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By Gianni Bartolacci, Patrice Nadeau, Szatvanyi. Gerard, Carl Duchesne, Claude Chrétien

"Combustion is used throughout the mineral processing industry to produce steam in boilers, to dry concentrates in rotary dryers, and to apply heat treatments in pyrometallurgical furnaces. Tight combustion control is very important in latter type of furnace since the combustion conditions directly affect final ore quality. However, achieving tight combustion control is not straightforward since most of the flames encountered in industry are turbulent non-premixed flames, they are affected by several unmeasured disturbances and are often produced by burning several types of fuel simultaneously, some of them coming from other parts of the plant. A novel method is proposed in this paper to improve process and product quality control as well as to optimize the combustion conditions based on digital flame color images. Multivariate Image Analysis and Regression is to used extract the flame color characteristics from images to predict the solids discharge temperature of an industrial rotary kiln. It is shown that this method yield extremely good 10 minutes ahead forecast of the temperature and should lead to a substantial reduction in product quality variability as well as in fuel consumption.INTRODUCTIONFuel-fired furnaces are often used in the mineral processing industry for various purposes, such as for the production of steam (utility boiler), in conjunction with rotary dryers to dry mineral concentrates or in pyrometallurgical processes for induration, roasting, and so forth. These furnaces are necessary in the supply chain from the mine to the metals, but their operating costs are constantly rising due to the fluctuations in fuel prices. Moreover, these processes are now targeted by the Kyoto Protocol since they are energy intensive and they produce significant amounts of CO2 and other pollutants such CO, NOx and SO2. To achieve both a reduction in operating costs (i.e. fuel consumption) and in pollutant emissions while maintaining or improving product quality, one needs to have a very good control of the combustion process."

Jan 1, 2005

By Åke Krukka, Heribert F. Broicher

"The iron ores of the Kiruna Mine in Sweden are of exceptional quality but for the phosphorus content in certain zones of the orebody. The prevention of mixing ores high in phosphorus with those low in phosphorus has always been of significant economic importance. The ongoing introduction of tele-mining and automatic haulage by LHDs requires new means in the field of quality control underground, as the experienced miner as well as the underground laboratory assistant no longer are involved in the process. As of 1998 LKAB has been testing prototypes of LIF Analysers for non-contact and real-time measurement of the phosphorus content of ore being transported by LHDs from the stopes to the respective ore pass assigned to a certain ore quality. The principles of the analysis of laser-induced fluorescence, the different test phases and results are described and conclusions made. With bulk sorting of ore underground the mining engineer supports the efforts of the metallurgist in the processing plant.INTRODUCTIONThe Kiruna Mine of LKAB, Sweden is the largest underground iron ore mine in the world. In the early nineties LKAB decided to develop the Kiruna orebody further down from the 775m main level to a new main level at 1045m. This development programme was realised while in the mineral processing section and in the pellet plant further capacity was added (Wyllie 1996).In addition to deepening of the mine, which opened up 330 million tonnes of ore, the exploitation of the so-called lake ore was included in the future planning, adding another 1 15 million tonnes of mineable ore. At an annual production of approximately 20 million tonnes of ore the Kiruna Mine today looks at a developed ore reserve sufficient for the next 20 years.All of the competitors’ ores traded in the world market are from open pit operations. LKAB compensates for the obvious disadvantages by continuous efforts to make the best possible use of her high quality magnetite ore deposit. This objective is realised by combined efforts in the pellet plant, the mineral processing plant and the mine. Propriety processes, latest big scale equipment and high tech solutions for automation lead to high quality sales products at a reasonable cost."

Jan 1, 2002

By Yongbao Zhu

The Ag2O-mediated reactions of cycloaurated compounds with a general formula Au(L)Cl2 (L = bi-dentate C?N ligand) with thiosalicylic acid, N-acetyl cysteine or 1,2-benzenedithiol in DMF proceeds via ligand substitution of the Au?Cl bonds to afford the S-O and S?S adducts all in good yields. The reactivity of the dichloro, S-O and S-S adducts towards thiols were examined by reacting with cysteine in an aqueous medium, revealing that all of Au-Cl, Au-O and Au-N are labile for thiol displacement. The measurement of the inhibitive activities of these compounds against human cathepsins B and K showed that the dichloro and S-O adducts are effective inhibitors with IC50 values ranging from 0.1 to 2.6 -M, and that the S-S adducts are inactive.

Oct 1, 2003

By T. Hidayat, D. Shishin, S. Sineva, M. Shevchenko

The effects of the slagging components Al2O3, CaO and MgO on the thermodynamics and phase equilibria of the gas/slag/matte system with major elements “Cu2O”-“FeO”-SiO2-S are characterised using an integrated experimental and thermodynamic modelling approach. The experimental technique included high-temperature equilibration experiments using a spinel substrate in controlled gas atmosphere (CO/CO2/SO2/Ar), quenching of the sample and subsequent measurement of the compositions of equilibrium phases with Electron Probe X-ray Microanalysis (EPMA). Thermodynamic modelling is undertaken using the computer system FactSage. In previous experimental studies on this system, the separate effects of Al2O3, CaO and MgO were determined. In the present investigation, the combined effects of these additional components are investigated at 1200oC and P(SO2) = 0.25 atm and a range of P(O2)’s. Special attention is paid to ensuring chemical equilibrium is achieved in each case, for this reason possible kinetic factors are systematically analysed. The results obtained are presented in the form of graphs showing the compositions of matte and slag phases as functions of copper concentration (matte grade). The new experimental data are used for the improvement of the thermodynamic database for multicomponent copper-containing systems. The effects of the slagging elements on this multicomponent system will be presented in the paper. INTRODUCTION Whilst Fe-O-Si form the principal components of copper smelting and refining slags, additional impurities are present in industrial practice typically at 2–5 wt.% Al2O3, 1–4 wt.% CaO and 1–2 wt.% MgO levels (Davenport, King, Schlesinger, & Biswas, 2002). These elements are introduced into the slag as impurities in concentrates and other feedstocks, in fluxes added to the process and in refractory materials. Understanding, and accurate description, of the changes that take place in the smelting process in the presence of these additional elements is of major importance to the optimization of industrial operations. Although experimental data are available on slag/copper matte equilibria, further work is needed to accurately characterise the influence of Al2O3, CaO and MgO on phase equilibria and elemental distributions of elements in gas/slag/matte systems. The individual effects of the Al2O3, CaO and MgO slagging components on equilibrium phase assemblages under selected conditions have been quantified in a recent series of studies on the Cu–Fe–O–S–Si-(Al, Ca, Mg) gas-slag-matte-metal system (Fallah- Mehrjardi, Hayes, & Jak, 2018; Fallah-Mehrjardi, Hidayat, Hayes, & Jak, 2017a, 2017b; Hidayat, Fallah-Mehrjardi, Hayes, & Jak, 2018a, 2018b; Jak et al., 2016; D. Shishin, Decterov, & Jak, 2018; Denis Shishin, Hayes, & Jak, 2018). Since, thermodynamically, the condensed phases do not behave ideally, it is to be expected that the effects of individual elements may not be additive, and the additional interactions between the Al2O3, CaO and MgO slagging components will also have to be taken into account. These additional effects are expected to be smaller than those of the individual components, so higher accuracy is needed. The present paper describes analysis of the precision and accuracy of the experimental technique on multi-component, multi-phase equilibria in these systems to enable the combined effects of Al2O3 + CaO + MgO on slag/matte/spinel equilibria, i.e. for high Fe/SiO2, to be accurately measured. The effects of Al2O3, CaO and MgO on the gas - slag - matte are analysed using a thermodynamic modelling approach with the computer package FactSage.

Jan 1, 2019

By S. R. Knowles, R. J. McDonough

"The purpose of this paper is to introduce to the minerals processing marketplace a viable alternative to conventional mechanical agitation and pachuca airlift agitation. What follows is a brief introduction to the Atara Corporation and the fundamentals of how an Atara ""cannon"" mixer operates. The main body of the paper is concerned with the results of a study to evaluate the cannon mixer for a gold cvanide leach application. A brief summary of research and testing for other metallurgical applications is also presented.1. 1 THE COMPANYThe Atara Corporation is a privately owned Canadian company, headquarted in Dorval, Quebec. Its subsidiary, Atara Incorporated, located in Paramus, New Jersey services the municipal wastewater treatment market in the United States. Dorval focuses on industrial mixing applications in Canada and the US. The Atara Corporation provides design, engineering and specifications of agitators for mineral land other) processing applications. Fabrication of mixers is pursued in either Canada or the US, depending on the ultimate destination.Although Atara and its unique static in-tank mixer are relative newcomers to the mining industry, the cannon mixer has demonstrated its value over the past 20 years in municipal wastewater treatment services. In the past four years the Atara unit has been developed for industrial applications; the bulk of the development work has been for metallurgical applications. To-date the cannon mixer has been evaluated for mixing slurries in the following applications: nickel-copper concentrate storage, copper concentrate storage, coal slurry storage, gold cyanide leaching, uranium acid leaching, silver leaching and zinc acid leaching. Atara mixers have been installed with successful performance in full scale tanks containing nickel-copper concentrate slurry (Falconbridge) and gold cyanide leach pulp (Dome"

Jan 1, 1984

By C. O’Hara, S. Roy, K. Swedburg, J. Katchen

"New Gold Inc.’s New Afton concentrator commenced operation in June 2012, producing a copper-gold-silver concentrate. During the first two years of operation, various optimization efforts have improved mill throughput, recoveries and concentrate grade. Daily mill throughput has increased 20% above the design rate. This was achieved through more consistent instantaneous feed rate and size distribution from the mine reclaim stockpile, higher pebble crusher reliability, changes to the SAG and ball mill grinding media sizes, larger SAG grate openings, reduced SAG discharge screen-deck aperture size and an increase in the maximum ball mill power draw limit. Metal recoveries at New Afton are primarily limited by liberation in the coarser size fractions; therefore, improving the grind size at a given mill throughput has been the main means of improving recovery. The average rougher flotation feed F80 size was reduced from 175µm in Q1 2013 to 165µm in Q1 2014, while the average operating mill throughput increased by 25%. Other flotation circuit changes focusing on recovery improvement include the addition of froth crowders to the rougher cells and the use of a stronger frother. The average concentrate grade increased from 22% Cu in Q1 2013 to 25% Cu in Q1 2014. This was achieved by redirecting the flash flotation concentrate stream to the regrind circuit and by the addition of lime to the cleaner circuit.This paper describes the above improvements made at the New Afton mill. The paper describes the objectives, timing and end result of each area of improvement.IntroductionThe New Afton Mine is situated approximately 10km west of Kamloops, British Columbia, 340km north-east of Vancouver. The mine has a moderate climate, access to transportation and electrical infrastructure, nearby fresh water supply, and close proximity to industrial and mining service businesses. The population of Kamloops is around 90,000 with most mine employees living in or around the city."

Jan 1, 2015

By K. J. Fair, H. W. Smith, D. R. Francis, J. M. Toguri

"Bench-scale batch milling and screening tests were carried out on secondary aluminum dross 10 produce an aluminum concentrate. To complement these tests, an analysis of a commercial plant was also performed by sampling dross at various stages in the plant's milling and screening circuit. These studies have indicated that benefits of increased capacity, grade and recovery of aluminum metal can be realized by addition of screens before the ball mill, longer grinding period and by grinding the smaller size fractions more efficiently.To test the predictions, a plant test was performed on the milling of100tons of secondary dross. The recycling of the large size fraction (+1/8 in.) of aluminum dross through the impact mill rather than through the rate limiting ball mill resulted in a comparable aluminum grade. The ball milling of the _1/ 8 in. + 10 mesh size gave a dross grade of71% AI. A lower feed rate to the ball mill resulted in a higher final grade. With minor modifications, secondary dross can be processed in 22% of the time it takes with the present circuit without a sacrifice in grade.IntroductionSecondary aluminum dross is a mixture of metallic aluminum, aluminum oxides and salts (alkali halides). Any comminution process deforms or slowly grind s the malleable metal phase and reduces the size of the friable, brittle, oxide-salt phase relatively fasterr(1).The milling of aluminum dross is performed to upgrade the metallic aluminum fraction. Figure I shows a flowsheet for the milling of secondary dross as presently practised at Metals and Alloys Co. Ltd., Toronto, Ontario. At point A, large acceptable grade material is hand picked for refurnacing, the unacceptable off-grade material is sent to the sweat furnace and the remaining, + 2 in. fraction is recycled through the 3.9 ft by 4.1 ft impact mill. For simplification, three ball mills are shown. However, in reality there is only one, a 5 ft by 10 ft ball mill used in a semi-batch mode. The 2 in. + 3/8in. and 3/8 in. + 10 mesh products are remilled in the ball mill. The -10 mesh material is discarded as waste."

Jan 1, 1987

By Barara Rose

Presentation Outline ?Introduction of BMS ?Resource Integration Process ?Methodologies ?Tools ?Case Studies ?Zone 01 : 725 SOZ ?Zone 16/17 : 1000 NRP ?Conclusions

Oct 1, 2010

By J. Goyman, K. R. Rawling

"1.1 Location and Transportation ServicesNanisivik Mines Ltd. is located at latitude 73°, 3,200 km north of Montreal and 700 km north of the Arctic circle, on the south side of Strathcona Sound, which is an arm of Admiralty Inlet, in Northern Baffin Island. The orebody and mill site are 4 km distant from Strathcona Sound which provides deep water anchorage for ocean transportation of concentrate to Europe during the short northern shipping season from mid-July to mid-October.The operations and the resident community have direct jet aircraft service from Montreal two days per week, and local nights connect with other Arctic communities in the northern Baffin region. Bulk supplies and general cargo are delivered in the summer shipping season.1.2 HistoryThe Texas Gulf Sulphur Company, now Kidd Creek Mines Limited, staked claims in the Nanisivik area in 1957 and carried out exploration through to 1968. After the Kidd Creek orebody was found, Texas Gulf optioned the property in 1972 to Mineral Resources International Inc. (MRI), which undertook further exploration and completed a feasibility study.Nanisivik Mines Ltd. was formed in 1975, with MRI as the majority shareholder and minority shareholdings held by Metallgesellschaft, Billiton and Texas Gulf. Strathcona Mineral Services Limited was retained to manage the project during both the construction and operational phases."

Jan 1, 1984

By David Rahal, Des Erasmus, Ken Major

"Over the past twenty years there has been an increased emphasis on fine grinding in the minerals industry. This spurred the development of a range of new fine grinding equipment in the 1990s. At that time, the Knelson-Deswik mill was developed in South Africa for the pigments industry.Knelson Milling Solutions currently offers a wide range of laboratory, pilot and production scale mills. These mills bridge the gap between traditional low speed vertical mills and the high speed horizontal mills (tip speed < 3 and > 15 m/s respectively). They are designed to run at tip speeds between 10 and 12 m/s and are capable of operating with very dense grinding media. The result is a power intensity that is higher than the low speed mills and overlaps that of the high speed mills. This allows the mill to be customized for a wide range of grinding applications.A case study at Aquarius Platinum’s Kroondal Mine shows that the Knelson-Deswik technology can produce a consistent product size despite feed variations. It also shows that the throughput was proportional to the slurry density at Kroondal. The case study identified increasing the slurry density as a process change that can increase throughput and reduce the specific energy consumption.INTRODUCTIONThe increasing complexity and finer grain sizes of modern ore bodies have increased the importance of effective mineral liberation in obtaining acceptable grades and recoveries (Jankovic, Valery and La Rosa, 2003; Lichter and Davey, 2006; Napier-Munn, Morell, Morrison and Kojovic, 1996). This trend has increased the significance of fine grinding technology because the input energy increases exponentially as the required product size decreases from 100 to 10 microns (Gao and Weller, 1993a).The US Department of Energy recently provided the context for the potential energy savings in the US Mining Industry (BCS, 2007). They reported that grinding consumes approximately 494 TBtu/year. This was over double the consumption of the second highest equipment category, diesel materials handling systems (211 TBtu/yr). The proportion of grinding energy allocated to fine grinding can only be expected to increase as finer ore deposits are mined. It is therefore critical that fine grinding efficiency continue to improve through the selection of appropriate equipment and the development of best practices for existing applications."

Jan 1, 2011

By Y. Özçelik

Rocks show a variety of engineering and physical properties that affect typical quarry operation such as diamond wire cutting in the marble quarry. The physical and mechanical properties of rocks depend on their mineralogical and petrographical characteristics. The purpose of this study is to investigate the effects of mineralogical and petrographical properties of a rock, such as grain size and mineral content, and how these affect the wearing of diamond bead and cutting rate in a diamond wire cutting operation in a marble quarry. Statistical analysis is used to carry out the study. Three different rock types were examined, namely, hard rock (andesite) and softer rocks like limestone and marble. The study revealed that the mineralogical and petrographical properties of the rocks, such as percentage of quartz, biotite, plagioclase, matrix minerals, and opaque minerals, are important. In addition, the grain size of quartz and plagioclase in andesitic rocks and calcite grain size for carbonate rocks significantly influenced the wear rate and cutting rate in diamond wire cutting operations.

Jan 1, 2005

By Markus Timusk

This paper describes a research project that focuses on developing a diagnostic routine to assist in decision support for the condition based maintenance of mobile mining equipment subject to unsteady duty. The objective is to develop a general method for initial identification of mechanical faults in machinery operating under non-steady state conditions. The platform to be used for the experimental development and validation of the system is the swing machinery in an electric mining shovel operating in an open pit mining environment. The strategic approach that is proposed for the diagnostic routine will involve using novelty detection augmented by temporal classification.

May 1, 2004

By Jos. Kalbhenn

PART of the plan of re-allocation evolved by the engineers of the Dominion Steel and Coal Corporation in 1932 to retard the rapid advance of the submarine workings seawards was the opening of Dominion No. 20 Colliery, in the Harbour seam, by a pair of cross-measure tunnels from the workings of an older mine working the Phelan seam, which lies 430 feet below the Harbour seam. The tunnels, 8 ft. by 13 ft. in size, were started away from the old workings of Dominion No. 2 at a point 1.5 miles beyond the shore line and were driven on a rising grade of 1 per cent for a distance of 5,335 feet, tapping the Harbour seam at a point 2 ¼ miles off-shore. For transportation and ventilation, shafts and roadways already existing in the Phelan seam were made use of during the stages of development and up to the present time. One of the two tunnels served as a main haulage road and an intake airway, and the other as a return airway and travelling road. However, as the workings of this new colliery expanded, the need for additional airways arose as was anticipated when the plans for the development were formulated. To meet this need, work was started on October 1st, 1942, to establish a new opening between Nos. 2 and 20 Collieries in the form of a vertical shaft to provide a passageway for the ventilating air current of some 250,000 cubic feet per minute on its return to the upcast shafts in No. 2 Colliery, thus making both tunnels available for intake airways. In the interest of safety, speed, and economy, the shaft was raised from the Phelan to the Harbour seam. It is 20 ft. by 12 ft. in size and, with the exception of three timbered compartments across the narrow end, is untimbered. One of the three timbered compartments housed the ventilating tubing and pipe lines, the centre one served as a cage-way for hoisting men and material during the operation of raising, and the third one contained a ladder way. The rest of the shaft was filled with debris during the period of shaft raising.

Jan 1, 1944

By Graham Holmes, John Starkey

"The Kinross Kubaka Project is a gold mine located in the Russian Far East. The grinding circuit, comprised of a 6.1 m diameter x 2.74 m long SAG mill and a 4.1 m diameter x 5.5 m long secondary ball mill in closed circuit with cyclones, was built using SAG Power Index and Bond Ball Mill Work Index testing to determine the grinding energy requirements. Extremely cold climatic conditions and the need to keep heated space and capital costs to a minimum, dictated a grinding circuit with no in-circuit crusher and no conveyors external to the mill. High energy requirements for both the SAG mill and the ball mill were correctly predicted and have allowed grinding production tonnage forecasts to be met. Design test data and production results are given.INTRODUCTIONIn 1995 Davy International Canada, now Kvaerner Metals E & C, was commissioned as the Engineer and Project Manager for the Omolon Gold Mining Company, to design and construct a gold extraction plant for the Kubaka gold deposit, located in the Russian Far East. This deposit had been studied extensively in Russia during the exploration phase and a Feasibility Study was completed in 1993 by Kilborn who visited the site twice during that year to inspect facilities and to take metallurgical test samples. More samples were taken in 1995 to check ore hardness variability, as part of the final design program by Davy.The client’s objective in designing the Kubaka grinding circuit was to achieve design tonnage at all times, even when milling the hardest ore zones in the deposit. Since the samples taken in 1993 were taken as composite samples, it was necessary to take additional samples in 1995 to determine the extent of the variability. Six samples were sent to Canada for SAG Power Index (SPI) testing. Five of these were combined as a composite open pit sample, while the sixth sample was taken from the site adits as a composite sample to represent undergound ore. These two composite samples were tested to determine the MacPherson Autogenous Work Index for comparison with the SPI values."

Jan 1, 2001

By J. C. Loretto

"OPENING REMARKS Yesterday and today we have heard some very interesting papers on operating matters and some of you are probably wondering what we are now doing talking about Communications in Plant Design. Let me tell you! Before the techniques we have heard being discussed can be used, there has to be a properly operating plant. It is certainly a fact that many mineral processing plants achieve only limited success and a number of them can even be said to be failures. Some of you sitting here are probably living with operating problems that are clue to errors in the design.If the histories of these problem plants are examined, it will be found that in many cases, the necessary skills were available during the period of the plant design. There was extensive operating know¬ledge together with a full range of project expertise. Why then the failures? In a substantial number of cases it can be traced to the old, old problem of communications. As plants get bigger, money costs more and smooth startups become more important, it becomes less and less economic to fix up any design errors during plant operations.During our careers in mineral processing, nearly all of us will be involved in at least one plant design and I feel that it is as well if we understand some of these communication difficulties that can lead to a problem plant. There is little point in us being experts in mineral processing if the knowledge we have acquired doesn't somehow get incorporated into the plant.I would, therefore, like to present this short paper that mentions a few of the significant communication problems that can occur during the design of mining and mineral processing plants, together with some thoughts on answers to these problems."

Jan 1, 1973

By L. Connolly, F. R. De Luca

"Rubber liners at Denison Mines Limited are used in 10 1/2x 24' low discharg0 pebble mills. These were originally 10 1/2 x 13 Dominion overflow type ball mills. Experience here shows that the wear of rubber and ni-hard lifters is approximately the same in the feed end half of the mill, while the wear of rubber lifters is much greater in the discharge half. The wear of rubber plates is considerably less than white iron in the feed end half of the Mill and slightly more in the discharge end half of the Mill. Rubber components are lighter to handle but their installation is time consuming. This leads to the conclusion that a combination of ni-hard lifters a~~ rubber plates is the most economical compromise in Denison's case, for the Mill. Rubber discharge grates are superior to steel grates, while steel feed end liners are superior to rubber.The Use of Rubber Mill Liners at Denison Mines LimitedGrinding is done in two identic0al circuits each consist-ing of one 10 1/2 x 14' Dominion overflow rod mill, two Dorr Oliver quadraplex rake type classifiers, two 10 1/2 x 24' Dominion low discharge grate pebble mills and ancillary pumps and conveyors for pebbles. There is one centrally located distributor box that receives the discharge of the 4 pebble mills and splits it out to the classifiers."

Jan 1, 1974

By K. L. Murphy, G. Multamaki, P. M. Huck

"A preliminary evaluation, based on existing data, has been made of the implications of placing radium-barium sludge in tailings areas. The study was restricted to a consideration of possible increases in the quantities of radionuclides escaping to the environment through either groundwater or surf ace water, considering the types of tailings treated and the effluent treatment systems currently operating in Canada.IntroductionIn the recovery of uranium from ore deposits, the tailings produced by mine/mill complexes are conveyed to impoundment areas in slurry form. After settling, the supernatant is discharged to the environment together with runoff from precipitation on the tailings bas in. Currently, all operating uranium mines in Canada employ barium chloride treatment to control the release of dissolved radium to the aquatic environment. The dissolved radium in the tailings decant is precipitated with barium chloride, forming (Ra,Ba)SO4, and allowed to settle in ponds or lakes. In some instances, settling tanks have replaced ponds and flocculants have been added to aid settling. Because the Atomic Energy Control Board does not consider the precipitation ponds to be suitable for final disposal of these sludges, acceptable sites must be found. Options which have been suggested for sludge management include underground placement either in worked-out mine areas or in special chambers, or placement in the tailings areas. Conceptually, the latter alternative is attractive and probably would minimize sludge handling. This alternative would be subject to the AECB policy which requires that upon abandonment, radioactive releases from a tailings area must be within present regulatory limits and that treatment to meet these limits should not be required in perpetuity.No quantitative data exist concerning either the effect of physical and chemical conditions in the tailings on resolubilization of radium from precipitated sludges or the fraction of this additional radium which would be released."

Jan 1, 1982

By Paul J. Sylvester, Yeonuk Choi, Mike Nelson, Louis J. Cabri, Mike Tubrett

"The development and characterization of sulphide standards containing as many as seven precious metals has increased the efficiency and comprehensiveness of micro-analyses for deportment studies using laser ablation microprobe inductively coupled plasma mass spectrometry (LAM-ICPMS). Because trace precious metals occurring in solid solution or as sub-micron inclusions in sulphides, arsenides, and sulpharsenides are often heterogeneously distributed, a significantly large number of analyses are required. Using well-prepared samples it is possible for up to 120 analyses per day, far more than by other comparable methods. Examples will be discussed from projects focused on the deportment of Au and the platinum group elements (PGE).INTRODUCTIONBecause gold and the platinum-group elements (PGE) occur as both discrete minerals and in trace quantities in a variety of minerals (mostly sulphide, arsenide, and sulpharsenide minerals), specialized trace analytical methods were developed and applied to determine the deportment of precious metals in ore deposits, requiring sensitivities ranging originally from about hundreds to presently tens of ppb for individual precious metal or less.In mineralogical studies, micro-analytical techniques such as the electron microprobe were first applied to obtain analyses for major elements in about 1959-60, but as the instrumentation improved early attempts for PGE in potential carrier minerals indicated that reasonable levels of detection (LOD) were of the order of 300-400 ppm, depending on analytical conditions, X-ray spectral lines, and mineral matrix (e.g., Cabri and Laflamme, 1976). Eventually, the lowest detection levels by electron probe micro-analyses (EPMA) obtained for some PGE were of the order of 10s of ppm using high accelerating voltage and current for extended measuring time on peak and background (Gervilla, Cabri, Kojonen, Oberthür, Weiser, Johanson, Sie, Campbell, Teesdale and Laflamme, 2004)."

Jan 1, 2010

By M. Arvola, A. Mäkinen, N. Isomäki

Arsenic is a compound that has no significant market value. However, it needs to be removed from ores, concentrates and other process streams because of environmental or technical processing concerns. A wide range of arsenic containing minerals exists in nature, and in many instances these minerals are also associated with the ones that have commercial value. For example, sulfide copper ores are normally closely associated with minerals like enargite, Cu3AsS4 and tennantite Cu12As4S13. After mineral processing these arsenic sources can report to the waste waters and these effluents need to be treated before discharge or recycling. Ferric arsenate precipitation is a well-established method for stabilizing arsenic in effluents. Electrochemical arsenic removal utilizes the same adsorption/precipitation ideology as ferric arsenate precipitation. Electrochemical arsenic removal, even though it is a simple process in terms of equipment, is a complex system involving chemical and physical mechanisms taking place simultaneously to remove dissolved and/or solid arsenic components from wastewaters. The whole process can be described by the following three steps: 1) electrolytic oxidation at a sacrificial anode (dissolving electrode metal, iron for example), 2) chemical reaction between dissolved iron and arsenic to form a solid precipitate and 3) aggregation of the particles to form flocs, which can be removed by known solid/liquid separation methods. Electrochemical arsenic removal is a very efficient way to remove arsenic from different waters to very low residual concentrations.

Jan 1, 2016

By G. Couture

"The Glencore Raglan mine Concentrator, located in Quebec’s Nunavik region, has been in operation since 1997. The nickel metallurgical plant was originally designed to process 100 tonnes per hour of ore to produce 130 000 tonnes of nickel concentrate per year at 16% Ni. The increased grinding capacity and the discovery of rich ore bodies have increased the annual production to more than 190 000 tonnes of concentrate at 19% Ni. In 2014, the Metallurgical group, with support from BBA, implemented an expert control system on the flotation circuit. This project was initiated to cope with the high variability of the concentrator’s feed. Increasing the plant recovery and final concentrate grade were also important project objectives. The implementation of the expert system ensures better control of concentrate inventory while maintaining maximum plant throughput. This paper describes the successful implementation of the new control system, the control technology selection and the flotation circuit optimization. It will also discuss the performances obtained with this new approach and the improved process stability.IntroductionThe Raglan Mine is located in Northern Quebec along the 62th parallel. It has been in operation since 1997 and was originally designed to produce 130 000 tonnes of concentrate annually at 16% Ni. The increasing of the grinding capacity and the discovery of rich ore bodies have increased the annual production to more than 190 000 tonnes of concentrate between 18 and 20% Ni."

Jan 1, 2015