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By Vasile Murariu, William Pate, John Herbst, Dilek Alkac

"Multiphysics models are essentially first principles models capable of providing very accurate micro scale predictions. The computational requirements for Multiphysics Models are extensive, precluding their direct use for flowsheet simulations. Population balance models get their form from theory but the model parameters have to be provided from experiments. The prediction errors for the population balance models are typically significantly higher than those for the Multiphysics Models but the computational effort for Population Balance Models is typically much less than that for the Multiphysics models. The hybrid model described here takes advantage of the strengths of each of the two primary model types and minimizing the weaknesses of each. The Multiphysics Model is used to perform high accuracy "experiments" that are difficult or impossible to conduct in laboratories or plants. The results of these experiments are combined with standard laboratory or plant data to parameterize and further enhance the Population Balance portion of the hybrid model. The creation of a useful Hybrid Model is demonstrated for a MP1000 secondary crusher. The validation of the hybrid crusher model is also presented. Finally the use of the Hybrid Model is illustrated in a full comminution flowsheet simulator."

Jan 1, 2014

By Venkataramana Runkana, Shantanu Maheshwari

As the world reserves of high quality ores are getting depleted at a rate higher than ever, the liberation of valuable minerals from low grade ores is becoming more and more relevant and imperative. But, liberation of minerals from low grade ores requires grinding of ore to extremely fine sizes. High energy milling in a planetary ball mill is one such option where one can produce particles in the nano-meter range. Although planetary mill is employed extensively for ultrafine grinding, dynamics of grinding inside the mill is not fully understood because of the dependency of grinding kinetics on many interconnected phenomena like collisions between media, particles and wall, time dependent rheology, adsorption and desorption of dispersant, abrasion of media, agglomeration of particles, etc. It was well articulated in literature that media motion and number of media collisions have strong effect on grinding kinetics and final product size distribution. Simulations were carried out using the discrete element method (DEM) to compare the performance of a planetary mill with a ball mill, with and without lifters, in terms of impact energy and number of collisions and it was found that number of collisions is considerably high in the planetary mill. The high number of collisions might be the reason for production of ultrafine particles in the planetary mill. We have also fitted a population balance model (PBM) to experimental data from a laboratory scale planetary mill for prediction of particle size distribution. Unlike previous models, we have incorporated functional forms for the selection function and the breakage distribution function so that the number of parameters in the PBM is just five. The predicted product particle size distributions at different grinding times are in reasonably good agreement with experimental data.

Jan 1, 2014

By L. Stamenov, H. Bouzahzah, S. Gaydardzhiev, D. Naumov

"The Chelopech epithermal arsenic bearing high-sulphidation, copper-gold deposit located in Bulgaria is often referred as the richest European gold deposit currently under exploitation. Key points from the flotation circuit of the processing plant have been sampled and selected physicochemical parameters measured. Plant survey has followed with selected samples being submitted to chemical and mineral liberation analysis (MLA). Quantitative analysis has enabled to link the flotation response of the main copper bearing minerals with the physiochemical parameters (Eh, DO, EDTA extractable Cu and Fe) being measured. Data from mineral liberation analysis have highlighted an important process-relevant information explaining the variable floatability in the various granulometric classes.The low chalcopyrite recovery could be linked to the non-sufficient amount of dissolved oxygen measured in the copper selective flotation circuit. Given the finely-disseminated copper bearing minerals, the observed copper losses inside the flotation could be also explained by the insufficient degree of liberation of the mineral grains. Suggestions for improvement in metallurgical recovery are therefore proposed.INTRODUCTIONThe Chelopech deposit is a high sulphidation (HS) volcanic-hosted epithermal gold-copper one (Bonev et al., 2002; Kouzmanov et al, 2009; Strashimirov, et al. 2002). It is considered as one of the largest and economically most important ore deposits in Bulgaria, and often is referred to Europe’s largest currently mined gold resource. It is located in the Srednogorie zone which falls within the central sector of the extensive Tethyan–Eurasian copper belt formed during Mesozoic–Cenozoic time along the southern margin of Eurasia. The Srednogorie zone has the features of a subduction-related, Late Cretaceous island arc, with development of a calk-alkaline to sub-alkaline volcano-plutonic magmatism and associated hydrothermal ore deposits (Bonev et al., 2002).Ore mineralisation occurs as veins, mineralised breccia, and massive sulphide replacements and disseminations. Three mineralisation stages have been identified at Chelopech deposit. An early pyrite–marcasite mineralisation (stage I), characterised by disseminated to massive pyrite followed and partly brecciated by enargite– luzonite and tennantite–chalcopyrite–bornite (stage II) mineralisation. The gold is met in ores belonging to the stage II. Sphalerite and galena veins characterise stage III, best developed below and adjacent to the pyrite–enargite– chalcopyrite ore bodies. Advanced argillic altered volcanoclastic rocks commonly host this mineralisation (Chambefort and R. Moritz, 2014)."

Jan 1, 2018

By L. X. Zhang

It is very important to improve the A/S of the bauxite to keep sustaining development of Chinese alumina industry. This article summarized the issues of several desilication technologies, which are named as normal flotation, reverse flotation and bi-flotation. Normal flotation has been got industrialization because of technologic advantages. The campaign experiment of reverse flotation which has principle advantage was carried out in 2004, and bi-flotation which is combined the advantages of both the normal flotation & reverse flotation has the most attractive future. The development of bauxite flotation will be focused on multi-utilization of bauxite by mineral process technology and corresponding equipment which satisfied with the flotation technology and reagent.

Jan 1, 2014

By Paulo Castillo, Cesar Gomez, Jaime Alvarez

Operations using flotation to produce mineral concentrates require testing of frothers to characterize their ability to preserve bubble formation size and to build a stable froth. Many techniques have been proposed to measure parameters associated with these two roles. These techniques focus, in general, on only one of these roles and are based on special equipment operated at conditions quite different from those existing in industrial cells and columns. Both roles have been simultaneously characterized in a laboratory flotation column, but the requirements associated with the installation and operation of one of these units, are a serious limitation for its use on-site. A technique based on the use of a laboratory mechanical cell, a common piece of equipment in operations, will have wider application. Establishing the ability of a frother to control coalescence by preserving bubble formation size is done through bubble size measurements as a function of frother concentration. Froth build-up and stabilization is associated with the amount of water carried by bubbles into the froth layer, which has been demonstrated to correlate with the gas holdup in the collection zone. Procedures devised for determining the critical coalescence concentration (CCC) from measurements of bubble size as a function of frother concentration, and the gas holdup by collection of water displaced from the cell by the presence of bubbles at different frother concentrations, were tested. Three analytical-grade frothers were utilized: a straight-chain (1-heptanol) and a branched (MIBC) alcohol and a polyglycol (PPG425). The results obtained at a standard set of conditions, demonstrated consistent differences between these frothers, and the ranking from least to most effective for reducing bubble size or decreasing water drainage followed the same sequences found when more complex frother characterization techniques are used.

Jan 1, 2014

By M. Evertsson, E. Hulthén

"In aggregate production and mining the operators are responsible for controlling and monitoring the process to maintain high plant throughput and safe operation. Operators have to make different decisions to control the process due to changed demand on the operation from both management and conditions of the process. The quality of the response and the time it takes for an operator to respond to altered demand relies on what information is available and the experience of the operator. In this work a dynamic simulation platform has been developed to be used for operator training. Models for representing production units and process control for plant simulations have been developed and implemented in MATLAB/SIMULINK to simulate time-dependent plant behavior. Stochastic and scheduled events are included using the discrete events simulation toolbox SimEvents. The human-machine interface was developed using the human-machine interface software ICONICS. The operators’ cognitive process, in interpreting the plants semantic, has been studied by observations and with informal interviews with operators. This was done to get information about the daily operation and the problems that occur in the process. By interacting with operators that experience different physical interactions with the process; more qualitative e-learning software for supporting operator training in a dynamic operator environment could be developed. The quality of the operator training environment was evaluated with a usability study that was performed with operators and others within the production."

Jan 1, 2014

By J. Jávor

The response of the air/water interfaces to deformation in presence of surfactants is affected by the adsorption/desorption rate, re-orientation and exchange rate of surfactant. These surface properties can be observed using equilibrium and dynamic surface tension and surface elasticity measurements. However, the effect of these parameters on bubble size in dynamic conditions has not been studied due to the difficulty in capturing freshly formed bubbles in dynamic conditions. The paper presents a new experimental set-up designed and built at the Aalto University, called Shear Force Observation Chamber(SOC). The setupallows the monitoring and analysisof freshly formed air/liquid interfaces in dynamic conditions and facilitates the study of the effect of dynamic surface tension and surface elasticityon freshly formed air bubblesin presence of surfactants. The method helps to establish correlation between bubble size and dynamic interfacial properties and bubble-bubble interaction in turbulent flow. Dowfroth 200, Nasfroth 240 and Dowfroth 250 commercial flotation frothers were tested in this study. The results show a marked difference between results obtained in dynamic conditions compared to the static conditions. The results are presented and the reasons and implication to flotation modelling are discussed in the paper. Keywords: shear force observation chamber, flotation frothers, flotation bubbles, critical coalescence concentration

Sep 1, 2012

By B. McFadzean, K. Moller

"The mechanism whereby thiol collectors adsorb onto a mineral surface has been widely studied. Most of these studies examine the mineral surface at equilibrium state and, often, well above monolayer coverage. However, the formation of species at the mineral surface is a complex process that is both kinetically and thermodynamically controlled. In a typical industrial application, the dosage of collector will be around monolayer level. This study uses isothermal titration microcalorimetry to measure the heat evolved during the reaction of sodium ethyl xanthate (SEX) and sodium isobutyl dithiocarbamate (SIBDTC) and their mixtures with galena and chalcopyrite. The sensitivity of the instrument allows heats of reaction of sub-monolayer quantities of thiol collector to be measured.The study found that both the magnitude and kinetics of the reaction between a collector and a mineral surface was dependent on the type of mineral and the type of collector. Proposals are made for the reactions based on literature and the evidence from this investigation. It was found that when collectors were reacted with mixtures of galena and chalcopyrite, that the magnitude of the reaction was lower compared to that measured for the pure minerals alone. This may be due to galvanic interactions between the minerals, resulting in a passivating effect on one or both of the minerals."

Jan 1, 2014

By Kaioeng Wang, Qi Liu, Yahui Xiang

"In the differential metal sulfide ore flotation it is desirable to replace the toxic inorganic depressants with environmentally benign chemicals. Chitosan, as a natural and non-toxic polymer, has been proven to be an efficient depressant for chalcopyrite while allowing galena to be floated by xanthate collectors. However, the poor solubility of chitosan limits its potential applications as the flotation could only be carried out at about pH 4 where chitosan is soluble. A carboxymethyl derivative of chitosan, named N-carboxymethyl chitosan (N-CMC), was synthesized by substituting the amino groups of chitosan with carboxymethyl groups. The substitution significantly improved the solubility of chitosan. The structure of N-CMC was studied and compared with chitosan via Fourier transform infrared spectroscopy (FTIR). Flotation tests were performed on single minerals and mineral mixtures (with weight ratio of 1:1) with the addition of appropriate amount of potassium ethyl xanthate (KEX) and N-CMC. The solution pH was varied from neutral to alkaline. The flotation concentrates and tailings were collected and analysed for the contents of copper and lead. FTIR measurements showed that new peaks of C=O stretching of -COOH and N-H deformation of -NH- appeared in N-CMC, which indicated that the carboxymethyl groups were introduced and the amino groups were the sites for the substitution. Flotation results indicated that N-CMC could depress either chalcopyrite or galena depending on the pH. The results were not affected by the sequence of KEX and N-CMC addition. Therefore, N-CMC is potentially useful in Cu-Pb sulfide separation following a bulk Cu-Pb flotation. The N-CMC was also found to have surface cleaning functions, and was able to remove contaminating copper ions from galena surfaces. Therefore, its application in sulfide ore flotation is expected to be more robust than the original chitosan."

Jan 1, 2014

By Kyle P. Flynn, Frank J. Hrach, James D. Bittner

ST Equipment & Technology, LLC (STET) has developed a processing system based on tribo-electrostatic belt separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to other electrostatic separation processes that are typically limited to particles greater than 75µm in size, the triboelectric belt separator is ideally suited for separation of very fine (<1µm) to moderately coarse (300µm) particles with very high throughput. The high efficiency multi-stage separation through internal charging/recharging and recycle results in far superior separations that can be achieved with a conventional single-stage free-fall tribo-electrostatic separator. The triboelectric belt separator technology has been used to separate a wide range of materials including mixtures of glassy aluminosilicates/carbon, calcite/quartz, talc/magnesite, and barite/quartz. An economic comparison of using the tribo-electrostatic belt separation versus conventional flotation for barite / quartz separation illustrates the advantages of dry processing for minerals.

Jan 1, 2014

By Edson Charikinya, Pierre-Henri Koch

"The extraction of mineral values from ore requires liberation followed by separation steps. Liberation is achieved by size reduction operations which are energy inefficient processes typically dominating the energy consumption in a mineral concentrator. As the grade of ore reserves declines, future viability of mineral operations will be determined by energy costs of comminution. The application of high power microwave energy to secondary crusher products has been suggested as a possible commercially viable thermal treatment method for reducing comminution energy and improving value mineral liberation. Recent studies have shown that microwave pre-treatment of coarse sphalerite ore particles (> 5mm) at specific microwave heating energies (1-3 kWh/t), induces microfractures and creates new crack surfaces. This suggests that subsequent crushing of these microwave treated particles could yield enhanced liberation. However, limited studies have been carried out investigating the mode of breakage and the extent of enhanced liberation in that case. The objective of this study is to develop numerical methods for quantifying the extent of enhanced liberation and mode of breakage in crushed microwave treated and untreated particles. Sphalerite ore particles representing small (-5+4.75) mm, medium (-16+9.5) mm, and large (-25+19) mm HPGR and cone crushed particles were microwave treated at specific energies between 1-3 kWh/t. Cracks in the ore particles before and after microwave treatment were analysed with QEMSCAN and numerical models of the measured particles (before and after microwave treatment) were developed in MATLAB. The propagation of random and non-random cracks was investigated by simulating comminution of the modelled treated and untreated particles. Results of this study demonstrate that the breakage mechanism and the liberation of valuable minerals from gangue in microwave treated and untreated particles is significantly different. This study contributes to the development of numerical tools to quantify crack propagation in heterogeneous ore particles."

Jan 1, 2018

By Cagri Emer

In conventional mechanical flotation cells, when the size of particles exceed a particular value, that is of the order of 100 µm for metal sulphides, the recovery of particles decline rapidly. It appears that the turbulence in the agitated vessel is sufficiently intense to rupture the forces of attraction between the particles and the bubbles, so the large particles are flung off the bubbles in the turbulent field. It has recently been suggested, that a fluidized bed would be a very favorable environment in which to contact bubbles and the particles. In a fluidized bed, particles are supported by rising flow of fluid, which separates them from each other and allows them to move freely while remaining close together. In this novel method, bubbles injected into the fluidized bed are able to rise through it, colliding with hydrophobic particles, transporting them to the top of the column where they can form a froth layer that overflows into a launder. The flow in a fluidized bed is generally slow and nonturbulent, and preliminary experiments have shown, that it is possible to collect mineral particles as large as 1 mm and coal particles as large as 5.5 mm. If the upper particle size limit can be extended, there could be significant reductions in the overall energy consumption in concentrators. Calculations show for example that if the top size for flotation could be increased from 100 µm to 400 µm, there would be a reduction in grinding energy of the order of 40%. It is therefore, important to study the mechanism of coarse particle capture in fluidized beds. In this work, the factors governing the capture rate of particles, particularly the particle and bubble size, the fluidization velocity and the superficial gas velocity have been investigated, and the results will be presented.

Sep 1, 2012

By D. I. Verrelli

Within the flotation community a belief has developed that some particle shapes are more ?floatable? than others. This is usually attributed to an influence of particle shape or roughness on the induction period required to achieve attachment between the particles and the air bubbles in the pulp. Up to now, such measurements have not been able to readily isolate the effect on individual flotation subprocesses. In contrast, our experimental apparatus, the CSIRO Milli-Timer, enables us to directly observe the process of particle?bubble interaction and attachment by means of a high-speed video recording, thus providing a direct measure of the induction period for attachment. To assess the influence of particle shape on induction time we used two varieties of methylated borosilicate glass particles ? spheres and angular ?frit? ? in a range of tightly-sized fractions. In doing this, we take care to account for the influence of other factors that could affect the induction time, such as the polar angle of sliding commencement, and approach velocity. These parameters are recorded as variables for each interaction, and corrected for using multiple nonlinear regression. Our results illustrate the importance of particle shape on induction period, with angular particles exhibiting induction periods that were an order of magnitude lower than those of spheres. Furthermore, the induction period was seen to decrease with increasing particle velocity, or kinetic energy on approach, but increased as the trajectory approached the limit of just grazing the bubble. Particle shape in mineral processing is a consequence chiefly of the mineral type and the type of grinding employed. The results presented herein indicate that attention should be paid to the shape of particles obtained from the grinding operation, besides particle size. Keywords: attachment, bubbles, flotation, induction period, particles, shape effects, surface roughness

Sep 1, 2012

By A. Sand

Within stamp-charged coke making a large volume of coal is compacted to one single coal cake before entering the coke oven chamber. This is done by means of several falling stampers in a stamping machine having a mold nearly of the oven?s dimensions. Producing a high quality coke also from inferior coals requires a cake density of approximately 80% of the coal density. Besides that the industrial stamp-charging process demands a minimum mechanical strength of the coal cake to move it from the stamping mold into the oven chamber without failure. Densification and the build-up of cake strength were investigated earlier in stamping tests using a micro-stamping device. The quantities derived from these tests (as e.g. cake density or porosity) represent average values for the entire cake. Statements describing the local compaction state at different heights are difficult to achieve without destructing the cake. In order to gain better insight into the densification process and the inner structure of the coal cake a computational model based on the discrete element method (DEM) has been set up using 2 and also 3-dimensional simulation software. The stamper?s position and velocity as well as the force acting on the stamper were monitored and the model?s response was compared against measurement data from laboratory stamping tests. It was possible to reproduce the force and displacement pattern of the stamper in response to the viscoelastic properties of the cake using standard DEM bonding and contact models. Furthermore, the rearrangement of particles in response to the compaction by the stamper was tracked by calculating their displacement at the point the stamper hit the coal surface. The latter can also be used as indicators of particle deformation or breakage. By defining control points at different heights the particle displacement, stress and strain rates, porosity could be studied at different heights. Keywords: coke making, coal stamping, compaction, agglomeration, DEM, simulation

Sep 1, 2012

By W. P. Roux

With depletion of higher grade iron ore reserves, and the need to process finer, lower grade material; there is a need to better understand the recovery efficiency of jigging process. The use of Positron Emission Particle Tracking (PEPT) was examined as a technique, to study the motion of particles inside a laboratory batch jig. PEPT is a noninvasive method that can provide three dimensional kinetic data of a particle during jigging. Particles with different densities and sizes were traced under the same jigging parameters, to obtain a data set that can be used for the development and verification of jigging models. From the results, detailed information on the stratification rate of a particle was obtained, with adequate resolution to see particle movement through an individual pulse. Detailed data of this nature is critical for the validation of CFD and DEM models. Keywords: positron emission particle tracking, jigging, jig models

Sep 1, 2012

In looking to the future of mineral processing the focus is typically on improved processing units. Basically it is a search for an elusive wonder machine that could revolutionise the economy of mining: the sorter that strips 50% of the ore with only a few % loss of value; the comminution device that uses 5% of the energy while producing fully liberated particles; or the recovery device capable of producing a 99% recovery at 99% grade. These aspirations are propounded against a reality backdrop of sorters rusting in back yards, mill throughputs below design and varying by 30%, cyclones flaring and cut-sizes fluctuating, mediocre recoveries and soaring processing costs. This disconnect between aspiration and reality appears, to these authors at least, to be a mighty chasm. Moreover, it remains one over which we are expected to magically leap rather than methodically bridge. Indeed one may be forgiven for thinking that should such a wonder machine come along, taking advantage of it would be highly improbable. Questions would inevitably emerge on how to feed the correct material, how to cope with the wide variability of feeds, how to control such advanced equipment and how to handle the new product from such a machine. It is likely these questions might lie unanswered, or more regrettably, unasked. It is generally accepted that as an industry we are exceedingly unlikely to teleport from the current status quo to an entirely new reality in a single flash. It is our thesis that the probability of these magical machines materialising is remote, and even if they miraculously appeared, we simply wouldn?t know what to do with them. Rather, it is our contention, that a step change will only arise through a staircase rather than from a single giant leap. We should focus on building those steps and linking them together into a firm structure ? a workable mineral processing circuit. This paper addresses the alternative of a coherent set of modest but significant improvements, integrated to produce the step change we desire: essentially, a reduction of processing energy to below 40%, which we believe is achievable without recourse to any mystical machines. A key underlying capability to designing these dramatically improved processes, is the weaving of independent process models into a coherent circuit simulation, in order to design the new generation of mineral processing circuits. Keywords: step change, circuit design, circuit simulation, energy reduction

Sep 1, 2012

By R. Hejazi, Saghaeian. M., H. Abedini

Continuous vacuum belt filters mainly carry out an important duty in the solid-liquid separation processes such as iron ore concentrate dewatering. However as the particles become finer, the resistance to filtration and dewatering would increase and as the result cake moisture content tends to increase. So in recent decades, using additives in order to improve the filtration performance has been considered by many researchers. In the present study, the effect of several surfactants on the filtration rate and cake moisture content of Chadormalu iron ore concentrate (80% =40 micron) was investigated using a laboratory scale vacuum filter. The results of several tests indicated that a non-ionic surfactant (Lauryl Alcohol Ethoxylated, LAE) has the best performance on reducing the moisture content of the cake and reducing the cake formation time. The optimum dose of LAE was found to be 300 g/ton which reduced the concentrate cake moisture content from 13.76 to 11.28% (wet weight base). Some industrial filtration tests were performed in Chadormalu iron ore concentrate plant to prove the effectiveness of this surfactant. The surfactant is mixed with water and added to the concentrate slurry before distributing on the vacuum belt filter. The industrial and experimental results were almost similar, so that adding about 300 g/ton of LAE would reduce the final cake moisture content from 12.87 to 10.76%.

Jan 1, 2014

By M. E. Taranenko, V. A. Krivonosov, S. A. Nemykin

"In concentrating production energy-consuming power installations are wide used, the most powerful of them are the wet autogenous grinding mill operating in closed circuit with a spiral classifier. The analysis of the current state of the automation of the grinding process shows that the reserves for maximizing productivity and minimizing electricity consumption have not yet been exhausted on the existing process equipment. Usage of the achievements of the modern management theory reveals an opportunity for further optimizing of the grinding process. The purpose of the research is to develop an automated control system of complex ""the mill-classifier"" to conduct the grinding process in the most operating efficiency, ensuring the maximization of productivity and minimization of specific electricity consumption. The main idea of this work is to study the specific features of the ore grinding process and creation on this basis of automated control system complex ""mill-classifier"" which allows to find and to maintain the optimal mode of grinding based on identification of the current object parameters, observance and regulating of the object state coordinates. Research methods. We used the methods of system analysis, mathematical statistics, modern automated control theory, theory of systems identification, optimal control, modelling of dynamic processes. Developed scientific provisions: - identification algorithm of the loading sub-system management object of complex ""mill - classifier"" allowing to obtain the unbiased estimators of its parameters according to the data of normal object exploitation; - observing device, which differs from the classic version of the observer Luenberger with possibility of estimating not only the state coordinates of the control object, but also the low-frequency perturbation component; - automated system stabilizing the active power of the grinding mode on the basis of a states controller with Luenberger observer; - structure of the software and hardware that implements the developed models, algorithms, methods of control, management and optimization in the framework of the automation of grinding."

Jan 1, 2018

Opportunities to monitor and control primary grinding mill performance are strongly sought after in the mineral processing industry. Currently, limited on-line information about mill charge motion and content is available to mill operations for control purposes, leading to periods of lower throughput, instability, variable product size and accelerated mill liner and lifter wear. In response to this need, CSIRO has developed an on-line surface vibration monitor for primary grinding mills which produces data that has been shown to provide new information about the mill charge in terms of toe and shoulder position, as well as potentially key features such as the overall charge level, the distribution between rock and balls in the mill, and the impact of the charge on the mill liners and lifters. This paper outlines the key features of the on-line monitor system, particularly those relating to data transmission, data analysis, and the design of the monitor and its independent power supply. It describes the coupling of single vibration sensor data from the CSIRO on-line monitor to the actual operating conditions of a SAG mill and how the vibration response and hence mill operating conditions vary as a function of time, including during mill equipment failures such as a broken discharge grate. Opportunities for improved mill control based on the data from the on-line monitor are also discussed, as well as the implications in terms of mill processing and maintenance performance. Recently a CSIRO monitor was also installed on a ROM ball mill and analysis of the vibration sensor data from this installation is currently underway. Preliminary findings from this installation will be presented along with comparisons of generic information, such as toe position (measurement precision and operation variability) and vibration signal (intensity, sensitivity and operation variability), between this type of primary grinding mill and AG/SAG mills.

Sep 1, 2012

By A. Kurkov

Flotation process is based on the formation of primary collector-based supramolecular associates at the mineral surface and within the pulp. Supra molecular chemistry allows studying within a common framework, all kinds of molecular associates, from dimers to large assemblies, resulting from spontaneous association of a large number of interacting components of the flotation system, where the collective action of non covalent bonds can have an important role. Self-organization of supra molecular assemblies in the flotation process can be controlled by modifying the chemical structure of the collector, the nature and arrangement of functional group in it, by introducing secondary agents (SA) into the process, to adjust the interaction between the collector and the surface and to control the hydrophobicity of the adsorption bed. This offers broad opportunities to build supramolecular assemblies to improve the efficiency of flotation. Besides, the more complex is the system, the weaker are the interactions, that determine its behavior. This powerful factor still is not employed deliberately to control the flotation process. Organophosphorus compounds (OPC) - dialkyl phosphoric acids whose radicals contain ethoxylated groups ? are considered as nanocompounds, that can be used in building supramolecular assemblies. The presence in an OPC molecule of functional groups (P=O, P (O) O-, P (O) OH), ethoxylated groups, and aromatic rings is the basis for the formation of stable supramolecular associates. Gross formula: C54H94KO16P. Molecular weight is 1069.39. Phosphoryl anion has a regular tetrahedral structure with the angle of 109.5°. Lengths of -P-O- bonds in a PN molecule are 1.7345Å; length of the hydrocarbonic radical C42-C72 = 33.942Å. In an alkaline environment, PN is in the form of the anion, in an acidic environment ? in the form of the polycation due to protonation of the oxygen in the EO group. Chem Office software suite was used to generate three-dimensional images of an OPC molecule in acidic and alkaline environments, to reveal the OPC geometry (bond lengths, valence angles, aliphatic radical length), to identify the collector&apos;s binding sites with the mineral surface, to find the most stable and energy-efficient molecular conformations of an OPC molecule and its complexes with minerals under various conditions. Mechanisms of interaction between OPCs and the mineral surfaces are different. In ores whose minerals are dominated by ionic bonds (fluorite), the interaction mainly involves the anionic form of the collector; in ores, whose minerals are dominated by covalent bonds - the oxygen of the phosphoryl group (donor-acceptor interaction) and the oxygen of the ethoxylated groups. This difference is responsible for the formation of spatial associates with different surface layer structures. Introduction of supramolecular chemistry concepts into the analysis of flotation phenomena and mechanisms can become an effective tool for better understanding the flotation process and offers new means of consistently improving its effectiveness.

Sep 1, 2012