were characterized by X-ray diffraction, scamiing electron microscopy and magnetization measurements. The glass-ceramic material exhibits very high coercivity value up to 10 kOe. The samples of magnets were obtained by pressing of the hexaferrite powder at RT and subsequent aging in the range 900-1200°C. The aged samples exhibit coercivity value up to 8 kOe.IntroductionStrontium M-type hexaferrites have been widely used in technology and industry mainly for production of permanent magnets owing to their appropriate magnetic properties, chemical stability and low cost [1,2]. The SrFe12019-based compounds are characterized by high magnetocrystalline anisotropy and single easy magnetization axis. The highest coercivity is received for monodomain, defect-free single crystal particles with size D - 100 mn. Finely grained strontium hexaferrite prepared by chemical methods such as sol-gel pyrolysis and oxide glass crystallization exhibits high coercivity up to 6-8 kOe [3-5]. Owing to the partial substitution of Al for Fe in the strontium hexaferrite leading to the increase in the magnetic anisotropy field Ha=2Ki/M,, the increase in the coercivity may be received [6]. The notable results were achieved using the SrO-Fe2O3-AlzO3-B2O3 glass crystallization and formation of perfect submicron crystals of alumina-doped hexaferrite [ 6, 7]. The coercive force of glassceramics reached values of up to 10 kOe. Hexaferrite particles are well faceted and have the shape ofhexagonal bipyramids with truncated vertexes [7].In the present paper, we report results of our investigation into the SrO-Fe2O3-B2O3(Al2O3) glass crystallization, hexaferrite powders and permanent magnets, which were prepared by pressing submicron-sized hexaferrite powders at RT and subsequent sintering at 900-1200°C."

Jan 1, 2012

By Susana Caballero, Lourdes Yurramendi

Air Pollution Control (APC) ashes from Municipal Solid Waste Incineration (MSWI) plants need to be treated prior to landfilling due mainly to their heavy metals content. This research evaluates the capacity of the APC residues to sequester carbon dioxide, while the ash becomes stabilized for storage. It has the benefit of using two wastes, with no addition of any raw material. APC samples from different MSWI plants were treated by gas/solid accelerated carbonation at different temperatures and carbon dioxide concentrations to evaluate the residue behaviour to the process. The extent of carbonation was evaluated by means of weight gain upon carbonation and by the measurement of the final carbonate content. The APC residues were analyzed before and after the treatment in order to know their composition and their leaching behaviour according to the criteria for the acceptance of wastes at landfills established by the European Council Decision 2003/33/EC.

Jan 1, 2008

By S. A. Platias

Large amounts of dunile tailings can be recycled for olivine produdion from the existing beneficiation adivity of chromite ore in northern Greece. This olivine production aims at the preparation of a material suitable for the substitution of the environmental hazardous quartz sand in the foundries of Europe In smelting of chromite ore the losses that occur ore usually of the order of 6-8% Cr that report in the slag. Most of this is in the form of oxides that cannot be recovered, but usually 30-35% is in the form of FeCr alloy that can be recovered by gravity methods. About 90% of the produced slag is sold for road construdion after crushing to a desired grain size. Finally, recycling of chromites sludges from the ferrochrome produdion plant, through the preparation of pellets, improved the total chromite yield by 2%.

Jan 1, 1996