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By Joseph J. Garbarino

World demand for phosphate fertilizers has grown at an average annual rate of between 6 and 7 per cent over the past 10 years. In the next five years world demand is expected to at least continue to grow at that rate. Also, the continued need for improved fertilizer materials, coupled with improvements in fertilizer technology, have placed added importance on the use of phosphoric acid as a starting material for high analysis phosphate fertilizers. This demand for phosphates and phosphoric acid must be met by increased production. Increased phosphoric acid production also brings increased demand for chemical processing agents including foam control agents. We at Arizona Chemical Company have closely followed the phosphate fertilizer industries needs. Arizona Chemical Company has been an important supplier of flotation agents to the phosphate industry, primarily from its Panama City, Florida plant. We have also recognized the important role played by foam control agents in the wet-phosphoric acid manufacturing process. We feel it is the responsibility of the supplier of foam control agents to offer specifically designed products that are highly efficient and economically useful. The difficulties involved in evaluating foam control agents in the plant are recognized. Owing to the large number of variables present, and the difficulties in controlling these variables during the period of a plant trial, plant evaluation of a large number of foam control agents is impractical. We have attempted to develop a practical, reproducible, and yet rapid, laboratory evaluation test which correlates with plant performance.

Jan 1, 1966

By F. M. Doyle, K. Osseo-Asare, E. Peters

With the aid of molecular orbital theory, a discussion is presented of the relationship between the electronic structures of ions and molecules, and the elementary steps involved in homogeneous electron transfer reactions. An electronic theory of the reactivity of oxidants and the mechanism of action of oxidation catalysts is then presented, with emphasis on the oxidative decomposition of metal sulfides. For model oxidants, two molecular reagents: O2 and Cl2, and two ionic reagents: Fe3+ and CU2+ were selected; silver (1) was chosen as the model catalyst. The reactivities of these reagents are rationalized in terms of constraints on orbital overlap, the availability of unoccupied d orbitals, and the rearrangement of electronic configurations.

Jan 1, 1993

By Peter Zhang

The immediate roof at the test site consisted of laminated clay shale that is likely to be susceptible to weathering. With seasonal dry-wet cycles in the mine ventilation air, the roof in the intake air would deteriorate and lose integrity over time. In many instances, the weathering-prone roof would gradually scale off piece by piece between bolts and over the entry corners. In some long-term entries, roof weathering could develop up to 2-3 ft deep with columns of bolted roof hanging under the upper intact roof. If wire mesh is used, the roof bags down and reduces the entry height, and the weight of the bagged roof tends to pull the bolts out and poses a safety hazard. An effective measure is always sought to support this type of weak roof that is sensitive to moisture degradation. One solution is to seal the roof shortly after entry development to prevent moisture penetration so that roof integrity can be maintained for the long term. In this application, a polymer-based sealing material was tested in the Rockspring mine for weathering protection and reinforcement. The material is a one-component polymer powder for spray application onto the roof and rib. The sealant material is mixed with water in the spraying nozzle to apply to the roof and rib as a paste. The product sets within 5-10 minutes and forms a membrane as thin as about 1/8-in. The membrane will quickly develop tensile and bonding strength within minutes and completely cure within a few days. Through sealing, bonding and lateral reinforcement, the integrity of the weak roof can be maintained. The material has been tried in a long-term evaluation over several months in a set of main entries in the Rockspring mine owned and operated by Rockspring Development, Inc., affiliate of Foundation Coal. Preliminary evaluation has shown that the material is an effective and economical solution to ensuring the long-term stability of weathering-prone roof.

Jan 1, 2009

By Otis M. Clarke

Domestic bauxite used in aluminum production comes from Arkansas where syenite was lateritized forming bauxite. Part of the residual bauxite and kaolinized syenite were eroded, deposited downdip, lateritized with bauxite formed in place, and covered by sediments. The unconsolidated overburden causes problems in mining. Bauxite for refractories and chemicals comes from Alabama and Georgia. Sediments were deposited in karst lakes and were lateritized forming bauxite and kaolin. Ferruginous bauxite in Washington, Oregon and Hawaii, derived from weathered basalt, can be used in aluminum production.

Jan 1, 1984

By S. Ostap

INTRODUCTION Paradoxically, it has been found that the people who are the most aware of the origin, mineralogy and composition of bauxite are also the people who are the least aware of how bauxite composition affects its treatment by the Bayer process. These people are the exploration and mining geologists normally associated with aluminum producing companies. The purpose of this paper is to give some idea of how the concentration and physical nature of the different minerals found in bauxites affect the operation of the Bayer process used to extract their alumina content. The bauxites we will consider here will be only the tropical bauxites such as occurring in Jamaica, various countries in South America i.e. Guyana, Surinam, Brazil, African bauxites, Malaysia and in Australia. When we speak of the Bayer process, it will be the North American version of the Bayer process using low caustic concentrations and bauxite digestion temperatures varying between 130° to 250°C. TABLE 1 shows the minerals and elements of interest occurring in tropical bauxites. The minerals and elements listed in the table do not by any means represent all of those identified in bauxites. Using mass spectrographic analysis on six bauxites from different geographic locations, we managed to identify between 50-60 different elements. Fortunately, only about 13-14 of these elements possess the necessary chemical properties to be able to accumulate in caustic Bayer solutions. The remainder are either not attacked, or form insoluble reaction products with some main liquor component, i.e., hydroxide, aluminate or carbonate, or reprecipitate with alumina trihydrate during the precipitation stage.

Jan 1, 1984

By M. Hardy, K. Nielsen, M. Ramey

American Soda, LLP has commissioned the first solution mine for recovery of naturally formed sodium bicarbonate (nahcolite) from low-grade deposits using high-pressure, high-temperature injection fluid. This project, known as the Yankee Gulch Project, was commissioned33 years after discovery of the deposit and followed an intensive four-year feasibility study that included a full-scale pilot test. The nahcoliteis co-mingled with oil shale and is impermeable. Solution mining is achieved by a combination of thermo-mechanical cracking and dissolution. Elevated temperatures are required to initiate the thermally induced cracking and to enhance solubility of the nahcolite, which is highly temperature dependent. This paper will provide an overview of the development of the project from discovery, characterization, pilot testing, permitting and commissioning, with emphasis on the solution mining aspects.

Jan 1, 2003

The trend in the U.S. coal industry in recent years has been a continuous increase in the percentage of coal produced by surface mining methods. Though the predicted energy demands promise a good market for coal, growing legal and environmental issues make the exploitation of a coal deposit by surface methods a difficult and challenging task. Major emphasis has to be placed on the development of integrated mining and reclamation schemes which enhance the possibilities of post mining land uses. Since no major breakthroughs are foreseen in the near future in surface mining equipment, innovative applications of current equipment must be developed. Draglines have been and are expected to continue as the primary earthmovers in surface mining of coal. A dragline simulation model has been developed which has the capability to analyze various deployment schemes such as conventional side casting, advance benching, and extended benching. The mathematical aspects of the model, the input data, and the output results are discussed with reference to an application in an operating mine. The model can be used to select a suitable dragline for given geological and mining conditions and to study the effect of alternative mining layouts and spoiling plans on machine production.

Jan 1, 1979

By T. W. Camm

One function of the U.S. Bureau of Mines is assessing potential economic impacts of federal land withdrawal policies. This often requires performing economic ana1ysls for an area with limited geologic information available. Input to the economic decision process relies heavily on estimates of mine and mill costs for the potential resources in the area being considered. A methodology for performing these cost estimates was needed to address this situation.

Jan 1, 1992

By I. W. Farmer, R. E. Finky

Design of structures in rock based on ultimate limit states or strength criteria is unrealistic. The fracture process which inevitably occurs in rock around an underground structure is an energy release phenomenon. The development of fractures and associated displacements around a structure may therefore be more logically described using strain energy concepts and design may sensibly be based on serviceability limit states.

Jan 1, 1986

By Zsolt Csillag, Dragorad Ivankovic, Miomir Ceh, Anna Csordás-Tóth

Results of the common research work of ALUTERV-FKI and RI in field of ore dressing are presented here. Although monohydrate types of bauxites consist of finely dispersed minerals, however, in some cases certain contaminants (carbonates mainly), can be reduced by physical methods before Bayer process. Electronmicroscopy combined with computerized data processing is proven to determine the possibility of beneficiation and to control the different stages of ore dressing. Test results gained by Hungarian and Yougoslavian bauxite samples, contaminated by calcite, dolomite, siderite and pyrite, are discussed. Basic operations were: grinding (mostly dry) and classification, magnetic separation (mostly wet) and selective agglomeration. Only simple processes, having high efficiency and mostly dry ore dressing technique may meet the requirement of economical criteria. 1. [CONDITIONS OF ADAPTING THE BAUXITE DRESSING METHOD] Bauxite is a relatively cheap raw material, occurring in great bulks. Bauxite deposits may often lay far from the traditional ore processing plants, and in such cases the ore reaches the plants after long transportation. Some of these plants must face the difficulty that the resources of high quality ore are exhausted, they fall short of supply and, consequently, they must decide on whether to utilize the existing resources of poorer

Jan 1, 1984

By Alfred A. Roetzer

In several sections of the country new demands are being brought bar cement users. Among these the demand' for truck shipments; and palletized loads present new problems that do not lend themselves to sample solution. In fact these demands have far-reaching effect in the way bagged cement might be marketed. Early solutions of palletized truck loads filled from existing packing and loading facilities have resulted in' slowdown in packing, additional labor and space for palletizing, considerable experimentation in type and construction of pallets, and usually far from optimum truck handling and loading methods.

Jan 1, 1961

By J. K. Szymanski, Val Srajer

In this decade mining companies in western Canada have searched for reliable and inexpensive ways to improve mine productivity. Truck dispatching systems, equipment vital sign monitoring and sensing, vehicle guidance systems, have all been considered. In this paper the off -highway vehicle monitoring systems used or planned to be installed at surface coal mines in western Canada are described. The monitoring systems are divided according to their function and application; installation and testing procedures are described, as well as the economic benefits to the mining operation.

Jan 1, 1989

By Harold A. Taylor

The first use of graphite is lost in the mists of time. It was used by primitive man to make drawings on the walls of caves and by the Egyptians to decorate pottery. As early as 1400 AD graphite crucibles were being made in the Haffnerzell District of Bavaria. Through the Middle Ages graphite was confused with other minerals, especially galena and molybdenite. Two common names that are still being used for the mineral are plumbago, meaning lead-silver, and black lead. The latter name implied that graphite is either composed of lead or at least contains a large percentage of it. Gessner is credited with having recognized it as a separate mineral in 1565, but its composition was not determined until 1779, when Scheele demonstrated that graphite oxidized to carbon dioxide, thus proving its carbon constitution. In 1789, Werner named it graphite from the Greek word graphein, meaning to write. The United States has long relied on foreign countries for its graphite supplies. This reliance has been due more to the lack of suitable domestic graphites than to any particular preference for buying minerals overseas. Sri Lankan graphites were imported as early as 1820, and Madagascar graphites have been imported since the properties on that island were opened up about a hundred years later. Mexico has long supplied the United States with most of its requirements for amorphous graphite.

Jan 1, 1994

By Donald A. Brobst

The minerals barite (BaSO, -barium sulfate) and witherite (BaCO, -barium carbonate) are the chief commercial sources of the element barium and its compounds, whose many uses are nearly hidden among the technical complexities of modem industrial processes and products. Barite, the major ore mineral, is extremely vital to the petroleum industry, which in 1990 consumed about 90% of the world's production of 4.9 Mt as a major ingredient of the heavy fluid called mud that is circulated in rotary drilling of oil and gas wells. The remaining 10% of the barite production was consumed chiefly in the manufacture of barium chemicals and glass and as a pigment, filler, and extender. Barite is found throughout much of the world and is available from three major geologic types of deposits-vein and cavity-filling, residual, and bedded-in sufficient quantity at competitive prices to meet current demands. The world's demand for barite is expected to increase because of the world's need for oil and gas. Geologic circumstances are favorable for the discovery of new deposits of commercial value. Witherite, desirable as a raw material for the production of barium chemicals, is much less common and abundant than barite.

Jan 1, 1994

By N. B. Aughenbaugh

A study was made to determine those petrographic parameters that are correlative with carbonate-aggregate quality as indicated by the Los Angeles abrasion and absorption tests. Samples collected at 28 sites in northern and eastern Indiana were analyzed petrographically, chiefly for void content, grain size, grain-size variation, grain shape, and grain interlock. Most of the sampled sites are in the belt of Silurian rocks of east-central and north- western Indiana. Though a few sites lie outside this belt, most of these have only a thin Devonian section above the Silurian. Three sites are non-Silurian and are included for comparison. Most of the samples studied are from Middle and Upper Silurian units. Both biohermal and nonbiohermal facies are included. The biohermal rocks are typically dense but vugular, finely crystalline granular dolomite. Nonbiohermal facies are porous, medium to coarsely crystalline, granular dolomite with dolomite rhombs The Los Angeles abrasion losses ranged from 20 to 46 per cent, the rocks in the eastern part of the state showing the higher values. Absorption tests indicate the same general quality trend. Comparison of petrographic studies with Los Angeles abrasion- and absorption-test results indicate the following correlations. (1) As per, cent of voids increases, quality decreases. (2) As average grain size increases, quality decreases. (3) Variations from mean grain size appear to have no effect on the quality. (4) As angularity and roughness of the grains increase, quality increases. (5) As grain-to-grain interlock increases, quality increases. Variations in the calcium-magnesium ratio have no apparent effect on aggregate quality, except as they affect the texture.

Jan 1, 1966

By Cindi Byrns, Andy Davis, Amy Tisdale

The Robinson district, Ely, Nevada is a hydrogeologically complex system with several distinguishable geologic blocks, each with a distinct background groundwater chemistry. To discriminate between background and mine-impacted groundwater, background wells, monitoring wells, pit lakes, waste rock seeps, and surface water samples were analyzed for a suite of major cations and anions, together with trace and precious metals, rare earth elements, 2H-deuterium and 18O/16O. The data allowed identification of groundwater flow paths, verification of hydrochemical source areas and characterization of natural attenuation mechanisms (e.g., mixing, dilution and mineral precipitation) that control the concentration and migration of metals at the site.

Jan 1, 2000

By Terry S. Maley

With some exceptions, minerals may be acquired on the unappropriated public lands by one of three methods: (1) mining claim location under the General Mining Law of 1872; (2) mineral lease under the Mineral Leasing Act of 1920; and (3) sale contract under the Mineral Materials Act of 1947. Leasable minerals such as oil, gas, coal and phosphate are specifically designated as leasable in the Mineral Leasing Act so the method of acquisition is clear. As a general rule, metallic minerals are acquired by mining claim location. However the nonmetallic minerals, most of which are industrial minerals or gemstones, present a more difficult problem. These minerals are acquired either by mining claim or a sale contract depending on their chemical composition, physical properties and the use to which they are put. The Act of July 23, 1955 (30 U.S.C. 61 1) provided that uncommon varieties of sand, stone, gravel, pumice, pumicite or cinders are locatable; whereas, common varieties of such minerals may only be acquired by a contract of sale. The widespread location of mining claims to appropriate such deposits has caused many land management problems. Federal court and Interior decisions offer the most useful guidelines in determining the most appropriate method of acquisition.

Jan 1, 1991

By John A. Herbst

Mathematical models of mineral processing unit operations have been developed and used for a variety of purposes. Models, defined as equations which mathematically approximate the behavior of process units, are being employed in simulators to evaluate proposed flowsheets, to investigate flowsheet modifications, to study the effect of variables on circuit behavior, to optimize the performance of circuits off-line, and to compare alternate control strategies (Mular and Herbst, 1978). Models developed for mineral processing operations may be placed in one of two general categories: phenomenological (based on mechanism) and. empirical (based on experimental data only). Dynamic models (including time as a variable) .are useful for control studies, while steady-state models (independent of time) are employed in flowsheet evaluations. Phenomenological models are potentially more flexible and accurate than empirical models. However, models constructed from theoretical knowledge are less easily developed compared to empirical expressions fitted statistically to experimental data. The latter apply only over the range of data acquired. Most often, models used in practice are the result of a combination of theoretical and empirical approaches.

Jan 1, 1979

By Cheryl L. Mardock, Michael D. Strickler

The Bureau of Mines is examining mineral deposits bearing strategic elements such as cobalt, for which the United States heavily relies on imports. The Turner-Albright volcanogenic sulfide deposit in southwestern Oregon is marginally economic based on its gold content and associated silver, copper, zinc, and cobalt values. Bureau research on the Turner-Albright deposit was performed (1) to evaluate domestic cobalt recovery as a byproduct of gold production from massive sulfide ores; (2) to develop an analogue of modern sea-floor polymetallic deposits to determine the economic potential of the deep-sea resources; and (3) to compile information on the geochemistry and genesis of the deposit that can aid in future onshore exploration. Cold was introduced as near micrometer-sized disseminations by exhalative hydrothermal fluids near sea-floor vent sites and by late influxes of mineralizing fluids into lower zones of brecciated sulfides and basaltic fragments. Cobalt is a substitutional element in pyrite that occurs in outlying halos around original vent sites. Mineralogic studies conducted with a scanning-electron microscope and an electron microprobe determined that none of the ore minerals are amenable to traditional beneficiation methods such as gravity and flotation. An experimental oxygen pressure-leaching procedure developed by the Bureau has proven successful in treating such complex ores.

Jan 1, 1990

By T. T. Chen, J. L. Jambor, J. E. Dutrizac

A reconnaissance study of the neutralization potential of 30 diverse minerals, 28 of which are silicates and aluminosilicates, has shown that most of these minerals contribute minimally to the neutralization potential (NP) in standard static tests. Feldspars in particular give low NP values and would not be expected to attenuate the acidity to any significant extent in acid rock drainage settings. The BET-determined surface areas of the minerals vary considerably, and the large surface areas of some of the pulverized samples have clearly affected the NP values even though the standard static-test protocol was used for the preparation of the samples. The low NP values of most silicates and aluminosilicates are in general agreement with the laboratory-determined slow dissolution rates for these minerals. The results suggest that, in the prediction of whether rocks will be acid-producing, the most realistic measure is that of the carbonate content. In mine wastes from metalliferous ore deposits, the contribution to the NP by the non-carbonate gangue assemblage is unlikely to be more than a token amount until well after the establishment of an acid rock drainage situation.

Jan 1, 2000