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By S. D. Cramer

Corrosion research is being conducted by the Federal Bureau of Mines to determine suitable construction materials for geothermal resource recovery plants. As part of this research, the corrosion resistance of 31 iron-nickel-, aluminum-, copper-, titanium-, and molybdenum-base alloys was characterized and evaluated in laboratory corrosion studies in low-and high-salinity geobrines representative of those found in the Imperial Valley, Calif. General, crevice, pitting, weld, and stress corrosion were measured at 105° and 232° C in deaerated brines and brines containing dissolved 02, C02, and CH4 General corrosion rates in deaerated brines at 105° and 232° C were usually below 5 mpy for the alloys tested except carbon steel, the low-alloy steels, Monel 400, 70-30 cupronickel, and the aluminum-base alloys. Dissolving carbon dioxide and methane in the brines at 2320 did not markedly alter these results. However, the introduction of oxygen, which can enter the brine during process operations, seriously degraded the corrosion resistance of many alloys by increasing the incidence of stress corrosion cracking, crevice corrosion and, except for the titanium-base alloys, pitting. In deaerated brine at 2320 C, the general corrosion rates for carbon steel and the low-alloy steels were relatively unaffected by pH in the range of 6.1 to 3.0. However, general corrosion rates increased sharply below pH 3.0. In deaerated brine at 232° C, welds in several iron-, nickel-, and titanium-base alloys corroded at rates comparable to the general corrosion rates of the alloys, but the addition of oxygen to the brine increased corrosion rates for welds in Inconel 625 and E-Brite 26-1. Alloys exhibiting good corrosion resistance in the deaerated Salton Sea KGRA-type brine at 232° C were E-Brite 26-1, Inconel 625, Hastelloy S, Hastelloy G, Hastelloy C-276, TiCode-12, Ti-0.2Pd, Ti-2Ni, Ti-1.7W, and TZM. The alloys most resistant to corrosion in oxygenated Salton Sea KGRA-type brine at 232° C were the titanium-base alloys. These alloys appear the most suitable for use in the construction of geothermal resource recovery plants. Carbon steel and the low-alloy steels are unsatisfactory for high-temperature, high-salinity brines and alternative low-cost materials with improved corrosion resistance should be sought.

Jan 1, 1980

By T. T. Campbell

This investigation was undertaken by the Bureau of Mines to determine if high-purity ductile molybdenum of uniform quality can be prepared by bomb reduction techniques. Molybdenum trioxide (Mo03) and mixtures of molybdenum dioxide (Mo02) and trioxide were reduced by magnesium in closed steel bomb reactors. Very high pressures in excess of 5,000 p.s.i. developed during magnesium reductions of Mo03. The addition of calcium oxide to the bomb charges caused a significant reduction in pressure. Reaction efficiencies higher than 95 percent were obtained during magnesium reductions of either Mo03 or mixtures of Mo02 and Mo03, but high pressures were encountered when the charges contained from 30 to 60 percent Mo02. Reaction efficiencies were usually low (less than 80 percent) when the bomb charges contained more than 40 percent Mo02. The charges with the best composition considering operating pressure, yield, and purity contained from 10 to 30 percent Mo02. The addition of small amounts of carbon to the reaction charges was helpful because some deoxidation occurred during the reduction and also during subsequent arc-melting of the regulus metal. The purity of the bomb-reduced, arc-cast molybdenum metal ranged from 99.2 to 99.8 percent and in some instances the metal contained as little as 5 parts per million oxygen.

Jan 1, 1962

By Charles D. Wood

"Selected Topics,? in reviewing the control of emissions from diesel engine powered equipment used in underground mining, explores these fields of interest: hydrogen as fuel; lubricating oil as a source of particulates; applicability of stationary source scrubbers; worldwide diesel exhaust scrubbers; instrumentation technology for measurement of N02; control of emissions through application of sensors and microprocessors; use of fuel additives; technology transfer of marine diesel practice; technology required to use 4-stroke, aftercooled, turbocharged, direct injection engines; oxidation and reduction catalysts for diesel engine exhausts. "Selected Topics? makes recommendations for research and provides a bibliography and lists of references.

Jan 1, 1979

By K-H. Frohne

This report presents a study of the Cooper sand of the Fork Run pool of Warren and McKean Counties, Pa., and a prediction of the secondary oil recovery by gasflooding the reservoir. A computer program employing a modification of the Craig, Geffen, and Morse secondary recovery calculation was used to make the gas flood performance forecast and is presented in the appendix. The Cooper sand reservoir in the Fork Run pool lies at a depth of about 1,900 feet and covers an area 1/2 mile wide by 2-1/4 miles long. Original oil in place is estimated to have been 8,266,000 STB. The primary recovery mechanism is solution gas drive, and ultimate primary recovery may reach 20 percent over a well life of 90 years. Two computer predictions were made for gas flooding the Cooper reservoir. The first was for a 25-acre pilot five-spot utilizing existing wells, but project economics were poor since only 25 percent of injection gas is utilized for pilot oil recovery. Recovery was 71,000 STB, or 22 percent of oil in place at flood initiation, but required 25,700 scf gas injected per STB of oil recovered. In the second prediction, pilot area performance was projected for the entire Fork Run pool, and economics became good. Recovery was 1,753,000 STB from 25 five-spots after the injection of only 6,400 scf per STB of oil recovered.

Jan 1, 1969

By Louis P. Domingues

As part of a study on high-temperature ceramic materials, the ammonium sulfate, carbonate, nitrate, oxalate, and sulfate salts of yttrium, lanthanum, and cerium were analyzed thermogravimetrically. The temperature ranged from room temperature to 1,500° C. Each salt was decomposed by heating at a rate of 2.5° C. per minute, and some of the salts were subjected to additional rates of 5° C. per minute or 10° C. per minute. The decomposition sequences have been identified, and the temperatures of formation of intermediate compounds and of the oxides have been determined. The minimum oxide formation temperature of a given lanthanum salt exceeds that for the similar salt of yttrium, and both exceed that for the same salt of cerium except for one cerium carbonate. Variation of the heating rate indicates a thermal lag in the materials and produces the shift of formation temperatures to higher values and loss of resolution in the weight-loss distribution as the heating rate increases.

Jan 1, 1962

By John H. Johnson

This report covers research which is directed toward the measurement and control of underground mine diesel emissions. The report consists of three separate reports presented as Sections 1, 2, and 3. Section 1 "Emissions Measurement Apparatus" (EMA 1) discusses the selection and evaluation of instruments and procedures to be used as part of a diesel tailpipe emissions dilution and measurement apparatus. The instruments selected for gaseous pollutants are the Energetics Science Inc.* E.S.I.) 2000 for CO, the E.S.I. 7000 for NO and N02, and the Fuji ZFP5 for C02. Particulate matter is presently measured with the Celesco 1013 Smoke Opacity Meter. The raw exhaust concentration of one of these constituents is used Lo calculate the dilution ratio. Either a modified high range E.S.I. 2000 CO instrument or a Daco Products Cobra C02 instrument can be used, but neither is totally satisfactory. The study also indicated that it may he possible to increase the sample collection time from 15 seconds to the total 30 seconds over which the engine can be loaded without increasing the probability of damaging the vehicle hydraulic systems. Section 2 "The Effect of Fuels, Catalysts and a Filter Trap on Drift Pollutant Concentrations" discusses research in the Mine Air Quality Laboratory. A Wagner ST5D LHD with a Deutz F8L714 engine was used to compare three exhaust aftertreatment devices and a muffler-only system. The effect of these four systems on CO, C02, NO and N02 and on total, soluble, sulfate, and solid particulate matter was measured in the drift and on the LHD. The filter trap successfully reduced particulate matter for both fuels without significantly increasing the concentrations of any of the other constituents. The PTX catalyst was effective in reducing CO, and soluble particulate, but significantly increased N02 and solid and sulfate particulate matter. The Oxy Cat catalyst tested didn't seem to he working on the gases, and it significantly increased sulfate, soluble arid solid particulate concentrations. Section 3 "Diesel/Coal Particulate Matter Characterization by Laser Raman Spectroscopy" covers basic research on a method for determining the percentage by weight of diesel particulate on a filter containing a diesel-coal mixture. Signal-averaged Raman spectra provide the necessary precision. The method developed is non-destructive and uses as-received filters requiring no sample manipulation. Particulate with diesel contents in the range of 10 to 50% by weight have been analyzed with accuracies better than 6%t of the mean value. A number of samples containing diesel-coal mixtures were characterized by the procedures developed and the results are analyzed in light of various spectral and other system variables including coal rank and form and diesel engine operating conditions.

Jan 1, 1982

The Appalachian Mountains divide Pennsylvania into two distinct coal regions, bituminous and anthracite. The western region of the the state, where the majority of bituminous mines are located, is characterized by mountains and gently rolling hills. Bituminous coal seams underlie about 12,000 square miles in 28 counties. The anthracite coal region, located in the northeast, covers approximately 3,300 square miles. This area contains more than 20 different coal beds that vary in thickness from a few inches to 50 or 60 feet. The anthracite region is characterized by steeply pitching seams that require highly specialized mining techniques and present unique challenges for solving problems such as the mine subsidence associated with abandoned underground anthracite mines. For more than a century, coal has played a major role in the economic and industrial development of Pennsylvania, particularly the steel industry. Estimated bituminous reserves total 23 billion tons, or 5.3 percent of U.S. reserves, and anthracite reserves total 7.1 billion tons, or 97 percent of U.S. anthracite reserves. Pennsylvania received conditional approval of its regulatory program July 31, 1982. Pennsylvania's Abandoned Mine Land Program was approved on the same date.

Jan 1, 1992

From the time of its establishment in 1910, the Federal Bureau of Nines has studied the carbonization of coal, and a considerable part of this effort has been devoted to investigations in the so-called low-temperature carbonization range, 450° to 700° C., in which there is minimum decomposition of primary products and maximum yield of Liquids - a yield two to threefold the amount produced in high-temperature carbonization at 900° to 1,200° C, The solid residue, char, or coke, produced in low-temperature carbonization is 70 to 80 percent of the coal charged and may be used directly as a smokeless fuel or for blending with coals to produce metallurgical coke, Although some thought was given to the use of tar and to the illuminating value of gas derived from lm-temperature carbonization, the main emphasis in early work of the Bureau of Mines was on the preparation of smokeless fuel, especially for home use, For example, a carbonizer was designed and operated for making char and briquets from North Dakota lignite without recovery of by- products; however, the shortage of high-temperature coal-tar products in the United States during World War I had already indicated the potential usefulness of low-temperature tar.

Jan 1, 1959

By Fred Leighton

The Bureau of Mines has developed rock noise source location techniques that may be used to obtain precise and practical source locations from micro-seismic field data. These techniques enable one to monitor all or any part of a rock structure and map progressive stress buildup or rock movement. Thus, the microseismic method of determining instability in rock structures is becoming an invaluable engineering tool for the mining or civil engineer engaged in rock excavation and construction.

Jan 1, 1970

By Terry R. Neumann

In 1989, the Bureau of Mines conducted a mineral resource investigation of the 52,350-acre Jersey Jack study area, located in the Clearwater Mountains of north-central Idaho. Twenty-eight mines and prospects were examined, and 483 rock, placer, and petrographic samples were collected during the field study. Two properties contain gold resources; mining company data show the Robinson Dike mine contains an estimated 940,000 tons of "drill proven and probable reserves" averaging 0.041 oz/ton gold, and the Bureau of Mines investigation showed the Blacksand placer mine contains an estimated 64,000 cubic yards of identified placer resources averaging $8.13 in gold per cubic yard. Sample analyses from other properties indicate that gold resources are likely to exist; however the low tonnage, narrow, fissure-vein type deposits would require mining by relatively high-cost underground methods and would be subeconomic at a gold price of $400/oz.

Jan 1, 1991

By Mark Sanders

This report compares a proposed 10/60 "piggyback" 02 generating self-rescue unit to the standard CO self-rescue unit with respect to work task interference. A simulated low seam coal mine was constructed and subjects performed locomotion, shoveling, cart pushing, and timbering tasks with the 10/60 or self-rescuer attached to their belts. Task completion time was longer on all tasks when wearing the 10/60 unit, although only locomotion was statistically significant. The 10/60 unit was bumped over 100% more often than the standard self-rescuer. Implications for design of the proposed 10/60 container are: 1) unit?s container must be extra durable to withstand the added abuse it is likely to receive by low coal miners; and 2) extra consideration must be given to preventing the device from slipping on the belt while working, especially in low coal.

Jan 1, 1980

By Donald O. Capstick

A mineral survey of the approximately 144,000-acre Borah Peak study area was conducted by the U.S. Bureau of Mines in 1985 at the request of the U.S. Forest Service. The area studied included the Borah Peak RARE II roadless areas (No. 14210, 119,864 acres of land recommended for wilderness designation; and No. X4210, 18,440 acres of land recommended as non-wilderness) and other contiguous Forest Service administered land. The study area is in Challis National Forest in southeast Idaho about 30 miles south-southeast of Challis, ID. Burnt Creek, a conterminous study area to the northeast, on lands administered by the U.S. Bureau of Land Managment, was examined concurrently. Dolomite and limestone inferred reserve bases exceed 1 billion tons each within the Borah Peak study area. The material is widespread and of high quality. Extensive sampling and more detailed mapping are required to better define the resources; however, ample dolomite and limestone occur nearby, outside the study area. Dolomite is the main constituent of several geologic formations within the study area. Sample analyses indicate that the more than 1,000-ft-thick Jefferson Formation dolomite is the most pure and is equivalent to material being mined at a dolomite-to-magnesium processing plant near Addy, WA. Analyses from limestone-bearing formations underlying much of the study area indicate that large quantities of the limestone may be suitable for a variety of uses.

Jan 1, 1987

By Thomas E. Finch

This report is a continuation and expansion of a previous USBM grant (No. G0254004) which examined alternative methods of handling the parting between two coal seams in a surface mining operation. The alternative methods consist of equipment implementation in either a stowing or haulback technique. Following a typical strip mine conformation, the parting is directly stowed or hauled back and placed in the pit bottom after second seam removal. The objectives are to produce an environmentally sound material placement technique and to increase prime stripping machine utilization. This report contains the engineering philosophy behind two computer programs created to evaluate parting handling methods over d wide range of coal and parting thickness ratios. The nature of the computer approach allows cost sensitivity analysis and quick updating of costs. The two programs are clearly presented with documentation and examples such that consumers may apply then to their own operations.

Jan 1, 1977

By Duane L. Abata

Toxic gases produced by the detonation of six explosives were measured in an underground hardrock metal mine during actual mining operations. The six explosives included two semi-gelatin dynamites, three slurry explosives and an ammonium-nitrate, fuel-oil/ammonia dynamite combination. Explosives were detonated at the face of a drift and the toxic gases produced by the detonation were trapped to the end of the drift by a bulkhead located a short distance away from the face. Toxic gas concentrations were then measured with direct readout instruments and together with the containment volume, the toxic gas volumes per mass of explosive were calculated. Toxic gas measurements were found in the following ranges (ft3/lbm): N02 0.010-0.035; N02, 0.003-0.019; CO, 0.08-0.30; S02, 0.00-0.05; and C02, 0.7-1.8. Results showed that toxic gas production (ft3/lbm) correlated with the densities (kg/m3) and energy densities (kJ/kg) of the explosives tested.

Jan 1, 1978

By G. E. McElroy

As one phase of a general program of enthracite mine-fire research initiated by the Bureau of Mines in September 1935, a study of the records of past fires was considered a necessary approach to a proper understanding of present and future fires because only limited information could be obtained directly from existing active fires on account of their inaccessibility. Through the courtesy of interested operators, all available records of fires that had occurred in a large group of steep-pitch anthracite mines in the Western Middle and Southern fields of the Pennsylvania anthracite district were examined and analyzed for data on the causes, costs, behavior, and control of fires, and this report is primarily a discussion of these factors based on a close study of these particular records. Mining Conditions The records pertain to a group of mines that have contributed about 12 percent of the total Pennsylvania anthracite production and constitute a large proportion of, and well represent, steep-pitch operations in this district. Throughout the area represented, the coal occurs as a series of up to 20 parallel seams in folded slate and sandstone strata and almost entirely on pitches of 400 to 80°, with vein thicknesses of 5 to 60 feet. Practically all are old mines with histories dating back to 1850, or thereabouts, and present operations are either under or adjacent to mined-out areas extending to surface or to the saddles of anticlines. All operations are at relatively shallow depths, that is, within 1,000 feet, vertically, of the surface. Mining methods are largely a heritage of the past and embrace typical breast and pillar operations with practically no mechanized mining and with the coal shot ?off the solid.? Most of the mines are rated as gassy and are operated now on a closed-light basis. Permissible explosives are now used entirely for breaking coal, and dynamites for rock work and chute-starting blasting.

Jan 1, 1938

By Stephen D. Smith

The following tables summarize data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in these tables is what is termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines. Because of inadequacies in the statistics available, some series deviate from the foregoing definition. For copper, gold, lead, silver, tin, and zinc, the quantities are recorded on a mine basis (as the recoverable content of ore sold or treated). However, the values assigned to these quantities are based on the average selling price of refined metal, not the mine value. Mercury is measured as recovered metal and valued at the average New York price for the metal. The values shown are in current dollars, with no adjustments made to compensate for changes in the purchasing power of the dollar.

Jan 1, 1995

By P. L. Swanson, F. M. Boler

The U.S. Bureau of Mimes conducts research at the Galena Mine, Wallace, ID, with the aim of mitigating the effects of rock bursting. Destress blasting is commonly used as a stress control technique at the mine. A digital seismic array and an array of borehole pressure cells (BPC's) had been installed near the site of a stope undergoing mining and periodic destressing. The instrumentation was being monitored at the time of a destress blast of the 46-99 stope. No significant seismic events occurred coincident with the destress. However, the destress was followed by a 21/2-week period of increased seismic activity, including two damaging events on February 7, 1990, at 034500 (hour, minute, and second) and 122020 Pacific standard time. BPC measurements indicated coseismic ground pressure changes on the order of 200 to 300 kPa associated with the damaging events. Fault plane solutions and dislocation models established that stress changes induced by the event at 034500 may have been significant in promoting the occurrence of the event at 122020. Theoretical investigations suggest that applying knowledge of the existing stress field, an understanding of rock burst mechanics, and fracture mechanics principles can improve destress effectiveness.

Jan 1, 1993

By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip core lion (method 530.22), color (method 10.11), sulphur content (method 520.11) evaporation residue (method 530.1), and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and tax will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation. It has been the feeling of some investigators that the practice, followed in previous semiannual surveys, of grouping all types of motor fuel together without discriminating between "competitive price gasoline," benzol blends, Ethyl gasoline, "high-test" fuels, etc., has detracted from their usefulness because the data did not permit drawing conclusions in regard to any one type of fuel, and tended to obscure differences between fuels of the various types. Therefore, in order to remedy this condition, the samples of the present survey have been divided into two groups; one called "competitive-price gasoline" and a second group called "premium-price motor fuels."

Jan 1, 1930

By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip corrosion (method 530.22),5 color (method 10.11),6 sulphur content (method 520.11) copper-dish evaporation residue (method 520.11),7 and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and try will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation.

Jan 1, 1930

The following report summarizes the results of engineering feasibility studies whose purpose was to assess the probable efficiency, reliability, safety and cost of a number of possible methods for removal of radon gas from the ambient air in underground mines. Fourteen candidate techniques were evaluated. Seven of these were based on specific individual principles, and seven were based on combinations of these principles. The individual principles were as follows: 1. Activated charcoal 2. Organic fluids 3. Semipermeable membranes 4. Molecular sieves 4. Cryogenics 6. Chemical reaction 7. Centrifuge The combinations were: 8. Cryogenics and activated charcoal 9. Cryogenics and molecular sieves 10. Cryogenics and chemical reactions 11. Membrane filters and organic fluids 12. Membrane filters, cryogenics and activated charcoal 13. Membrane filters and chemical reactions 14. Silica and an Organic Fluid

Jan 1, 1975