Search Documents

By H. Zhong, S. Wang, Q. Lin

To improve the flotation performance of chalcopyrite collector, 2-(tert-butoxy)ethyl xanthate (TBEX) and its derivative O-(2-(tert-butoxy)ethyl)-N-ethyl-thionocarbamate (TBEETC) were designed and prepared by the introduction of a 2-(tert-butoxy) ethyl group into xanthate and thionocarbamate. TBEX and TBEETC were both prepared via the one-pot method with superior efficiency, which has significant commercial implications. The micro-flotation tests demonstrated that compared with sodium isobutyl xanthate (SIBX) and O-isopropyl-N-ethyl-thionocarbamate (Z-200), TBEX and TBEETC both possessed better collecting ability and selectivity for chalcopyrite. DFT calculations and XPS were utilised to investigate the flotation mechanism involving TBEX or TBEETC and chalcopyrite. The results demonstrate that although 2-(tert-butoxy) ethyl group does not interact with minerals directly, its introduction reduces the energy of HOMO, so that they can better accept electrons instead of donating electrons which leads to better interaction with copper atoms rather than iron atoms. Keywords: Chalcopyrite, flotation, thionocarbamate, xanthate, synthesis

Jan 1, 2020

By J Taguta, B. McFadzean, P. E. Ngoepe, M. G. Mulaudzi

Computational modelling methods and isothermal titration calorimetry (ITC) were employed to investigate the interaction of a pyrite surface with thiol collectors. Modelling work was conducted in the presence and absence of water. Microcalorimetry was employed to investigate the resultant energy of interaction pyrite as a result of mineral-collector interactions. Sodium ethyl xanthate (SEX), diethyldithiocarbamate (DTC) and diethyl dithiophosphate (DTP) were investigated in this study. The results showed that the calculated surface energies and morphologies for FeS2 showed that (100) and (111) are the most stable surfaces. The morphology also indicated the appearance of the (100) and (111) surface facets and no presence of others. The calculated adsorption energies between thiol collectors and the pyrite surface were always more exothermic than the experimentally determined ones. When comparing different ligand types with the same alkyl chain length, the heat of adsorption of diethyl-DTC was greater than that of ethyl xanthate and diethyl-DTP for pyrite. Experimentally, the diethyl DTP barely adsorbed onto the pyrite surface and this may be due to a different mechanism of action. In computational calculations, water adsorption was found to reduce the reactivity of the Fe atom for the interaction with thiol collectors, and bring the adsorption energies closer to the magnitude of the experimental values. Keywords: Computational modelling, microcalorimetry, experimental and thiol collectors, adsorption energies

Jan 1, 2020

By S. Banisi, S. Zare, M. Mahmoudi, M. Maleki-Moghaddam, M. Yahyaei

As the orebodies become more complex and lower grade, there is an increasing demand from crushing circuits for a finer product. When the product from a crushing circuit does not satisfy the requirements of the downstream processes, the cost of production increases. Thus, enhancing the performance of cone crushers through optimisation of their operating factors becomes important. One of the key factors affecting performance of cone crushers is the filling of the crushing chamber during the operation. The effect of varying the filling of the crushing chamber of a cone crusher was investigated. To assess the crusher performance, parameters such as crusher capacity, power utilisation, and reduction ratio were used. Extensive plant trials were conducted to obtain samples and operational data when the crusher chamber was 50% full (half-full) and 100% full, which is 300 mm above the top of the crusher chamber (super-choked condition). The results indicated a 62% difference in the crushing capacity when the crusher was operated in a super-choked condition compared to the half-full chamber level. In the super-choked condition, the size-specific energy at 12.7 mm was 20 % lower than that of the half-full condition. The Bond ball mill work index (BBWI) of crusher product indicated that the BBWI of the product of the super choked condition is 5.6% less than that of the product of half-full condition. This can be attributed to the generation of micro cracks in particles due to increase in the interparticle breakage when the crusher was operated in the super-choked mode. Keywords: Cone crushers, crushing efficiency, crushing chamber filling

Jan 1, 2020

By M. Rudolph, J. Sygusch

Froth flotation is well-established and efficient in the selective separation of valuable particles from unwanted material with sizes ranging from 10 μm to 200 μm. However, when it comes to the separation of ultrafine particles (< 10 μm) there are still some challenges, or rather opportunities. This research aims at developing a method for the separation of ultrafine particles based on multiple particle properties. Amongst such properties are wettability, morphology (shape or roughness) and size with applications not only in mineral processing but in general chemical engineering. In this study, three differently shaped fractions are used as valuables for testing: spherical particles, elongated particles and irregularly shaped particle fragments; together with ultrafine magnetite as the gangue material, in order to investigate the effect of particle morphology on ultrafine particle flotation, as well as wettability, which is varied by esterification using alcohols. Flotation tests are carried out using a novel flotation device that was designed especially for the flotation of ultrafine particles, combining advantages from machine-type froth flotation and column flotation. The results showed that, in contrast to previous studies, recoveries for ultrafine spheres were higher than for ultrafine fragments for all wettability conditions, and hydrophobisation generally increased particle recoveries for said morphologies. Tests using fibres showed different behaviour as hydrophobisation had negative effects on their recovery, despite increased selectivities and kinetics. These findings suggest that apart from influences of particle properties within the suspension zone, their effects on the froth characteristics should be studied in more depth. Keywords: Ultrafine particles, Flotation, Particle shape, Wettability, Esterification of glass, Hydrophobisation

Jan 1, 2020

By B. McFadzean, M. Becker, S Geldenhuys, A. Molifie

Mineral hydration is known to result in low flotation recoveries and grades within primary platinum group element ores worldwide. This is because the phyllosilicate minerals derived from hydration reactions of silicate minerals (i) form electrostatic coatings on valuable minerals that in turn hinder collector adsorption, (ii) alter the viscosity of the slurry leading to poor gas dispersion and (iii) decrease the concentrate grade due to naturally-floating gangue. Sodium silicate was investigated because its dispersant, rheology modifying, and depressant properties could prove promising in combating the problems associated with these ore types. Quantitative evaluation by scanning electron microscopy analysis revealed large quantities of serpentine and talc present within the ore sample used in this study, which led to a poor flotation response as indicated by batch flotation tests. Using sodium silicate improved the recoveries and grades at high dosages (>1000 g/t). The zeta potential experiments indicate that improved recoveries are, in part, as a result of the reversal of serpentine surface charge, creating electrostatic repulsion between serpentine and valuable minerals which prevents the coating of valuable minerals by serpentine slimes. Ore dilution and rheology tests indicated that decreased viscosity at high dosages also improved recoveries. Talc micro-flotation tests revealed that the depression of talc occurred at higher sodium silicate dosages, which improved concentrate grade. The processing of nearsurface altered ores is becoming an increasing problem worldwide and the use of sodium silicate proved valuable in mitigating the problems associated with the altered ore investigated in this study. Keywords: Alteration, phyllosilicate slimes, colloidal chemistry

Jan 1, 2020

By R. B. Khumalo, F. K. Mulenga

Sampling in a continuous flotation plant is always a challenge as these plants are meant for production and not research work. The continuous flotation operation used in this work produced three sets of data: the first was based on overall plant performance, done by sampling the feed, concentrate, and tails; the second was based on the roughers row cell-by-cell; the third set of results came from the cleaners/recleaners row cell-by-cell. The highest recovery results in all sets of data obtained lie in the particle size ranges of 40 μm and 100 μm, which is in agreement with results by other researchers in the same field. King’s theoretical (model) recovery proved to be able to fit the experimental data but there is still room for improvement as the sum of squared error ranged between 400– 1200. Data obtained in continuous flotation operation could be used with batch flotation test-work to characterize scale-up of flotation cells.

Jan 1, 2023

The established shared laboratory facilities between the Departments of Metallurgy and Chemical Engineering of the Vaal Triangle Technikon and the University of Potchefstroom are already proving to be a great success.

Jan 1, 1992

By C. S. Erasmus, L. C. Woollacott

The distribution of gold loaded onto carbon particles from a carbon-in-pulp operation was measured by neutron activation analysis. The nature of the distribution is examined, and the implications for operating plants and CIP simulators are discussed.

Jan 1, 1992

By P. E. Hand

SYNOPSIS This paper describes some of the markets for South African coal and their particular coal requirements. It describes how reserves are being used and suggests new strategies to make possible a synergistic ap¬proach that would benefit coal producers and end-users.

Jan 1, 1991

By N. Gibson

The application of oxygen in a copper smelter by N. GIBSON* (Visitor) This paper describes how the problem of increasing the capacity of the Rokana copper smelter was handled, and how oxygen was found to be technically and economically the best solution. The first phase of its implementation is outlined.

Jan 3, 1974

By D. Visser, P. D. Toens

The development of a continuous recording scintillation counter mounted on a cyclometer by P. D. Toens (Fellow) and D. Visser (Visitor) In order to facilitate ground radiometric surveys the Atomic Energy Board has developed a continuous recording device attached to a scintillation counter which is mounted on a cyclometer. Details concerning the construction are given.

The 97th Annual General Meeting of the The South African Institute of Mining and Metallurgy was held in the Gold Room, Transvaal Automobile Club, 60 5th Street, Lower Houghton, Johannesburg on Wednesday, 10th August, 1994. Obituaries The President announced the passing during the year of the following members:

Jan 1, 1994

The 93rd Annual General Meeting of The South African Institute of Mining and Metallurgy was held in the Highveld Room of the Carlton Hotel in Johannesburg on Wednesday, 15th August, 1990. Obituaries The President announced the deaths of the following Members of the Institute:

Jan 1, 1990

By J. L. Taylor

The belt-filtration plant at Chemwes Limited has been in operation for three years. The plant design is discussed. Operational and engineering problem areas are reported, and where possible the modifications or practices that led to their solution are mentioned. Capital and operating costs, together with selected general operating data, are also included.

Jan 1, 1983

The 88th Annual General Meeting of The South African Institute of Mining and Metallurgy was held at Kelvin House, Johannesburg, on Wednesday, 14th August, 1985. Mr J.D. Austin (President) was in the chair and declared the meeting open at 16h00.

Jan 1, 1985

By B. H. Sandelowsky

Prehistoric metal-working in South West Africa by B. H. SANDELOWSKY*, Ph.D. (Visitor) This paper describes a three-hundred year old metal-working site at Rehoboth, and makes a plea for information on such sites elsewhere in South West Africa so that they can be investigated. The technique of ore smelting that was used at Rehoboth appears to be different from that practised elsewhere by Bantu peoples before the modern era.

Jan 5, 1974

By E. O. M. Hanisch

Copper working in the Messina district E. O. M. HANISCH. B.A. (Pretoria) (Visitor) By reference to the available literature, an account is given of the manufacture of metal ingots by the Messina copper workers. These workers are thought to have been Balemba tribesmen, of the Musina Clan, who came from across the lebombo Mountains. A description is given of their methods of mining, smelting, and casting, and of the vlrious types of ingots they produced.

Jan 1, 1974

By R. G. B. Pickering

Conventional mining is an excellent match of mining method and equipment. The result is guaranteed performance. Change in the form of different technology requires change in mining method until the best match is achieved. This paper covers the development of technology and mining method that has occurred in the last five years to arrive at the objective of successful mechanized mining in narrow reef platinum deposits of the Bushveld Complex.

Jan 1, 2004

By E. H. van Niekerk

The production of high-strength Iow-alloy (HSLA) steels containing either niobium or vanadium as the principal micro-alloying element is discussed, including recent developments in steelmaking practice that have had a great effect on the development of HSLA steels; strengthening mechanisms, as well as the principles of thermomechanical treatment during controlled rolling on a hot-strip mill; and the results of production heats with various amounts of micro-alloying elements.

Jan 1, 1984

By C. M. Sellars, W. E. Stumpf

SYNOPSIS The effects of concurrent recovery, prior creep deformation and concurrent high temperature fatigue on the coarsening of some carbides in steels have been studied. It was found that concurrent recovery enhances the coarsening rate by orders of magnitude and prior creep deformation causes an enhancement of about two times. Finally, concurrent fatigue causes an initial greatly enhanced coarsening rate but after prolonged cycling dissolution of the carbides occurs.