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By T. J. Chen

Vanadium-beard bone coal is one of important vanadium resources in China.To extract vanadium tailings from Stone coal is produced after extracted vanadium from stone coal through the roasting, leaching and other processes. About 120-150 tons of tailings will be produced in extracting 1 ton of vanadium pentoxide. A lot of tailings that are willfully piled up have caused serious environmental pollution and wasting of resources; it is therefore necessary to realize its resource utilization. This study increases the activity of vanadium tailings by means of alkali fusion, and then uses different alkali activators to react with vanadium tailings so that geopolymer with high value added is produced. Sample of geopolymer is acquired from a mixture containing vanadium tailings, alkali activators, water and a little sodium aluminate through compression-molding process under 20MPa pressure. After cured in room temperature for three days, the maximum compressive strength of the sample can reach 36.2MPa. XRD analysis indicates quartz, the major crystal phase in vanadium tailings is decomposed,and the activity of vanadium tailings is heightened. FTIR and SEM analyses show: structural change having an important impact on the mechanical strength of geopolymer occurred during the process of vanadium tailings generating geopolymer.

Sep 1, 2012

By Xing Yang, Zhen Peng, Guangwen Zhang, Haifeng Wang, Yaqun He

"Triboelectric separation of ilmenite ore based on the tribocharge differences between ilmenite and gangue minerals was conducted in this study. Triboelectric characteristics of ilmenite and its associated minerals were studied using polyvinyl chloride (PVC), pentatricopeptide repeats (PPR), copper, polymethyl methacrylate (PMMA), stainless steel (SS), teflon and quartz glass (QG) tribochargers in lab triboelectric unit. Results demonstrated that the ilmenite particles tribocharged positively while gangue minerals tribocharged negatively using PVC as tribocharger. The particle size also has a significant effect on tribocharge, and the -0.125+0.074 mm is the optimal size fraction of triboelectric separation. Charge-mass ratios of minerals increase with the increases of tribocharging length, but the increasing rate gradually reduce. At 1.5 m tribocharging length, charge-mass ratios of ilmenite, quartz, feldspar and mica are up to 6.07 nC/g, -6.05 nC/g, -4.30 nC/g and -4.56 nC/g, respectively. Based on the triboelectric characteristics of each mineral, triboelectric separation of ilmenite was conducted, and the grade of ilmenite ore increased from 15.47% to 28.40%. INTRODUCTION As a transition metal titanium plays an irreplaceable role in medical, aerospace and materials due to its light weight, high strength and corrosion resistance. Pure titanium dioxide is an excellent white pigment and is widely applied in industries of paint and textile. Ilmenite is the main raw material for titanium industry. For the beneficiation of ilmenite, series methods have been proposed, such as the application of dry magnetic and wet gravity separations to separate the ilmenite from the zircon and rutile. Electrostatic separation is extensively used in the beneficiation of heavy mineral sands for the recovery of rutile, zircon and ilmenite while flotation is used to separate fine ilmenite (Mehdilo et al., 2014; Fan et al., 2014). Compared with flotation and gravity separation, electrostatic separation does not consume water, and native properties of materials will not be changed and energy consumption will be reduced (Wang et al., 2014). Thus, the wide application of electrostatic separation and other dry separation methods is a trend in separation and purification industry, especially in water-scarce areas."

Jan 1, 2018

By J. Leite

In a small-scale mining in Brazil?s northeast, scheelite were exploited since 1940?s using a traditional gravity concentration flowchart (composed by jigs and shacking tables) that operates with low efficient for fine particles. Tailing of this plant was submitted to chemical, mineralogical and size characterization. Results pointed 50% smaller than 74µm with a grade of 0.11% WO3. The particle?s size is an important operational variable to heighten recuperation by shacking tables. Tests using Falcon SB40 centrifuge concentrators and shacking table were realized, optimizing their operational variables. Based on the tests results a new flowchart was proposed for concentrating and tailings recovery.

Sep 1, 2012

By I. Zh. Bunin, G. K. Khachatryan, N. E. Anashkina

For optimization of diamond processing technology the influence of nanosecond high voltage pulses on mechanical and technological properties of diamond crystals and kimberlite rock-forming minerals (calcite, olivine, serpentine) was investigated. Using methods of Fourier Transform Infrared Spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), microscopy and mikrohardness measurement the changes of structural, physic-chemical surface properties, and microhardness of minerals as the result of impacts, was studied. Non-thermal impacts caused a decrease of kimberlite rock-forming minerals microhardness in general to 40-66% as the result of surface microstructure destruction which is caused by formation of micro cracks, traces of surface breakdown and other defects. At the same time, the pulse energy impact on natural diamonds led to formation of B2 type crystal lattice microsift defects, elevated concentration of which increases the hardness properties of crystals. The obtained result indicates possibility of applying pulsed energy effects to improve the softening efficiency of diamond-bearing kimberlites rock-forming minerals without damaging the diamond crystals and ensuring their preservation by the subsequent grinding of ores. By IR and X-ray photoelectron spectroscopy revealed that processing by hight voltage pulses causes a change of natural and synthetic diamonds surface functional cover composition. Short-term exposure (~ 10 - 30) leads to detachment and partial destruction of secondary phases mineral films on the surface of natural technical diamonds, increasing floatability and hydrophobicity of crystals. However, with increasing duration of treatment (~ 30 - 150) occurs surface hydroxylation (found by XPS for synthetic diamonds), as a result of diamond surface layer oxidation. The effect of increasing the natural diamonds flotation activity by 14% (from 47% to 61%) was experimentally established as a result of processing diamond crystals with nanosecond pulses (~ 10-50 sec), which indicates the principal possibility of using pulsed energy impacts to intensify the diamond flotation during processing diamond-bearing kimberlites.

Jan 1, 2018

By C. R. Mambote

One of the processes developed for vanadium recovery from the fly ash of crude oil is through acid leaching. In the process, iron is one of the impurities that should be removed before vanadium precipitation, due to the fact that iron tends to co-precipitate with vanadium. The mechanism of iron precipitation is understood in terms of ferric hydrolysis, followed by the dimerization and subsequent polymerization of the crystalline iron compound. In order to develop a new approach for the fly ash processing, in the present paper the precipitation of iron from the liquor after the leaching process was studied with addition of NaOH or NH4OH in the presence of H2O2 or Na2C2O4 at 80°C. The objective was to investigate the feasibility of the selective precipitation which could be applied to vanadium and nickel recovery from the fly ash. The experimental results show the difficulties of removing iron by precipitation without co-precipitating nickel and vanadium.

Jan 1, 2014

By J. Drzymala

Ores and raw materials are subjected to mineral processing operations to increase the content of their useful components. Upgrading of these materials can proceed with different selectivity and therefore, there is a need to know and monitor the separation results of the process. The separation results can be evaluated using tables and graphs called upgrading curves. The course of lines in the upgrading curves is usually complex and depends on the graph type and process parameters. The Halbich grade vs. recovery plot is frequently used because is practical and it indicates several characteristic features of separation results. Separations by means of flotation of several different shale, dolomite and sandstone copper ores were performed along with determination of their mineral composition, copper content, liberation degree, and the maximum theoretical copper content in the first concentrate. These data, plotted as the Halbich upgrading curves, allowed to find other characteristic points such as practical maximum copper content in the first concentrate, maximum curvature coexisting with the liberation degree, maximum recovery of ore valuable components, and the slope the recovery-grade line at high recoveries as a measure of liberation. Correlations between theoretical and practical maximum copper contents in the first concentrate as well liberation degree and maximum curvature were also presented. They show that the ore type significantly influences the shape of the Halbich curve and its characteristic points.

Sep 1, 2012

By F. Q. Cheng

As the important potash, the product yield of KCl in winter is low and the resources waste is serious according to the deficiency of collectors, which can be used in this condition currently. This paper studied on the change of contact angle, turbidity, and flotation recovery of KCl particles when different chain lengths, ratios of amines were used as collectors in KCl flotation process to get a new mixed collector. The contact angle values of KCl crystal in its brine solution added different amine collectors were first measured by captive bubble method. The turbidity of brine solutions were then measured by the laboratory turbidimeter at room temperature when different amine collectors were contained. In the end micro-flotation experiment using mixed amine with fixed ratios and ODA as collectors respectively at 5 °C, 23 °C were performed. The results show when the ratio of the mixed amine is DDA- 20%, ODA-60%, C20-20%, the contact angle at KCl surface is the maximum and the hydrophobic state is best. Meanwhile the result of turbidity measurement indicates that the dispersion of mixed amine colloids is better than the ODA collector due to the addition of DDA, which plays the role of frother. The flotation results also prove that the mixed amine is not only fit for the KCl flotation at room temperature but also fit for its flotation at low temperature. This study provides strong technical support to extend the production time of potash business in Chaerhan areas in China.

Sep 1, 2012

By A. N. Zagorodnyaya, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva, A. S. Sharipova

"In Kazakhstan, there is a unique sulphide copper deposit, in the ores containing the natural isotope of osmium-187 (more than 90 %). In the pyrometallurgical processing of concentrates for the target metal, osmium is mainly sublimated, with wet cleaning of metallurgical gases (dust and gas mixture) 40 % of it together with rhenium passes into washing solutions (wash acid). On the basis of this acid, the production of ammonium perrhenate was organized at the enterprise of the RSE ""Zhezkazganredmet"" and for the first time in the world practice - the isotope of osmium-187. However, the degree of its recovery from solutions does not exceed 8 % of the amount supplied with the charge or 25 % of the amount that was received for extraction. But the bulk of it (~ 75 %) remains in the raffinate, discharged to sewage treatment plants (wastewater). The studies presented in this work are aimed at solving the problem of osmium isotope-187 extracting from wastewater, which are a potential source of increasing metal production in Kazakhstan. The aim of this work is the development and scientific justification of osmium deposition regimes from wastewater using such reagents as thiosulfate and sodium sulphide. The influence of various physicochemical factors on the precipitation of the osmium was studied and optimal conditions for its maximum transition to sediment were chosen. An original method for obtaining osmium concentrate in the presence of sodium thiosulfate with the addition of potassium iodide from a new type of wastewater - man-made ammonia solutions has been developed. These solutions were combined mother liquors of solid-phase stripping operations and dissolution of pulp of crude ammonium perrhenate. On the basis of the obtained results, a settling technology for extraction of the osmium from man-made ammonia rhenium-containing solutions was introduced at RSE ""Zhezkazganredmet"". It should be noted that the degree of extraction of osmium, depending on its concentration in solutions entering on the settlement, and taking into account the addition of sulfuric acid, will vary from 60 to 90 %. The recovery of osmium during the test period was 58 %."

Jan 1, 2018

By O. N. Mohanty, S. Mohan Rao, N. D. Rao, T. Mukherjee, P. V. T. Rao

"Chromite ore is an indispensable raw material in the manufacture of ferro-chrome and charge-chrome, which are used for the production of stainless and other alloy steels. The demand for chromite ore is ever increasing because of increasing consumption of these steels. Keeping this in view, Tata Steel is keen to recover values from fines and wastes, and also to produce value added products from their captive chromite mines and its processing plants.Tata Steel has its captive chromite resources at Sukinda, Orissa. They contain two ore types, i.e. (i) Ferruginous and (ii) Siliceous. The generation of off-grade ores is an increasing trend and simultaneously customer quality requirements are becoming ever more stringent. The ferruginous type ore also contains a considerable quantity of in-situ fines (~20% particles below 0.5 mm) that compound the beneficiation problem.In many places, in India and abroad, mined non-marketable off-grade and low grade chromite ores are upgraded by using either simple classification techniques like screw classification, hydrosizing, hydrocycloning or conventional gravity concentration processes such as Heavy media separation, Jigging, Spiraling, Tabling etc.At Tata Steel, the ferruginous type ores are treated in Chrome Ore Beneficiation (COB) Plant that comprises: a crushing and grinding circuit; a classification circuit using hydrocyclones; and a beneficiation circuit using 4 stage spirals in the coarse circuit (-0.5+0.1 mm) and 3 stage spirals & tables in the fine circuit (-0.1+0.038 mm). In this process, 3 types of tailings are being generated and together analyses about 17 % Cr2O3, which is high. From the present operation the chromite recovery is around 70% and could not produce coarse concentrates (+0.5 mm size). Whereas the siliceous type ore is treated in the Lumpy Ore Processing (LOP) plant, consisting of crushing-washing & classification-hand sorting operations, to produce marketable grade lumpy ore and –10 mm de-slimed fines. These fines are intermittently treated in the COB plant. The higher silica content (greater than 1%) and low Cr/Fe ratio (less than 2.8) are the problems with these concentrates."

Jan 1, 2003

By A. N. Zagorodnyaya, T. N. Bukurov, Z. S. Abisheva, A. S. Sharipova

"This work presents the results of the development of a flowchart for the processing of copper production dusts resulting in the production of of lead sulphate, tribasic lead sulfate (TBLS), ammonium perrhenate, zinc, copper-cadmium cake.Dust having the following composition (wt. %): Pb 39.3, Zn 6.5, Cu 5.5, Stotal 10.8, As 1.05, SiO2 0.6, Cd 0.8, Bi 0.04, Ag 0.02, Re 0.03 was used in the work. Chemical and X-ray analyses indicated that lead, zinc and copper are generally present in dusts in the form of sulfates, various amounts of oxides, sulfides, silicates; sulfur (according to chemical analysis data) is present in the form of sulfates (~ 90%) and in the form of sulfides (~ 10%).Studies have been made on two-stage stripping of copper production dusts containing lead, zinc, copper, cadmium, rhenium in the form of various compounds, at first with soda solution, then with nitric acid solution. It has been indicated that the combination of the operations allows the recovery of 98% rhenium, 82% lead, 92% copper, and 96% zinc and cadmium each in the solution. Furthermore, at the stage of dust leaching with soda, 80% of rhenium and 0.01% of nonferrous metals each are recovered in the solution. Remaining quantities of all metals are recovered in nitric acid solution up to maximum values. Such behaviour of metals is caused by metal phase content in dusts and properties being formed during leaching of compounds. At the stage of dust leaching with soda solutions, carbonates with various compositions are formed due to the exchange reaction between nonferrous metal sulfates and sodium carbonate. The conversion of PbSO4 into PbCO3 is apparently occurs in the solid phase and the conversion of readily watersoluble zinc, copper, and cadmium sulfates into that of carbonate salts occurs in the liquid phase. Rhenium passes into solution due to the presence of rhenium greater quantity in dust in the form of readily soluble perrhenate. Some portion of the perrhenate is, probable, blocked by lead sulfate and liberated in the conversion of PbSO4 into PbCO3."

Jan 1, 2003

By C. R. Mambote

Vanadium is an important metal that is used mainly in ferrous and non-ferrous alloys due to the high tensile strength, hardness, fatigue resistance and corrosion resistance. Vanadium consumption in the steel industry represents about 85% of the vanadium-bearing products produced worldwide. The primary sources of the metal are patronite, roscoelite, and mottramite. Vanadium has also been produced as a by-product of the uranium production program which uses carnotite ores as a source of uranium. Vanadiferous magnetite iron ores are used for producing vanadium as well. In addition, it is known that vanadium can be recovered from the ashes of crude oil and petroleum coke. The process for treating boiler residues, fly ash and petroleum coke is similar to the process used to treat spent catalysts and ores. However, some of these materials may contain high carbon that must be removed at specific stage of the operation. Several processes are available for obtaining vanadium from fly ash, such as roasting vanadium bearing materials in the presence of sodium salt. The salt roasted calcine is subsequently leached with an alkaline or acidic solution. To obtain a cal-cine from which the vanadium can subsequently be recovered, the carbon in the source materials has to be eliminated prior to the roasting process. Other processes use the conventional hydrometallurgical route, in which fly ash is leached with sulphuric acid to obtain an impure vanadium pentoxide. The impure vanadium pentoxide is then treated with a sodium carbonate solution under atmospheric conditions to subsequently precipitate vanadium as ammonium metavanadate. Actually, the salt roasting process is the only process used commercially. In the present study, the progress in the technology of vanadium extraction from secondary materials is reviewed. The perspectives and the challenges for new process development are discussed.

Jan 1, 2014

Pyrite and Chalcocite have different crystal lattice, with different dissolution rate in the same ac-id solution, the dissolution rate of which is accelerated with increasing redox potential, they are leached simultaneously at high redox. In present work, some methods are adopted to inhibition the bioleaching of the pyrite by controlling the redox potential. Shake flask experiment shows that the dissolution of pyrite and chalcocite is slow as redox potential <700mV(Eh), but the dissolution in-creases exponentially as redox potential>800mV(Eh), they have good selectivity at redox potential between 700mV and 760mV(Eh).

Jan 1, 2014

By S. Banisi, E. Arghavani, Gh. Parsapour, S. Mousavi

Maximization of water recovery in thickeners is an essential step in the mineral processing industries. The Gol-E-Gohar iorn ore processing plant uses a center pier thickener with a diameter of 38 m and depth of 4 m. The feed rate is 50 t/h solids with a concentration of 5% (w/w), and it has been designed to provide an underflow containing 50% solids. The performance of the thickener was not as expected judged by the overflow stream containing 0.6% solids and water loss of 52 m3/h in the underflow. A criterion called the index of flocculation incorporating the perimeter-based fractal dimension of flocs, floc size, and settling velocities was proposed and used to determine the optimum flocculant dosage which was found to be 20 g/t. The fractal dimension of flocs in a pulp containing 5% solids was found to be between 1.16 (no flocculant) and 1.56 (40 g/t flocculant) which indicated highly branched and loosely bound structures for the flocs as flocculant dosage increased. At these conditions, the size of the flocs which was recorded by a digital microscope increased from 93 µm to 403 µm. A new feedwell with a special design with the aim of preventing flocs breakage and maximizing energy dissipation of pulp was constructed and installed. These modifications led to an increase in the thickener drivehead torque from 5% to 18% of the rated torque, indicating a higher bed depth. Finally, installation of a PID controller reduced the drivehead torque relative oscillation from 52.0% to 12.7%. These changes increased the solids concentration of the underflow from 49.0% to 56.9%, decreased the overflow solids concentration from 0.6 % to values smaller than 0.01% and resulted in a reduction of 27% in water loss in the thickener underflow.

Jan 1, 2014

By M. Maldonado

A flotation bank is a serial arrangement of cells. How to optimally operate a bank remains a challenge. This article reviews three reported strategies: air profiling, mass-pull (froth velocity) profiling and Peak Air Recovery (PAR) profiling. These are all ways of manipulating the recovery profile down a bank, which may be the property being exploited. Mathematical analysis has shown that a flat cell-by-cell recovery profile maximizes the separation of two floatable minerals for a given target bank recovery when the relative floatability is constant down the bank. Available bank survey data are analyzed with respect to recovery profiling. Possible variations on recovery profile to minimize entrainment are discussed.

Sep 1, 2012

By T. Wajima

We tried to convert paper sludge ash (PSA) into zeolitic product with high cation exchange capacity (CEC) through acid leaching. Typically, PSA from incineration of paper sludge contains a high percentage of calcium in the form of anorthite (CaAl2Si2O8) and gehlenite (Ca2Al2SiO7). It is difficult to convert the ash with a high Ca content into zeolites, or at least into more desirable zeolite phases. Acid leaching with HCl was applied to reduce the Ca content to synthesize zeolitic product with high CEC. The raw ash was treated with 1 M, 3 M, and 5 M HCl solution for 0.5~24 hours (the ratio of the ash to volume of HCl solution was 1/4), and then zeolitic product was synthesized from leached ash through the reaction with 2.5 M NaOH solution at 80 oC for 24 hours. During acid leaching, gehlenite is readily dissolved in a lower HCl concentration solution than anorthite. With increasing HCl concentration, the amounts of Ca, Mg, Si, Al, Fe and Ti extracted from the ash increased. Ca and Mg contents were easily extracted from ash than other elements. The contents of Ca and Mg extracted rapidly at initial stage, and then levelled off. The saturation times of Mg and Ca are almost 0.5 h using all concentrations of HCl solutions. After the synthesis from leached ashes, zeolite-A and -P were synthesized from ash leached in 1 M HCl solution, and 3 M and 5 M HCl solutions, respectively, regardless of leaching time. With in-creasing HCl concentration, the Ca content eluted from the product decreased, due to the removal of Ca via acid leaching before the synthesis, while the Na content eluted from the product increased to 3 M HCl and then decreased, which was almost similar to the CEC of the product, due to the ion exchange of Na-type zeolitic phase in the product. The change of zeolite phases in the product and the CEC of the product depend on the concentrations of Si and Al in the solution during the synthesis. The highest CEC of the product is about 220 cmol/ kg, which was synthesized from the ash leached in 3 M HCl solution.

Jan 1, 2014

By Fu Ping-Hao, Sergio Mauricio Vianna, Ewen Silvester, Emmy V. Manlapig

"Over the last 5 years, an ambitious project has been undertaken at the Julius Kruttschnitt Mineral Research Centre (JKMRC) aiming to isolate, study and, if possible, model the effect of particle size, liberation and collector adsorption density on the floatability of mineral particles. As part of this project, we have conducted highly controlled flotation test-work, combined with state-of-the-art solution and surface analytical techniques such as High Performance Liquid Chromatography (HPLC), Time of Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) and detailed mineralogical analysis to fully characterize the flotation behavior of a natural ore.The flotation tests were undertaken using a high-grade lead-zinc ore from BHP-Billiton’s Cannington mine (Australia) in a specially designed continuously operated laboratory scale flotation rig. Solution and adsorbed collector concentrations were measured independently during the course of the flotation tests using HPLC based ex-situ techniques. Liberation studies were performed using the JKMRC Mineral Liberation Analyser (MLA) on selected size intervals of different streams to estimate the specific surface area of galena. These results were used to calculate the collector adsorption density (collector coverage) on galena particles, with the eventual aim of developing a mathematical model describing the relationship between pulp chemistry, feed mineralogy, and floatability of galena particles."

Jan 1, 2003

By J. Seo, W. Kim, I. Bae

"Microcrystalline silica impurities such as quartz and opal-CT commonly associated in bentonite should be controlled and removed as far as possible when bentonite is used as biocompatible raw material because they show sufficient evidence of carcinogenicity. Since opal-CT contained in bentonite in trace amounts cannot be well separated by conventional sedimentation method, in this work, the ultrasound-assisted removal of the impurity was attempted. Irradiating ultrasound into bentonite-water suspension promoted the production of fine montmorillonite particles in the suspension and the production markedly increased when montmorillonite was activated by Na2CO3. Subsequent centrifugation of the suspension made it possible to recover pure montmorillonite particles as an overflow product. Only 16.2 mass % of total solids was recovered as an overflow from the non-activated suspension, whereas 63.5 mass % was recovered from the activated suspension at centrifuging speed of 10000 rpm. Increasing sonicating time enhanced the yield of overflow, however, excessive sonication up to 10 min hindered the purification of montmorillonite. It was observed that the peak reflection of (101) plane of opal-CT in overflow increased as sonicating time increased during prolonged sonication. INTRODUCTION Bentonite consisting predominantly of mineral montmorillonite is clay-rich soft rock generated frequently from the alteration of volcanic ash. Depending on the nature of its genesis, bentonite contains a variety of accessory minerals, which may include mainly quartz, feldspar, opal cristobalite/tridymite (opal-CT), calcite, illite and mica. The presence of these accessory minerals can impact the industrial value of the deposit, reducing its commercial value depending on its applications. Therefore, bentonite is often purified by removing these impurity minerals for special applications where specific properties and characteristics are required (Murray, 1999). Among the special applications, bentonite is often used in the cosmetic and pharmaceutical industry as both excipient and active ingredient in the forms of liquid (suspensions, emulsions), semi-solid (creams, ointments) and solid (powder, capsules and tablets). The basic requirements for bentonite to be used as raw material are pure, microbiological and mineralogical inertness. Physical properties such as swelling volume and gel formation are also important. Particularly, microcrystalline silica polymorphs such as quartz, cristobalite and opal-CT should be controlled and removed as far as possible because they show sufficient evidence of carcinogenicity in humans."

Jan 1, 2018

By Naoki Hiroyoshi, Hajime Miki, Tsuyoshi Hirajima, Masami Tsunekawa

Acidic solutions for chalcopyrite leaching contain cupric, ferrous and ferric ions, and the oxidizing power of the solutions is indicated by a redox potential, determined by the concentration ratio of ferric to ferrous ions. This paper reviews our previous studies on the redox potential dependence of chalcopyrite leaching in sulfuric acid solutions. Leaching and anodic-polarization experiments showed that coexistence of cupric and ferrous ions activate anodic dissolution of chalcopyrite, causing faster copper extraction at the potentials below a certain value (critical potential). The analysis of the AC impedance spectra for chalcopyrite electrode indicated that a high-resistance passive layer grows on the chalcopyrite surface without cupric and/or ferrous ions, and that coexistence of these ions causes a formation of another product layer and inhibits the passive layer growth at low potentials. These results are explained by a reaction model assuming the formation of intermediate Cu2S due to chalcopyrite reduction and the subsequent oxidation of the Cu2S. The critical potential corresponds to the redox potential of the Cu2S formation and the predicted values matched with the experimental results. Catalytic effect of silver ions on chalcopyrite leaching was also discussed based on experimental results and the above model.

Jan 1, 2003

By Rasool Hejazi

The feed to Chadurmalu iron ore concentrator plant is a mixture of magnetite and haematite iron ore with a Fe/FeO ratio of about 8. The feed to plant, after grinding via wet SAG mill, is pre-separated by wet low intensity magnetic separator. Magnetic product is conducted to magnetite processing circuit for producing magnetite concentrate, and nonmagnetic product is directed to haematite processing circuit. Due to surface oxidization of magnetite particles and a decrease in magnetic attraction properties, significant amount of these particles are misled to tailing which results in decreasing the efficiency of haematite processing circuit. This problem can be remedied by using magnetic drum separator with more magnetic intensity and/or gradient. In this paper, the replacement of LIMS separators with wet medium intensity magnetic separators with a field intensity of 3800 gauss on drum surface (MIMS) have been suggested and considered as the most suitable solution to prevent the loss of magnetite particles. The results of carried out investigations with replacement of drum separators in industrial scale, showed that utilizing MIMS in magnetite processing circuit resulted in increasing final concentrate weight recovery on average by 2.59%, without any adverse effect on the concentrate quality; decreasing the magnetite content in the feed to high gradient magnetic separator (HGMS) by about 3.5%; decreasing the feed to floatation part by about 7% and consequently decreasing consumption of chemical reagents; increasing Fe/FeO ratio of the feed to plant. Keywords: iron ore, medium intensity magnetic separator, haematite, Chadurmalu

Sep 1, 2012

By Venkataramana Runkana, Pradip Gautham, Beena Rai, Sreedhar Reddy

"IT enabled platforms are the key to provide an integrated view of the business activity or an enterprise as a whole. Attempts to integrate all functions in an enterprise such as mine-to-market initiatives, wherever and to whatever extent implemented, have provided significant benefits to the industry. The transformative potential of IT enabled integration platforms is illustrated in this communication from our own work in this field. TCS PREMAP (Platform for the Realization of Materials and Products) is a knowledge-driven engineering design and development platform which leverages modeling and simulation and artificial intelligence into the engineering design process. We illustrate the customization of this generic platform for the design and optimization of mineral processing plants in an integrated manner. TCS PEACOCK (Process and Equipment Analytics for Optimization and Control) has been developed to enable automation of data analytics in the operating plants. We illustrate its utility and power in improving the plant performance with the help of case studies from our work on pelletization of iron ores and optimization of flotation plants. INTRODUCTION We are living in an exciting digital era. With the advent of cloud computing and social media on the one hand and rapid advances being made in several research areas of interest to us in the minerals and metals industry such as artificial intelligence (AI) & machine learning, robotics, unmanned vehicles including drones, big data analytics, 3D printing, sensor technologies, renewable energies and internet of things (IoT), many disruptive transformations in our industry are on the horizon. Recent advances in information technology (IT) and knowledge engineering, in combination with appropriate domain expertise, that is, our enhanced understanding of the underlying science of mining and mineral processing operations and the availability of a variety of powerful modeling-simulation tools make it possible to address the challenging problems facing the mining and mineral processing industry, in an integrated manner."

Jan 1, 2018