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By D. X. Chen

Comprehensive utilization of the copper associated with the complex lead and zinc sulphide ore is a recognized and difficult technical issue in ore dressing field. Qi Baoshan lead-zinc mine is a typical complex copper-lead-zinc polymetallic ore deposit and difficult to process. The application of the. traditional process is not able to make the substantive progress. According to its mineralogical characteristics, the association of copper minerals with lead minerals is very close, and their particle sizes are very fine, and the copper and lead minerals are partially oxidized. Based on the laboratory tests and comparison between different process flowsheets, preferential flotation of copper minerals, being suitable for this ore, was chosen to recover copper. The separation of copper from lead applies the following technology: regrinding middlings with cyclones to classify, which improves copper lead mineral liberation, and increases copper and lead recovery; using new high-efficient collector with good selectivity, which is able to float copper minerals; and non-toxic combined depressant which depresses lead minerals. The above technical innovation, optimizing the process flowsheet, overcoming the complex traditional process flow with high production cost, obtained good technical and economic indicator. The difficult technical problem of copper lead separation was solved smoothly. After successful performance of the bench-scale experiment, commercial-scale test was carried out. In industrial trial, a copper concentrate containing Cu18.60 %, Pb7.40 % and Zn2.50 % was obtained with copper recovery of 58.49%, lead concentrate quality improved largely. The process opened up an unique path for the comprehensive recovery of Cu from similar lead and zinc non-ferrous metals mineral to comprehensively recover copper.

Jan 1, 2014

By Carina Ulsen

The existing construction and demolition (C and D) waste recycling technologies and standards have been essentially focused on the production and use of coarse recycled aggregates. Very few papers focus on the production of recycled sand, although some previous results show that fine aggregates fraction represents around 40 to 60% (in mass) of the Brazilian waste and it is usually used as road sub-base or disposed in landfills. The quality of the recycled aggregate is strictly related to the content of porous and low strength phases, mainly the patches of cement remaining on recycled aggregate surface. Some technologies have already been described in the literature, even though, to the moment none of these technologies has clearly succeeded in reaching the large market available. This paper presents a summary of the main properties of the sand produced from C and D waste by tertiary crushing at vertical shaft impact crusher (VSI). Additionally mineral processing technologies were applied on the attained product, such as gravity concentration by shaking table and spirals and removal of cement paste by attrition. The main properties of recycled sand are discussed and compared to the previous C and D waste, respectively: particle size distribution, particle shape, chemical composition, cement paste content and porosity. The results demonstrates that the crushing allowed producing a VSI-sand with low porosity and water absorption due to the increasing on the content of silicates from natural rock phases and increasing liberation between these phases and porous cement paste; the particles from the attained product presented also a better shape (sphericity and aspect ratio). The attrition tests assayed on VSI recycled fine aggregates accomplished a further selective disaggregation of cement paste and other porous materials - the porosity was reduced from 10% to 7%. The concentration by shaking table at narrow sieve fractions led to a product with low porosity and reduced content of cement paste, however, concentration on spirals did not succeed since separation was performed essentially by the size of the particles. The heavy product from shaking table represented almost 75% in weight and has less than 60% recovery of CaO+LOI, and expressive reduction on porosity. The aim of producing sand from construction and demolition waste through mineral processing unit operations changes the recycling approach and contributes for up cycling the recycled sand. The exhaustion of sand deposits on Brazilian large centers, the increasing price and the construction boom encourages the development of alternative materials as construction raw material. Keywords: recycled sand, construction and demolition waste, technological characterization

Sep 1, 2012

"A sulfide ore containing 2.19 g/t Au and 13.13 g/t Ag was studied for the deportment and extractive metallurgy of pay metals. The ore is composed mainly of non-sulfide minerals with approximately 10% pyrite and minor amounts of marcasite, chalcopyrite, galena, sphalerite, and arsenopyrite. The deportment study using a comprehensive approach showed that gold and silver minerals in the ore are mainly native gold (Au), electrum (Ag, Au), petzite (Ag3AuTe2), hessite (Ag2Te) and volynskite (AgBiTe2) with minor amounts of acanthite (Ag2S) and argyrodite (Ag8GeS6). At current grinding fineness (P70@150µm), the majority of liberated native gold and electrum particles are larger than 20µm with 85% >40µm, some of them are even larger than 150µm, indicating that extended leach time may be required to dissolve these coarse gold grains to completion and gravity concentration needs to be considered. Petzite is relatively fine with all liberated particles being less than 80µm in size. Gold distribution and leach testwork results showed that liberated gold accounts for 50% of the head assay, exposed gold associated with sulfide and non-sulfide minerals accounts for 30% and 11% of the head assay, respectively. Gold locked in sulfide and non-sulfide accounts for 4.8% and 4.1%, respectively. Thus, it is recommended that cyanide leaching be considered for extracting gold in this ore. This paper presents the detailed results of the gold and silver deportment study and extractive metallurgy testwork, and discusses the impact on process selection and flowsheet development.INTRODUCTION Gold and silver have been found in various geological environments and ore types. In terms of the gold deportment and extractability, gold ores can be classified into two categories and 12 types. Their extractive metallurgy is largely driven by mineralogical factors such as particle size, association with other minerals, coatings and rimmings, presence of cyanicides, oxygen consumers and preg-robbers, presence of refractory gold minerals and locking of submicroscopic gold in sulfide and sulfarsenide mineral structures (Zhou et al., 2004; Marsden & House, 2006; Zhou, 2013a, 2013b). Compared to gold, silver mineralogy is more complex and metal extraction is more challenging due to its presence in over 200 Ag-bearing minerals (a silver-rich ore body would typically contain 5 to 10 different silver minerals) (Gasparrini, 1984), presence of refractory silver minerals (such as pyrargyrite, prustite and stephanite) and submicroscopic silver in sulphide minerals (such as galena and copper minerals) (Chryssoulis et al., 1985; Di Prisco et al., 2002). The presence of these issues often causes problems in Ag-bearing ore processing. Therefore, knowing the deportment of gold and silver in the ores and metallurgical products is important for flowsheet development and process optimization."

Jan 1, 2018

By F. S. Niu

With the feature of finely-dissemination particle and complex mineral composition, oolitic hematite is considered to be the ore dressing difficult problem in the world. Series research on refractory oolitic hematite in Zhangjiakou Area are introduced as following: ore properties?technology mineralogy and mineral processing technology. The survey shows: with the fine grinding of the hematite to a fineness of -0.076mm 95%, obtaining iron concentrates grading 62.74% Fe at the recovery of 46.80% by high intensity magnetic separation- reverse flotation flowsheet; under the three stages intensity magnetic separation,four stages grinding and four stages gravity separation, getting the iron concentrates grading 61.09% Fe at the recovery of 45% using high intensity magnetic separation- gravity separation flowsheet; with roasting temperature of 800°C, time for 75~90min and ore-coal ratio of 11, gaining the iron concentrates assaying 62.74% Fe at the recovery of 87% by roasting- magnetic separation flowsheet. At present, this research is still doing for the target of raising the concentration recovery on the base of high grade concentrate. It is in the hope of fully utilizing the existing hematite resources in Zhangjiakou

Jan 1, 2014

By Andrew Logan

Newcrest has a strong history of growth over the past 20 years, yielding value from previously marginal ore bodies. We have grown regionally in Asia Pacific through our operations in Australia, Indonesia and Papua New Guinea, and also established a beachhead in West Africa. The company has a reputation of realizing value from large, low-grade deposits adopting step change approaches. Newcrest is focused on an overall strategy of gold, low cost, long life and moderate growth. Capability step changes play a large delivery role. They transition from a business offline-to-online approach as opportunities mature. Newcrest believes in a) Knowing what ?good? looks like, b) An open innovation approach to actively working with others, c) The leap frogging leverage of making the ?old new again?, d)An adopt-adapt-develop methodology enabled by rapid prototyping/piloting, e) Getting our handsdirty with test work and plant analysis, and f) Staying focused on a few high business leverage areas. This paper describes Newcrest?s approach and our experiences in establishing renewed metallurgical processes, specifically aimed at increasing innovation adoption. Some of our step changes discussed include: 1) Early waste rejection to avoid high energy processing downstream, 2) Broader gold product channels to reduce site based processing needs, 3) Lower energy processing, and 4) Geo-Metallurgy approaches. Keywords: Newcrest, gold, step change, open innovation, adopt, adapt, develop, offline, online, prototyping, old new again, waste rejection, low energy, geo-metallurgy

Sep 1, 2012

By T. Fraszczak, U. A. Peuker, T. Mütze, T. Leißner, A. Wikedzi

The present paper highlights on the comminution and liberation properties of two greisen-type lithium bearing-mica ore blends (L1, L2) subjected to different breakage devices; cone crusher (CC), roller crusher (RC), rotor beater mill (RBM) and a screen mill (SM). The particle size distribution (PSD) of the products from each device were evaluated to search for an appropriate PSD model using Gates-Gaudin-Schuhmann (GGS) and Rosin-Rammler (RR) functions. In order to determine an appropriate function that could better describe the PSDs from the devices used, the coefficient of determination (R2) was used as a criterion. In terms of mineral liberation studies, due to costs, only products from rotor beater mill (RBM) were examined through an automated scanning electron microscope (SEM) technique. It was found that RBM, RC and SM products were better described by the RR model than the GGS model with higher R2 values (0.97-1.0). However, cone crusher products for L1 were better described by GSS model, while that for L2 were better described by RR model. In terms of the spread of size distribution as indicated by RR model parameters, RC products were more uniformly distributed compared to products from other devices, for both ore blends. Also the RBM products were more scattered than products from other devices. The results indicate that the composition of individual ore blends affected the comminution products PSDs since different PSD model parameters were obtained for samples comminuted by same devices. The modal mineralogy of the two ore blends indicate both to be rich in quartz, topaz, zinnwaldite and muscovite. Further, the result indicate that, for both ore blends, zinnwaldite phase is more enriched in the fraction < 250 µm. Moreover, better liberation of zinnwaldite is observed for L1 compared to L2. This could be explained by differences of the two ore blends in three aspects; the nature of mineral association, reduction ratio of the fractions analysed and the nature of spread of the size distribution.

Jan 1, 2018

By A. Pirson, J. Souza, A. Araujo, M. Barbosa, F. Guimarães, J. Lima

"Although a large number of processes have been developed and applied to the separation of barite from other minerals, there is a lack of information in the literature about the separation of barite from iron ores. Nowadays, there are millions of tonnes of iron ore disposed as a waste or tailings given its high content of sulphur in the form of barite. In order to effectively separate barite from iron ore and ensure that mining business is truly creating economic and sustainable values, this paper provides a greater understanding of barite properties, the origin and occurrence of this barium-bearing mineral, and the employed beneficiation processes. A test work is conducted in a barite bearing iron ore from a deposit located in the Republika Srpska (Bosnia and Herzegovina) in order to separate the barite and check if a marketable by-product can be produced by drawing upon rich barite tailings. INTRODUCTION The exploration of iron ore containing barite results in a large amount of unrecovered material. The main difficulty in processing and using barite bearing iron ores is given by their high content of sulphur, silica and barium, which are unwanted chemical compounds in the subsequent processes in iron industry. As a result, millions of tonnes of iron ore are discarded every year into tailings or as a waste, which results in production losses, higher operation costs and environmental impacts (Praes et al. 2013). Therefore, the separation of barite from iron ores not only means reducing the environmental impact, but also an opportunity to generate income and beneficiate society. The beneficiation of barite bearing iron ores is a subject which requires a deeper investigation to solve the challenges faced by the iron industry. There are only a few studies that describe flowsheets proposed for the production of barite concentrate of iron ores. The most likely reason for this gap is that barite is frequently exploited commercially as a primary product rather than a by-product. In order to effectively separate barite from iron ore and ensure that mining business is truly creating economic and sustainable values, this paper provides a greater understanding of barite properties, the origin and occurrence of this barium-bearing mineral, and the employed beneficiation processes. A test work is conducted in a barite bearing iron ore from a deposit located in the Republika Srpska (Bosnia and Herzegovina) in order to separate the barite and verify if a marketable by-product can be produced by drawing upon rich barite tailings."

Jan 1, 2018

The molybdenum ores currently utilized in China are mostly molybdenum sulfide ores whereas oxidized molybdenum ores, being finely disseminated and difficult to process, have not been exploited and utilized effectively. In this article the beneficiation process of a molybdenum ore occurred in an oxidized ore zone was investigated in order to provide a new way for the development and utilization of the oxidized molybdenum ores in China. The molybdenum mineral in the ore was mainly wulfenite and the associated minerals included barite, limonite, quartz and small amount of cerusite. Limonite in the ore occurred in a crust and honeycomb-like colloidal state and composed the framework for the formation of the other minerals in the ore, which filled the pores in the framework. Wulfenite was mainly fine-grained and occurred in the fine porous crust and honeycomb-like framework. The finely disseminated ore structure made the separation and recovery of the molybdenum mineral in the ore very difficult. On the basis of the mineralogical study of the ore, experiments were conducted to compare the various mineral processing methods for the beneficiation of the ore, including single gravity concentration, single magnetic separation, single flotation, and a combination of high intensity magnetic separation and gravity concentration. The results indicated that with single gravity concentration a molybdenum concentrate containing 5.85 % Mo with a yield of 11.76 % and a Mo recovery of 43.5 % was produced. With single high intensity magnetic separation it was very hard to obtain a molybdenum concentrate product. With single flotation process a molybdenum concentrate containing 7.06 % Mo with a yield of 15.14 % and a Mo recovery of 62.63 % was produced. With a combination of high intensity magnetic separation and gravity concentration a molybdenum concentrate containing 6.46 % Mo with a yield of 11.81 % and a Mo recovery of 42.11 % was produced. In conclusion, compared to the other methods the flotation process can produce more reasonable technological and economical results and is the best process for the exploitation and utilization of the finely disseminated oxidized molybdenum ore.

Jan 1, 2014

By X. Q. Chen

According to the different characters of the middle-low grade bauxite, based on the normal flotation & reverse flotation technology, the author innovates the new technology which is named bi-flotation, it integrates the advantages of normal flotation & reverse flotation, while avoids their disadvantages. Take Henan middle-low grade bauxite as research object, according to the pilot experiment of bi-flotation technology, the concentrate A/S is 9.37 and the recovery of alumina is 80.18% by flotation separate the raw ore which A/S is only 4.19.

Jan 1, 2014

By T. Fujita

The incinerated bottom ash includes titanium oxides and a small amount of chromium oxides. Initially, 89 % of chromium was removed from ash at magnetic flux density at several stages of wet magnetic separation from 0.05 T to 6 T. The bottom ash from an industrial waste incineration process includes about 10 % of TiO2. The minerals that contain titanium are rutile and perovskite. These minerals are paramagnetic and show low magnetic susceptibility, therefore, the high magnetic field strength, created by a superconducting magnet, is necessary to capture these minerals. At the first stage of separation, a magnetic field strength of 6T was applied in order to attract the particles that contain iron oxides to the higher magnetic field region. At the second stage of separation, the magnetic capture rate of weekly magnetic particles decreased with increasing the magnetic susceptibility of the aqueous solution (i.e. the medium for dispersing the particles) in order to separate the highly magnetic materials. The para-magnetic salt such as ferric chloride was dissolved in the water to increase the magnetic susceptibility of the medium. After a two-step wet HGMS with superconducting magnet, the grade of TiO2was increased from 10 % to 28 % with a recovery of 64 %.

Jan 1, 2014

By Lei Wang, Qi Zheng, Xiao-kui Che

"The wastewater emitted by gold chemical industry contained vast of different heavy metal ion, such as Zn, Cu and Ni etc. Among them Zn is the main ion in the waste water which causes the serious environment pollution. A method of preparing a kind of resin which is used for the removal of Zn by magnetic adsorbent was developed and was applied in practice. This adsorbent is a chitosan made of a kind of Fe3O4-chitosan modified by epichlorohydrin. The adsorption capacity of the absorbent and it was concluded that under the laboratory conditions, the maximum adsorbing capacity of this adsorbent could be 287.58 mg/g. The absorbent was also applied in the wastewater emitted by a gold industry in Shandong province. Its performance was tested and the result showed that the concentration of Zn ion in the wastewater was reduced from 0.58 mg/L to 0.0174 mg/L. What is more, the adsorption rate could be more than 97% when the dosage was 100L/m3 after adsorbing for 1h. KEYWORDS Selective, preparation, laboratory experiments, industry experiment, comparation INTRODUCTION Currently, most gold chemistry use cyanide to leach gold ore. Many different metals participate to this reaction besides the gold ion in this processing, so that the composition of the water is very complex. The waste water emitted by gold chemistry industry contains large amount of heavy metals. Definitely, if it was discharged without any treatment, the water would threaten the environment. The recuperation of any ion in the water would mitigate the pollution. Ion exchange resin, which is an effective material to do the water treatment with low cost, became widely applicated in this field [Yu-jiao Wang,2013]. Different kinds of resin were developed and the influence factors such as pH, adsorption properties and selectivity for different ions were investigated [CA Cruz et al,2018; PawanKumar et al.2016; Y Zhang, et al,2010; and ShengingSun, Aiqin Wang, 2006;]. The waste water mentioned in this article has a high Zn concentration, so a magic resin for Zn adsorption selectively we designed was used to manage this water. And the recovery of Zn could not only contribute to pollution abatement but also a best way to settle a dispute to the short of Zn resource. So the article mainly describes the preparation and the application of a kind of magnetic adsorbent used for the removal of Zn both in laboratory and industry. The aim of this article is to compare the effect of this resin in industry and laboratory?"

Jan 1, 2018

By C. Y. Wang

Anodic reaction mechanism of complicated antimony-lead concentrate in Slurry Electrolysis has been investigated by the anodic polarization curves determined under various conditions. The main reactions on the anode are the oxidation of FeCln (2-n), though the oxidation of jamesonite particle on the anode can occur during the whole process, it is less. With the help of mineralogy study and relevant tests, the leaching reaction mechanism of jamesonite and gudmundite during Slurry Electroly-sis has been ascertained also. Because of the oxidation reaction of FeCl3 produced by antimony-lead concentrate itself, the non-oxidation complex acid dissolution of jamesonite, the oxidation complex acid dissolution of gudmundite, and the oxidation of air carried by stirring, the leaching ratio of antimony reaches to about 35% when using HCl-NH4Cl solution to leach antimony-lead concentrate directly. So given the theoretical electric quantity, which to oxide antimony in Slurry Electrolysis, all of antimony, lead and iron, which contained in antimony-lead concentrate, are leached.

Jan 1, 2014

By A. K. Majumder

In an effort to test the extent to which fundamental fluid mechanics can provide a prediction of particle separation, a study on a simple parallel-sided sluice has been carried out using glass bead and ilmenite mixtures at various particle concentrations and flow rates. Great care was taken to devise a flow splitter at the end of the sluice that permitted accurate measurement of the fluid flow profile and collection of slurry samples, allowing evaluation of the particle species concentration profiles. The actual particle separation taking place was compared to predictions made by first describing the fluid flow by a modified ?law of the wall? model. The hydrostatic pressure variation in the flow was taken into account and the eddy viscosity was calculated from a mixing length expression incorporating Van Driest?s damping function. Using an average density and viscosity provides an explicit expression for the velocity gradient that can be numerically integrated for the flow profile. The particle concentration distributions were then modelled with Hunt?s sediment transport model assuming the particle eddy diffusion coefficient to be the same as that for the water. Hindered settling velocities of the particles were calculated using Brauer and Thiele?s formula, which takes the particle size and density distributions and solids volumetric concentration into account. The resulting predictions of particle separation are shown to be a strong function of the settling velocities of the particles used. Keywords: flowing film concentrators, fluid velocity

Sep 1, 2012

By T. Kumaresan

The Bayer process used for refining bauxite to smelting grade Alumina serves as the linchpin of the Aluminum production industry worldwide. Even though the process is well established, the presence of impurities in the liquor affects the quality of product and imposes a major economic cost on the industry. This review article focuses on the issues pertaining to Gibbsitic (Al2O3.3H2O) precipitation circuit. The comprehensive review provides a basic understanding of the aluminum trihydrate precipitation and agglomeration phenomena. Crystal growth rate and agglomeration play a significant role in determining the output PSD of agglomerates. Hence, the effect of certain thermodynamic and hydrodynamic parameters along with the impact of impurities (oxalates, aldols, acids etc.) and additives on hydrate growth has been reviewed.

Sep 1, 2012

By N. Gurulaxmi Srikakulapu

The demand for high-grade iron ore has increased the importance of beneficiation of low-grade iron ores. The captive mines of Tata Steel Limited, India has reserves of Banded Haematite Jasper (BHJ) ore assayed 40% Fe, 40% SiO2 and <1% Al2O3. QEMSCAN study has revealed haematite and quartz as a major iron bearing and gangue mineral phases respectively. Liberation characteristics have showed 80% liberation can be obtained at particle size below 10µm. In the present study, reverse cationic froth flotation of BHJ using ether diamines is explored in Denver-D12 flotation cell. Polynomial response surface regression equation coupled with six-factor Box-Behnken design of experiments is used to generate the correlation between process separation efficiency and flotation parameters. Flotation studies of BHJ indicated that concentrate of 62% Fe can be achieved with 62% Fe recovery from Jig concentrate at optimum conditions. The obtained product can blend with pellet fines to feed in blast furnace. Keywords: banded haematite jasper, flotation, box-behnken design, response surface methodology

Sep 1, 2012

By H. D. Yu

In this paper, an evaluation about the process mineralogy of the rich iron mine in Mongolia with comprehensive methods is given; this provides foundation of the comprehensive recovery of iron and cobalt in the ore. The research shows that the iron?s grade is 61.23%, Co?s grade is 0.02%, the ore is rich iron ore and its Co content also reaches border mining grade. For the ore, if want get high grade iron concentrate powder, must identify the mineral composition and the occurrence of iron and take into ac-count the recovery of Co content as associated resources. Chemical phase analysis results show that 86.35% of iron exists in magnetite, which means that the theoretical recovery ratio of iron is close to 86%. Minerals spectrum analysis confirmed that the magnetite containing a small amount of Mg, Al, and other impurities, the actual iron minerals to 70.28%, which means that theoretically iron grade iron concentrate only close to 70.28%. Based on the result of iron chemical phase analysis, by investigating the liberation of sulfide minerals and gangue, the recovery index of iron can be forecasted, when grinding fineness is 35%, 45%, 55% and 65% bellow 0.074mm,theoretical content of Fe in iron concentrate separately is 67.71%,67.88%,68.78%,and 69.43%,accordingly the theoretical recovery of Fe is 87.38%,87.05%,86.92% and 86.63%. From the perspective of process mineralogy, the forecast mineral beneficiation indicators show that the ore is easy sorting ore, iron processing operations have higher recovery rate, but wants sorting of high-grade iron ore concentrate still need appropriate grinding fineness. Furthermore, associated element Co, existing mostly in pyrite and pyrrhotite, is valuable in the ore. Pyrite and pyrrhotite have ideal liberation under grinding, so cobalt can be easily enriched in sulfide concentrate.

Jan 1, 2014

By B. Courtaud

Uranium plants are generally located quite far from conversion plants, resulting in high transport costs. One way of reducing such costs involves putting more uranium in each drum by increasing the final product?s bulk density, which can be achieved via mechanical compaction of the powder and/or improved precipitation. For most of its plants, AREVA has adopted the latter approach, involving a new precipitation process applicable to all kinds of yellowcake produced (via uranates, uranium peroxide, etc.) that achieves bulk density of 3 for soda uranate, for example, instead of the 1.5-2 density available via conventional processes. At present, this process is being undertaken on an industrial scale and will become the norm for precipitation processes at all AREVA U plants. In addition to producing dense yellowcake, the process also delivers a product with no fines, a spherical particle shape (which allows for high-quality powder flow) and superior post-precipitation filterability

Sep 1, 2012

By D. Tang

The froth zone in a flotation cell is recognised as a region which contributes to the overall flotation performance. Froth recovery is a measure of the efficiency with which the froth phase delivers particles arriving at the pulp-froth interface to the concentrate. Poor froth recovery in scavenger stages is generally attributed to poor froth stability. The key indicators of froth performance: froth recovery, entrainment and water recovery were measured in an OK3 pilot cell installed at a zinc concentrator in Australia and supplied with scavenger feed. Cell hydrodynamic and pulp chemical conditions during the operation of the cell were also measured as well as bubble growth across the froth phase. The objective of the work was to assess the impact of a number of commercial frothers on the froth performance in the OK3 cell and assess the suitability of using bubble growth as an indicator of froth stability.

Jan 1, 2014

By Junwei Han, Wenhua Li, Wenqing Qin, Fen Jiao, Wei Liu, Jiaqi Xu

"A novel technology was developed to study the process of recycling copper from waste printed circuit boards (WPCBs), which are the main source of metal production in the next decades. The chemical compositions of the WPCBs were investigated. The results indicated that the PCB powder was mainly composed of copper (38.5 wt.%), iron, aluminum, and non-metallic materials. Copper is mainly in the form of Cu and is the most valuable metal for the recycle of WPCBs. The concentrated WPCBs powder, obtained by the mechanical process, were pressed as the anode, which was directly electrolyzed to produce copper. The effects of H2SO4 concentration, Cu2+ concentration, current density, pole pitch, and liquid-to-solid ratio on the voltage, current efficiency, and copper extraction were investigated. The results indicated that the optimum conditions were liquid-to-solid ratio of 30 mL/g, current density of 571 A/m2, sulfuric acid concentration of 180 g/L, 50 g/L of copper ion, polar distance of 3 cm. Under the conditions, a desired current efficiency could be achieved. Meanwhile, about 95.62% Cu was recovered from the WPCBs. The experimental studies also revealed that the purity of copper obtained at the highest current efficiency was higher to 99.98%. Produced copper sheet were characterized by X-ray diffraction (XRD). XRD analysis indicated that the copper was the main phase. INTRODUCTION With the rapid development of electronic industry, more and more waste electronic and electrical equipments (WEEE) are generated every year (Fogarasi et al., 2012; Liang et al., 2013). The production of printed circuit boards (PCBs) is the base of electronic industry, because it is the essential part of all electrical and electronic equipments (Schlummer et al., 2007). As a result, a considerable amount of waste PCBs containing plenty of heavy metals have to be treated. In general, PCBs contain about 28% metals that are abundant non-ferrous metals such as Cu, Pb, and Sn. Printed circuit boards can be considered as a secondary resource for recycling rather than wasting. The contents of gold and silver respectively reach 80 g/t and 3300 g/t, which are much higher than that of primary ores. Copper is the main metal of PCB and its content is as high as 26.8% ( Zhang et al., 2009)."

Jan 1, 2018

By G. Rajesh

Mathematical modeling of bioremediation has gained importance as it is used as an optimization tool for the remediation process involved in contaminated sites. The bioremediation of Cr(VI) has been studied taking into consideration the initial Cr(VI) concentration Cr(VI)ini, bacterial growth substrate concentration (S), maximum growth rate (µmax), yield coefficient (Y), half saturation constant (Ks), and inhibition constant (KI). As the enzymatic reaction is also affected by initial substrate concentration (Sini) and Ks, different ratios of (Ks/Sini) are analyzed. As the inhibition constant (KI) is not constant for all the enzyme reactions and it varies with Cr(VI)ini, the correlation between (KI) and Cr(VI)ini is developed. A set of differential equations pertaining to bioremediation of Cr(VI) has been solved using FORTRAN 90 program adopting the model developed. The results are verified with the experimental data from the literature and a good correlation has been obtained between the experimental data and the model predictions. Keywords: bioremediation, hexavalent chromium, mathematical model, inhibition kinetics

Sep 1, 2012