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By Stephen D. Cramer

The Bureau of Mines conducted a series of in situ linear polarization measurements in high-temperature, high-pressure hypersaline geothermal brines at the Bureau of Mines Geothermal Test Facility in the Imperial Valley of California. The measurements represented an evaluation of the linear polarization technique for obtaining instantaneous corrosion rates of materials of construction in flowing hypersaline hydrothermal fluids that rapidly form scales on exposed surfaces. A special method was devised for use with the linear polarization technique that resulted in obtaining corrosion rates for 1020 carbon steel, 316 and 430 stainless steel, titanium, various nickel-based alloys, and aluminum 6061 under strong scale-forming conditions. The measurements also provided information on scale-deposition rates in various geothermal environments. Exploratory in situ potentiostatic polarization measurements were made in the flowing brines to qualitatively determine scale-deposition effects on the electrochemical measurements.

Jan 1, 1978

By John Nagy

The Bureau of Mines examined explosion development in a closed spherical vessel, mathematically correlating flame travel, pressure, and time with parameters defining the reaction. The model assumes that burnt and unburnt zones are separated by a thin, radially moving flame front. Isothermal and adiabatic systems are considered. Correlation with gas and dust explosion data is better for the adiabatic system, but the isothermal development is simpler and in reasonably good agreement. Interpretation of the explosion phenomena is facilitated by expressing the rate of mole change in the flame front in terms of elementary parameters. This expression is developed by examining the components of spatial-flame velocity.

Jan 1, 1969

By John H. Perry

The Bureau of Mines has developed several techniques for draining methane from coalbeds in advance of mining. Drilling long horizontal holes from an underground location is one such technique, which was successfully demonstrated in the Pittsburgh and Sunnyside Coalbeds. The same technique has now been applied in the Mary Lee Coal bed at Jim Walter Resources, Inc.'s No. 4 Mine, Brookwood, Ala., where two holes were drilled horizontally--one to a depth of 1,010 feet (308 m) and the other to 540 feet (165 m). The 1,010-foot (308-m) hole proved successful in degasifying a portion of the Mary Lee Coalbed. The hole drained methane for 1 year, during which time the initial gas flow of 200,000 ft3/d (5,663 m3/d) declined to 65,000 ft3/d (1,840 m3/d). Total gas production was 40 x 106 ft3 (1.1 x 106 m3). The gas was of commercial quality, with 98 pct methane and a heat rating of 990 Btu/ft3 (36.89 Mj/m3). The methane emissions from the faces of the mine section advancing into the degasified zone were reduced by 60 pet. The 540-foot (165-m) hole was terminated prematurely when it became impossible to maintain an open hole. Because of caving, very little gas was drained through this hole.

Jan 1, 1982

By G. E. Rennick, F. E. Armstrong, J. Pasini, J. R. Abrams

An oil well penetrating the Pittsburgh bituminous coalbed in northern West Virginia was plugged and safely mined through 3 months later. A sensitive chemical tracer, introduced into the oil reservoir before the test, was not detected in the mine air following the plugging and during mining of the pillar and penetration of the well. Effectiveness of the plugging in preventing reservoir gas from entering the mine through the well hole was verified by continuous monitoring of the mine air for indications of sulfur hexafluoride, an inert gas detectable in amounts as minute as 112 part per billion. Expand- able cement and fly ash-gel-water slurry were utilized to seal the well above and below the coal seam. Three other wells were also plugged using various techniques.

Jul 1, 1972

By A. J. Rambosek

An evaluation of diamond-bit performance data accumulated from core drilling in quartzite shows that core recovery and physical characteristics of drill bits and diamonds have economic significance. Relatively inexpensive, low-quality, small Congo diamonds will perform as well as, or better than, other diamonds used as drill bart. M-type bits set with oriented Congo diamonds provide those engaged in core drilling with near optimum combination. Various factors that affect bit performance, including size of diamonds, size and type of bits, grade or quality of diamonds, and percentage of core recovered, are evaluated by means of tables, charts, and discussion.

Jan 1, 1958

By John C. Holtz

The Bureau of Mines studied air contamination caused by diesel exhaust in a 10,000-ft ventilated tunnel. Sequential air samples were taken at the ends and middle of the tunnel during an operating cycle. Observed and calculated results for carbon dioxide, carbon monoxide, and nitrogen oxides were essentially in agreement. Nitrogen dioxide was present only in trace amounts. It was found that contamination was related to the volume of ventilating air, the number of haulage trips, train speed, and engine load.

Jan 1, 1968

By D. L. Paulson

The Bureau of Mines studied the feasibility of producing copper matte in an electric furnace from blends of copper concentrate similar to those currently smelted in a gas-fired reverberatory system at an installation in Tacoma, Wash. A 800-kva electric-arc furnace was used to determine the distribution of constituents when arseniferous concentrates are being smelted in an electric-arc furnace. Test results from smelting 40 tons of materials indicated that electric smelting is more like a conventional gas-fired system than originally expected. Although gas composition over the molten bath is much different in an electric furnace, the secondary constituents such as arsenic, lead, zinc, and antimony behaved the same as in a reverberatory furnace. The results established that an electric furnace would be compatible with sulfur and particulate recovery facilities that are being used.

Jan 1, 1976

By J. Douglas Causey

In 1984, at the request of the Bureau of Land Management, the Bureau of Mines studied 29,020 acres of the 43,165-acre Terry Badlands Wilderness Study Area (MT-024-684) in order to evaluate its mineral resources. Within this report, these 29,020 acres are referred to as the study area. Located in Custer and Prairie Counties, MT, the study area is about 2 miles northwest of Terry. The study area is underlain by essentially flat-lying units of the Fort Union Formation of Paleocene age with some Quaternary alluvial deposits in stream valleys. No mines or prospects were found in the study area. Bentonitic clays and lignite coal units were examined and sampled; however, no clay resources or coal reserves were identified. Estimates of coal resources will be reported by the U.S. Geological Survey in a joint U.S. Geological Survey-U.S. Bureau of Mines publication. Gravel along the Yellowstone River, a source of agate for private collectors, could also be used as sand and gravel aggregate although material on the south bank of the river is closer to population centers and road systems. Clinker found in the study area could be a source of road metal, but is not well situated in relationship to areas of use. No geothermal resources have been identified although water suitable for direct heat applications may underlie the study area. All the area is leased for oil and gas exploration.

Jan 1, 1985

By T. E. Sterner

A laboratory investigation was conducted to determine the applicability of the thermal oil-recovery method as a means of increasing ultimate oil recovery in the Appalachian region. The primary objective was to establish self-sustained combustion in consolidated and unconsolidated sand test assemblies saturated with various amounts of Pennsylvania Grade crude oil and synthetic brine. Tests using blocks of sandstone were unsuccessful because of sealing problems and fracturing of the rock due to thermal stresses. A combustion wave of about 700° F was propagated through the sand-oil-water packs in the linear tube tests. The high air flux used resulted in high oil consumption and rapid movement of the combustion wave through the tubes. Analytical tests on the sand pack showed that sufficient fuel was deposited during the linear tube experiments for a self-sustained combustion wave.

Jan 1, 1967

By J. E. Tiffany, Z. C. Gaugler

"In presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 20 and 25 outlining the conditions in use under which, and only under which, the explosive or blasting device is permissible.In view of a recent publication recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 20 and condition 2 on page 25. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.PERMISSIBLE EXPLOSIVES TESTED UNDER SCHEDULE 17CAn active list of permissible explosives was published in October 1938 as part of Bureau of Mines Report of Investigations 3421, under the title ""Active List of Permissible Explosives and. Blasting Devices Approved Prior to June 30, 1938."" This list included 191 brand names.Changes in the list that have been authorized to June 30, 1939, placed 56 additional brands of permissible explosives on the active permissible list as a result of tests, changes in brand names, or transfer from the inactive list. Fifty-seven permissible explosives were transferred from the active to the inactive list. The brand names of four explosives were rescinded curing the year. The present list contains 18G brand names. The brand names of the Permissible explosives placed on the active list are as follows:"

Sep 1, 1939

By Leon W. Dupuy

"INTRODUCTION Scheelite occurring in tactite at the Black Rock tungsten mine, near Benton in Mono County, Calif., was investigated by the Bureau of Mines in cooperation with the Geological Survey as part of their search for additional sources of supply of strategic minerals authorized under the Strategic Materials Act. 3/4/The work accomplished by the Bureau, and the assays of samples taken are described in this manuscript. The ore found aided materially in prolonging the operating life of the mine during the recent national emergency, supplying much-needed tungsten for war use. ACKNOWLEDGMENTSIn its program of investigations of mineral deposits, the Bureau of Mines has as its primary objective the more efficient utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, under the direction of Lowell B. Moon, chief, conducts preliminary examinations, performs the actual development work, and prepares the final report. The Metallurgical Division, under the direction of C. C. Ralston, chief, analyzes samples and performs beneficiatibn tests."

Mar 1, 1948

By J. P. Coughlin

Gypsum plaster is calcium sulfate hemihydrate (CaS04-1/2H2O). There are two varieties, commonly designated as a and ß. The hydration setting) of this plaster involves the chemical reaction: CaS04?1/2H20(c) + 3/2H20(l) = CaSO4?2H20(c); that is, the hemihydrate combines with water to form the dihydrate. Many substances, when present as impurities, either in the hemihydrate or the water have influenced the rate of the hydration reaction. The objective of the Bureau of Mines work described in this report was to investigate the accelerating or retarding effects of small amounts of dissolved substances and to attempt to classify these effects upon a chemical basis. To eliminate competing effects, the work was conducted separately on the two varieties of hemihydrate; both were in highly pure form. (Commercial plasters usually are a mixture of the hemihydrates, with other substances present as impurities.) As the hydration reaction of each variety of hemihydrate evolves heat in amounts known from previous work, 5,6/ the authors decided to use calorimetric methods to follow the extent of the hydration reaction as a function of time. Two calorimetric methods were employed. One was designed to study the hydration reaction with a large water to plaster ratio and the other with a small water to plaster ratio (to simulate commercial practice in utilizing plaster).

Jan 1, 1959

By Michael D. Fenton

Detailed comprehensive assessment of the performance of Afghanistan's mineral industry during 1987 is virtually impossible, owing to the paucity of reliable published information. It was evident, however, that the level of civil disorder, now in its eighth year since the arrival of significant numbers of Soviet troops, was in actuality little removed from open civil war. Insurgents controlled substantial areas of the country and imperiled any industrial activity in many places. Assistance programs by the U.S.S.R. and other Eastern European nations were directed at developing the country's meager mineral industry, but the economy was generally viewed as chaotic. The inflation rate was somewhere between 20% and 30%; major food shortages contributed to the discontent of the population, and numerous villages were devastated by Soviet and Afghan Government campaigns to destroy the insurgents and cut their supply routes. Moreover, proposals by the Soviets and the Kabul Government aimed at reducing tensions with the rebels and scaling down the warfare seemingly were taken by the opposition as signs of weakening by the Soviet-backed Government, and rather than reducing aggressions, seemed to heighten insurrectionist activities. Efforts to entice the substantial number of Afghans who have fled to nearby areas of Pakistan and Iran to return to their country seemingly were failures, and indications near yearend that the Soviet Union might soon begin withdrawal of its occupation force of nearly 120,000 did little if any to reduce disorder.

Jan 1, 1989

By A. F. Colombo

Infrared spectroscopy employing attenuated total reflectance (ATR) techniques on thin films of dried gelatinized starch solution was used during Bureau of Mines research to determine the structural and impurity differences in starch products and to correlate these characteristics with the flotation response of a nonmagnetic taconite. All of the starch products evaluated gave spectrograms which were characteristic of the anhydroglucose monomer and its polymerization product. Distinct infrared absorption peaks caused by the protein molecule were observed and were used to classify the starches. Correlation of laboratory flotation of calcium-activated gangue from a Mesabi Range nonmagnetic taconite and infrared spectra produced from gelatinized starches showed that protein impurities and linear chain structure limited the effectiveness of starches as iron mineral depressants. Starch products having spectrograms similar to pure amylopectin were generally good depressants for iron oxides, were effective at about one-half the addition that was required for starches that gave infrared responses similar to pure amylose, and yielded acceptable iron concentrates containing 61.5 percent iron and 6.5 percent silica.

Jan 1, 1969

By Robert C. Gabler

The extraction of metals from coal ash was investigated by the Bureau of Mines in an effort to produce a more environmentally acceptable waste and offset waste disposal costs with recovered metal values. The research was conducted in two steps: determination of the parameters that affect extraction of metals from coal ash and development of extraction-recovery procedures. Data obtained indicate that the major parameter affecting the extraction of metals from coal ash is the calcium content of the ash. Other parameters such as furnace type and operating temperature had much smaller effects on metal extraction. Two procedures were studied for metal extraction: an acid leach procedure for high-calcium ashes and a lime sinter-acid leach procedure for low-calcium ashes. An alumina product was recovered that, with sufficient washing, meets Hall cell specifications. The leach residues pass the EPA EP Toxicity Test and are thus nonhazardous wastes available for a variety of uses.

Jan 1, 1983

By D. E. Hirsch

The types of compounds present in aromatic concentrates derived from high-boiling petroleum distillates can be estimated from a gel permeation chromato-graphic (GPC) analysis by the use of tables developed from extensive GPC and mass-spectral analyses on fractions from four crude oils. For a fraction from the GPC analysis, the retention volume and the molecular weights (from mass spectrometer) suffice to indicate the types of compounds which predominate. The tables which show these qualitative analyses were developed through the use of pure compounds as well as the extensive analyses on Prudhoe Bay (Alaska), Gach Saran (Iran), Swan Hills (Canada), and Wilmington (California) crude oils. These tables provide a rapid method for determining which types of compounds are present in a GPC fraction before attempting to develop quantitative data.

Jan 1, 1974

By James J. Olson

The Bureau of Mines recorded peak particle-velocity levels and vibration frequencies to determine the nature and intensity of ground vibrations for tunnel blast rounds at the NORAD Complex, Colorado Springs, Colo. Previous Bureau of Mines studies in quarries and underground mines had shown that scaling (dividing) the distance from the blast by the square root of the charge weight removed the effect of the various charge weights on vibration amplitudes. The analysis of variance tests performed on the NORAD vibration data, however, indicated that the cube rather than square root scaling exponent grouped the data more effectively. The empirical propagation equation, V = 560 (D/w1/3)-2.04, where V is the maximum peak particle velocity in inches per second, D is the distance from the blast in feet, and W is the zero-delay charge weight in pounds described the attenuation, with distance, of the particle velocities from the tunnel blasts in the Pikes Peak Granite of the NORAD Complex.

Jan 1, 1972

By F. N. Kissell

The Bureau of Mines used sulfur hexafluoride (SF6) tracer gas to evaluate the effectiveness of gob ventilation and/or sealing practices at three coal mines, each having different problems associated with their mined-out areas. The purpose of these ventilation studies was to better understand whether current techniques employed for ventilation or sealing are successful at minimizing the potential for gob fires and explosions. The work performed at each mine is discussed: One is a long-wall operation that uses ventilation to carry off hazardous gases, and two are room-and-pillar operations, each with far different concerns, that seal off the gobs to isolate them from the main mine ventilation. In all cases employment of the Bureau's SF6 tracer gas technique resulted in answers to questions raised by the mine operators concerning the effectiveness of their gob ventilation or sealing practices in preventing mine fires.

Jan 1, 1986

By G. S. Scott, G. W. Jones

"INTRODUCTION In the course of the investigation the Bureau of Mines is carrying on to determine the causes, behavior, a. control of mine fires, the detection of incipient heating underground in the mines and above ground in refuse banks has received consideration.Many of the anthracite fires have been active for years and have progressed considerable distances free their original source.Some of the fires are in inaccessible territory, and it is often impossible to determine with any degree of accuracy their exact location or even the veins of coal that are afire, especially when the fire is in the upper strata and when it is impossible to go underground because of flooded conditions or the presence of an irrespirable atmosphere.In such cases, the only means by which the trend of a fire may be ascertained (as a result of any fire-fighting methods that may have been employed) are the sampling, exanination, and interpretation of the gaseous products coming from the fire area. The most important information desired is to know whether the temperature in the heated area is increasing or decreasing and to determine whether a fire that has been sealed is cooling down to normal mine temperatures or is maintaining its heat or is increasing in intensity due to infiltration of outside air.Interpretation of the analyses of gaseous products from refuse banks on the surface also should be of value in combating such fires. Refuse bank fires, with the additional danger of starting an underground fire through ignition of the outcrop, are by no means unknown in the anthracite coal region, and the causes of such fires are not always apparent. In a few cases the causes have been strongly suggestive of spontaneous origin."

Jun 1, 1938

By Thomas A. Gray, Lynn M. Crayne, Michael A. Trevits, Phil Glogowski

Mine seals can be remotely constructed in underground coal mines, through vertical boreholes, when direct access to a fire is impossible or considered to be too dangerous. This method has great merit because boreholes can be drilled to specific mine areas and seals can be positioned close to a fire zone. The technology however, can be largely ineffective if the constructed seals do not provide effective barriers to airflow or cannot be used to impound water and other inert materials. Unfortunately, no viable alternatives exist to sealing the entire mine at the ground surface. Full-scale remote mine seal construction research is being conducted at the National Institute for Occupational Safety and Health’s (NIOSH) Lake Lynn Laboratory (LLL). Under this effort, Howard Concrete Pumping Company and GAI Consultants, Inc. have joined forces to evaluate a potentially significant improvement to the current state-of-the-art. This paper will cover development of novel technology for remote mine seal construction, evaluation of the materials used, construction practice, and follow-up testing.