Search Documents

By Yushiro Hirai

Saganoseki smelter & refinery had operated two flash smelting furnaces from 1973, attaining 330,000 mtpy of copper production in 1989. In 1996, however, it carried out a "integration of two flash furnaces". That is, it doubled the feeding capacity to one flash furnace to shut down another furnace while maintaining the same production. Single flash furnace operation has successfully started in March 1996 accomplishing a great reduction of the total production cost. The production had reached to 350,000 mtpy in 1997, and further increased to 450,000 mtpy by executing the expansion program with single flash furnace in 1998. This paper introduces results of the single flash furnace operation and describes about an outline of the expansion.

Jan 1, 1999

By William K. Connor, O&apos

The U.S. Bureau of Mines (USBM), in cooperation with the American Society of Mechanical Engineers (ASME), conducted over 200 hours of melting tests to vitrify residues from five municipal waste combustion facilities. Combined residues (grate residue and f1yash) from three municipal waste combustors, a waste water treatment sludge combustor, and flyash from a refuse-derived-fuel (RDF) boiler, were sequentially melted in a I-metric-ton (mt) water-cooled-wall electric arc furnace. Each of the residues underwent magnetic separation, screen size analysis, and bulk chemical analysis prior to melting. The furnace products were examined by optical and electron microscopy and by X-ray diffraction. Bulk chemical analyses were acquired for the metal, fume, and vitrified furnace products. The material balance for the furnace operation indicates that from 69 to 86 pct of the feed reported to the vitrified furnace product, which had leaching potentials well below the EPA limit for each metal, as determined by the EPA TCLP. The electric arc melting furnace currently is being utilized in a cooperative research project between the USBM and the Idaho National Engineering 'Laboratory (INEL) for melting tests on simulated low-level radioactive wastes,

Jan 1, 1991

By Yuanbo Zhang, Zijian Su, Bingbing Liu, Guanghui Li, Tao Jiang

With the depletion of rich manganese ores, high-Fe content manganese ores are becoming the mainstream resources for manganese extraction. Reduction roasting-magnetic separation process is reported as a relatively effective route to realize the separation of manganese and iron. This study investigated the phase transformation of MnO2 and Fe2O3 briquettes (molar ratio 1:1) roasted under various temperatures and CO–CO2 atmospheres. Results showed that when the CO content was in the range of 0–10 vol%, MnxFe3−xO4 (x = 0−1) phase was formed and its content increased with the rising of temperature. The formation of ferromagnetic MnxFe3−xO4 with strong magnetism resulted in an inferior separation of manganese and iron by magnetization roasting-magnetic separation process. With the increase of CO content to over 25 vol%, the MnxFe3−xO4 content decreased while the content of feebly magnetic substance (MnO)y(FeO)1−y(y = 0−1) increased. Further increasing the CO content to over 80 vol%, (MnO)y(FeO)1−y was reduced to MnO and metallic iron.

Mar 1, 2017

By Katsuyoshi Kondoh

The utilization of silica particles originated in rice husks as reinforcements of magnesium composites was discussed. By using the solid state reaction of rice husk silica particles with magnesium powder, P/M magnesium based composites dispersed with the magnesium silicide (Mg2Si) and magnesium oxide (MgO) were fabricated. High-purity silica particles were originated from rice husks, one of the major agricultural wastes, via the citric acid leaching treatment and combustion in air. The effects of the silica particle characteristics such as size, crystalline and porous structures, on the reactivity of silica and magnesium to synthesize Mg2Si intermetallic were discussed. Amorphous silica was more useful for this reaction than crystalline one. The reactivity of rice husk silica was superior to that of the conventional mineral silica particles because of not only its amorphous structure but the larger specific surface area due to their pore structures. In the case of the green compact of the mixture of the rice husk silica and Mg powder, the silica particle size was not effective on the reactivity because the coarse particles were fractured into fine ones by cold compaction. The distribution of Mg2Si intermetallics of magnesium powder composites consolidated by SPS process was investigated by XRD and SEM-EDS analysis. Their mechanical and physical properties were also evaluated in detail.

Jan 1, 2009

By Kazuhiro Nisizono, Takashi Kuroki, Nobuyuki Mori, Keisaku Ogi

"The improvement of critical current density and mechanical property is essential to the practical application of the superconductive oxides. A solidification technique is developed in this study for the growth of columnar or single Y123 crystal with finely dispersed Y211 and Ag particles through a monotecto-peritectic reaction of Li.(Ba-Cu-Ag-0 rich liquid)+ Y211-+ Y123+Lz(Ag rich liquid). The large solidification rate and temperature gradient can refine the Ag and Y211 particles. But Ag-free region is widely formed along the crystal growth direction in the central part of the Y123 cell. Since this phenomenon occurs because of the cellular growth, it is necessary to narrow Y123 cell width or to grow Y123 crystal with flat freezing interface. By controlling crystal growth direction using a seed crystal, Y123 columnar or single crystal with uniformly dispersed fine Ag particles are obtained. The· behavior of Ag and Y211 particles during the solidification of Y123 crystal is simulated by the peritectic growth model of faceted Y123 crystals.IntroductionY-Ba-Cu-0 superconducting oxide (YBCO) with high critical temperature also has excellent superconducting characteristic under the high magnetic field. The critical current density (Jc) has been enhanced by ·using unidirectional-solidification technique, which can overcome the weak-link problem at grain boundaries and control the crystal orientation and the distribution of Y211 particles which give effective magnetic flux pinning centers in the Yl23 matrix [1-4].In addition to improving superconducting properties, it is necessary to improve mechanical property for the practical application. The silver addition to the melt-textured YBCO superconducting oxide has been reported as the effective method to improve mechanical properties without degrading superconducting properties. Since the material properties are considered to be largely affected by silver particle size, form, dispersion state etc. in the Y123 phase, it is important to control Ag distribution in YBCO/Ag composites. Besides, it is also reported that the silver addition improve the corrosion resistance to the water and CO2 [5,6]. Nishizono et al. [7-9] have reported that the silver distribution in the YBCO/Ag composites is largely affected by the solidification condition, but yet some unclear points are also remained. YBCO has been also fabricated by the zone melting method [10-12], and Furuya et al. [5] and Hirano et al. [13] have reported the fabrication of silver added YBCO composites, but the distribution and behavior of Ag are not investigated in detail"

Jan 1, 2000

By Alexander A. Knminskii

Polymorphism of BaR2F8 compounds is analyzed, and some peculiarities of obtaining monoclinic low-temperature (3-BaR2F8 crystals (R=Y, Ho-Yb) and orthorhombic high¬temperature a-ßaR2F8 crystals (R=Yb, Lu) by the Bridgman-Stockbarger growth technique are discussed. We pay a special attention to BaYb2F8:Er3+ crystals, which are able to generate both 2:µm SE using the new four-level operating scheme (4F9/2?4I11/2 laser channel) and 2- and 3-µm SE by means of the cascade scheme (4F92?+4I11/2?+4I31/2). This 2-µm generation of Er3+ ions has an advantage over similar SE of Ho3+ and Tm3+ ions (especially under diode laser pumping), that is important in designing the medicine and ecology laser. We report on orthorhombic BaR2F8 crystals with the ordered structure, a new crystalline materials for generating Ln3+ ions. The growth conditions are determined and orthorhombic BaLu2F8 crystals of several cm3 in volume doped with Ce3+, Nd3+, Ho3+, Er3+, and Tm3+ ions are obtained for the first time. Spectroscopic and laser characteristics of these crystals are discussed for Nd3+-and Era+-doped samples serving as representative examples. In particular, low-threshold stimulated emission was excited in 4F3/2?+4I11/2 channel of Nd3+ ions in the BaLu2F8. Room-temperature generation was obtained also at -1.317 µm wavelength for Nd3+ and at ~2.8 µm (several lines) for Era+ ions in this new laser crystalline host with a threshold of about 20 J.

Jan 1, 1997

By Natalya. N. Ankusheva

The problems of ore-bearing palaevolcanic structures in folded belts are actual because of their high productivity in nonferrous, ferrous and noble metals ores. Now relationships of location and conditions of formation for sulfide-massive and gold-bearing deposits are investigated very well in Urals. But carboniferous sulfide-barite mineralization, for example the barite veins in Arcaimsky palaevolcano are?nt studied enough now [3-5]. The purpose of this research is the studying of mineralogy and thermobarogeochemistry of barite from the hydrothermal veins. It will allow to determine the conditions of its formation and to compare it to the similar mineralization of others ore types.

Jan 1, 2006

By Baoxiang Zhang, Jing Zhang

"As extruded Mg-9Zn-0.6Zr-2Er magnesium alloys were hot-rolled at 400°C, followed by solution treatment at 400 °c for 1. 5h and artificial aging at 200°C for 10h. Microstructures and tensile mechanical properties of the alloys after hot rolling, solution and aging treatment were examined respectively. Optical micrographs of the as-rolled and as-solution alloys showed fine grain structures, due to the formation of Er-and Zn-bearing compounds at grain boundaries which obviously improved the thermal stability of the alloy. Yield strength as high as about 335 MPa was obtained for the as-rolled alloy, showing that the mechanical properties of the alloy was greatly benefit from the grain refinement and dynamic precipitation of fine MgZn2 during hot rolling. Due to solution heat treatment, vast majority of the Mg-Zn phases dissolved into the matrix, and precipitated out again as fine dispersoid during the subsequent aging, resulting in an enhanced aging-hardening effect.IntroductionWith high specific strength and low density, magnesium alloy has stimulated significant interest for the applications in microelectronics, aerospace and automobile industries. Due to its HCP structure, magnesium alloys exhibit relatively poor strength and ductility. Great efforts have been made to improve the properties of magnesium alloys.Thermo-mechanical processing which combined with subsequent heat treatment can strengthen magnesium alloys due to the strain-hardening mechanism, homogeneous distribution of second particles and grain refinement [1, 2]. However, commercial wrought magnesium alloys have high tendency of grain growth at high temperature due to lack of effective solutions to stabilize the microstructure [3, 4, and 6]. But Magnesium-RE alloys containing high rare earth were reported to have remarkable thermal-stability, Rare earth (RE), such as Y, Nd, Yb, Gd, Ce, were known to form second-phase particles that have higher thermal stability combining with Zn and matrix in Mg[12-17]."

Jan 1, 2012

By F. A. Guo

Ultrafine-grained surface layers were obtained by surface mechanical attrition treatment (SMAT) in copper and titanium samples. The thermal properties of the deformed layers were characterized using a scanning thermal microscopy (SThM) that allows thermal conductivity to be mapped down to the submicrometer scale. A theoretical approach, based on this investigation, was used to calculate the heat flow from the probe tip to the sample and then estimate the thermal conductivities at different scanning positions. Experimental results and theoretical calculation demonstrate that SThM can be used as a powerful tool for the thermal property and microstructural analysis of ultrafine-grained microstructures.

Jan 1, 2006

By Ludovic Charpentier

Production of metallic wires directly from liquid jets would avoid drawbacks of extrusion (space needed, damaging, cost?) and enable recycling. But liquid jets tend to break, due to capillary instabilities, unless a solid layer (coating or start of solidification) surrounds it. We recently developed a process to produce tin wires, cooled by water flow parallel to the jet. Superficial oxidization of tin produces a glass coating around the jet. Studies showed the length of wires increased when increasing speed of tin jets, and that water average speed should be the closest possible to the jet one to have smooth fibers. Producing 1 mm diameter wires is possible. The length of wires is limited by the experimental setup, which does not provide possibilities to coil the wire. Most of other metals do not generate glass-like oxides. The lack of coatings makes it necessary to reduce the capillary instabilities to obtain fibers.

Jan 1, 2006

By Hui Wang

With the great increasing use of nickel metal hydride batteries recently, the waste of this kind batteries have been paid for close consideration. For the main reason that the waste of the batteries contained precious metals and lanthanide which cost great lose. This paper introduces the pyrometallurgical process of recovering nickel and cobalt from the waste of the nickel metal hydride batteries. Particularly, the waste for the process was from factory during the producing program. The use of designed solvent to divide nickel and cobalt in melted state from the waste is described. Also, the result of the nickel and cobalt and melted gangue that mainly consist of lanthanide oxide are included in details. The aim of the paper is to find out a simple and feasible way to reuse waste from nickel metal hydride batteries.

Jan 1, 2009

By G. N. Shannon

Keywords: inclusions, slag, modeling, interfacial energy, capillary force, particle flotation, particle separation A previously introduced model of inclusions separating across a steel-slag interface, developed by Nakajima/Okamura and Bouris/Bergeles, is expanded to include different inclusions shapes (octahedral and plate-like, besides spherical) as well as comparison between model ladle-, tundish-, and mold-slags. Investigation of the relation of these shapes with the interfacial capillary force ? which arises due to the dynamic interfacial energy during separation ? has shown that the force has a significant effect on whether the inclusion separates rapidly or settles at the interface. For the slags considered, the most significant physical property is found to be viscosity, which resulted in fast separation times for inclusions in the mold and ladle slags, relative to the more viscous tundish slag. Particle dissolution (using experimental data) is included in separation modeling.

Jan 1, 2005

By W. C. Chang

Phases and magnetic evolutions of melt spun Nd9.5(Fe1-xCox)85.5B5 (x=0, 0.05, 0.1 and 0.15), (Nd1-yLay)9.5Fe85.5B5 (y=0, 0.0.5, 0.1; and 0.15) and (Nd0.95La0.05)9.5(Fe1-zCrz)81.5B9 (z=0, 0.033, 0.067 and 0.1) nanocomposites: have been investigated. It was found that a. dilute Co substitution for Fe, x=0:05-0:15, in Nd9.5(Fe1-xCox) 85.5B5 improved not only Curie temperature but also the remanence and maximum energy product. Partial substitution of La for Nd in(Nd1-yLay)9.5Fe85.5B5 may suppress the grain growth of the materials during thermal treatment. Exchange coupling between the Nd2Fe14B and a-Fe was found: to increase with increasing La content. A dilute La-substitution, y=O. 10, has proven to decrease the optimum wheel speed required for preparing melt spun ribbons with better magnetic properties; Furthermore; a slight substitution of La for Nd in (Nd0.95La0.05)9.5(Fe1-xCrx)81.5B9 nanocomposite reduced the crystallization temperature of the over-quenched ribbons and led to the formation of a multiple phases mixture. Nevertheless, a dilute Cr addition increases the Tg of (Nd0.95La0.05)9.5(Fe1zCrz)81.5B9 and also suppresses the formation of the undesired (Nd,La)2Fe23B3 and Fe3B phases: Cr was found to play an important role in grain smoothening or magnetic separation which consequently increased the Hc of Cr-containing materials.

Jan 1, 1997

By Hans Korfmacher

Product take-back regulations implemented in Europe have presented significant challenges to the consumer electronic product and battery industries. Initially companies established single compliance organizations within individual Member States. These programs met business needs but were inefficient and costly. They were protected from pressures of marketplace competition and could not leverage economies of scale. In order to address these problems P&G, Hewlett Packard, Sony and Electrolux conceived a pan-European compliance organization to collect waste electronic equipment Europe-wide. This organization, called the European Recycling Platform (ERP), operates in competition with existing national compliance systems. Since 2005 ERP has collected 800,000+ tons of waste electronic products and delivered millions of dollars in cost savings. This presentation reviews the steps needed to establish successful competitive collection organizations that provide sustainable recycling at the lowest cost.

Jan 1, 2010

By Ailton da Silva Ferreira

Thermoset polymers, like the polyester, become harder with increasing temperature owing to molecular crosslink formation, which is a thermal benefit for composite matrix applications. Natural lignocellulosic fibers, however, have low thermal resistance and tend to degrade with increasing temperature. Therefore, the combination of a lignocellulosic fiber, as reinforcement, with a thermoset polymer, as the matrix, results in a composite material with complex thermal behavior. In the present work, a thermal analysis was conducted on polyester composites with different amounts of curaua fibers. Both TGA and DTG curves were analyzed to determine the effect of the curaua fiber on the thermal resistance of the composites. It was found that the curaua fiber sensibly affects the thermal behavior of the polyester matrix for fiber amounts above 10% in volume. This effect is associated with an increase in thermal degradation.

Jan 1, 2010

By Jiongtian Liu, Guihong Han, Shuzhen Yang, Yanfang Huang

Binder, as a necessary functional material of electrode in lithium ion battery, has a vital influence on the electrochemical performance. The humics, coupled with polyacrylamide (PAM) and sodium carboxymethyl cellulose (CMC), were used as a water-soluble binder for LiFePO4 (LFP) cathode using in lithium ion battery. The techniques of cyclic voltammetry (CV) and galvanostatic charge-discharge were conducted to evaluate the performance of humics binder in LFP electrode. The reversible specific capacity of LFP (HA + PAM + CMC) electrode can reach to 142 mAh g−1 after 50th cycling (100 mAh g−1) on conditions of raw materials with 1 wt% PAM addition, humics and CMC with a mass ratio of 3:1 in binder, and the raw materials mixed in an interval order. Humics has the potential to be used as a novel, eco-friendly and high-efficient binder for lithium-ion battery.

Mar 1, 2018

By Lucas Lopes da Costa

In this work, a natural foam extracted from the Amazon buriti palm tree is investigated as possible substitute for synthetic foams. The basic physical and mechanical properties of this biofoam were evaluated. Its sponge-like structure was characterized by the amount of pores and morphological aspects. It was found that the buriti biofoam displays a very low density of the order of 0.1 g/cm3 with a relatively good compressive strength. This would be suitable for several engineering applications and as a new material with the potential for replacing currently applied synthetic polymeric foams.

Jan 1, 2010

By Zhou Wenbin

In this paper the mechanical properties of high carbon equivalent cast iron for automobile brake discs were analyzed through thermal analysis curves. Experiment results show that the mechanical properties have a strong correlation with thermal analysis curves and an effective way to predict the mechanical properties of high carbon equivalent cast iron was proposed based on the features of thermal analysis curves.

Jan 1, 2010

By Alicia Esther Ares

The family of Zn-Al (ZA), Zn-Ag and Zn-Al-Ag (ZINAG) alloys offers high mechanical properties, ease of finishing, the advantage of low energy and pollution-free melting. Also, present alternatives to the well developed alloy systems, such as brasses, bronzes, cast irons and aluminum alloys. The main objective of this paper is to measure thermal parameters in ZA, Zn-Ag and ZINAG hypoeutectic and hypereutectic alloys directionally solidified which present columnar, equiaxed and columnar to equiaxed transition structures (CET). Also, estimate the mechanical properties, such as microhardness and tensile parameters and correlate these with the thermal (cooling rate) and structural parameters (grain size and dendritic spacing). The different types of structures were analyzed with optical and scanning electron microscopy. The results showed the influence of concentration, microstructural arrangement and thermal conditions during solidification on the mechanical properties. The results of the present investigation are compared with previous experiments.

Jan 1, 2010

By Paul-Dominique Oudenne

For many years, CMI NESA has gained considerable experience in the field of alternative thermal processing processes by which useful by products result in addition to the destruction of the raw wastes. The CMI NESA pyrolysis process has been extensively applied to a wide range of sewage, industrial sludge and residues. This paper describes in details the development works carried out at the pilot stage as well as the key parameters of the process. Some of the industrial realisations are briefly described, the most recent one being the erection of a sludge pyrolyser on predried sludge at 90% dryness of a capacity of 100 tons of dry matter per day for the Valenton plant of the SIAAP (city of Paris).

Jan 1, 2006