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By Carson Sharp Beltch

The determination of aqueous cyanide is accomplished by either detection in the sample as collected or by removal of the cyanide of the collected sample, followed by detection. The direct determination of the cyanide content of a solution can only be used in the simplest of systems, since many interferences can result in errors. Thus the most widely used method for total cyanide determination involve the reflux distillation of the sample using heat, acid and vacuum or air flow. The basic theory underlying this analytical approach is that by reducing the pH, the quality of molecular hydrogen cyanide will be in- creased and can be removed from the solution by elevating the temperature. The hydrogen cyanide is then collected in a caustic solution and analyzed. The general approach of removing the cyanide from the sample by distillation represented a major advance in this area of analytical chemistry. It enabled the determination of cyanide in many additional types of samples. When it became apparent that the tightly bonded cyanide complexes were not being detected by this approach, many methods fox complex ion destruction were proposed. These methods usually involved low pH adjustment with oxidizing mineral acids, coupled with the catalytic decomposition of the tightly hound complexes. All off the complexes except the strongest could he broken by these methods. The catalytic reflux distillation step has been found to have some negative aspects, since many materials that can be distilled with hydrogen cyanide will interfere with the color development step and result in a false positive reading.

Jan 1, 1981

By Alexander May

In its role of providing technology to promote the efficient use of minerals and mineral process waste, the U.S. Bureau of Mines has conducted research at: its Tuscaloosa Research Center to identify and develop high volume uses for phosphogypsum. Mixtures containing a maximum of 50 percent phosphogypsum, 6 to 10 percent lime, and the remainder fly ash had compressive strengths as high as 4,800 psi. The effects of the mounts of phosphogypsum, lime, and fly ash were investigated. Also, the effects of fly ash to lime ratios were studied.

Jan 1, 1983

The concept of "classification is expanded beyond the performance of the classifying equipment to include all aspects of the fines removal system of the grinding circuit. Design and operating parameters which affect fines removal are identified and discussed, and a quantitative index for circuit fines removal effectiveness is defined. This approach lends new interpretation to certain observed phenomena, and suggests useful guidelines for circuit design and operation.

Jan 1, 1985

By V. F. Hollister

Epithermal gold deposits occur in and near the marginal fault that circumscribes the Goldfield, Nevada, Tertiary caldera. The gold occurs disseminated in alunite, pyrite, and kaolin- bearing silicified zones that are controlled by the circular faults. Other Tertiary calderas (i.e., Summitville and Red Mountain No. 3) have epithermal disseminated gold deposits located in and near their marginal circular faults in settings that resemble the Goldfield example. These additional caldera- controlled epithermal gold deposits are also characterized by alunite, pyrite, and kaolin-bearing silicified rock that act as hosts for the gold disseminations. The Goldfield District is therefore an exploration model for those seeking disseminated epithermal gold deposits in a caldera setting.

Jan 1, 1986

By Alvin W. Schillinger

Drilling was not entirely satisfactory in the search for native copper in the Osceola amygdaloid footwall as mining showed oreshoots to be more continuous than drilling indicated. The Geophysics Department of Michigan Technological University developed a portable induced polarization drill hole probe with a 3 electrode configuration and a sampling radius of 5'± A 20 ma current of alternately reversed polarity is pulsed at 3.5 sec. intervals and readings are taken every two feet. Potential is read during the "on" cycle for resistivity determinations. During the "off" cycle, after 10 ms delay, the I.P. potential is sampled for 10 ms and recorded. Resistivity (ohm-feet) and "S" values (mv/v) are plotted on semi-log paper. A lithologic log is plotted based on resistivity and anomalous "S" values noted. The low resistivity amygdaloid contains sills of high resistivity basaltic trap. Verified by core logs, amygdaloid-trap contacts could be picked to ±.5' from resistivity alone. Lithologic logs of long steel holes, based' on resistivity, now replaced sludge logging. An "S" value of 30 mv/v was established as the lower limit of diagnostic I.P. effects in mineralized amygdaloid and 50 mv/v as a threshold value for ore. Of 914 footwall zones drilled, 315 were probed yielding 203 anomalies. Success increased from 34% for drilling to 72% for drilling and probing. As checked by mining, 46 probe results were 78% correct. Failures were due to the instrument not detecting copper or to the misinterpretation of an anomaly. No false anomalies were found.

Jan 1, 1964

By Dave D. Ferris

Today the coal industry is beginning to use some very fundamental economic evaluations to determine the most economical circuit to produce a specified saleable product. The fundamental economic methods used are standard return on investment and net present value calculations. By utilizing these economical evaluations, one can justify a larger capital expenditure and realize more return for an investment over the life of a coal property.

Jan 1, 1983

By Terry D. Vandell

The purposes of this presentation are: (1) to discuss the actual as well as potential incidents that have caused and that could cause groundwater contamination at uranium in situ leach mining sites and (2) to discuss remedial actions and solutions that have been or that could be implemented in the future to stop or prevent serious groundwater contamination from in situ leach mining in Wyoming?s Powder River Basin. Open pit, underground, and existing and proposed in situ leach uranium mine sites in the Powder River Basin are shown in Figure 1. In situ leach mining or solution mining for extracting minerals in liquid form is a relatively new addition to the list of conventional mining methods currently used to extract uranium in Wyoming's Powder River Basin. Basically, the in situ leach mining method involves: (1) the injection of a leach solution lixiviant (an acidic or basic oxidizing solution) into a uranium-bearing ore body, via injection wells, to complex the contained uranium, (2) mobilization of the uranium complex from the host material via creation of a soluble complex salt, and (3) surface recovery of the solution bearing the uranium complex via production wells. Uranium is then separated from the leach solution by conventional milling unit operations (ion exchange).

Jan 1, 1981

By K. A. Brunk

This paper describes Newmont's research, operations, history and experience with pre-treatment of preg robbing carbonaceous ores. The chemistry, physics and kinetics of chlorine treatment are described. Present operations, control strategy and projected changes are discussed. Included is a summary of the adsorption of chlorine into pulps and off-gas scrubbing.

Jan 1, 1987

By S. E. Sankey

High anionic functionality acrylamide co-polymers and poly(sodium acrylate) are used as red mud flocculants in bauxite processing operations. These synthetic polymers are effectively displacing starch as the dominant polymer in red mud settling. The performance of these polymers is primarily dependent on the bauxite mineralogy, the alkalinity of the red mud slurry, and the anionic functionality and molecular size (viscosity) of the polymer. In this paper, the physical and chemical properties of the synthetic watersoluble polymers will be reviewed. The relationship between polymer structure and red mud slurry properties as they control polymer performance in settling red muds common to digester and washer circuits will be illustrated. The availability of polymers of varying functionality and viscosity will permit bauxite processors to make significant improvements in the economics of red mud disposal and valuable reagent recovery.

Jan 1, 1982

By O. D. Christensen

The Carlin Trend is a 60 km (38 mi) long northwest alignment of epithermal, sediment-hosted, disseminated gold deposits. Collectively, these orebodies contained more than 620 t (20 million troy ounces) of gold. The Carlin deposit, located near the center of the Trend, has become the "type" deposit of this class. There are, however, significant differences between the individual deposits. Six subdistricts can be distinguished, based upon geographic, structural, lithologic, alteration, mineralization style, and geochemical characteristics. They are, from northwest to southeast, the Bootstrap, Bluestar-Goldstrike, Lynn, Maggie Creek, Rain and Bullion (Railroad) subdistricts. Regional Geologic Setting The Carlin District is located centrally within the Great Basin Geologic Province. Host rocks for the deposits include sedimentary units that range in age from Ordovician to Mississippian, as well as a Jurassic-Cretaceous granodiorite stock. During the Early Paleozoic, the area that is now Nevada lay along the western margin of the North American continent. A westward-thickening wedge of sedimentary units was deposited offshore in a eugeoclinal basin; these vary from continental shelf carbonates toward the east to fine-grained siliceous clastic and cherty units to the west. Tectonic activity associated with the Antler Orogeny in Late Devonian to Early Mississippian time resulted in the eugeoclinal Western Assemblage rocks being thrust as much as 140 km (90 mi) eastward over time-equivalent transitional to miogeoclinal Eastern Assemblage rocks along the Roberts Mountains Thrust fault system. The leading edge of the Roberts Mountains Thrust plate formed the emergent Antler highland from which siliceous clastic sediment, eroded from the overriding eugeoclinal rocks, was shed eastward into the adjacent foreland basin. Erosional products derived from the overthrust plate are termed the Overlap Assemblage.

Jan 1, 1987

By M. G. Ayat

A novel tracing technique employing specifically prepared trace particles has been applied to coal preparation separatory systems. The technique employs individually prepared trace particles representing specific known sizes and densities of coal particles. These trace particles are injected into the feed, to the processing circuit, and are then detected at locations in the coal product and refuse streams. It is anticipated that on-line input of the generated partition data will be linked with computer technology to provide rapid analysis of the processing efficiency, and to allow for process control. This tracing technique can revolutionize many processing operations from the diagnostic viewpoint as well as from the coal processing standpoint.

Jan 1, 1986

By Christopher J. Bise

Traditionally, mine drainage systems have not received the high level of emphasis on careful engineering design which has been rendered to many of the other auxillary operations. This may be due, in part, to the situation-response approach toward dealing with an influx of water. When the installed system becomes inadequate, costly alterations to the pump, such as staging or speed increases, are considered expedient solutions. In order to rectify this situation, computer-aided solutions to mine drainage problems could represent an efficient alternative to the methods presently used. This paper will consider the application of microcomputer technology to mine drainage problems and will show how the relative economy and convenience of microcomputers can make them become valuable analytic tools at any mine site.

Jan 1, 1983

By Hugh McMillan

To protect the water supply for the Metropolitan Chicago area, the Illinois legislature, in 1889, created the Metropolitan Sanitary District of Greater Chicago. To insure the quality of the water supply, the Sanitary District collected and diverted the wastes of 750,000 people away from Lake Michigan. Today, the Sanitary District collects and treats the wastes from a domestic population of 5 ¼ million people and an industrial waste load equivalent to 4 ¼ million people. The District serves Chicago and 120 other cities and suburbs in an 858 square mile area. An average of 1300 million gallons of wastewater is treated each day, producing as a by- product about 700 dry tons of solids which contains more than $10,000 worth of plant nutrients when equated to the value of commercial fertilizer purchased in the retail market. The Sanitary District considered several alternatives to past methods for disposing of these solids, and chose land application as a technique to utilize the solids produced by the wastewater treatment process in a beneficial manner.

Jan 1, 1973

By W. J. Turbeville

The subject of this discussion is timely. The U.S. phosphate industry is suffering the throes of depression. It's plight is a matter of widespread concern. The future role of the U.S. industry in world markets is of particular interest. If we should prognosticate phosphate supply-demand on the basis of recent history, we would face a puzzling choice of scenario. In 1980, perhaps the best year ever for U.S. phosphate, 54.6 million metric tons of phosphate rock entered the market place. Of this, more than half was exported -- divided almost equally - as rock or phosphate fertilizer. During the last half of 1981 the situation had begun to change.

Jan 1, 1983

By Adrian Brown

Floor heave can be a major problem in large open pit mines. Unrestrained floor heave can lead to flooding, equipment destruction, slope instability and subsidence. It is particularly troublesome in coal mines where the floor is frequently relatively flat, and is often underlain by major water Searing units. This paper examines methods of analysis used in computing floor stability, and sets out a simple rational method of evaluating the required level of water pressure control to maintain acceptable floor stability. The approach is illustrated by reference to the stability of the floor of the Morwell open cut lignite project in Southeast Australia, where this approach has been used successfully for over a decade.

Jan 1, 1982

By Sarkis G. Ampian

This late 1979 Bureau of Mines report presents current stocks and monthly consumption rates for Guyanese refractory bauxite (GRB), with emphasis on the impact of the GRB shortage on the refractory and downstream industries, general background material, and an evaluation of the situation resulting from the strike of Guyanese bauxite workers during the summer of 1979. A study by the Bureau indicated that industry stocks contained little more than a month's supply of GRB--30,000 calcined short tons (CST), at present consumption rates of 25,000 CST per month. The report was requested by the Federal Emergency Management Agency (FW) in response to refractory industry requests that the Government release GRB from the National Stockpile to minimize forecasted industry problems. The report traces the historical innovations in the high-alumina and/or bauxite-type refractory products industry, eventually leading up to fabrication of modern, high-quality firebrick and monolithic refractories.

Jan 1, 1980

By C. R. Peterson

A cutter vibration monitoring system is described which would map seam strata non-uniformities to permit guidance within the seam. An extremely simple and rugged transducer is used which is compatible with conventional cutters and cutter replacement practices, and believed to be suited to the mining environment. Laboratory tests show that the system can detect bedding planes in otherwise homogeneous material. A data display system which would employ the human operator's natural pattern recognition skill and judgement will be developed, Intended for remote control applications in general, the system is of direct interest for today's continuous excavators in coal or in any other machine excavated bedded deposit.

Jan 1, 1985

By C. Trepka-Bloch

Silver-copper-zinc mineralization is confined to metasomatically altered late Paleozoic and Cretaceous sediments consisting predominantly of limestone, siltstone and sandstone units. Mineralized alteration halos are spatially and presumably also genetically related to the emplacement of a Cretaceous quartz monzonite stock. Several generations of ore formation and alteration took place. Distribution of skarn and ore was influenced by intrusive contacts, calcareous horizons and by relatively less permeable rock units which served as barriers. Most of the ore bodies form conformable near horizontal mantos but some follow steeply dipping monzonite dikes. Structurally controlled alteration pipes connect the mantos locally. The deposit is strongly affected by mineralized fault and breccia zones.

Jan 1, 1986

By Edward W. Long

The Density Separator is basically a hindered settling classifier with automatic control features that provide steady, sharp classification irrespective of extreme variations in dry tons per hour of feed solids up to the design maximum throughput for the particular material being treated. The size and capacities of commercially available units and operating data comprise the scope of the paper. Applications of the unit for other than classification are proposed, i.e. washing and desliming.

Jan 1, 1982

By Anthony Edey

It is a generally accepted and widely discussed fact that the world in general, and the United States in particular, face a shortage of energy at the present time which will become worse in the future. There is, however, no sign of a similar concensus as to the actions which would prevent or overcome this expected shortage. An immense variety of solutions has, however, been put forward, ranging from the purely political to the outer fringes of sophisticated technology. One resource which surprisingly is often only cursorily included in this discussion is the immense known petroleum reserve lying within the United States. When this subject is discussed, indeed, it is usually in the context of the improvements in production or new discovery rate that could be expected to result from possible politico-economic actions that would raise the real price obtained for domestic crude. This interest in the potential for improved domestic production is undoubtedly justified, but very little attention is normally drawn to the fact that even under the most favorable policy framework the majority of the oil that has been, or will be, discovered will remain in the ground due to the inherent limitations of production through surface wells.

Jan 1, 1979