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By Venkata S. Buddhiraju

Pelletization of iron ores involves balling on a rotating disc to produce wet pellets and induration of wet pellets on a moving grate to produce fired pellets. The quality of pellets produced and the productivity of the pelletization process depend strongly on the characteristics of the feed to the pelletization disc, especially the particle size distribution and the moisture content. The upstream processes involved in the preparation of pelletization feed include grinding, thickening and filtration of the iron ore slurry. The focus of the present work is the closed circuit wet grinding of iron ores. The circuit consists of a primary ball mill, a regrind mill and a hydrocyclone. A population balance model was developed to predict the grinding kinetics and an empirical model was fitted for the separation of fine particles from the coarse particles in the hydrocyclone. Batch grinding kinetics experiments were performed on a laboratory scale ball mill to obtain the ore breakage parameters which were subsequently used for the simulation of the industrial mills. The models were customized for the industrial operations and the effects of different process variables like feed flow rate, water flow rate, etc., on the size distribution of product from the grinding circuit were studied. Additionally, different circuit configurations were simulated to determine operating conditions that could result in the desirable product particle size distribution. The results of simulation were in close agreement with plant observations and the new circuits explored through simulation have helped in identifying potential opportunities for process optimization and control

Sep 1, 2012

By S. S. Indi, D. Santhiya, S. Subramanian, K. A. Natarajan

"With the gradual depletion of the high-grade ores and finer dissemination of values in the leaner samples, it has become imperative to develop innovative approaches to process such complex ores. The beneficiation of complex sulphide ores containing copper, lead and zinc minerals, remains one of the most important challenges in base metals metallurgy. The advent of biotechnology in mineral processing has opened up immense possibilities to exploit such difficult-to-treat ores. Bioprocessing techniques thus hold promise as potential substitutes for the conventional technologies in vogue. Several types of autotrophic and heterotrophic bacteria, fungi, algae and yeasts are implicated in mineral beneficiation processes. Adopting a bioprocessing route to mineral beneficiation has attractive benefits, such as lower cost and energy requirements, environmental acceptability and operational flexibility.The interaction of sphalerite- and galena-adapted Bacillus polymyxa (B. polymyxa) cells with sphalerite and galena has been investigated through adsorption, electrokinetic and flotation studies. The amount of sphalerite-adapted cells adsorbed onto sphalerite and galena is found to decrease with increase in pH. On the other hand, the adsorption density of galena-adapted cells onto galena shows a feeble maximum around pH 8, and the amount adsorbed is marginally higher in the pH range of 8 – 11.5. In the case of sphalerite the amount adsorbed is higher in the pH range of 5 to 7. The adsorption density of both the adapted cells is higher for galena vis-à-vis sphalerite. Electrokinetic studies indicate significant surface chemical changes on the chosen sulphide minerals and the bacterial cells, consequent to microbemineral interactions. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite could be preferentially floated from galena, using galena-adapted cells, but not with the sphalerite-adapted cells. The cells adapted to galena assay a higher polysaccharide content and are more hydrophilic, while the sphalerite-adapted cells have a higher protein content and possess greater hydrophobicity. Transmission electron microscopic studies have provided evidence in support of the differences between the cell surface characteristics of sphalerite- and galenaadapted cells (Figure 1). Possible mechanisms of interaction between the minerals and the bacterial cells are discussed."

Jan 1, 2003

By A. T. Sutaone

"In the Dongri Buzurg Manganese Mine of M/s Manganese Ore (India) Ltd., high grade lumpy manganese ore required for iron and steel industries is produced through multi-stage crushing and screening. This has resulted in accumulation of 50,000 tonnes of low grade fines over the years. This production of such fines is still going on. The fines create environmental problems, like air and water pollution and siltation in adjoining fields. Besides containing lot of manganese values, they occupy large space which is very scare in mining area.The Indian Bureau of Mines under one of its statutory functions has suggested the company to explore the possibility of recovery of additional values under conservation and environmental aspects. Hence the company has sponsored a bulk sample for beneficiation studies in the Modern Mineral Processing Laboratory and Pilot Plant of Indian Bureau of Mines at Nagpur, India. The main manganese minerals present in these mine rejects have been identified as pyrolusite and psilomelane. The purpose of this study was to explore the possibility of evolving a suitable beneficiation flowsheet to obtain manganese concentrates assaying over 72% MnO2 to be used as raw material for the manufacture of dry cell batteries.The sample/material was subjected to characterisation studies in terms of chemical analysis, granulometry and mineralogical compositions. Based on these characterisation studies, the beneficiation process developed comprised of desliming, jigging and low intensity magnetic separation mainly to reject quartz, silicates and jacobsite. The manganese concentrate thus produced assayed 70.2% MnO2 with MnO2 recovery of 78% and weight per cent yield of 63.5. This natural concentrate could be mixed with the electrolytic manganese dioxide produced by the company and this blend can thus be used as a raw material for the manufacture of dry cell batteries by the end users. The paper deals with the details of test work carried out in evolving the process flowsheet."

Jan 1, 2003

By Masoud Askari, Ahmad Rafizadeh, Shahamat Rostami, Mohammad Qaredaqi

Gole - Gohar Iron ore mines located in Sirjan, Southeast of Iran, have more than 1 billion Iron ore deposit and this area comprises 45 % of Iran Iron reservoirs. The aim of Wet tailing processing line is recovering Hematite ore from wet tailing of Gole - Gohar iron ore processing plant. The Investigations of Hematite recovery plant showed that the recovery of Iron ore to concentrate in Wet Tailing Processing (WTP) line is very lower than that has been predicted, sampling, and designing of the process parameters are not accurate and designed magnetic field intensity is not reasonable for the recovery of Iron in form of Hematite in this line feed. Applying of MIMS in WTP separator and changes in circuit caused in overwhelming increase of Fe recovery, from 11 to 40%. Although recovery of WTP line was improved, but low recovery of this processing line and high content of Hematite ore in WTP tailing, made applying Wet High Intensity Magnetic separators unavoidable. Two kinds of WHIMS have tested for processing of WTP line tailing. Results showed that traditional Jones separator with grooved plate matrix, is more suitable to achieve a better quality of concentrate compared to Slon® separator.

Jan 1, 2014

By D. B. Mazzinghy, L. C. de R. Machado, H. Delboni, M. G. Bergerman

"The use of vertical stirred mills in the mining industry has increased remarkably over the past few decades, as a result of growing requirement for finer ore grinding. This equipment delivers higher energy efficiency in fine grinding operations when compared to conventional tubular mills. Methods for designing vertical stirred mills involve operational experience, pilot plants and bench tests. An important issue is that these tests require, at a laboratory scale, at least 10–20 kg of material, depending on its density, which is not available in many cases, particularly in the early stages of greenfield projects. For the regrind of flotation concentrates, several bench scale flotation cycles are required to generate such a sample. This paper describes the development of a laboratory jar mill test using a 6”x8” jar – smaller than that commonly used – based on the overall specific energy method, which requires significantly less mass compared with existing tests. The proposed test has proven to be more practical than tests normally used, requiring about a quarter of the mass, and also shows good adherence to industrial results for the studied iron ore processing plant. INTRODUCTION A significant demand for finer grinding has been noticed over the past few decades in several mining projects to achieve the mineral liberation required for the concentration of valuable minerals. However, the finer the product size, the greater the grinding energy consumption, resulting in an overall increase in operating costs, which may reach or even exceed 50% of the mineral processing cost (VIEIRA, PERES, 2013; DANIEL, LEWIS-GREY, 2011). Comminution technology can have a major impact on subsequent ore concentration stages (DANIEL, LEWIS-GREY, 2011; MARSDEN, 2009; NAPIER-MUNN, 2012; PEASE et al., 2010), which further strengthens the importance of proper technology and equipment selection. Adequate grinding circuit selection and design is thus a key aspect associated with mining projects."

Jan 1, 2018

By E. V. Mezentseva, S. M. Okunev

"In the article there is set forth a development experience of JSC LEBEDINSKY GOK Beneficiation Plant concerning the plan of increase in the production volumes of the iron ore concentrate with Fe content more than 69.5%. There are considered the issues regarding implementation of the updated process scheme of the concentrate beneficiation using fine screening operation, its industrial tests have shown an exploitability of this development direction. There are described the issues relating to the ceramic filters for dehydration of the additionally-beneficiated concentrate, there are given the production and process figures achieved during the exploitation. The methods of the research. In the paper there have been used the following scientific research methods: the methods of system analysis, mathematical statistics, classification, comparison, modelling, observance, experiment. INTRODUCTION JSC LEBEDINSKY GOK is the largest leading enterprise for iron ore beneficiation and the unique RF producer of the merchant hot briquetted sponge iron (HBI) highly demanded by the consumers. Raw materials for hot briquetted iron production are fluxed pellets produced from iron ore concentrate with Fe content more than 69.5% (additionally-beneficiated concentrate). Strategic program of the plant’s development foresees expansion of production of the highly demanded products that imposes a necessity of expending capacity of the enterprise and implementation in production of modern processes and equipment having low resource intensity and ensuring in addition a high efficiency. Construction of the third stage of the HBI Plant became one of directions for the strategic development of JSC LEBEDINSKY GOK implemented in 2017 that caused a demand in the production volumes and filtration of the iron ore concentrate with Fe content more than 69.5%. Purpose of the work – to develop and to provide a rationalization for efficiency of the production process and filtration of the iron ore concentrate with Fe content more than 69.5% ensuring increase of production volumes and its prime cost."

Jan 1, 2018

By V. A. Feofanov

Technogenic water of ore mining enterprises, nonferrous metals operations, the enterprises of electroplating and instrument making, containing copper in the form of those or other connections can serve as perspective sources on receiving the copper-bearing raw material. Extraction of copper from the given water also solves a problem of water treating from a toxic component that reduces environmental load at evacuation of water in an open basin. The method of case hardening allows extracting copper selectively with reception of a deposit with the content of copper up to 70%. Weakness of the method is its efficiency basically in acid reduction, and also its low degree of copper extraction. On the basis of case hardening the method of galvanic coagulation is devised. It is based on the work of a short-circuited galvanic cell of iron-coke at variable contact of coupled metals components among themselves, cleared by the oxygen of air. The following processes of galvanic coagulation are considered: ? Extraction of copper; ? Formation ferrites of copper; ? Copper sorption on just-aggregated oxide forms of iron. Establishing conditions for passing the given stages provides an opportunity of copper extraction from technogenic water at any value of ??, content of salt and concentration of copper with reception of a compact deposit from which it is possible to extract copper by the known ways of enrichment and metallurgy. Investigations on optimization and intensification of galvanic coagulation with the purpose of reception the maximum rich deposit on copper have shown that the average contents of copper in a solution of 100~200 mg/dm3 the contents of copper in a deposit is 6%~10% at extraction 85%~90%, depending on characteristics of treated technogenic water. Using methods of scanning microscopy it is determined structures, composition and mechanism of phase formation in investigated electro-chemical process. The second stage of galvanic coagulation increases a degree of copper extraction up to 98%~99% that allows returning the cleared waters in circulation for waste recycling or evacuation in an open basin. Nowadays the method of galvanic coagulation is the most acceptable for copper extraction from technogenic water both from the point of view of efficiency and instrument setting that allows applying the method in conditions of the working enterprises.

Jan 1, 2014

By Peter Ay, Harry Pempel, Satya Narra, Mike Müller, Jens Markowski

"Within the next few years major changes in mobility are expected. Increasing numbers of electric powered cars, electrobikes and E-Scooters define the transport sector. Recently lithium based traction batteries as storage medium have led into matrurity of series production combining high electrical efficiencies with low weights and compact dimensions. Due to the relatively young development with lithium batteries utilization, only few investigation were conducted regarding their recycling. Conventional battery recycling processes can not be applied due to differences in design and chemistry. So an automated disassembly and processing procedure for lithium traction batteries has been developed in the R/D-project ""Li-WERT"". Instead of complete smelting of the batteries without pretreatment, an automated disassembly and specific treatment of the material streams was realised, adjusted to the needs of the subsequent recovery technologies. A higher quality, with reduced expenses for the separation of fine-grained or fused material mixes, can be obtained for the individual components. The automated disassembly using an industrial robot significantly reduces dangers for the operating crew. The selective disassembly and beneficiation allows full recovery of the fractions. The batteries will be disassembled to cell level by the industrial robot. Anodes, cathodes, and separation layers are isolated and processed. The technology is designed, that no waste is generated for disposal. The pelletised cathode coating and the other separated metals (stainless steel, copper, aluminum) can be used in respective metallurgical plants. Circuit boards and plug contacts are also coveted secondary raw materials for reuse. The process is modular and offers high flexibility, e. g. for new battery types/ sizes by quick adjustment of the robot and tool change. Adaptation to other cathode materials (e. g. Li[FePO]) is possible. After finishing the R/D-project, a pilot plant for demontage was realised in 2013."

Jan 1, 2014

By A. S. Broesder

"With depletion of global ore deposits, there has been an increasing industry trend towards mining of lower average grade deposits in order to meet global demand, resulting in increased processing cost, energy usage and water usage. Consequently the industry is seeking pre-concentration technologies to reduce costs, increase production in existing operations and potentially enable the economic mining of previously uneconomical deposits. This pre-concentration can also advantage downstream processing and metal recovery. CSIRO has developed a large scale magnetic resonance based technology for the rapid quantitative detection of selected copper, iron and arsenic minerals in bulk ore. The technology is suited to measurement on large primary conveyors for enabling “pod” based sorting. The approach used in high tonnage sorting is to not sense and divert individual rocks, but to instead measure groups of rocks (“pods”) carried continuously on a single primary conveyor that can be diverted by conventional mechanical means. Bulk ore sorting operates by removing barren ore pods from a stream of crushed ore based on a bulk sensor measurement at a pod resolution of ~1 – 10 tonnes. The sorting process is based on the intrinsic variability of grade during the mining process that often occurs at the few tonne scale, and for instance, is common in many porphyry copper deposits. The MR technology has been proven in the laboratory for a wide range of copper, arsenic and iron minerals. A full scale prototype sensing system has been demonstrated in a trial at an Australian copper mine. Implementation trials of commercial MR based bulk sorting systems are progressing during 2018.INTRODUCTION An increasing trend in the mining industry is the exploitation of larger lower-grade deposits to meet global demand. Low-grade deposits involve increased processing cost, energy and water usage and increased tailings. There is therefore growing interest in technologies that enable more efficient extraction of low grade deposits. Water intensity of mining activities in a context of water scarcity, and the environmental and health implications of mine tailings are existing challenges, which are only made worse by the progression to lower grade orebodies. There is therefore also an interest in safer, cleaner and less wasteful extraction and production to ensure community well-being and environmental resilience."

Jan 1, 2018

By T. Mütze

The progress in comminution is often described by the specific surface area and the energy utilization or the brakeage ratio and breakage function. The principal mechanisms of size reduction are therefore, well known. All four parameters share a common disadvantage: They are limited in describing the behavior of a feed material with fine particles and a wide particle size distribution. An alternative is to describe the progress in comminution with ? The particle size distributions Q(x) before and after the stress or ? The particle concentration ratio pcr(x), which combines these two states. In the case of a self-similar fracture behavior, (in short: self-similarity) the progress in comminution can be simplistically described by the relationship between a reference particle size and the stress intensity. Self-similarity means self-similar breakage functions of geometrically similar particles of the same strength, a certain stress situation and stresses up to the breakage point. Self-similar breakage functions show the same curve at different stress intensities when the fragment size x is normalized with a reference particle size xNorm. This behavior was demonstrated for single particle comminution repeatedly and unequivocally. In the field of particle bed comminution, these results differ in literature. Therefore, the self-similarity in particle bed comminution was systematically investigated at the Institute of Mechanical Process Engineering and Mineral Processing of the TU Bergakademie Freiberg as part of a research project. Limestone, quartz, silicon carbide and glass beads, were examined with a hydraulic press. The particle sizes covered monodisperse fractions in the range of 1-1000 µm, bimodal mixtures of these fractions and polydisperse fractions. The results obviously show that there is no self-similar fracture behavior in the case of glass beads, quartz and silicon carbide. Statements on the self-similarity of limestone are much more difficult: Only some of the investigated limestone fractions show a similar clear, non-self-similar behavior. Self-similar curves appear particularly for fine monodisperse fractions as well as bimodal mixtures, which stressed with pressures above 200 MPa. Considering the measurement accuracy of particle size analysis the coincidence of the curves can be explained by the fact that progress in comminution almost ends above 200 MPa. At this point, a hydrostatic stress state is reached in the particle bed which is known from the literature. This stress state inhibits further fractures. Overall, it has been verified for the investigated materials that there?s no self-similar fracture behavior in particle bed comminution. One reason for the diverse opinions in literature is that there are three types of particles after the comminution in the particle bed: ? Particles which are stressed below their breaking point, ? Particles which are stressed right up to the break point, and ? Particles which are stressed beyond their breaking point.

Sep 1, 2012

By M. Brennan, A. Majumder

"The mineral processing research community has devoted enormous efforts to the modelling of mineral separators over the last 50 years. While many efforts have been made to use only fundamental physics as a basis for the models, fluid flow patterns in separators are not simple while the motion of particle swarms through fluids is extremely complex.One of the simplest separators is the sluice, in which separation takes place in a flowing film a few millimetres thick. The particles are suspended by turbulent eddies and motion relative to the fluid takes place in so-called hindered settling mode.In an effort to test the extent to which fundamental fluid mechanics can provide a prediction of particle separation, a study on a simple parallel-sided sluice has been carried out using glass beads at various particle concentrations and flow rates.The actual particle separation taking place was compared to predictions made by first describing the fluid flow by a modified ‘law of the wall’ model.Particle concentration distributions were described using Hunt’s sediment transport model, assuming the particle eddy diffusion coefficient to be the same as that for the water. Settling velocities were calculated using either the Richardson and Zaki or Brauer and Thiele models. The latter takes into account particle size and density distributions and solids volumetric concentration.The resulting predictions of particle separation are remarkably good, even though the model does not model the local settling velocity in the slurry."

Jan 1, 2003

By P. Knüpfer, B. Babel, M. Rudolph, F. Perez Maldonado, U. A. Peuker, L. Ditscherlein

"In heterocoagulation processes for the separation of mineral particles, the most famous being froth flotation, the main characteristic of separation is a differing wettability of the constituents to be separated. This most crucial property in the economically important process of flotation is often only and incompletely, quantitatively described in terms of contact angles against water. A water contact angle larger than 90° is referred to as hydrophobic and hydrophilic vice versa. Looking at Young’s equation shows that it is actually the surface energy of the solid in interaction with the surrounding phases and their surface energies (or surface tensions for liquids) which describes whether there will be hydrophobic/hydrophilic hydration interactions leading to attraction or repulsion. This, we have previously published for various more or less hydrophobic minerals in correlation to their flotation response, i.e. flotability (c.f. Rudolph & Hartmann, Coll.Surf.A 513, 380-388). In the same paper we also discussed the heterogeneity of wettabilities as assessed with the novel method of inverse gas chromatography. Furthermore we have also reported on hydrophobic force distributions as assessed with atomic force microscopy which are as well due to wettability heterogeneities (c.f. Fritzsche et al., Coll.Surf.A 459, 166-171).In this paper we present wettability distributions of different substrates and particles with various surface roughnesses/shapes and degrees of hydrophobization as assessed with iGC, AFM and dynamic sessile drop analyses. We are putting the results in context in unifying models and present methodologies helpful to make use of the fundamental information and their impact on the actual industrial separation process in fundamental process models. Besides froth flotation we also emphasize the impact on selective hydrophobic flocculation process."

Jan 1, 2018

By Teja Reddy, Narasimha Mangadoddy, Mandakini Padhi

"In mineral comminution circuits, the feed to hydrocyclone consists of a heterogeneous mixture having varied degrees of liberation and sizes leading to the multi-component particle system. The presence of multicomponent particles exhibits a significant change in the classification performance parameters. In this work, a numerical study is conducted with an artificial mixture of magnetite and silica of different proportions having similar particle size distribution to understand the multicomponent interaction in a laboratory scale hydrocyclone. The heterogeneous feed is injected tangentially would attain different settling rates under the influence of centrifugal, drag and turbulent dispersion forces. In this work, Large Eddy Simulation (LES) is used to resolve the continuous phase turbulence. Modified Algebraic Slip Mixture (ASM) model using the corrected Newtonian rheology of fines to simulate multi-density and multi-size particles of the mixture in a hydrocyclone. The influence of the multi-component particles on classification performance is extracted from the simulation in terms of the performance curve, i.e. recovery to underflow, volume fraction distribution and the key forces acting on each particle in the mixture. An interaction was observed between different components during the classification process, featuring accumulation of heavier particle at wall-side pushing the lighter particles into the inner locus of zero vertical velocity (LZVV) zone. The comparison of separation factors of different size particles presented the higher probability of the magnetite of same size reporting to wall region and hence to underflow. Hence, an increased component cut-size with the increased magnetite proportion, particularly a profound effect on lighter density component’s cut-size was observed. INTRODUCTION The multicomponent existence is found in naturally occurring ores, affecting the pure metal extraction, nonetheless also affects the comminution and classification processes. Among many another classifier, hydrocyclone is a vital equipment used vastly in many industries. The main advantages over other classifiers are a static body, low operating cost and maintenance, high throughput, low floor space requirement etc. A typical hydrocyclone consists of a cylindrical section with a central tube connected to a conical section with a discharge tube. The fluid is injected tangentially into hydrocyclone causes swirling and thus generates centrifugal force within the device. The multiphase interaction inside the hydrocyclone is extremely complex and mostly explained by theories based on hypothesis. In past years, many theoretical models were proposed like a balanced orbital model (Criner, 1950), the residence time model (Reitema, 1961) etc. Though these models give an estimation of the cut-size and other performance parameters, it cannot predict the accurate performance of the actual state of operation. Among these models, the balanced orbital theory is the most adapted concept, based on the force balances of the particle in the dual vortex flow of hydrocyclone. The finer particle is subjected to the inward drag force, generated from the outer vortex flow to the air core, and drags the particle towards the overflow. The larger particle with the higher mass have enhanced centrifugal force and falls into primary vortex near wall reporting to the underflow. Generally, the forces acting on the particle include the drag force, centrifugal force, pressure gradient force, added mass force, Saffman lift force, Magnus force and basset force (Kraipech, 2005). The major forces like a drag, centrifugal, pressure gradient are the function of the particle properties like the size and the density. Hence, the existence of the multi-size and the multi-density particle will affect the separation phenomenon, with the varied forces acting on it. The understanding of the multicomponent classification effect using ores has been only explored in few studi"

Jan 1, 2018

By James A. Finch, Linda Restrepo, Mitra Mirnezami, Amy Buchanan, Maryam Hashemi

Settling rate studies on slurries from Cu/Zn flotation plants occasionally reveals two aggregation maxima at pH 8-10 and 10-12 (Figure 1). From measurements on sphalerite and silica suspensions the double maxima could be replicated. These maxima correspond to the effects of Zn and Mg ions. The aggregation mechanism of both ions is related to the formation of the corresponding hydroxide precipitate. A combination of chemical and electrostatic bridging by the hydroxides is considered to be the aggregation mechanism.

Jan 1, 2003

By Thomas Pretz, Alexandra Pehlken

Sampling of municipal solid waste is known to be difficult to sample if it has to be representative. When dealing with municipal solid waste, the usual method is to study separately waste material below 40 mm and particles bigger than 40 mm. The material < 40 mm cannot be sorted manual and is termed the “fine fraction”. The particles > 40 mm can be separated manually and are usually sorted into pre-defined groups of materials. These groups can be defined depending on the demand of quality assurance. But standardisation of procedures is not far progressed, even for the widely practised sorting methods.

Jan 1, 2003

By A. Collings, A. Farmer

"Power ultrasound may be used in the processing of mineral suspensions to clean the particle surfaces of oxidation products and fine coatings, mainly through the large, but very localised forces, produced by cavitation, which is the formation and sudden collapse of bubbles in a fluid. Cavitation occurs preferentially at solid surfaces in a liquid: at container walls, inserted objects or suspended particles. When the cavitational bubbles collapse near a solid they do so by forming a very high energy jet directed from the point on the bubble furthest from, and directed towards, the surface of the solid, in effect micro jet blasting.This paper highlights some of the major mineral processes where ultrasonics is beneficial namely: Surface cleaning of detrital mineral particles, where container quality glass sand was upgraded to tableware quality and up to 20% improvements in the sharpness of high tension separation of mineral sands was achieved"

Jan 1, 2003

By N. Panteleeva, E. Konoplev, I. Michailova, S. Titkov, T. Gurkova, T. Chumakova, Sylvinit Co.

"INTRODUCTIONFlotation of mineral particles by cationic surfactants – namely alkyl amines and their derivatives – is finding ever growing application in processing of various ores and in quality refinement of the benefication end products, iron concentrates for example. In the recent years application of cationic collectors - alkylmorpholines - enabled the development of new highly efficient procedure of water-soluble mineral processing, being also the one with low energy consumption. This procedure is a reverse flotation of carnallite from bay salts of salt-pans and from carnallite ores.The efficiency of cationic SAS influence depends upon colloid-chemical state of the collector in flotation liquid phase, especially if the latter comprises mineral salts. Availability of clayey impurities or slime particles of iron oxide in cation flotation feed, which actively sorb the cationic collector, deteriorate considerably the cation flotation performances. In Halurgy Institute the investigations of cation flotation under potash and carnallite ore processing have been carried out, and new reagent modes, enhancing cationic surfactants sorption at mineral particles, have been developed. Application of new reagents enables one to decrease considerably the consumption of expensive cationic collectors and to enhance the floatability of coarse mineral particles."

Jan 1, 2003

By Yimin Zhu, Dezhou Wei, Haijun Liang, Zhifu Zhou

Pyrite is one of sulfide minerals most widely distributed in the earth. During the flotating separation of metal sulfide and the floating desulfation of coal, it is often requaired to restrain pyrite. However, the result is not very satisfactory because of the little difference of floatability of minerals to be separated. The problem is extremely outstanding for the floating desulfation of coal. Researchers carried out a number of experiments with T. ferrooxidans (Yang et al, 2001; Zhou et al, 2000; Zhou et al, 2001; Wei et al, 2001) for an enhanced restraint to pyrite. The results showed that the T. ferrooxidans after being cultured works the best in restraining pyrite. After 10 min pretreatment, the removal rate of pyrite from coal is up to 80%~90%. The research results by Yuan Xin et al (Yuan et al, 2000) show that T. ferrooxidans can restrain effectively the floatability of pyrite and can reduce the recovery of pyrite from 95% to 8%. Though the restraining properties of T. ferrooxidans to pyrite have been proved by many tests and experiments, there are very limited reports on its restraining mechanism. Thus, a systematic experimental research is carried out in this paper.

Jan 1, 2003

By P. M. Solozhenkin, V. P. Nebera, V. D. Skorohodov

"Aqueous dispersions of air specifically prepared on the basis of flotation reagent solution acquire active properties in relation to the solid surface and may be imply as a medium for flotation ores. Such aerated solutions were defined as Activated Aqueous Dispersions of Air (AADA) with 5-6:1 ratio and the procedure of mineral separation was defined as a flotation process under non-equilibrium conditions. These procedures differ from conventional flotation mainly in reagent interaction with minerals through their adsorption films on gas bubbles simultaneously forming flotation complexes. Gas-liquid mixture is kept till an adsorption layer of reagents close to the limit value is formed on the surface of bubbles. The theoretical basis of AADA is considered.The results of two-phase gas- liquid mixture (AADA) were studied. Two versions of AADA were considered. Electrical surface potential of the air bubbles with the surfactant film, untreated minerals particles in Coulomb attraction and flotation complex formation were analyzed. Special flotation machines were constructed for separation of mineral suspension in air dispersion, whose effectiveness was confirmed in flotation of apatite waste of Kovdor ore. FK-9 machine introduced on Kovdor iron ore combine for the recovery of apatite from current departures of factory. The froth product contained 7.2 % P2O5, with recovery of 44 % apatite, which was processed for getting melted phosphoric-magnesium fertilizers."

Jan 1, 2003

By E. V. Manlapig, M. C. Harris

"The complexity of the flotation process has made the identification of an appropriate model structure for the predictive simulation of flotation circuits far from obvious. Work performed under the auspices of the AMIRA P9 flotation program has indicated that the metallurgical performance achieved from a flotation cell arises from the interaction of two essentially independent property classes, namely the cell operating conditions and the properties of the cell feed stream. These observations have led to the development of a model structure that associates a constant set of flotation parameters to the streams of the circuit, which are transformed into a flotation response depending on the operating conditions within the flotation cell.A variety of alternative model structures exist within the literature which do not make this distinction between cell and stream flotation properties, and many of these models are in widespread use for flotation optimisation and design studies, both in industry and academia.In this paper, circuit survey and laboratory batch flotation data collected from an industrial flotation circuit are analysed. The data demonstrate that streams in an industrial flotation circuit exhibit varying particle floatability – concentrate streams typically float faster than tailing streams (Figure 1(a)). This floatability, however, is generally conserved around the various units within the flotation process (i.e. the effective floatability of the combined feed and product streams of a unit is equivalent (Figure 1(b)))."

Jan 1, 2003