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By V. G. Papangelakis, G. P. Demopoulos

The high temperature (180-200 OC ) pressure oxidation (02 - HzSO4) process for the recovery of gold from refractory concentrates (FeS2/FeA8S) is simulated with the aid of a computer model. The model centers on the continuous operation of a multi-stage horizontal autoclave. In particular the effects of key process parameters controlling the autogenous operation of the autoclave are critically examined. The building elements of the model are (i) the continuous particle size distribution function of the concentrate, (ii) the residence time distribution function of the slurry and (iii) the shrinking core kinetics. Conversion is calculated on the basis of the segregated flow model. For the calculation of the particle size distribution at the exit of each compartment the population balance model is employed. The effects of feed rate, feed preheating, cooling, autoclave configuration and rate limiting regime (chemical reaction vs. gas-liquid mass transfer) on the autogenous steady state operation are discussed. Finally optimum reactor design and operation criteria are indicated.

Jan 1, 1990

By Jeff Schwoebel, Arcy, D&apos Horner

The Deep Coal Seam Project is a multi- year, large-scale research and development effort between the Gas Research Institute (GRI) and Resource Enterprises, Inc. (REI). The project is being conducted at the Red Mountain Site, a multi-well test site located in the southeastern portion of the Piceance Basin near Collbran in Mesa County, Colorado. The project objective is to develop the drilling, reservoir evaluation, completion and production technology required to produce gas from a thick, deeply buried coal seam. To understand the parameters controlling gas production, project efforts are focused on the Cameo "D" coal reservoir which lies at a depth of about 1707 m (5,600 ft) at the test site. This paper overviews the drilling, testing, completion, and production techniques used on the 1, 2 and 3 Deep Seam wells and implications for resource development.

Jan 1, 1987

Since gold was first discovered in Colorado in the late 1850s' mining has been a major part of the state's economic history, according to Stanley Dempsey, chairman and chief executive officer of Denver- based Royal Gold Inc. While the mining industry has seen some lean times throughout the past century, it has always bounced back. Today, dozens of major gold companies are headquartered in the Denver area. The state's coal mines produced record amounts during 1996. And even some of Colorado's uranium mines are resuming production. Dempsey joined other speakers in addressing the state of Colorado's mining industry during the Colorado Mining Association's (CMA) National Western Mining Conference. Some 800 people attended the CMA meeting, held Feb. 2-5 in Denver. The meeting was the association's 100th since it was incorporated in 1897.

Jan 1, 1997

By Rodger E. Denison

The Middle Ordovician Simpson Group in the Arbuckle Mountains of southern Oklahoma contains sandstones of unusual purity. These have been exploited as glass sands since 1913 (Ham, 1945). Where quarried, the sandstones are uncemented or weakly cemented, greatly facilitating mining and processing. The origin: sedimentary setting, and lack of cementation of these valuable sands has been the source of much discussion. The lowest of the sandstone units in the Simpson is at the base of the Oil Creek Formation. The basal Oil Creek sandstone is exposed in a series of accessible quarries north of the town of Mill Creek in Johnston County. Virtually all conclusions and generalizations concerning origin of the Simpson sandstones are based upon observations made in these quarries. The three Simpson sandstones overlying the Oil Creek share many of the same distinctive qualities, and there is an assumption that they share a common origin.

Jan 1, 1999

By V. Kontogianni

The underground extraction of coal is associated with ground movements extending from the mining area to the ground surface, which result in bowls of ground subsidence, with amplitude exceeding the amount of several meters and occasionally with important tilt and curvature of ground surface. Such changes at both the underground environment and surface topography lead to destruction of buildings, failure of utilities and transportation networks, and occasionally formation of areas vulnerable to flooding, or even small pools. Based on geodetic surface measurements of ground elevation changes, various theories and empirical models relating surface subsidence with the geometry of underground voids formed have been proposed, and predictions of expected subsidence in the form of contours have been estimated. In this study a case study of planning of a new highway network through areas in which coal extraction was also planned is discussed. This work is partly funded by EU. The optimum solution selected was a modification of the initial highway planning, so that the road is increased in length and by-passes the richest coal-field, where maximum post-exploitation subsidence was predicted, and only crosses either minor coalfields, which are not to be exploited, or even margins of main coalfields, in which minor post-exploitation subsidence is expected.

Jan 1, 2006

By L. Bloom

In 1996, lack of confidence in assaying methods and sample handling affected companies as diverse as Bre-X and Timbuktu. Share prices and the ability to raise financing are impacted when the quality of assay data is suspect. Overseas projects are subject to enhanced scrutiny when local facilities are used that are unfamiliar to brokers, financing agencies and banks. Quality control systems can be implemented but there are associated costs. These costs should reflect the risk to the mining company, investors and financiers and the size of the proposed investment. In this regard, assay control can be considered a form of insurance to enhance the value of an exploration or mining project. Providing reliable assay data in a production laboratory is challenging. Pressures such as time constraints and profitability affect data integrity. In Australia and North America, reliable assaying services have been provided by several laboratories. Mistakes are primarily due to human error but systems are available that monitor results and identify these types of errors. As the mining industry expands globally, mining companies encounter difficulties in some of these areas due to lack of infrastructure, poor communications, bureaucracy and political risk. These challenges also apply to the operation of laboratories, enhancing the risk of compromised data.

Jan 1, 1997

By Lars Lövgren, Jörgen Jönsson

Heavy metals may be retained within deposits of sulfide minerals under oxidation and in the nearest recipients of drainage water by sorption to secondary iron precipitates. The extent of sorption is strongly influenced by solution pH and presence of complexing ligands, such as sulfate and natural organic acids. Desorption of metals and organidinorganic anions to recent secondary Fe precipitates, collected at the Kristineberg mine, Sweden, has been investigated under different geochemical conditions. Elemental composition and structural characterization (X-ray powder diffraction) indicate presence of schwertmannite. While metals such as Ni and Pb were fractionally desorbed from the precipitates under acidic conditions, oxyanions, e.g. arsenatdarsenite and sulfate were desorbed preferably under alkaline conditions. In a separate study the adsorption of NOM onto synthetic goethite was investigated. NOM adsorption showed a strong pH dependence, 95% was adsorbed at pH 3 and 40 % was adsorbed at pH 9. Addition of 2 mM of sulfate desorbed about 10 % of the adsorbed NOM.

Jan 1, 2000

By R. R. Klimpel

The efficiencies of plant-scale comminution processes are often evaluated by various indices calculated and/or measured somewhat independently of the performance of any associated downstream froth flotation processes. To compare specific comminution factors, such as energy utilization, media consumption and equipment utilization time, comparisons of comminution efficiency independent of flotation behavior are appropriate. However, as increasingly detailed plant-level information is gathered on the joint and highly interactive nature of comminution and froth flotation, it is becoming even more obvious that knowing and using simple efficiency indices are not enough. What is needed are more performance-related measures of the efficiencies of the combined size reduction froth flotation system for effective plant-level economic optimization to occur. The purpose of this paper is to present examples of some of the important interactions that influence the joint efficiencies of size reduction and froth flotation processes.

Jan 1, 1999

By R. J. Sweigard

Fine coal refuse is often pumped, as slurry, into surface impoundments as a means of permanent disposal. As the available volume is filled, the height of the embankments are frequently increased. Many times the additional embankment material is placed upon consolidated fine coal refuse. There has been some concern about the long-term effect of consolidation of this material at or above the liquid limit upon its shear strength. A laboratory investigation was performed using three different types of fine coal slurry taken from Central Appalachian coal preparation plants. The refuse was consolidated in 10-foot plexiglass columns under incremental amounts of surcharge loading. The incremental loads were designed to simulate the effect of increasing the height of a refuse embankment on top of the consolidating coal slurry. After the refuse in the columns had consolidated for several months, the columns were cut apart and triaxial tests were performed on both the consolidated material and unconsolidated material for comparison of their shear strength parameters.

Jan 1, 1997

By M. Yavuz

The use of natural stones like marble is approximately as old as the emergence of human. Marble and natural stone usage of Turkey also dates back to very old times. Marble is produced in Anatolia since the ancient times. The archaeological excavations made in Anatolia indicate that the modern methods that are used for the production of marble blocks in modern world were first used by Anatolian people. Turkey is one of the oldest natural stone producers with its 4000 years of production history, starting from the Marmara Island. Therefore, the territory of Turkey possesses 4000 years of natural stone processing technology and experience. Turkey has fairly richer reserves of marble compared to other countries. This is why the rich and quality marble deposits of Turkey are resembled to the appearance of the Alpine-Himalayan marble belt of the world. Turkey has almost 40% of the total marble reserves (13.9 billion tones) of the world with 5.2 billion tones. Turkey?s marble reserve?s monetary value is worth about 2 trillion dollars. However, only 1% of these reserves are currently being utilized.

Jan 1, 2011

By H. Verakis

A fire in a coal mine conveyor belt entry represent a major safety and health risk to miners. Fighting belt entry fires can be a commanding effort. If there is a failure of one aspect in the fire fighting needs such as a dissimilar hose-valve connection, then it can result in the inability to extinguish a fire. Fire incident data compiled over nearly 30 years for underground coal mines shows that fires in belt entries account for 15-20 percent of the total number of fires. Fires in the belt entries of coal mines have resulted in injuries and fatalities. New regulations have been promulgated that require an unplanned fire not extinguished within 10 minutes of discovery to be reported to the Mine Safety and Health Administration (MSHA). A fire that is not extinguished within several minutes may take hours or days to extinguish or may require sealing a section or the mine in some cases. The current fire protection regulations in the U.S. Code of Federal Regulations (CFR), Title 30, Part 75 are designed to prevent or control the fire hazards present in a belt entry. These requirements and other factors affecting belt entry fires are discussed, including fire detection and warning, fire suppression devices, type and location of fire fighting equipment, waterlines, and cleanup and removal of combustible materials. The fire suppression systems used to extinguish/control a belt fire and the effect of ventilation on the propagation of conveyor belt fires are also discussed.

Jan 1, 2009

By P. D. Pack, E. H. Skinner

During design of a 550-foot rectangular shaft in alluvium, lateral support within the excavation was an anticipated construction problem. Actual experience showed that the nearly 9 x 14 foot excavation required no lateral support. A strain measurement program con- current with construction and for a 9-month period following completion of the shaft detected only minor strains. Shaft design included consideration of available geological information. Site exploration included a 754-foot drill hole, cored at selected intervals, and a suite of geophysical well logs. Generalized physical properties of the alluvium were developed from laboratory core testing. An elasto-plastic, finite element computer program (DAHLKE) developed by the Spokane Mining Research Center U.S. Bureau of Mines, has been recently used to analyze the behavior of the alluvium around the shaft. Analysis showed that yielding first develops in the shaft corners and progressively expands into the wall zones around the shaft as loading increases. Gradual growth of a plastic zone progressed outward from the excavation boundary at increasing loads but had limited extent and was surrounded at all stress levels by an infinite elastic zone. This design review, aided by computer analysis, confirmed that the shaft would have been considered theoretically stable as designed.

Jan 1, 1977

Over the past few years, the School of Mines of Paris has carried out a program of research* on the grade-tonnage relationships in the border zones of porphyry copper deposits. The initial problem was quite difficult : how does the grade vary at the border of the known orebodies? Does it decrease regularly, or do some thresholds exist, where the grade diminishes abruptly? The answer to these questions have important repercussions on the prediction of the future reserves in the fringe of the orebodies. If the grade decreases regularly, very important reserves could exist; if not, there would be strong limitations to the possible recoverable reserves. The first step of our study was a critical study of previous work done on the subject. It appeared that, following Lasky's pioneering paper (Lasky, 1950), most of the authors used what we can call an historical approach to the problem. In this, the grade-tonnage relationships are calculated from the available figures for production and reserves and the results are then extrapolated to the future. The strong limitation of this model are brought out in this article.

Jan 1, 1982

By D. A. Peterson

Laboratory testing was completed to determine the effectiveness of a fiberglass cable bolt (FCB) as a cuttable rock support for a continuous, hard-rock mining method. The FCB consists of four Polystal tendons combined in a node/antinode fashion, with polyvinyl chloride (PVC) spacers forming the anti-nodes. The largest ultimate pull-out load achieved by the FCB was 22 t (48,400 lb) at 89% of the tendons' theoretical pullout load. This premature tendon failure is accredited to: • differential stresses within the tendons and • differential tendon displacement. An increase in pull-out resistance for a given embedment length is due to: • increased bond area, • reduced interfacial shear and • "wedge" effect. The critical embedment length was found to be 40% less than for conventional steel cable bolts (SCB) at a 127-mm (5-in.) node spacing. An FCB can have up to a 92% increase in load-carrying capacity over a conventional SCB at equal embedment lengths. The load carrying capacity is equivalent to SCB at a 960-mm (37.8-in.) embedment length. Though the FCB is 7.5% more expensive than the conventional SCB (installed), this cost may be offset by increased performance. FCBs are a potentially viable support alternative for continuous hard-rock mining.

Jan 1, 1993

By Claude Hébert

The Grenville structural province, a 400 km-wide belt of Precambrian metamorphic rocks which crosses the province of Québec in a northeasterly direction, is the host of several wollastonite occurrences. Most of these are found in marble and calc-silicate rocks enclosed within or located near intrusive bodies. Reconnaissance and detailed mapping of such zones have helped to identify areas of interest for wollastonite exploration. The most important zone is located in the huge Lake Saint-Jean anorthosite massif in the central part of the Grenville. A recent geological mapping project has revealed the presence of wollastonite in metasedimentary faulted remnant of the roof. The main occurrence consists of diopside and wollastonite in a zone at least 3 km long and 150 m wide. Preliminary sampling suggests and average grade of 50 percent wollastonite with an aspect ratio of 151. Other wollastonite deposits occur in the western part of the Grenville, mainly north and west of Montreal, where the Morin anorthositic complex and a large syenite mass intrude the metasedimentary rocks of the Grenville Supergroup. Marble bands with up to 70 percent wollastonite occur locally at the southern margin of the complex or as an inclusion in the syenite. Significant wollastonite occurrences have recently been found in the eastern part of the Grenville. One of them is located in metamorphosed calcareous rocks which are part of the granulite facies Manicouagan metamorphic complex. A representative sample analyzed 54 percent wollastonite. Farther south, an inclusion diopside-wollastonite gneiss containing an estimated 40 percent wollastonite occurs at the margin of the Pentecôte River anorthositic complex.

Jan 1, 1995

By Numan Elmas

This paper presents detailed information on the genesis, formation, and industrial utilization of Yaylacik magnesites. Tectonically, the study area is located within the Tavsanli Zone, immediately south of the Izmir-Ankara suture in western Turkey. The geologic setting mainly comprises ophiolitic melangks basics, and ultrabasics associated with very rich magnesite deposits and lacustrine sediments. The ophiolitic unit tectonically overlies the schists and carbonate rocks. The presence of glaucophane and lawsonite indicates a low-temperature/high-pressure metamorphism. The ultra- basic rocks, which exhibit cumulate composition, have been mostly serpentinised and represent the oceanic floor of the Yaylacik ophiolite. Basic intrusives consist of dolerite and diabase, and they show the characteristics of within-plate dolerites. The magnesite occurrences are commonly observed in block, stockwork, lens, and vein forms and were deposited within the serpentinites. In most magnesite samples, secondary quartz/chalcedony formations are observed as fracture fillings due to the highly effective tectonic movements. Field surveys and microscope studies reveal that magnesites had been formed by the metasomatic alteration of serpentinites. Chemical analyses show that, although MgO content of the magnesites varies from 43.41% to 50.48%, Fe203 and CaO are lower than 1%. Silica contents are as high as 5.52% in a few samples. Although Yaylacik magnesites are not suitable for making basic refractory bricks, they are widely used as caustic-calcined magnesite in a variety of applications, including animal food, artificial fertilizer, chemical (acid neutralizer), medical and pharmaceutical, and water treatment.

Jan 1, 1999

By Charles N. Speltz

The cost of transportation of industrial minerals frequently is higher than the cost of the product. When a mine, industrial-mineral plant, or customer is served by a single railroad, because of the lack of competition, that railroad may in- crease rates and/or reduce service so that the economics of that mine, plant, or customer are affected adversely. Transloading of industrial minerals from rail-to-truck or truck-to-rail to improve economics and sales of product is not a new concept. However, transloading to create competition and reduce freight costs or to improve service is a relatively new concept brought on by the recent mergers of many of the main-line railroads, both in the eastern and western United States. For example, in 1998, with completion of the Burlington Northern/Santa Fe (BNSF) and the Union Pacific/Southern Pacific mergers (UPSP), the western United States has only two main-line railroads. The industrial-mineral producer, to reduce the cost of transportation or increase the level of service, must evaluate potential transloading opportunities in light of higher prices and reduced service brought on by reduced railroad competition. This paper discusses industrial-mineral transloading and examines the case history of the Tucker Hill perlite project in southern Oregon. The Tucker Hill project is a classic study of industrial-minerals transloading where the project would have failed without the transloading.

Jan 1, 1999

By M. A. Marticorena, R. Stratton-Crawley, C. I. Basilio

Diethylenetriamine (DETA) is a selective depressant for nickeliferous pyrrhotite during pentlandite flotation. Laboratory flotation tests conducted on ore and process samples showed that pyrrhotite rejection is greatly improved by small additions of DETA; however, the effectiveness of this depressant is most noticeable when the mineral sample is oxidized. LIMS and XPS analyses conducted on flotation products and pyrrhotite specimens showed that the difficulty in pyrrhotite rejection arises from inadvertent activation of the mineral by heavy metal ions, such as Ni2+, cu2+ and Ag+, that are present in the process water. In the presence of DETA, however, the mineral is deactivated under oxidizing conditions. The deactivation mechanism may involve oxidation of the activation products, which are likely in the form of heavy metal sulfides, followed by solubilization by DETA. FTIR spectra of pyrrhotite electrodes contacted with DETA showed no trace of the reagent on the surface, substantiating the view that its role is one of complexing agent that enhances the dissolution of activation products under oxidizing conditions. FTIR spectra of pyrrhotite contacted with amyl xanthate solutions showed that both dixanthogen and iron xanthate are formed on the surface, the latter becoming more predominant at higher potentials. In the presence of DETA, however, only a small amount of xanthate is adsorbed on the mineral at potentials (Eh) approximately 200 mV higher than the case without DETA.

Jan 1, 1995

By E. J. Beckman, R. M. Enick, C. Powell

Liquid carbon dioxide can be used as a replacement for organic solvents in the extraction of anionic platinum group metal complexes from an aqueous phase. However, because conventional extractant-metal complexes are not soluble in liquid carbon dioxide, this can be achieved only if highly carbon dioxide-soluble extractants are developed. For example, trioctylamine-gold chloride is not soluble in liquid carbon dioxide, although trioctylamine is CO2 soluble. The novel CO2-soluble extractants presented in this paper have a CO2-philic fluorinated tail to enhance solubility and a conventional amine head group for extraction of metals. Both the extractant and the extractant-metal complex are soluble at ambient temperature at pressures from 7 to 35 MPa. Efficiency factors as high as 2.23 have been measured using 1,1,2-trichlorotrifluoroethane (TCTFE), a low pressure screening liquid for carbon dioxide, indicating that these compounds will strongly bind the metal chloride. For example, 84% of Pt-chloride was extracted into TCTFE using a 3.5:1 ratio of a double¬tailed fluoroalkyl amine extractant: metal chloride. An 88% recovery of Pt-chloride into high-pressure liquid carbon dioxide was achieved using the same extractant at a 3.5:1 ratio. Therefore, it appears possible to replace organic solvents with liquid carbon dioxide during the extraction of platinum chlorides if highly carbon dioxide-soluble extractants agents are employed.

Jan 1, 2002

By A. K. Bakshi, Komar S. Kawatra

A plant trial of a new on-line pressure vessel rheometer for slurries, developed at Michigan Technological University, was carried out at a nearby copper concentrator. The rheometer measured the flow curves (shear stress vs. shear rate) of chalcocite slurries. Viscosity of non-Newtonian slurries changes with shear rate and so, for such slurries viscosity measurement at a single shear rate (often seen in the literature for grinding and classification studies) cannot be correlated to process performance. For these slurries, viscosity at various shear rates can be measured from flow curves generated by the pressure vessel rheometer. Other rheological properties, such as flow type and yield stress can be determined by this rheometer to better characterize the slurries. The slurry at the copper concentrator consisted of ground chalcocite ore. The solids content in the slurry varied between 30-60 % by weight. Top size of the particles was 125 micron, and 80% passing size was 34 micron. Measurements by the pressure vessel rheometer showed that most of the slurries had pseudoplastic flow at shear rates below -3000 sec-l, where the viscosity of the slurry decreased with increase in shear rate. Above -3000 sec-l, like a Newtonian fluid, the viscosity of the slurry remained steady. Flow curves and viscosity from the pressure vessel rheometer were verified with a Brookfield viscometer and a vibrating sphere viscometer, and the results were found to be accurate.

Jan 1, 1997