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By A. Kapoor

Gold mill effluents contain toxic pollutants such as cyanide (CN), thiocyanate (CNS), ammonia (NH4-N), and a variety of toxic metals. Various practical and economical technologies are in use for the removal of CN and toxic metals from gold mill effluents, however, the removal of CNS and NH4-N is challenging. The presence of CNS and NH4-N may make effluents toxic to aquatic life. The new Canadian Metal Mining Effluent Regulations will require mine effluents to be nontoxic. As a result, there is a need to develop practical and economical technology for CNS and NH4-N removal. The Mine Effluents Program in the Environment Group is presently evaluating biotechnology processes for the removal of CNS and NH4-N from gold mill effluents. The processes being evaluated are attached growth systems such as a Rotating Biological Contactor (RBC) and completely mixed suspended growth systems such as a Sequencing Batch Reactor (SBR) operating in a batch mode. The research to date at MMSL has shown that the RBC is very effective in removing CNS and NH4-N from simulated effluents. The NH4-N removal project showed that the RBC is capable of removing 0.8 g NH4-N/m2 of RBC disk area per day at an average temperature of 4.5 oC and hydraulic loading rate of 0.02 m3/m2/d. The RBC was also found to be very effective in removing CNS (feed = 200 mg/L and effluent < 1 mg/L) at 8 oC and a hydraulic loading rate of 0.02 m3/m2/d. The SBR was effective in removing CNS and NH4-N (generated from CNS degradation) at SBR operating conditions of two-12 h treatment cycles and a temperature of 12 oC. The end product of CNS and NH4-N oxidation was NO3-N, which is relatively non-toxic.

Nov 1, 2002

By J. Jara

Oxygen, ozone and air were evaluated in the oxidation of ferrous iron in the presence of hydrochloric acid ranging from 0.1 to 4 M HC1. Stoichiometric coefficients were determined through mass balances of gases and ferrous titration. The molar ratio ferrous to ozone increases from two at 0.1 M HC1 concentration to six at 4 M HC1. For oxygen the same ratio is constant and equal to 2 and it is in agreement with other works. The stoichiometric coefficient of hydrogen ion was not defined due to the effect of hydrolysis of ferrous and in particular ferric ion on measuring acid concentration by titration with sodium hydroxide. Agitation, gas flow and pressure contribute in the utilization of gas. A technique to compare the gas efficiency at several conditions is discussed and it is based on the relationship between oxygen and ferric during time. There is a strong compromise between gas efficiency and ferrous conversion. Oxygen efficiency decreased with time due to ferrous depletion. The gas efficiency ranged from 3 % (low level of agitation) producing 25 g Fe(III)/h to 12 % at 1000 rpm with 60 g Fe(III)/h converted. At 405 kPa absolute the oxygen efficiency was in the range of 80 % producing 300 g Fe(III)/h. The replacement of chlorine with oxygen to enrich molybdenite concentrates by reducing copper to less than 0.2 % was evaluated. Oxygen can be employed in batch or continuous operation and it can treat molybdenite concentrates with high variation of copper content. The dissolution rate is mainly controlled by oxygen addition in which utilization of oxygen plays an important role. Improvement on safety and environmental conditions is feasible by using oxygen instead of chlorine gas. The economics indicate good opportunities to implement oxygen without significant modifications to the actual circuit and enough benefit when oxygen is well used.

Jan 1, 2007

By O. Rabeau, M. Legault, F. Fallara

"Abstract - The development of robust 3-D geological models involves the integration of large amounts of public geological data, as well as additional accessible proprietary lithological, structural, geochemical, geophysical, and diamond drill hole data. 3-D models and maps have been available, particularly in the petroleum industry, for more than 10 years. Here, we demonstrate how robust 3-D maps can be used as interactive tools for mineral deposits exploration. In particular, we show how the interrogation of 3-D data sets can constrain exploration targets at depth. The main advantages of this technique for the mining industry are the homogeneity of data treatment and the validation of geological interpretations, taking into account geophysical and geochemical data. Data integration and cross-correlation of geology and geophysics can be achieved in two dimensions in any good GIS package. However, the added strength of 3-D analysis is the integration of separate data sets in three dimensions to build more complete, more realistic models, and in delineating areas of high economic potential at depth. Furthermore, these models can be modified and improved at any time by adding new data from ongoing drilling and geoscientific surveys. This paper presents two examples of 3-D models used for mineral exploration: the Joutel VMS mining camp and the Duparquet gold camp, Quebec. In both examples, the creation of the model is discussed and queries specific to the relevant exploration model are introduced. Eight potential exploration targets are generated at Joutel and seven at Duparquet. Although the targets defined are dependent on the details of the chosen queries, it is apparent that this technique has the potential to generate promising exploration activity that can engender new targets. Sommaire - Le développement de modèles 3-D géo-intégrés fiables implique l’intégration de grandes quantités de données géologiques publiques ainsi que des données lithologiques, structurales, géochimiques, géophysiques et de forages en provenance du secteur privé. L’industrie pétrolière dispose de modèles et de cartes 3-D depuis plus de 10 ans. Ce manuscrit présente un exemple d’utilisation de modèles et de cartes tridimensionnels détaillés comme outils interactifs dans l’exploration de dépôts métallifères. L’emphase est mise sur le processus d’interrogation des données en 3-D pour la définition de cibles d’exploration en profondeur. Les avantages principaux de cette technique sont l’uniformité du traitement des données et de la validation des interprétations géologiques, tout en tenant compte des données géophysiques et géochimiques. L’intégration de données et la corrélation de la géologie et de la géophysique peuvent être accomplies en deux dimensions dans n’importe quel logiciel SIG. La plus grande force de l’analyse 3-D demeure cependant la possibilité de construire des modèles complets et réalistes permettant de cibler des secteurs à haut potentiel économique en profondeur. De plus, ces modèles peuvent être modifiés et améliorés de manière interactive en ajoutant de nouvelles données provenant de forages et de levés géoscientifiques en cours. Ce manuscrit présente deux exemples de modèle 3-D géo-intégrés développés pour l’exploration minérale : le camp de SMV de Joutel et le camp aurifère de Duparquet, Québec. Dans les deux cas, la construction du modèle est décrite et les requêtes spécifiques à chaque type de gisement sont présentées. L’exercice a permis de définir huit cibles d’exploration potentielles à Joutel et sept à Duparquet. Bien que les cibles identifiées dépendent des contraintes utilisées pour les requêtes choisies, cette technique permet de générer de nouvelles cibles qui pourraient relancer l’activité d’exploration dans les camps miniers " matures " ou dans des secteurs moins explorés."

Jan 1, 2006

By Christopher Boys

"Abstract -Many water inflows in Saskatchewan potash mines are linked to salt anomalies. Potash ore and three anomalies in the PCS Cory potash mine in the Patience Lake Member of the Prairie Evaporite Formation were studied to understand the processes involved in their formation. Another goal was to find geological indicators of the proximity of anomalies. A geological model that relates the potash to the salt anomalies has been developed.Up to five post-burial facies may be recognized . These range from carbonate-mud collapse breccias to bedded sylvinite, and probably result from post-burial leaching. ln this model, the same fluids that caused widespread recrystallization and possibly enrichment of the potash salts, started by dis­ solving huge cavities in the evaporites . The effects of the leaching were highly variable, indicated by selectively preserved delicate laminae and chevron textures, to deformed and totally dissolved salt beds . ln at least two major events, Late Devonian and Cretaceous, collapse structures may have acted as conduits for overlying formation waters to cause pervasive leaching and recrystallization of the Prairie Evaporite Formation .Geological indicators of the proximity of an anomaly may include: a change in Insoluble seam color from greenish-gray to mottled brown and greenish-gray, unusual local increases in ore grade, large patches (e.g., >200 cm2) of sylvite-poor potash crosscutting units near the top of the ore zone, and drops in topography >10 m of the marker seams. Anhydrite was more common in an anomaly than in ore. The local abundance of anhydrite in ore may indicate the proximity of some salt anomalies.Once an anomaly has been encountered, indicators of a major collapse feature may include: stretched clay seams, folded beds, small collapse features (1 m to 20 m), numerous washouts, or split clay seams with injected salt. Any number, or none, of these indicators may be found close to a major collapse feature."

Jan 1, 1993

By Th. Hassel

The application of magnesium as an absorbable biomaterial demanded the consideration of the alloy composition, the mechanical properties and the corrosion a special adapted material development in terms of the human biological system. Magnesium for technical applications mostly comprised alloying elements up to 10 wt%. Thereby often metals (e.g. rare earth and aluminum) with high toxic potentials are used to optimize the mechanical properties. To minimize toxic reactions during the degradation of a absorbable magnesium alloy, the Mg-Ca system is being selected and investigated because both elements belong to the mineral nutrients. Rods and small tubes are produced by extrusion of gravity die casting billets (Ca-content 0.4 to 4.0wt%). The positive grain fining influence of calcium and its improvement of the corrosion behavior are additional advantages. The microstructure, the mechanical properties and the corrosion attitude are investigated. The results show that an optimal composition of micro alloyed Mg-Ca and ideally processing parameters lead to 16% strain and a tensile strength up to 185MPa. Electrochemical investigations and measurements of the hydrogen production demonstrate the influence of the Ca-content to the corrosion behavior of the investigated alloys.

Jan 1, 2006

By R. A. Payant, J. A. Finch

Under certain conditions of air and moisture, sulphide materials can spontaneously heat, or selfheat. The reaction mechanisms of self-heating are not well understood. Most previous work has involved pyrrhotite because it is the most reactive sulphide. The current work investigates the self-heating behavior of sulphide mixtures composed of sulphides other than pyrrhotite. The four studied sulphides were pyrite, chalcopyrite, sphalerite and galena. The rest-potential was measured for each. Binary mixtures formed as a 1 : 1 weight ratio were pyrite-galena, chalcopyrite-galena, pyrite-chalcopyrite and chalcopyrite-pyrite. The four sulphides and the binary mixtures were subjected to standard self-heating tests. The four individual sulphides did not self-heat. However, mixtures of pyrite-galena and chalcopyrite-galena with rest-potential difference (?E) >0.3 volts did self-heat while the mixtures of pyrite-chalcopyrite and chalcopyritesphalerite with rest-potential differences (?E) = 0.1 volts did not self-heat. The results demonstrate that when certain non self-heating sulphides are combined they can self-heat. A possible explanation based on galvanic interaction and formation of hydrogen sulphide as an intermediate product is discussed.

Jan 1, 2009

By K. Murase

Potentiostatic electrodeposition behavior of dendritic copper from acidic copper(I) chloride (cuprous chloride) baths containing sodium chloride and sodium bromide was investigated. The morphology, or appearance, of copper dendrite and the sodium content in the dendrite as an impurity were both influenced by deposition potential (0 to ?150 mV vs. SHE) and bath temperature (R.T. to 60 C), while the current efficiency for the deposition was 99% or more irrespective of the deposition conditions examined. The bath pH did not affect the deposition behavior in the pH range of 0 to 2. Bath temperature was found to be the most important factor influencing the deposition current. The current density of the dendrite deposition on a titanium cathode was lower than that onto a copper cathode with the same substrate surface area. The reproducibility of the current for the dendrite deposition was poorer when an as-polished titanium cathode was used, although it was improved by surface treatment of the cathode with an HF-HNO3-H3PO4 solution before electrodeposition. The deposition behaviors were discussed with the potential-pH diagram of the Cu-Cl-H2O system.

Jan 1, 2007

By M. Doucet

The introduction of high-nickel anodes to CCR in 2006 resulted in an increase of nickel in anodic slimes. Removal of the nickel in these slimes to below 3.0% is necessary in order to prevent slag viscosity problems in the subsequent pyrometallurgical step. A lower specification of 0.5% was chosen in order to minimize Ni losses to the slag and to recover this nickel as NiSO4. A 2-stage autoclave process, which was patented by CCR in 1992, was chosen to treat the high nickel slimes. Laboratory and plant?scale tests were performed in 2004 in order to validate the results of this process with the present slimes. These results along with corrosion tests were used to design two brick-lined autoclaves. These autoclaves were installed in October 2006 and successfully commissioned within 8 weeks. A "Design of Experiment" test program was performed in 2006 on an alternative autoclave process that reversed the cycles in the patented process. The effects of temperature and acid content were modeled using the results. The alternative process will be validated with the new autoclaves.

Jan 1, 2007

By R. G. K. Morrison

As mines grow deeper, the problem of ground control becomes one of increasing importance. The literature on the subject has grown extensively in the past few years, but is still far from conclusive. Detailed and precise observations are on record covering most phases of the problem, and control measures have progressed to the point where, in a large measure, they are effective. The success of methods to date must be attributed to the efforts which have been exerted to reduce convergence of stope walls and to the realization that a regular progression of stope faces approaching longwall has a beneficial effect. This paper attempts to explain the relationship between these two factors and the general problem of ground control. The problem at present lacks the co-ordination of the practical with the scientific outlook, but fortunately as time goes on there are indications that our scientific friends are becoming more interested and more familiar with the practical issues involved. Opinions vary widely regarding the mechanism of the problem and there are several schools of thought, two only of which will be discussed. One associates the incidence of rock-bursts with the stresses built up by a sagging hanging-wall, while the other takes the view that stresses primarily responsible for the sagging hanging-wall are also the cause of rock-bursts. The first group starts its reasoning from the convergence of the walls, probably the most conspicuous feature of deep mining, and works back to the conclusion that rock-bursts are in sorne way due to the breaking up of the sagging layers. The second group begins with the stress zone apparent around excavations at depth and follows mathematical conceptions based on certain assumptions which, in the absolute sense, are known to be inaccurate, but which are justified by the similarity between the conclusions reached and the results obtained in practice. This reasoning is followed to the point where rock-bursts result from the failure, under stress, of rock in situ, quite independent of wall convergence.

Jan 1, 1939

By Z. -G. Ren, J. -S. Qian, Y. -G. Yang

The waste slags from chemical and metallurgical plants contain approximately wt 1% water soluble Cr6+. This hexavalent chromium is very harmful to human health, and the treatment of the slags has concerned metallurgists for many years. A sintering method was developed to treat the waste slag. In this process, sinter was made from a mixture of the waste slag containing hexavalent chromium, iron concentrate and coke breezes. During sintering, hexavalent chromium was reduced to trivalent chromium. The latter is known as a non-harmful material and can be used as chromium resource for the production of ferrochromium or chromium-containing cast iron. After sintering the hexavalent chromium in the sinter could be reduced to less than 0.0008%. It was found that the waste slag with fine particles was favourable to the Cr6+ removal. An increase of carbon content in the sintering mixture could increase the rate of Cr6+ removal and the strength of the sinter produced. The rate of Cr6+ removal increased with increasing basicity of the sintering materials with basicity less than B=1.8, above which it decreased with increasing basicity. Blast furnace was found to operate smoothly when using the sinter made from the waste slag containing chromium. However the productivity of sintering machine was slightly low compared to the sintering operation using ordinary raw materials.

Jan 1, 2004

By M. J. MONEA

Canada's only economic high-swelling bentonite deposit is mined in Wilcox, Saskatchewan, by A vonlea Mineral Industries Limited. The bentonite resulted from devitrified and altered volcanic ash released during the Laramide Orogeny. Volcanic ash was deposited in a pre-Cretaceous basin that was formed by salt solution collapse structures. Sedimentary rocks in the Wilcox area belong to the Snakebite Member of the Upper Cretaceous Bearpaw Formation. Bentonite beds are 61 cm, 46 cm and 30 cm thick; these are separated by 365 cm and 182 cm of shale respectively. Saskatchewan bentonite is used primarily in the oil well industry.

Jan 1, 1984

By CIM Mineral Resource, Mineral Reserve Committee

These Leading Practice Guidelines for Mineral Processing (LPGMP) were prepared by the Sub-Committee on Leading Practice Guidelines for Mineral Processing. The Sub-Committee reports to the Executive Committee of the Canadian Mineral Processors (CMP) which is a Technical Society of the Canadian Institute of Mining, Metallurgy, and Petroleum (CIM) and incorporates those members of the CIM who are concerned with the processing of mineral deposits. The LPGMP covers the involvement of mineral processing professionals, referred to as Practitioners in this document, in providing inputs to the estimation of Mineral Resources and Mineral Reserves and providing technical content for internal reports as well as public reports on mineral projects as required under National Instrument 43-101 Standards of Disclosure for Mineral Projects (NI 43-101). The LPGMP supplement the CIM Exploration Practice Guidelines (2018) and the CIM Estimation of Mineral Resources and Mineral Reserves Practice Guidelines (2019) which are referenced in Companion Policy 43-101CP to NI 43-101 and recognized internationally. The LPGMP consist of 3 sections: • Principles of Process Support in Mineral Resources and Mineral Reserves Estimation; • Appendix A – Use of Supporting Studies in Process Evaluation and Assessment for NI 43-101 Documentation; • Appendix B – Glossary of Terms Relevant to the LPGMP. The LPGMP deal primarily with the description of leading practice as it applies to the mineral processing and extraction of base metals, precious metals, and other mineral products by the application of mineral processing technology. Other commodities may be considered with future updates of these guidelines. It is expected that this is a ‘living’ document and that these guidelines will develop in the future to address the requirements of the mining industry, investing public, and mining professionals involved. Clarifications and changes to these guidelines will be done under the guidance of the Executive Committee of the CMP.

Nov 25, 2022

By G. Wang, L. R. Moore, Y. Xiong, A. Gorken

"Mining is a very water intensive industry. As such, the industry has become dependent on applying alternate sources in efforts to minimize the impact on the locally available fresh water. Sources such as recycled water, sea water, and even acid mine drainage have been applied at some limited applications, while other mines may not even have the option of fresh water available in their region. However, the different sources of water will have varying concentrations and types of soluble salts and suspended solids, which can lead to dramatic differences in mineral processing when comparing these types of waters. Water quality is known to affect bubble generation and strength, mineral surface charge, and even reagent coordination properties. This paper focuses on the exploration of how water quality and soluble salts affect the flotation of iron and titanium containing minerals from feldspar, and the design of flotation collectors for optimal performance in this water.INTRODUCTIONFeldspar is defined as a tectosilicate mineral with the generic structure of MAlxSixO8, where M represents the cation (Celik, 2001). Feldspar is most often found naturally occurring with quartz, iron containing minerals (i.e mica), and titanium containing minerals (i.e. rutile). The alumina component of feldspar is of interest to glass making, while the alkali metal component is of interest to ceramics (Vidyadhar, 2002). In glass making, the alumina is known to improve product hardness, durability, and resistance to chemical corrosion. In ceramics, the alkalis act as a flux; a flux lowers the melting temperature of the mineral mixture, and assists in connecting the other components present in ceramics. Quartz is stated as having a negative effect on the melting point of the feldspar. Although quartz is typically not removed during the feldspar applications in the glass industry, it needs to be reduced for the ceramics industry. Iron and titanium based minerals are known to have negative effects on color and quality of the products in both glass and ceramics. Thus, these “contaminants” must be reduced to a certain product specification via feldspar beneficiation (Table 1)."

Jan 1, 2016

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By Ken G. Stowe, Stephen L. Chryssoulis, Joe Y. Kim

"Lead ions originating from galena during processing of complex sulphide ores migrate to ""cover"" the surface of sphalerite and iron sulphide mineral rarticles, and cause poor selectivity in differential flotation. Generally in sulphide ore processing, the lead activated minerals float in the Cu/Pb circuit. Subsequently, surface lead complicates the zinc flotation circuit by lowering the concentrate grade due to the co-flotation of lead- activated iron sulphide minerals. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zn and Pb-Zn ores is discussed. Plant and laboratory test data are interpreted by determining the surface composition of individual grains of sphalerite and iron sulphide rarticles using two surface analytical techniques, Laser Ionization Mass Spectrometer (LIMS) and Time of Flight-Secondary Ion Mass Spectrometer (TOF-SIMS). Cationic and anionic species on the surface were analyzed to elucidate the phenomena.IntroductionSurface properties play a critical role in many aspects of mineral processing such as flotation, flocculation, etc. An understanding of interaction mechanisms of different reagents (inorganic cations and anions, collectors, regulators, etc.) with mineral surface in an aqueous solution is a very important pre-requisite in achieving the desired selective flotation. In the flotation of complex sulphide ores, the flotation collectors respond to the activation of minerals such as sphalerite, pyrite etc. by heavy metal ions of Cu, Pb or Ag, which is a strictly surface phenomenon."

Jan 1, 1995

By I. S. Zajac, Y. O. Oyediran, M. C. Robart

This paper presents an overview of the metallurgical work on the Strange Lake Alkalic Complex (SLAC), from historical development of the "Main Zone" to present day develoment of the "B Zone". The SLAC, originally discovered by the Iron Ore Company of Canada (IOC) in the northeastern Canadian Shield of Québec and Labrador, is one of the world’s largest deposits of rare earth elements (REE) including yttrium and high field strength elements (HFSE) including zirconium, niobium, and titanium. It is part of a Precambrian, post-tectonic complex of peralkaline granites which intruded along the contact between gneisses and monzonites of the Churchill Province of the Canadian Shield. Mineralization of interest at Strange Lake principally occurs within peralkaline granite-hosted pegmatite and aplite sheets and, to a lesser degree, within the host granites, particularly in intra-pegmatitic granites. The highest grade and metallurgically most favorable mineralization is in the upper, open pit mineable parts of the SLAC. Metallurgical development has been conducted under a number of mining companies, and various value metals have been targeted throughout the history of the deposit, including yttrium, zirconium, niobium, and rare earths. Historic processing routes tested have included ore beneficiation, atmospheric leaching, solvent extraction (SX), and metal precipitation. This paper also presents the metallurgical development supporting Quest Rare Minerals Ltd.’s (Quest) 2013 Pre-Feasibility Study (PFS) and 2014 Preliminary Economic Assessment (PEA).

Jan 1, 2014

By T. Patching

"COAL MINING at Canmore, Alberta, began in 1886 and continued there until July 1979. A comprehensive review of the Canmore operations is not available, but the following notes have been prepared to accompany references where more complete information about the operations and problems encountered may be found. The coal measures at Canmore occur in the Kootenay formation of Lower Cretaceous age, and at least twelve seams of varying thickness and horizontal extent have been recognized. The coal, of high quality, ranges from semi-anthracite in the lower seams to low-volatile bituminous in the upper seams. The strata of the Canmore area form an asymmetric syncline, the western limb being overturned to vertical by the Palaeozoic strata of the Mount Rundle Range. The eastern limb is more gently sloping, its dip ranging from IO to about 40 degrees. Tectonic movements have created a troubled and complex coal field. The seams were initially not regularly or uniformly deposited, and mountain-building activity folded and faulted the strata and in many places sheared and crushed the original structures of the coal(l,2,3,4,5). The lack of continuity of the seams, and changes in thickness and inclination, made longrange mine planning difficult and necessitated flexible methods of work, and the local disturbances sometimes created problems in roof support and contributed to the occurrence of sudden outbursts of coal and gas. Almost all of the coal was produced from underground operations but a few relatively small V-cut mines were worked along surface outcrops. These have all been filled in and revegetated. The basic method of underground work was by room-and-pillar, but many variations in layout and sequences were employed. Gangways were driven along the strike and pillars were formed by raises or slopes and crosscuts. Pillars were recovered to the extent that ground conditions permitted by splitting or taking 'skips' from the sides of the raises or splits or crosscuts. Because of the variety of conditions that existed in the field a considerable range of cutting, loading and support methods were employed, including hand-loading, slushers and scrapers, duckbills and shaker conveyors, mobile loaders and continuous miners. Except for the coal obtained by continuous miners most of the coal was broken out by blasting when driving narrow working places or by air picks when cutting from a face. In the early years hand loading onto cars or conveyors predominated. A continuous miner was introduced into Canmore in 1959 on a trial basis, and another was subsequently acquired, in order to minimize blasting and hand loading, but problems in operating these machines in inclining seams and difficulties in providing safe roof support for the machines and workers restricted their efficient use. Another major difficulty with the use of continuous miners was the problem of ventilating development headings in the very gassy conditions. In the early 1970s they were replaced by electric and compressed air slushers and scrapers, resulting in a general increase in productivity, roof control, safety, and flexibility of operations(1.6,7,8.9)."

Jan 1, 1985

By Karl J. C. Harries

"8.1. INTRODUCTIONThe purpose of this chapter is not to provide precedents or examples of provisions, but rather to offer some comments that may be worth considering in the negotiation or review of an agreement. These comments are not intended to be exhaustive. It must also be noted that, although the chapter is written in the context of a common law joint venture, the concepts and concerns for the most part apply equally to a corporation that is owned by only a few shareholders for the purpose of participating in the project held by the corporation.The corporation has the advantage of having much of its organization established by local corporate law, but the particular wishes of the shareholders will appear in a shareholders’ agreement. The principal differences will be surprisingly small, save for the acquisition provisions that appear in a farm-in agreement1 and the substantial portion of the joint venture agreement devoted to creating and organizing the joint venture entity. Where the joint venture agreement refers to venturers and committees, the shareholders’ agreement will refer to shareholders and the board of directors, but both will have to deal with such basic matters as decision-making, default, dispute resolution, first refusals, funding, and carrying out work on the project. For convenience, this chapter usually refers to “venturers”, which may be taken to include shareholders.Negotiations give rise to many varying circumstances and concerns, and the main asset of the negotiator is an open and flexible mind. A desired result can often be accomplished indirectly in circumstances where the other side has adopted an inflexible position on a suggested approach. As precedents and standard forms tend to focus a negotiator’s thinking, they can be counterproductive. It is after the deal has been agreed to that a precedent can be of great assistance to the draftsman.The concepts are arranged in alphabetical order for convenience, not to suggest their sequence or position in an agreement or their relative importance. An agreement should adopt a progression of subjects in what the parties consider a logical sequence to read and work with. However, experience has indicated that it is best to set out in a single article the substance of the deal (i.e. the terms relating to the farm-in and what the acquiring party has to do to acquire his interest), preferably near the beginning of an agreement. The acquisition of the interest is, after all, the first order of business. The joint venture provisions will then follow in a reasonable sequence. It is also worthwhile to devote a single article to any special provisions that may apply during the earn-in period. For example, it may be provided that, although all work is to be done by the acquiring party as operator (with the duty of care, liability, and reporting requirements as set out in the joint venture sections of the agreement), but during the acquisition period, the acquiring party, acting as operator, may be at liberty to do such work as he wishes, without the need for any committee or other approvals, and committee meetings may be suspended.2An agreement is divided into paragraphs and articles to make it easier for the parties to read and understand, and to assist a party in finding “that provision” when the need arises. A comprehensive table of contents will also assist the parties who must work under an agreement. An added benefit of a table of contents is that in preparing it, the draftsman sees the overall structure of the agreement and will often catch and correct flaws."

Jan 1, 2003

By Y. Vermeulen, J. Simoes, P. Guillo, A. Di Donate

New design techniques have been developed to optimize continuous casting (CC) refractory components. The overall objective is to increase CC productivity as well as steel quality by using optimized refractory from tundish-to-mold. These techniques allow the prediction of steel and refractory chemical interactions and, thus, steel chemistry evolution as well as build up and corrosion occurrence. Specific fluido-dynamic models (CFD) have also been developed to better take into account the physical parameters at the steel/refractory interface and to optimize steel flow control. The CFD model can be coupled with refractory chemical interactions to simulate steel chemical evolution. These two different approaches result in shape and material modifications. They are completed by dedicated thermal stress analysis in order to improve thermal shock resistance. The mechanical FEA evaluations take into account specific mechanical behavior of refractory components as well as high temperature evolution of their properties.

Jan 1, 2004

By P. V. Barr, Y. -H. Li, A. P. Watkinson

Subsequent to a campaign of pilot-kiln trials of firing bio-oil and natural gas, scale-up to commercial lime kilns was made using an in-house mathematical kiln model. Both dry limestone and lime mud kilns of 3.5 m OD. by 100 m length were used for bio¬oil firing simulations. Comparisons were made against natural gas firing on the basis of specific firing rate, off-gas volume, energy consumption and overall lime quality. Model simulation results indicate that conversion from natural gas to bio-oil with no productivity loss will increase energy comsumption by about 7.5% and total off-gas volume by about 8%. Alternatively, a 6% decrease in productivity would be expected if off-gas volume is maintained constant. The calculations are sensitive to deviations in the lower heating value (LHV) used in the simulations. A 5% increase in the LHV of the bio-oil, which could result from a 3% decrease in the moisture content, reduces the energy penalty to 2% coupled with a slight reduction in off-gas volume.

Jan 1, 2004